• Corrosion Science and Technology
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• v.18 no.4
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• pp.138-147
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• 2019

Pipes and components of the secondary system in the pressurized water reactor (PWR) are mainly comprised of manufactured carbon steel. Thus, the generated carbon steel corrosion products are transported into the steam generator and deposited, thereby deteriorating the integrity of the steam generator. Environmental condition in the secondary system of the PWRs differs across different locations. So, the corrosion rate and types of corrosion products depend on specific locations in the secondary system. In this study, the quantity and chemical compositions of corrosion products generated in various locations that vary in different temperatures and chemistry conditions were investigated. As a result of evaluating the PWR "Unit A" that is in current operation, the amount of corrosion products generated in the section of high temperature feedwater system was identified as the largest source in the secondary system. Major components of corrosion products were iron oxides such as magnetite, hematite, and lepidocrocite.

• Journal of the Society of Naval Architects of Korea
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• v.61 no.2
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• pp.135-142
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• 2024

There is a lot of concern around the world about air pollution from ships. The majority of air pollution from ships comes from fuel combustion. The combustion process produces various air pollutants such as carbon monoxide (CO), carbon dioxide (CO₂), nitrogen oxides (NOx), sulfur oxides (SOx), and particulate matter (PM), each of which has adverse effects on people and is a major environmental problem. To prevent this, the International Maritime Organization (IMO) has strengthened the regulation of pollutant emissions through the Convention for the Prevention of Marine Pollution. This paper discusses the types of air pollutants emitted by ships, their current status, and the latest technologies to reduce emissions of NOx and SOx.

• The Journal of the Petrological Society of Korea
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• v.28 no.4
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• pp.299-306
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• 2019

We estimated the provenance of the obsidian artifacts from Samgeori site at Yeoncheon, one of the prehistoric sites in South Korea. Pyroxene microlites are of hedenbergite to augite compositions, and intergrown and/or overgrown with Fe-oxides showing poikilitic texture. Major oxides contents for the matrix of the obsidian artifacts exhibit a narrow compositional range, especially SiO₂ contents being 73.0~75.5 wt.% of acidic rhyolitic composition. Also, rare earth element (REE) contents are relatively constant in the obsidian artifacts, and the chondrite-normalized REE patterns show a strong Eu negative anomaly. These mineralogical and geochemical features of the Samgeori obsidian artifacts were compared with those from both the Baekdusan obsidians and Japanese Kyushu obsidians which have been thought to be two major obsidian provenances around South Korea. It is suggested that the Samgeori obsidian artifacts were possibly originated from the Baekdusan obsidians.

• Transactions of the Korean Society of Mechanical Engineers
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• v.12 no.6
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• pp.1290-1295
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• 1988

Theoretical considerations in the development of new cutting tool materials for high speed machining is presented. The progressive wear of cutting tools is assumed to consist of the abrasive and solution components as major modes. Theoretical calculations of relative wear rates between various tool materials based on the two modes are possible using their hardness and solubility data. Assuming cementite as the major hard particles in machining steels, relative wear rates of possible tool materials were calculated. The results indicate that $Al_{2}$O$_{3}$ in oxides, HfN in nitrides and HfC in carbides are the optimal tool materials from the view point of mechanical and thermochemical wear resistance. And several methods for improving the fracture toughness of the above tool materials are suggested.

• Advances in nano research
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• v.2 no.2
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• pp.77-88
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• 2014

Solvothermal treatment of late transition metal acetylacetonates in a novel medium composed either of pure acetophenone or acetophenone mixtures with amino alcohols offers a general approach to uniform hydrophilic metal nanoparticles with high crystallinity and low degree of aggregation. Both pure metal and mixed-metal particles can be accesses by this approach. The produced materials have been characterized by SEM-EDS, TEM, FTIR in the solid state and by Nanoparticle Tracking Analysis in solutions. The chemical mechanisms of the reactions producing nanoparticles has been followed by NMR. Carrying out the process in pure acetophenone produces palladium metal, copper metal with minor impurity of $Cu_2O$, and NiO. The synthesis starting from the mixtures of Pd and Ni acetylacetonates with up to 20 mol% of Pd, renders in minor yield the palladium-based metal alloy along with nickel oxide as the major phase. Even the synthesis starting from a mixed solution of $Cu(acac)_2$ and $Ni(acac)_2$ produces oxides as major products. The situation is improved when aminoalcohols such as 2-aminoethanol or 2-dimethylamino propanol are added to the synthesis medium. The particles in this case contain metallic elements and pairs of individual metals (not metal alloys) when produced from mixed precursor solutions in this case.

• Journal of the Korean Chemical Society
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• v.27 no.1
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• pp.38-45
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• 1983

Aziridine derivatives were utilized for the formation of aziridine N-oxides at low temperature, which were subject to easy decomposition and/or rearrangement like the protonated aziridines at room temperature. t-Butyl nitroso compound formed by the decomposition of N-oxide is easily characterized by its blue color and it is the major product in case that no branched alkyl groups are substituted on the carbon atoms of the aziridine ring and the stationary groups on the nitrogen are inert to rearrange the oxide such as the t-butyl group. The oxidative rearrangement products, however, are mainly formed when the substituents are methyl or ethyl group on the carbon atoms. It is interesting to see that the sigmatropic rearrangement of 2-ethyl aziridine gave only cis olefinic compound selectively in case that t-butyl group was substituted on the nitrogen, whereas N-hydroxy aziridine compounds were formed exclusively when t-butyl group was replaced with ethyl group.

