• 한국초전도ㆍ저온공학회논문지
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• 제25권3호
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• pp.28-33
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• 2023

Magnetic relaxation properties of pure MgB₂ powder samples and diluted water-treated MgB₂ powder samples were investigated. The magnetic field H-dependence, m(H), and the time t-dependence, m(t), of the magnetic moment m were measured and analyzed using the PPMS-VSM magnetometer equipment, respectively. The m(t) reduction rates of pure MgB₂ powder samples and diluted water-treated MgB₂ powder samples decreased to about 0.7 ~ 1.8% and 0.6 ~ 1.0% for about 7200 s, respectively, at temperature T = 15 K. The magnetic relaxation properties of the two types of MgB₂ powders were analyzed by calculating the magnetic relaxation rate S = -dln(M_irr)/dln(t) values according to Anderson-Kim theory. The magnetic relaxation ratio S values of the two types of MgB₂ powder samples were almost similar. As a result of the quantum creep effect, the constant magnetic relaxation rate S characteristic was confirmed at a temperature range of T = 10 K or less.

• 한국자기공명학회논문지
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• 제11권1호
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• pp.1-9
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• 2007

An unequal site exchanging system induced by restricted rotation of 9-methyl group in 1,8-dichloro-9-triptycene has been studied by spin-lattice relaxation and 2D-EXSY experiments. The exchange rate obtained from relaxation studies is very well coincident to the result of line shape analysis, and the difference of the relaxation times ($T_1$) in two different sites has an important role to analyze 2D-EXSY experimental data.

• 한국자기공명학회논문지
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• 제2권1호
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• pp.66-83
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• 1998

Study on spin-rotation relaxation of nuclear spins located on a methyl group can reveal valuable dynamic information related to the internal rotation of methyl group itself. Toward this end we have measured methyl carbon-13 spin-rotation of methyl group itself. Toward this end we have measured methyl carbon-13 spin-rotational relaxation rate in toluene and 2-chloro-p-xylene over the temperature range of 179-363K. To interpret the temperature dependence of measured spin-rotational relaxation rate we have revised the temperature dependence of measured spin-rotational relaxation rate we have revised the expression derived thus far by other authors and reproduced experimental data on the basis of the newly derived expression. The results confirmed that our expression leads to better agreement with experimental data than the previous one over observed temperature range, especially at high temperature.

• 한국초전도학회:학술대회논문집
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• 한국초전도학회 2000년도 High Temperature Superconductivity Vol.X
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• pp.103-106
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• 2000

We have studied the magnetic properties in Bi$_2$Sr$_2$CaCu$_2$O$_8$ single crystal with columnar defects using micro Hall-probe array. We found that fold profiles inside sample were similar to the Bean's critical state model from the magnetic hysteresis measurement. In the magnetic relaxation measurement, the normalized relaxation rates were maximum near the center and decreased toward the edge of the sample expect zero gauss. The relaxation rates as a function of the temperature were maximum near the 40K and rapidly decreased both sides of the peak.

• Journal of Magnetics
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• 제1권1호
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• pp.1-3
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• 1996

The $YBa_2Cu_3O_{7-x}$ structure has been fluorinated by a gas phase exchange technique. The ${^19}F$NMR (nuclear magnetic resonance) spin-lattice relaxation rate (1/T1) measurements on a fluorinated sample gave superconducting energy gap of $2\Delta=4.6kT_c$.

• Journal of Magnetics
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• 제10권2호
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• pp.63-65
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• 2005

The $^1H$ NMR spin-lattice relaxation in a series of the organic-inorganic hybrid systems $(C_nH_{2n+1}NH_3)_2SnCl_6$ (n = 8, 10, 12, 14) undergoing two successive phase transitions was studied. A discontinuity characteristic of a first order phase transition was observed at the high-temperature conformational transition. Besides, the spin-lattice relaxation rate below the conformational transition temperature was well fitted by four types of molecular motions, from which the chain-length dependence of the activation energies of the molecular groups was obtained.

