• Title/Summary/Keyword: magnetic particle

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Dispersion Characteristics of Magnetic Particle/Graphene Hybrid Based on Dispersant and Electromagnetic Interference Shielding Characteristics of Composites (분산제에 따른 자성금속 무전해도금 기반 그래핀 분산 특성 및 복합재의 전자파 차폐 특성 연구)

  • Lee, Kyunbae;Lee, Junsik;Jung, Byung Mun;Lee, Sang Bok;Kim, Taehoon
    • Composites Research
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    • v.31 no.3
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    • pp.111-116
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    • 2018
  • In this paper, magnetic FeCoNi particles have been grown through electroless plating on the surface of graphene, and then this hybrid material has been dispersed by various surfactants to prepare films. The pyridine surfactant shows the highest dispersability and low surface resistance value (351 Ohm/sq) and the electromagnetic shielding ability at the frequency of 10 GHz. Specially, the evaporation of the pyridine during the drying process could be able to form the internal conductive network and high dispersion of FeCoNi on the surface of graphene.

Preparation and Characterization of La0.8Ca0.2MnO3 (La0.8Ca0.2MnO3의 합성 및 특성연구)

  • 정미원;이지윤;김현정
    • Journal of the Korean Ceramic Society
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    • v.40 no.5
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    • pp.434-440
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    • 2003
  • The powders of L $a_{0.8}$C $a_{0.2}$Mn $O_3$ Colossal Magnetoresistance (CMR) materials were synthesized by sol-gel process. Lanthanum(H), Calcium(II) and Manganese(III) 2,4-Pentanedionate were dissolved in a mixed binary solution consisted of propionic acid and methanol with PEG (15 wt%) aqueous solution. The progress of reactions was monitored by FT-IR spectroscopy. The Lao scao.2Mn03 gel powders were annealed at various temperatures. The structural changes were investigated by FT-IR, CP/MAS $^{ 13}$C solid state NMR spectroscopy and XRD. The thermochemical property, particle characterization, microstructure of sintered sample, and cation composition of gel powder were studied by TG/DTA, FE-SEM and ICP-AES. The magnetic characterizations were identified through measurement of magnetic moment by VSM.

Sources of the High-Latitude Thermospheric Neutral Mass Density Variations

  • Kwak, Young-Sil;Richmond, Arthur;Deng, Yue;Ahn, Byung-Ho;Cho, Kyung-Suk
    • Journal of Astronomy and Space Sciences
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    • v.27 no.4
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    • pp.329-335
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    • 2010
  • We investigate the sources of the variation of the high-latitude thermospheric neutral mass density depending on the interplanetary magnetic field (IMF) conditions. For this purpose, we have carried out the National Center for Atmospheric Research Thermosphere-Ionosphere Electrodynamics General Circulation Model (NCAR-TIEGCM) simulations for various IMF conditions under summer condition in the southern hemisphere. The NCAR-TIEGCM is combined with a new empirical model that provides a forcing to the thermosphere in high latitudes. The difference of the high-latitude thermospheric neutral mass density (subtraction of the values for zero IMF condition from the values for non-zero IMF conditions) shows a dependence on the IMF condition: For negative $B_y$ condition, there are significantly enhanced difference densities in the dusk sector and around midnight. Under the positive-$B_y$ condition, there is a decrease in the early morning hours including the dawn side poleward of $-70^{\circ}$. For negative $B_z$, the difference of the thermospheric densities shows a strong enhancement in the cusp region and around midnight, but decreases in the dawn sector. In the dusk sector, those values are relatively larger than those in the dawn sector. The density difference under positive-$B_z$ condition shows decreases generally. The density difference is more significant under negative-$B_z$ condition than under positive-$B_z$ condition. The dependence of the density difference on the IMF conditions in high latitudes, especially, in the dawn and dusk sectors can be explained by the effect of thermospheric winds that are associated with the ionospheric convection and vary following the direction of the IMF. In auroral and cusp regions, heating of thermosphere by ionospheric currents and/or auroral particle precipitation can be also the source of the dependence of the density difference on the IMF conditions.

