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The Influence of Surface Treatments on Shear Bond Strength between Zirconia Core and Heat Press Ceramic Interface (지르코니아 코어의 표면처리방법이 열 가압 세라믹과의 전단결합강도에 미치는 영향)

  • Park, Hang-Min;Chung, In-Sung
    • Journal of Technologic Dentistry
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    • v.31 no.2
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    • pp.23-30
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    • 2009
  • All-ceramic restorations have gained acceptance among clinicians and patients because of their superior esthetics. Most all-ceramic systems have a 2-layer structure, using a weak veneering ceramic over a strong supporting core. often, failure of all-ceramic restorations occurs when the veneering ceramic fractures, exposing the core material. The purpose of this study was to compare the shear bond strength of heat press ceramic system (Zirpress) to zirconia core with various surface treatments. 10 metal cores and 50 zirconia cores were fabricated and divided into six groups according to surface treatment such as Zirliner application, aluminium oxide blasting, and 9.5% HF etching. Sixty specimens were prepared using Zirpress, veneered 8mm height and 3mm in diameter, over the zirconia cores (n=10). The shear bond strength test was performed in a universal testing machine with a crosshead speed of 1/min. Ultimate shear bond strength data were analyzed with One-way ANOVA and the Scheffe's test (p=.05). Within the limits of this study, the following conclusions were drawn: The mean shear bond strengths (MPa) were: 12.93 for $110{\mu}m$ aluminium oxide blasting/Rexillium III/IPS e.Max Zirpress; 14.92 for $50{\mu}m$ aluminium oxide blasting ${\pm}9.5%$ HF etching/Zirconis core/IPS e.Max Zirpress; 16.37 for $110{\mu}$ aluminium oxide blasting + 9.5% HF etching/Zirconis core/IPS e.Max Zirpress; 12.89 for $200{\mu}$ aluminium oxide blasting + 9.5% HF etching/Zirconis core/IPS e.Max Zirpress; 19.30 for 9.5% HF etching/Zirconis core/IPS e.Max Zirpress; 19.55 for Zirliner/Zirconis core/IPS e.Max Zirpress. The mean shear bond strength for ZNTZH (Zirliner/Zirconis core) and ZNTEH (9.5% HF etching/Zirconis core) were significantly superior to MS110H ($110{\mu}$ aluminium oxide blasting/Rexillium III) and ZS200EH ($200{\mu}$ aluminium oxide blasting + 9.5% HF etching/Zirconis core) (p<0.05).

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Physicochemical Heterogeneity of the Supply Water Quality depending on Seasonal Changes in the Taejon Area, Korea (대전지역 상수도 물의 계절변화에 따른 물리화학적 불균질)

  • 이현구;이찬희;서호택
    • Economic and Environmental Geology
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    • v.33 no.6
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    • pp.505-517
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    • 2000
  • This study was undertaken to provide a drinking water quality on the basis of physicochemical properties. In this study, the 25 samples of supply waters of the Taejon area were sampled twice (February and August in 1999). Hydrochemistry of the supply water belongs to the $Ca^{2+}$-${HCO_3}^{-1}$ type, whereas the supply water was characterized by the relatively significant enrichment of ${Ca}^{2+}$, ${Na}^{2+}$, ${K}^{2+}$, ${Cl}^{2+}$ ions and heavy metals compared to the original water from the Daecheong lake. Generally, the supply water has a mean values for $10.7^{\circ}C$ of temperature, 6.86 of pH, -12 mV of Eh, 88 ${\mu}S$/cm of EC and 70.379 mg/l of TDS in February, whereas the waters of the same sites in August are a slightly high temperature ($26.1^{\circ}C$), TDS (78.069 mg/l) and extremely high EC (442 ${\mu}S$/cm) value. These values are similar with physicochemical properties of the original lake water depending on the seasonal differences. Results of speciation calculation indicate that potentially toxic ions might exist mainly in the forms of free metal (${Cu}^{2+}$ or ${Zn}^{2+}$) and a small amount of ${CO_3}^{2-}$and ${OH}^{-}$in the supply water. The water seemed to be in equilibrium with kaolinite field of the normal stability diagrams for the natural water. Based on enrichment parameter of the supply water normalized by original lake water composition, the average value of those parameter can be calculated with nearly 1.00, but the those values for Cu+Zn possible source of decrepit pipe lines are 126.75 in February and 115.63 in August samples. The parameter values varied with sampling sites, however, do not exceed by chemistry of drinking water standard. Solid compounds remained on the membrane filter papers after filtration are adhered to pale yellow or yellowish brown colored dissolved solids and precipitates, which are coated by 0.02 to 0.35 mm thick per 500 ml with colloidal particles of about 1 to 2${\mu}m$ size. The particles are mainly Fe-Cu-Zn compounds and partly detected to Mn and Pb.