• 한국자기공명학회논문지
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• 제2권1호
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• pp.1-23
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• 1998

The motions of carbon-chain backbone in n-undecance and n-dodecane dissolved in CDCl3 are investigated by 13C NMR relaxation study. For this purpose a model of C - C backbone motions for these molecules is introduced that takes into account the cooperativities between rotations about two $\beta$-coupled C - C bonds. In this model it is assumed that the major conformational interconversions occurring in the inner part of the chain involve the type II jumps only, although at terminal part of the chain both type II and type III motions are assumed to take place. Information of the rate constants of these conformational transitions could be extracted by comparing the T1's calculated on the basis of the assumed model with those observed over the temperature range of 248 - 308 K. The calculations were performed according to the method proposed by Wittebort and Szabo. The activation energies, ranging from ca 12 to 20 kJ/mol, could be obtained from the Arrhenius plots of these calculated rate constants.

• 한국자기공명학회논문지
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• 제22권4호
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• pp.107-114
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• 2018

In this exploration, the nuclear magnetic resonance of the $^{207}Pb$ nucleus in $PbWO_4:Mn^{2+}$ and $PbWO_4:Dy^{3+}$ Single Crystals using FT-NMR spectrometer is investigated. The line width of the resonance line for the $^{207}Pb$ nucleus decreases as temperature increases due to motional narrowing. The chemical shift of $^{207}Pb$ NMR spectra also increases as temperature decreases for both crystals. The spinlattice relaxation times $T_1$ of $^{39}K$ nucleus were calculated as a function of temperature (180 K~400 K). The $T_1$ of $^{207}Pb$ nucleus decreases as temperature increases. The dominant relaxation mechanism at the studied temperature range can be deduced as the Raman process, which is the coupling between lattice vibrations and the nuclear spins. This deduction is substantiated by the fact that the nuclear spin-lattice relaxation rate $1/T_1$ of the $^{207}Pb$ nucleus in $PbWO_4:Mn^{2+}$ and $PbWO_4:Dy^{3+}$ single crystal is proportional to $T^2$, or temperature squared. The activation energies for the $^{207}Pb$ nucleus in $PbWO_4:Mn^{2+}$ and $PbWO_4:Dy^{3+}$ single crystals are $E_a=49{\pm}1meV$ and $E_a=47{\pm}2meV$, respectively.

• Progress in Superconductivity
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• 제3권1호
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• pp.36-40
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• 2001

We have studied vortex dynamics in$ Bi_2$$Sr_2$$CaCu_2$O$_{8}$single crystals of unirradiated and irradiated samples by using 100 $\times$ $100\mu\textrm{m}^2$Hall sensor. Doses equivalent magnetic fields are 20 G, 100 G and 1 kG. In the magnetization measurement, a second magnetization peak (SMP) was observed in unirradiated, 20 G dose and 100 G dose samples in contrast to 1 kG dose sample. In the unirradiated sample, the SMP was observed in the range of 18 K ~ 35 K and the amplitude of the SMP decreased with increasing temperature. With increase of the irradiation dose, temperature region and sharpness of the SMP were reduced. In the magnetic relaxation measurement, we observed that the normalized relaxation rate S decreased with increasing the irradiation dose. Our results suggest that the vortex dynamics is not greatly affected by low-density columnar defects.s.

• 지구물리와물리탐사
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• 제16권2호
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• pp.97-105
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• 2013

자기공명검층은 수소와 자기장의 상호작용을 측정, 분석하는 물리검층 방법으로 이는 저류층 평가를 위한 중요한 물리검층 방법 중 하나이다. 측정된 감쇠 신호 즉, 이완은 측정지역 내 수소의 밀도에 대한 정보와 유체의 종류에 따른 감쇠속도에 대한 정보를 포함하고 있으며, 이를 바탕으로 공극률, 투과도와 습윤도 등을 예측할 수 있다. 1950년대 초반 랜덤워크로 자기공명의 이완감쇠를 시뮬레이션한 것을 시작으로 자기공명반응에 대한 연구가 급격히 발전되었다. 이 논문에서는 자기공명 시뮬레이션의 연구 동향을 먼저 살펴 보고, 자기공명반응인 이완을 발생시키는 이완메커니즘에 대해 간단히 알아본다. 이에 기초하여 자기공명검층에서 주로 측정하는 횡축이완곡선을 자기장구배를 고려하는 경우와 고려하지 않는 시뮬레이션 방법에 대해 비교분석하고 자기장구배가 이완메커니즘 및 횡축이완곡선에 미치는 영향에 대해 분석한다.