• Journal of the Korean Institute of Gas
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• v.23 no.6
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• pp.8-16
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• 2019

One of the methods for low-pollution combustion, flue gas recirculation(FGR) is effective to reduce nitrogen oxides and it was applied in CH₄/air premixed counterflow flames to identify the change of flame characteristics and NOx mechanisms. Considering that the mole fraction of the products varied depending on the strain rates, the major products: CO₂, H₂O, O₂ and N₂ were recirculated as a diluent to reflect the actual combustion system. With the application of the FGR technique, a turning point of maximum flame temperature under certain strain rate condition was found. Furthermore as the recirculation ratio increased, the tendency of NO was changed before and after the turning point and the analysis on thermal NO and Fenimore NO production was conducted.

• Economic and Environmental Geology
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• v.13 no.4
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• pp.215-227
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• 1980

The rock units of Goesan area in the Ogcheon metamor phic terrain established on the basis of field criteria should be redefined into following sequence. Based on shear senses in secondary small structures which are usually observable in the investigated area, the stratigraphy can be lithologically divided into the lower pelite, pebbly mudstone, upper pelite, quartzite and psammite unit in ascending order. This conclusion is in discordance with a previous opinion; Munjuri formation and Guryongsan formation may be equivalent to upper pelite unit, Iwonri formation and Hwanggangri formation to pebbly mudstone. From this, it may be inferred that isoclinal overturned folds repeatly occur in the area. The uranium bearing coaly thin layers in upper pelite unit have relatively broad exposures in Deogpyeongri block of Goesan area along culmination zone in the central part of the investigated area. It is believed that structural feature in the block recognized complexly refolded synform plunging to southwest. Mineralogical and radiometric studies were made on 135 representative samples from the Ogcheon Group of Korea. The mineralogy of all black slate samples is qualitatively similar but quantitatively ·different. The uranium distribution in the studied area show approximately log normal. Uranium in the black slates of the Ogcheon Group was deposited together under same physico-chemical environmental conditions. The chemical and geological factors that controlled the abundance of organic carbon and iron oxides also controlled the uranium content. The relationship of the major components to uranium can be expressed by the following regression equation: $Log(U\times10^4+1)$= 1.70999-0.00367(quartz)0.00512(micas)-0.00930 (other silicates)+0.01911 (iron oxides)-0.03389(other opaques)+0.02062(organic carbon).

• Journal of the Korean Ceramic Society
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• v.40 no.1
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• pp.11-17
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• 2003

The effect of$ZrO_2$addition on the microstructure and electrical properties of Ni-Mn oxide NTC thermistors was studied. Major phases present in the sintered bodies of $Ni_{1.0}Mn_{2-x}Zr_xO_4$ were the solid solutions of Ni-Mn-Zr oxides with a cubic spinel structure and the $ZrO_2$ with a tetragonal structure. The $ZrO_2$ was formed by the partial decomposition or incomplete formation of the Ni-Mn-Zr oxides during sintering. With increasing the amount of added $ZrO_2$, the $ZrO_2$ phase increased. The relationship between log resistivity (log p) and the reciprocal of absolute temperature (1/T) of the NTC thermistors prepared was linear, indicative of NTC characteristics. The resistivity, B constant and activation energy of the thermistors increased with increasing $ZrO_2$ content.

• Economic and Environmental Geology
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• v.28 no.5
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• pp.455-467
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• 1995

In order to investigate the dispersion patterns and speciations of Cu, Pb, Zn and Cd in soils, stream sediments and stream waters, geochemical studies of soil, stream sediment and stream water samples collected in the vicinity of the Shi-Heung Cu-Pb-Zn mine was carried out Cation exchange capacity measurement, size analysis, X-ray diffraction analysis and batch test were performed to select applicable soil for adsorption treatment The average content of Cu, Pb, Zn and Cd in soils collected from tailings and ore dressing plant is 1084 ppm, 2292 ppm, 3512 ppm and 29.2 ppm, respectively, and therefore, tailings and ore dressing plant site may be the major contamination sources in this study area. The mean content of Cu, Pb, Zn and Cd in stream sediments is extremely high up to 794 ppm, 1633 ppm, 2946 ppm and 25.2 ppm, respectively. Tailing particles and heavy metal ions are dispersed along the tributary system. Results from the sequential extraction analysis indicate; (1) most of Cu is bound to organic matters and sulphides, (2) fraction of Pb is mainly bound to Fe and Mn oxides. Most of Zn is largely bound to Fe and Mn oxides and residual fraction. Ion exchangeable fraction of Cd is relatively higher than those of Cu, Pb and Zn. Batch test on soils collected from the kaolinite and/or pyrophyllite mines and from the control areas was carried out to select an applicable soil samples for adsorption treatment The sample, S10, collected from the control area 2 (clay content 33.2%) shows the highest $K_d$ (distribution coefficient). Organic content in soils and several clay minerals shows relatively good correlation with $K_d$. It means that applicable soils for adsorption treatment of heavy metals show high organic and clay content.