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Efficacy of Concurrent Administration of Live and Killed Newcastle Disease Vaccines in Day - Old Broiler Chicks (육용계 초생추에 대한 뉴켓슬병 생독 및 사독 백신의 동시접종 효과)

  • 최정옥;박승주;위성하
    • Korean Journal of Poultry Science
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    • v.15 no.3
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    • pp.193-198
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    • 1988
  • In order to examine the efficacy of concurrent vaccination with live and killed Newcastle disease(ND) vaccines two types of each live($B_1$ and LaSota) and killed(gel and oil) vaccines of all commercial origin were administered either alone or simultaneously to day-old broiler chicks having maternal antibody. Live vaccines were given by conjuntival instillation in volumes of 25${\mu}\ell$ containing $10^{6.0}$ to $10^{6.3}$ median embroy infective dose(EH)) while killed vaccines were given in 0.3$m\ell$ volumes subcutaneously at the back of the neck Hemagglutination inhibition(HI) antibodies were determined at weekly intervals until 8 weeks of age and protection rate was determined at 4 and 8 week of age by challenge inoculation with virulent ND virus(NDV). During the 8 weeks experimental period concurrent administration of live and oil vaccine produced the highest level of HI antibody and the most satisfactory protection, whereas concurrent rent vaccination with live and gel vaccine induced poor immune responses. There was no noticeable difference in the efficacy between the live vaccines, Bl and LaSota when simultaneously administered with oil vaccine. Except for oil vaccine, single administration of either live or killed vaccine at day-old produced less than 50% protection at 4 and 8 weeks postvaccination(PV). Oil vaucine alone induced 80% and 70% protection at 4 and 8 week PV, respectively. Concurrent vaccination caused on visible side reaction like respiratory symptoms and did not negatively influence the growth rate of birds until the end of experiment.

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Characteristics of Groundwater Pollution and Contaminant Attenuation at Waste Disposal Sites (폐기물 매립지 주변의 지하수 오염과 오염물질의 지연 특성)

  • 오석영;전효택
    • Journal of the Korean Society of Groundwater Environment
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    • v.3 no.1
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    • pp.37-49
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    • 1996
  • The objectives of this study are to investigate the groundwater and surface water contamination, to interpret the attenuation mechanism of contaminant transport, and to find the appropriate contamination indicator. at the two big landfill sites : Nanjido Landfill and Hwasung Landfill. Leachate from the Nanjido, th, Hwasung and the Kimpo waste disposal sites is characterized by high temperature (31.7-40.1$^{\circ}C$), high electric conductivity (14,650-32,800 ${\mu}$S/cm), somewhat higher pH(7.58-8.45) and low Eh (-119.4-20.4 mV), and is enriched in both major (Na$^{+}$, K$^{+}$, Ca$^{2+}$, Mg$^{2+}$, HC $O_3$$^{-}$, Cl$^{-}$) and minor (Mn, Sr$^{2+}$, Ba$^{2+}$, Li$^{+}$, F$^{-}$, Br$^{-}$) ions. Municipal solid waste leachate and industrial waste leachate are effectively discriminated by the content of S $O_4$$^{2-}$, Fe, and heavy metals. The attenuation mechanism of each component was assessed using the chemical analysis. Cl-normalizing process, WATEQ4F simulation, and preceding flownet analysis. Based on the calculation of Contamination Factor, K, Na, Ca, Mg, B, Zn, HC $O_3$, Cl, F, Br and TOC are effective contamination indicators in the Nanjido landfill site, and K, Na, Ca, Mg, B, S $O_4$, HC $O_3$, Cl, F, Br and TOC in the Habsburg landfill site Particularly, TOC is the best contamination indicator in landfill sites influenced by sea water.

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Geochemical Characteristics and Nitrates Contamination of Shallow Groundwater in the Ogcheon Area (옥천지역 천부지하수의 지구화학적 특성 및 질산염 오염 특성)

  • Lee, In-Gyeong;Choi, Sang-Hoon
    • Economic and Environmental Geology
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    • v.43 no.1
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    • pp.43-52
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    • 2010
  • The geochemical and nitrogen isotopic analyses for shallow groundwater of Ogcheon area were carried out to characterize the geochemical characteristics of the groundwater and to identify the source of nitrate. Groundwater shows a neutral pH to weakly alkalic condition with pH values ranging from 6.9 to 8.4. The average of EC, Eh and DO is $344.2\;{\mu}s/cm$, 195 mV, 4 mg/L, respectively. According to piper diagram, chemical composition of groundwater is dominantly characterized by Ca-$HCO_3$ type. On the other hand, groundwater type in the study area include Ca-Cl+$NO_3$ type that were highly influenced by agricultural activities. $NO_3$-N concentration of the collected samples(n=45) range from 12.4 to 34.2 mg/l. These data show that the $NO_3$-N concentration exceeds Korea Drinking Water Standard (10 mg/l). The $\delta^{15}N-NO_3$ values range from $2.7^{\circ}/_{\circ\circ}$ to $18.8^{\circ}/_{\circ\circ}$. The enrichments of heavy isotope in the groundwater indicate that major origin of nitrate pollution were associated with animal and human waste. Also the denitrification may have partly contributed as one of the sources of nitrogen.

Changes in Phosphatase Activity of the Mouse Uterus during the Estrous Cycle (發情週期에 EK른 생쥐子宮의 Phosphatase 活性의 變化에 관하여)

  • Kim, Moon-Kyoo;Kim, Sung-Rye;Cho, Wan-Kyoo
    • The Korean Journal of Zoology
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    • v.23 no.2
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    • pp.61-68
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    • 1980
  • Quantitative analysis of the activities of transport ATPases as well as alkaline phosphatase of the mouse uterus was carried out during the estrous cycle. Even though the proportional patterns of the enzyme activities were similar each another between the stages of estrous cycle, the absolute activities of the enzymes except $K^+$-dependent and $Na^+$, $K^+$-activated ATPases at the time of estrus were significantly (p<0.025) higher than that at any other time of the estrous cycle. That is, the activities of $K^+$-dependent and $Na^+$, $K^+$-activated ATPases were negligible during the period of time from diestrus to estrus while the little activities (0.04 $\\sim$ 0.05$\\mu$M/mg protein/hr in average, $6\\sim7$% of the total enzyme activity) of these enzymes appeared at the time of metaestrus. On the other hand, at the time of estrus, the activities of $Mg^++$-dependent phosphatase, transport ATPase and alkaline phosphatase were rapidly and tremendously increased to be 0.69 (35%), 0.42 (21%) and 1.58 (79%), respectively. The activity of alkaline phosphatase was in the range of 0.60 $\\sim$ 1.58 (79 $\\sim$ 90%) and predominant throughout the estrous cycle. The activity of $Mg^++$-dependent alkaline phosphatase was estimated as 12 $\\sim$ 16% of the total enzyme activity. Therefore, it is assumed likely that $K^+$-dependent and $Na^+$, $K^+$-activated ATPases are not the main factors to control the fluid accumulation at the time of estrus, but may be the factors to reabsorb the luminal fluid into the uterine epithelium at the time of metaestrus, and that $Mg^++$-dependent phosphatase, transport ATPase and alkaline phosphatase must be closely involved in the secretion of luminal fluid from the epithelial cells of the mouse uterus.

