• Title/Summary/Keyword: luminescent light

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Recent Progress in Luminescent Lanthanide Complexes for Advanced Photonics Applications

  • Kim, Hwan-Kyu;Oh, Jae-Buem;Baek, Nam-Seob;Roh, Soo-Gyun;Nah, Min-Kook;Kim, Yong-Hee
    • Bulletin of the Korean Chemical Society
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    • v.26 no.2
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    • pp.201-214
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    • 2005
  • We have designed and developed novel luminescent lanthanide complexes for advanced photonics applications. Lanthanide(III) ions (Ln$^{3+}$) were encapsulated by the luminescent ligands such as metalloporphyrins and naphthalenes. The energy levels of the luminescent ligands were tailored to maintain the effective energy transfer process from luminescent ligands to Ln$^{3+}$ ions for getting a higher optical amplification gain. Also, key parameters for emission enhancement and efficient energy transfer pathways for the sensitization of Ln$^{3+}$ ions by luminescent ligands were investigated. Furthermore, to enhance the optophysical properties of novel luminescent Ln$^{3+}$ complexes, aryl ether-functionalized dendrons as photon antennas have been incorporated into luminescent Ln$^{3+}$ complexes, yielding novel Ln(III)-cored dendrimer complex. The novel Ln(III)-cored dendrimer complex has much higher PL intensity than the corresponding simple complex, due to the efficient site-isolation effect. In this article, we will deal with recent progress in the synthesis and photophysical studies of inert and stable luminescent Ln$^{3+}$ complexes for advanced photonics applications. Also, our review will include the exploratory investigation of the key parameters for emission enhancement and the effective energy transfer pathways from luminescent ligands to Ln$^{3+}$ ions with Ln(III)-chelated prototype complexes.

White Light Emitting Diodes for Illumination

  • Choi, Kyoung-Jae;Park, Joung-Kyn;Kim, Kyung-Nam;Kim, Chang-Hae;Kim, Ho-Kun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1090-1092
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    • 2006
  • There is provided white light illumination system including a radiation source, a first luminescent material having a peak emission wavelength of about 575 to about 620 nm, a second luminescent material having a peak emission wavelength of about 495 to about 550 nm, which is different from the first luminescent material and a third luminescent material having a peak emission wavelength of about 420 to about 480 nm, which is different from the first and second luminescent materials. The LED may be a UV LED and the luminescent materials may be a blend of three phosphors. A human observer perceives the combination of the blue, green and red phosphor emissions as white light.

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A Study on Low Location Lighting of Passenger Ship (여객선의 Low Location Lighting에 대한 고찰)

  • Kang, Ki-Won;Kwon, Ji-Min
    • Special Issue of the Society of Naval Architects of Korea
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    • 2017.10a
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    • pp.63-66
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    • 2017
  • All passenger ships aboard more than 36 passengers are to be able to easily find escape routes when the escape way by fire with flame spread were onboard vessel (incl. Ferry, Passenger, Ro-pax, Inland Ferry) It should be impossible by ordinary emergency lights. The international Maritime Organization (IMO) gives special requirement for luminescent evaluation onboard test procedure and applicable location of low location lighting. In order to maintain the residual light source for a certain time in the low location lighting with a strip-shaped light source, the light source material must be sufficiently exposed to the light due to the proper placement of the escape route. The lighting arrangement influence how maintain low location lighting strip luminescent which measured onboard in connection with what elements are mainly sustain luminescent.

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Luminescent Properties of Two-Ions Doped Phosphors for LED Application

  • Kim, Tae-Gon;Kim, Young-Sic;Im, Seoung-Jae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.52-55
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    • 2009
  • A red phosphor, $(Sr,Ca)_2P_2O_7:Eu^{2+},Mn^{2+}$, for UV-LED was synthesized under a reducing atmosphere, and its luminescent properties were investigated. The phosphor absorbs ultraviolet light at around 400 nm and efficiently emits red light at approximately 610 nm through an energy transfer from $Eu^{2+}$ to $Mn^{2+}$. Using the varied input current test for the phosphor-loaded LED lamps, it was found that the luminescent efficiency of the phosphor decreased with increasing light flux. This might be due to an increased probability of excited-state absorption and the consequent non-radiative relaxation in $Mn^{2+}$ ions in the condition of high photon influx.

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Synthesis of Phosphor for Light-Emitting Diodes by Sol-Gel Method (졸-겔법을 이용한 LED용 형광체의 합성)

  • Ahn Joong-In;Han Cheong-Hwa;Park Jung-Kyu;Kim Chang-Hae
    • Korean Journal of Materials Research
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    • v.14 no.10
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    • pp.749-753
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    • 2004
  • In this study, we attempt to synthesize the $Sr_{3}SiO_{5}:Eu$ yellow phosphor by sol-gel technique. Based on the blue emitting diodes as primary light source, white light emitting diodes have been manufactured using the $Sr_{3}SiO_{5}:Eu$ yellow phosphor as the luminescent material. Luminescent efficiency of yellow phosphor as well as that of blue LED is very important factor to enhance the luminescent efficiency of white LED. In order to improve the luminescent efficiency, we have synthesized the $Sr_{3}SiO_{5}:Eu$ phosphor by sol-gel technique. To research optimum condition of gelation reaction, the ratio of $H_{2}O$ to TEOS was fixed as 60:1. When the drying temperature was at $100^{\circ}C$, emission intensity was better than at $70^{\circ}C$. The critical $Eu^{2+}$ concentration was estimated to be about 0.05 mol and sintering temperature at $1300^{\circ}C$ was indicated best emission intensity.

Enhanced Light Outcoupling on Photo-luminescent Devices with Microcavity (Microcavity 적용 광자 발광 소자의 광 추출 향상 연구)

  • Lee, Han Byul;Lee, