• Title/Summary/Keyword: magnetic particle

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Eu-doped LGF Luminescent Down Converter Possible for TiO2 Dye Sensitized Solar Cells

  • Kim, Hyun-Ju;Song, Jae-Sung;Lee, Dong-Yun;Lee, Won-Jae
    • Transactions on Electrical and Electronic Materials
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    • v.5 no.3
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    • pp.89-92
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    • 2004
  • For improving solar efficiencies, down conversion of high-energy photons to visible lights is discussed. The losses due to thermalization of charge carriers generated by the absorption of high-energy photons, can largely be reduced in a solar cell if more than one electron-hole pair can be generated per incident photon. The solar cell was constructed of dye-sensitized anatase-based TiO$_2$, approximately 30nm particle size, 6$\mu\textrm{m}$thickness, and 6${\times}$6$\textrm{mm}^2$ active area, Pt counter electrode and I$_3$$\^$-/I$_2$$\^$-/ electrolyte. After correction for losses due to light reflection and absorption by the conducting glass, the conversion of photons to electric current is practically quantitative in the plateau region of the curves. The incident photon to current conversion efficiency(IPCE) of N3 used as a dye in this work is about 80% at around 590nm and 610nm which is the emission spectrum of Eu doped LGF. The Eu doped LGF powder was prepared by conventional ceramic process, and used as a down converter for DSC after spin coated on the slide glass and fired.

The role of heliospheric current sheet on solar energetic particles with enhanced Fe/O

  • Park, Jinhye;Bucik, R.;Moon, Yong-Jae;Kahler, S.W.
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.1
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    • pp.52.1-52.1
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    • 2018
  • We investigate initial Fe/O enhancements for 44 large gradual solar energetic particles events from 2010 to 2014 and examine the associations of the Fe/O enhancements with the structures of the heliospheric current sheet (HCS). For this study, we use STEREO SIT Fe and O data in 0.32-0.45 MeV channel as well as ACE ULEIS Fe and O data in 0.32-0.64 MeV channel. We determine 1) the magnetic polarities of the SEP source regions using the potential field source surface (PFSS) model of the coronal field and 2) the spacecraft magnetic footpoints with Parker spiral approximation of interplanetary magnetic field using the in-situ measurements of STEREO and ACE. We find that 29 out of 44 events have initial Fe/O enhanced more than 5 times of the typical gradual event values. In the 6 events, the enhancements are simultaneously observed by two spacecraft. There is a tendency that the high Fe/O enhancements are observed near SEP source regions. It is also noted that the Fe/O enhancements are associated with the polarity of the magnetic footpoints. The high Fe/O enhancements are usually observed where their footpoints lie in the same polarity regions of SEP sources rather than the opposite polarity regions. Although Fe/O enhancements could be due to a transport effect and/or a flare contribution, our result implies that the structure of HCS is likely to affect particle propagations in the interplanetary space.

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Enhanced bone morphogenic protein adenoviral gene delivery to bone marrow stromal cells using magnetic nanoparticle

  • Lee, Jung-Tae;Jung, Jae-Whan;Choi, Jae-Yong;Kwon, Tae-Geon
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.39 no.3
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    • pp.112-119
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    • 2013
  • Objectives: This study investigated the question of whether adenoviral magnetofection can be a suitable method for increasing the efficacy of gene delivery into bone marrow stromal cell (BMSC) and for generation of a high level of bone morphogenic protein (BMP) secretion at a minimized viral titer. Materials and Methods: Primary BMSCs were isolated from C57BL6 mice and transduced with adenoviral vectors encoding ${\beta}$ galactosidase or BMP2 and BMP7. The level of BMP secretion, activity of osteoblast differentiation, and cell viability of magnetofection were measured and compared with those of the control group. Results: The expression level of ${\beta}$ galactosidase showed that the cell transduction efficiency of AdLacZ increased according to the increased amount of magnetic nanoparticles. No change in cell viability was observed after magnetofection with 2 ${\mu}L$ of magnetic nanoparticle. Secretion of BMP2 or BMP7 was accelerated after transduction of AdBMP2 and 7 with magnetofection. AdBMP2 adenoviral magnetofection resulted in up to 7.2-fold higher secretion of BMP2, compared with conventional AdBMP2-transduced BMSCs. Magnetofection also induced a dramatic increase in secretion of BMP7 by up to 10-fold compared to the control. Use of only 1 multiplicity of infection (moi) of magnetofection with adenoviral transduction of AdBMP2 or AdBMP7 resulted in significantly higher transgene expression compared to 20 moi of conventional adenoviral transduction. Conclusion: Magnetic particle-mediated gene transudation is a highly efficient method of gene delivery to BMSCs. Magnetofection can lower the amount of viral particles while improving the efficacy of gene delivery.

Iron Oxide Nanoparticle-incorporated Alginate Capsules as Magnetic Field-assisted Potential Delivery Platforms for Agriculture Pesticides and Biocontrol Agents

  • Lee, Dohyeon;Choi, Kyoung Soon;Kim, Daun;Park, Sunho;Kim, Woochan;Jang, Kyoung-Je;Lim, Ki-Taek;Chung, Jong Hoon;Seonwoo, Hoon;Kim, Jangho
    • Journal of Biosystems Engineering
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    • v.42 no.4
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    • pp.323-329
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    • 2017
  • Purpose: Biocompatible capsules have recently been highlighted as a novel platform for delivering various components, such as drug, food, and agriculture pesticides, to overcome the current limitations of living systems, such as those in agriculture, biology, the environment, and foods. However, few active targeting systems using biocompatible capsules and physical forces simultaneously have been developed in the agricultural engineering field. Methods: Here, we developed an active targeting delivery platform that uses biocompatible alginate capsules and controls movements by magnetic forces for agricultural and biological engineering applications. We designed and fabricated large-scale biocompatible capsules, using custom-made nozzles ejecting alginate solutions for encapsulation. Results: To develop the active target delivery platforms, we incorporated iron oxide nanoparticles in the large-scale alginate capsules. The sizes of alginate capsules were controlled by regulating the working conditions, such as concentrations of alginate solutions and iron oxide nanoparticles. Conclusions: We confirmed that the iron oxide particle-incorporated large-scale alginate capsules moved actively in response to magnetic fields, which will be a good strategy for active targeted delivery platforms for agriculture and biological engineering applications, such as for the controlled delivery of agriculture pesticides and biocontrol agents.

Magnetic Field Dependence of the Activation Volume for Sr-ferrite Particles (Sr-페라이트 자성 입자의 활성화 부피의 자기장 의존성)

  • Kim, Hyeon Soo;Jeong, Soon Young;Kim, Kyung Min;Kwon, Hae-Woong
    • Journal of the Korean Magnetics Society
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    • v.26 no.6
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    • pp.196-200
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    • 2016
  • In this study the mechanisms of magnetization reversal and magnetic interaction effects on activation volumes for Sr-ferrite with different particle sizes are investigated. The activation volumes of C2 sample are larger than those of C3 sample in the range of low magnetic fields. But the fields above the coercivity of sample C2, the activation volumes of both samples are decreased linearly with increasing the applied magnetic field. These phenomena can be explained by the strengths of two critical fields representing the reverse domain nucleation field and the domain wall pinning field as well as the strength of dipolar interaction.

A Study on the Isotropic Nd$_2$Fe$_{14}$B/Epoxy Bonded Magnets with High Characteristics (고특성 등방성 Nd$_2$Fe$_{14}$B/에폭시 본드자석의 연구)

  • 조태식;정원용
    • Polymer(Korea)
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    • v.26 no.1
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    • pp.98-104
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    • 2002
  • This study was investigated to fabricate the isotropic $Nd_2Fe_{14}B$/epoxy bonded magnets with high characteristics paroduced by compression molding. The magnetic characteristics of the bonded magnets were directly proportional to the density of the magnets and were enhanced by using raw $Nd_2Fe_{14}B$ magnetic powders, having the mean particle size of $200{\mu} m$.without additional milling process. The high characteristics of the bonded magnets were achieved at the following conditions: epoxy resin of 2.0 wt%, silane coupling agent of 0.8 wt%, curing agent of 0.7 wt% on the base of magnetic powders, and curing condition of $150^{\circ}C$/3 hrs. The bonded magnets at the optimum conditions indicated the high characteristics such as the density of 6.1 g/㎤, the remanent flux density of 7.1 kG, the maximum energy product of 9.7 MGOe, and the compressive strength of 17 kg/$mm^2$.

Optimization of Slurry Preparation Process for Soft Magnetic Green Sheet (연자성 복합체 후막용 슬러리 제조공정의 최적화)

  • Oh, Sea Moon;Lee, Chang Hyun;Shin, Hyo Soon;Yeo, Dong Hun;Kim, Jin Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.12
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    • pp.792-796
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    • 2015
  • With high integration of electronic components, power inductors are also miniaturized. Recently, thick film processes for small size power inductors were developed and commercialized. However, the thick film process to prepare soft magnetic green sheets was not reported enough. In this study, we used Fe-Si magnetic and CIP (carbonyl iron powders) as starting materials to lead to a bimodal particle size distribution in the sheet. We proposed a newly developed 'Modified slurry preparation process' to get well dispersed condition even at high solid contents. Using the new process, it was possible to prepare a well dispersed slurry over 70 vol% of solid. BYK-103 was better than BYK-111 as dispersant in this slurry and the optimum amount was 0.6 wt%. The optimized slurry was formed into a sheet by tape casting process and then the sheet was laminated. We conformed that small size powder, large size powder, and epoxy resin were well dispersed in the green sheet.