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Hydrogeochemical study of a watershed in Pocheon area: controls of water chemistry

  • Kim, Kyoung-Ho;Yun, Seong-Taek;Chae, Soo-Ho;Jean, Jong-Wook;Lee, Jeong-Ho;Kweon, Hae-Woo
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.121-121
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    • 2004
  • The groundwater in the Pocheon area occurs from both a fractured bedrock aquifer in igneous and metamorphic rocks and an alluvial aquifer with a thickness of <50 m, and forms a major source of domestic and agricultural water supply. In this study, we performed a hydrogeochemical study in order to identify the control of geochemical processes on groundwater quality. For this study, groundwater level and physicochemical parameters (EC, Eh, pH, alkalinity) were monitored once a month from a total of 150 groundwater wells between June 2003 to August 2004. A total of 153 water samples (13 surface water, 66 alluvial groundwater, 74 bedrock groundwater) were also collected and analyzed in February 2004. Groundwater chemistry in the study area is very complex, depending on a number of major factors such as geology, degree of chemical weathering, and quality of recharge water. Hydrochemical reactions such as the leaching of surficial and near-solace soil salts, dissolution of calcite, cation exchange, and weathering of silicate minerals are proposed to explain the chemistry of natural groundwater. Alluvial groundwaters locally have very high TDS concentrations, which are characterized by their chloride(nitrate)-sulfate-bicabonate facies and low Na/Cl ratio. Their grondwater levels are highly fluctuated according to rainfall event. We suggest that high nitrate content and salinity in such alluvial groundwaters originates from the local recharge of sewage effluents and/or fertilizers. Likewise, high concentrations of nitrate were also locally observed in some bedrock groundwaters, suggesting their effect of anthropogenic contamination. This is possibly due to the bypass flow taking place through macropores. Tile degree of the weathering of silicate minerals seems to be a major control of the distribution of major cations (sodium, calcium, magnesium, potassium) in bedrock groundwaters, which show a general increase with increasing depth of wells. Thermodynamic interpretation of groundwater chemistry shows that the groundwater in the study area is in chemical equilibrium with kaolinite and Na-montmorillonite, which indicates that weathering of plagioclase to those minerals is a major control of hydrochemistry of bedrock groundwater. The interpretation of the molar ratios among major ions, as well as the mass balance calculation, also indicates the role of both dissolution/precipitation of calcite and Ca-Na cationic exchange as bedrock groundwaters evolves progressively.

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A Study of the Synoptic Climatology on the January's Cold and Warm Winter Especially in 600hPa Circulation : Case Study 1992 and 1984 in January (500hPa면 순환특성을 중심으로 한 동계 이상 한.난월의 종관기후학적 연구 -1992년과 1984년의 1월의 경우-)

  • Lee, Byung-Gon;Min, Woo-Ki
    • Journal of the Korean association of regional geographers
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    • v.2 no.2
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    • pp.103-111
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    • 1996
  • I followed the results of Lee and Min(1996) for classification of the months of cold and warm winter. The winter of 1992 and 1984 recorded extraordinary cold and warm. Study of the Synoptic Climatology on the January's cold and warm winter is below: (1) Climatology's characteristic. Temperature of extremely high temperature month is higher compared with extremely low temperature month. Also precipitation is more than over low temperature month compared with extremely high temperature month. (2) In circulation of 500hPa surface. (1) Extremely high temperature month At 500hPa, negative geopotential height anomalies in high latitude, three trough developed over eastern Canada. In midlatitude, a deep trough persisted in the central North Pacific and conspicuous positive height anomalies showed over northwestern Europe, Where a blocking anticyclone developed. It had been warmer than normal since last year in Korea due mainly to positive height anomalies stretched from central Siberia (2) Extremely low temperature month Appeared the strong meridional circulation and negative height anomalies showed from Far East to the Mid-Pacific and appeared ridge in the west of the North America and Atlantic. Alutien Low shows negative deviation during 1984. In northern hemisphere shows negative deviation. Therefore, we can show that the surface pressure distribution and height distribution of 500hPa level are closely connected with each other as parts of general circulation. (3) The characteristics of the general circulation pattern of the 500hPa (1) Extremely high temperature month is high than extremely low temperature month1984 in Zonal index (2) The majority type is S type in 500hPa level circulation of extremely high temperature month but extremely high temperature month is M type (3) The wave number in 500hPa all shows 3 wave. So can not distinguished by only predominant wave number pattern.