Studies on the Synthesis and Magnetic Properties of Cobalt Nanoparticles in the Polymer Film (코발트 나노 입자가 도입된 초상자성 고분자 박막의 제조 및 자성 연구)

  • Kim, Y.;Yoon, M.;Kim, Y.M.;Volkov, V.;Park, I.W.;Song, H.J.
    • Journal of the Korean Magnetics Society
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    • v.13 no.2
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    • pp.59-63
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    • 2003
  • Superparamagnetic properties of self-aggregated cobalt nanoparticles in the perfluorinated ion-exchange polymeric membrane (MF-4SK) prepared by ion-exchange and recovery methods were investigated by transmission electron microscopy (TEM) and superconducting quantum interference device (SQUID) magnetometer at various temperatures. Our experimental results show that cobalt nanoparticles in MF-4SK for the concentration of $7.8{\times}10^{19}$ atoms per 1 g of polymer membrane exhibit superparamagnetic properties above the average blocking temperature ($T_{B}$), which is determined to be around 185 K at applied field of 500 Oe. The average particle radius of 4.0 nm achieved from Langevin function fit is in good agreement with TEM observations. This experimental evidence suggests that cobalt nanoparticles in polymer film obey a single domain theory. The results are discussed in the light of current theory for the superparamagnetic behavior of magnetic nanoparticles.

Discussion on the Mechanical Alloying Process of Ni-20Cr alloy (Ni-20 Cr계 분말의 기계적 합금화 과정에 대한 고찰)

  • Yoo, Myoung Ki;Choi, Ju
    • Analytical Science and Technology
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    • v.6 no.2
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    • pp.197-205
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    • 1993
  • Blends of elemental Ni and 20 weight % Cr powder were milled for different period in a laboratory attritor. Powder size distribution, microstructure and X-ray diffraction characteristics were investigated as a function of processing period. Saturated magnetization, Ms and coercive force, Hc we also measured and compared with plasma melted ingot to confirm the mechanically alloyed states. Mechanical alloying occurred as a consequence of the partition of powders and the increase of interfacial area driving diffusing of Cr into Ni. However, magnetic properties of chemically homogeneous solid solution like melted ingot has not been observed even though steady state of submicron grain size has been achieved after milling over 15 hrs. Further mechanical alloying period gave refinement of grain size, which resulted in the increase of alloyed layer. It is concluded that homogenization should be controlled by the increase of interfacial area between constitutive powders caused by plastic particle deformation and by the diffusion of Cr within the alloyed phase into Ni-rich phase through lattice defects.

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Magnetic Characteristics of BaFe12-2xCoxTixO19 Particles Prepared by Sol-gel Synthesis (졸-겔 합성에 의한 BaFe12-2xCoxTixO19 미립자의 자기적 특성)

  • 최현승;정지형;박효열;김태옥
    • Journal of the Korean Ceramic Society
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    • v.40 no.1
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    • pp.62-68
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    • 2003
  • Ba-ferrite particles added with Co and Ti, which were known well the additives for the control in coercivity, were synthesized by sol-gel method. In the range 90 to 120 minute reaction time, a stable sol solution which showed no change with temperature, pH, viscosity and aging time. After dried and heat treatment of sol solution, Ba-ferrite phase formed at $700^{\circ}C$ with Differential Thermal Analysis(DTA) and X-Ray Diffractometer(XRD) measurement. The crystallinity became to be better with increasing the temperature. It were showed by Scanning Electron Microscopy(SEM) that Ba-ferrite increased to particle sizes as increasing heating temperature and obtained of narrow particles size distribution. Also, magnetic characteristics of Ba-ferrite powders Co and Ti added were observed by a Vibrating Sample Magnetometer(VSM). Saturation magnetization$(M_s)$ was not much changed, however. the coercivity$(H_c)$dramatically dropped with addition of Co and Ti.

Development of Polymeric Human Jelly Phantom for Hyper-Thermic Therapy by High Frequency Magnetic Field (고주파 자기장을 이용한 온열요법 치료용의 젤리형 고분자 모의인체)

  • Choi, Chang-Young;Kim, Byung-Hun;Hwang, Young-Jun;Kim, Oh-Young
    • Polymer(Korea)
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    • v.32 no.1
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    • pp.90-93
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    • 2008
  • We developed a variety of polymeric jelly phantoms that can be used in hyperthermia using an electromagnetic wave as an auxiliary cancer therapy. Particularly, using an appropriate material composed of polyethylene, deionized water, and sodium chloride, jelly phantoms for brain was prepared. Also, their electrical properties were characterized by measuring the dielectric constant and conductivity. As the results, overall electrical values of the phantoms decreased with increasing the amount of the components of the materials, excepted for sodium chloride. Additionally, storage characteristics of the phantoms showed a sustainable stability up to 6 months. Based on the experimental results, it can be proposed that jelly phantoms containing a ferro-magnetic particle could be a potential material for cancer therapy following the further study on the temperature elevation effect and the evaluation of electromagnetic properties of the materials.