Application of a Soil Separation System for the Remediation of Arsenic Contaminated Soil in a Metal Mining Area (폐금속광산 지역의 비소오염토양 처리를 위한 선별 기술 적용)

  • ParK, Chan-Oh;Kim, Jong-Won;Park, Jun-Hyoung;Lee, Young-Jae;Yang, In-Jae;Lee, Jai-Young
    • Journal of Soil and Groundwater Environment
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    • v.18 no.5
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    • pp.56-64
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    • 2013
  • After the law has been enacted for the prevention and recovery of mining damage in 2005, efforts of remediation have been started to recover heavy metal contaminated soils in agricultural land near mining sites. As part of an effort, the upper part of cultivation layer has been treated through covering up with clean soil, but the heavy metal contamination could be still spreaded to the surrounding areas because heavy metals may be remained in the lower part of cultivation layers. In this study, the most frequently occurring arsenic (As) contamination was selected to study in agricultural land nearby an abandoned metal mining site. We applied separation technologies considering the differences in the physical characteristics of soil particles (particle size, density, magnetic properties, hydrophobicity, etc.). Based on physical and chemical properties of arsenic (As) containing particles in agricultural lands nearby mining sites, we applied sieve separation, specific gravity separation, magnetic separation, and flotation separation to remove arsenic (As)-containing particles in the contaminated soil. Results of this study show that the removal efficiency of arsenic (As) were higher in the order of the magnetic separation, flotation separation, specific gravity separation and sieve separation.

Immobilization of GH78 α-L-Rhamnosidase from Thermotoga petrophilea with High-Temperature-Resistant Magnetic Particles Fe3O4-SiO2-NH2-Cellu-ZIF8 and Its Application in the Production of Prunin Form Naringin

  • Xu, Jin;Shi, Xuejia;Zhang, Xiaomeng;Wang, Zhenzhong;Xiao, Wei;Zhao, Linguo
    • Journal of Microbiology and Biotechnology
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    • v.31 no.3
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    • pp.419-428
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    • 2021
  • To efficiently recycle GH78 thermostable rhamnosidase (TpeRha) and easily separate it from the reaction mixture and furtherly improve the enzyme properties, the magnetic particle Fe3O4-SiO2-NH2-Cellu-ZIF8 (FSNcZ8) was prepared by modifying Fe3O4-NH2 with tetraethyl silicate (TEOS), microcrystalline cellulose and zinc nitrate hexahydrate. FSNcZ8 displayed better magnetic stability and higher-temperature stability than unmodified Fe3O4-NH2 (FN), and it was used to adsorb and immobilize TpeRha from Thermotoga petrophilea 13995. As for properties, FSNcZ8-TpeRha showed optimal reaction temperature and pH of 90℃ and 5.0, while its highest activity approached 714 U/g. In addition, FSNcZ8-TpeRha had better higher-temperature stability than FN. After incubation at 80℃ for 3 h, the residual enzyme activities of FSNcZ8-TpeRha, FN-TpeRha and free enzyme were 93.5%, 63.32%, and 62.77%, respectively. The organic solvent tolerance and the monosaccharides tolerance of FSNcZ8-TpeRha, compared with free TpeRha, were greatly improved. Using naringin (1 mmol/l) as the substrate, the optimal conversion conditions were as follows: FSNcZ8-TpeRha concentration was 6 U/ml; induction temperature was 80℃; the pH was 5.5; induction time was 30 min, and the yield of products was the same as free enzyme. After repeating the reaction 10 times, the conversion of naringin remained above 80%, showing great improvement of the catalytic efficiency and repeated utilization of the immobilized α-L-rhamnosidase.

The Control Method of Scale in Drainage Pipe of Deteriorated Tunnel used Magnetic Field and Quantum Stick (자화장치와 퀀텀스틱을 이용한 노후터널의 배수공내 침전물 방지 방법)

  • Nam, Joongwoo;Lee, Changgi;Lee, Jonghwi;Do, Jongnam;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.11
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    • pp.59-64
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    • 2011
  • Clogging in drainage pipe is one of the important problems, so it needs a remedy urgently. Recently, scale in drainage pipe is removed by water jet cleaning and other treatment. But these treatments need much cost and regular management. The principal component of scale in drainage pipe is $CaCO_{3}$. It was observed the setting of $CaCO_{3}$ by some kind of analysis such as SEM, XRD, visual and weight measuring analysis to solve these problems and prevent setting formation in drainage pipe. As a result, in case of magnetic, particle shape of $CaCO_{3}$ is changed Aragonite from Calcite. Also in case of Quantum Stick, the amount of scale is reduced by expert inspector's result. As a whole, Magnetic treatment and Quantum Stick have the effect for protecting of scale precipitation.