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Effect of Glue Plant(Codium Fragile) on Physicochemical Characteristics of Dongchimi During Fermentation (청각채가 동치미의 발효 중 이화학적 특성에 미치는 영향)

  • Park, Bock-Hee;Cho, Hee-Sook
    • Journal of the Korean Society of Food Culture
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    • v.20 no.5
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    • pp.508-515
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    • 2005
  • The effect of glue plant(Codium fragile) on the Dongchimi fermentation was investigated by measuring physicochemical properties during fermentation at $10^{\circ}C$. Dongchimi was prepared with various levels(0, 0.5, 1.0 and 1.5%) of glue plant(Codium fragile). The pH of Dongchimi decreased slowly in all samples during fermentation. Total acidity of Dongchimi increased gradually during fermentation and total acidity of Dongchimi with glue plant(Codium fragile) was higher than that of control. Redox potentials decreased until 30 days of fermentation but increased thereafter. Reducing sugar content increased in the initial stage of the fermentation periods, and then decreased gradually. The reducing sugar content of Dongchimi with glue plant(Codium fragile) was higher than that of control. The content of total vitamin C was much higher in dongchimi with glue plant(Codium fragile). In color measurement, lightness value decreased gradually. However, redness and yellowness values increased gradually during fermentation but decreased thereafter. The content of hot water soluble pectin(HWSP) decreased as the fermentation proceeded, but the content of hydrochloric acid soluble pectin(HClSP) and sodium hexametaphosphate soluble pectin(NaSP) increased.

Rhizosphere Enhances Removal of Organic Matter and Nitrogen from River Water in Floodplain Filtration (홍수터 여과를 이용한 하천수의 질소와 유기물 제거에 미치는 근권의 효과)

  • Jeong, Byeong-Ryong;Chung, Jong-Bae;Kim, Seung-Hyun;Lee, Young-Deuk;Cho, Hyun-Jong;Baek, Nam-Joo
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.1
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    • pp.8-15
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    • 2003
  • If contaminated river water is sprayed over a floodplain, the microbial processes can simultaneously remove organic matter and nitrogen during the infiltration through the sediment profile. The effect of rhizosphere on the removal of organic matter and nitrogen from contaminated river water was investigated using floodplain lysimeters. River water was sprayed at a rate of $68.0L\;m^{-2}\;d^{-1}$ on the top of the lysimeters with or without weed vegetation on the surface, Concentrations of $NO_3$, $NH_4$ and dissolved oxygen (DO), and chemical oxygen demand (COD) and Eh in water were measured as functions of depth for 4 weeks after the system reached a steady state water flow and biological reactions. A significant reductive-condition for denitrification developed in the 30-cm surface profile of lysimeters with weeds. At a depth of 30 cm, COD and $NO_3$-N concentration decreased to 5.2 and $0.9mg\;L^{-1}$ from the respective influent concentrations of 18.2 and $9.8mg\;L^{-1}$. The removal of $NO_3$ in lysimeters with weeds was significantly higher than in those without weeds. Vegetation on the top was assumed to remove $NO_3$ directly by absorption and to create more favorable conditions for denitrification by supply of organic matter and rapid $O_2$ consumption, In the lysimeters without weeds, further removal of $NO_3$ was limited by the lack of an electron donor, i.e. organic matter. These results suggest that the filtration through native floodplains, which include rhizospheres of vegetation on the surface, can be effective for the treatment of contaminated river water.