FEM Analysis of Conduction Noise Absorbers in Microstrip Line (마이크로스트립 라인에서 유한요소법을 이용한 전도노이즈 흡수체의 성능해석)

  • Kim, Sun-Tae;Kim, Sun-Hong;Kim, Sung-Soo
    • Journal of the Korean Magnetics Society
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    • v.17 no.6
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    • pp.242-245
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    • 2007
  • Conduction noise attenuation by composite sheets of high magnetic and dielectric loss has been analyzed by using electromagnetic field simulator which employs finite element method. The simulation model consists of microstrip line with planar input/output ports and noise absorbers (magnetic composite sheets containing iron flake particles as absorbent fillers). Reflection and transmission parameters $(S_{11}\;and\;S_{21})$ and power loss are calculated as a function of frequency with variation of sheet size and thickness. The simulated value is in good agreement with measured one and it is demonstrated that the proposed simulation technique can be effectively used in the design and characterization of noise absorbing materials in the RF transmission lines.

Biostability and Drug Delivery Efficiency of γ-Fe2O3 Nano-particles by Cytotoxicity Evaluation (세포독성 평가를 통한 γ-Fe2O3 나노입자의 생체안정성 및 약물전달효율)

  • Lee, Kwon-Jai;An, Jeung-Hee;Shin, Jae-Soo;Kim, Dong-Hee;Yoo, Hwa-Seung;Cho, Chong-Kwan
    • Korean Journal of Materials Research
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    • v.20 no.3
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    • pp.132-136
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    • 2010
  • This study examined the biostability and drug delivery efficiency of g-$Fe_2O_3$ magnetic nanoparticles (GMNs) by cytotoxicity tests using various tumor cell lines and normal cell lines. The GMNs, approximately 20 nm in diameter, were prepared using a chemical coprecipitation technique, and coated with two surfactants to obtain a water-based product. The particle size of the GMNs loaded on hangamdan drugs (HGMNs) measured 20-50 nm in diameter. The characteristics of the particles were examined by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-TEM) and Raman spectrometer. The Raman spectrum of the GMNs showed three broad bands at 274, 612 and $771\;cm^1$. A 3-(4, 5-dimethylthiazol-2-yl)-2, 5-diphenyltetrazolium bromide (MTT) assay showed that the GMNs were non-toxic against human brain cancer cells (SH-SY5Y, T98), human cervical cancer cells (Hela, Siha), human liver cancer cells (HepG2), breast cancer cells (MCF-7), colon cancer cells (CaCO2), human neural stem cells (F3), adult mencenchymal stem cells (B10), human kidney stem cells (HEK293 cell), human prostate cancer (Du 145, PC3) and normal human fibroblasts (HS 68) tested. However, HGMNs were cytotoxic at 69.99% against the DU145 prostate cancer cell, and at 34.37% in the Hela cell. These results indicate that the GMNs were biostable and the HGMNs served as effective drug delivery vehicles.

Empirical Modeling of the Global Distribution of Magnetosonic Waves with Ambient Plasma Environment using Van Allen Probes

  • Kim, Kyung-Chan
    • Journal of Astronomy and Space Sciences
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    • v.39 no.1
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    • pp.11-22
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    • 2022
  • It is suggested that magnetosonic waves (also known as equatorial noise) can scatter radiation belt electrons in the Earth's magnetosphere. Therefore, it is important to understand the global distribution of these waves between the proton cyclotron frequency and the lower hybrid resonance frequency. In this study, we developed an empirical model for estimating the global distribution of magnetosonic wave amplitudes and wave normal angles. The model is based on the entire mission period (approximately 2012-2019) of observations of Van Allen Probes A and B as a function of the distance from the Earth (denoted by L*), magnetic local time (MLT), magnetic latitude (λ), and geomagnetic activity (denoted by the Kp index). In previous studies the wave distribution inside and outside the plasmasphere were separately investigated and modeled. Our model, on the other hand, identifies the wave distribution along with the ambient plasma environment-defined by the ratio of the plasma frequency (fpe) to the electron cyclotron frequency (fce)-without separately determining the wave distribution according to the plasmapause location. The model results show that, as Kp increases, the dayside wave amplitude in the equatorial region intensifies. It thereby propagates the intense region towards the wider MLT and inward to L* < 4. In contrast, the fpe/fce ratio decreases with increasing Kp for all regions. Nevertheless, the decreasing aspect differs between regions above and below L* = 4. This finding implies that the particle energy and pitch angle that magnetosonic waves can effectively scatter vary depending on the locations and geomagnetic activity. Our model agrees with the statistically observed wave distribution and ambient plasma environment with a coefficient of determination of > 0.9. The model is valid in all MLTs, 2 ≤ L* < 6, |λ| < 20°, and Kp ≤ 6.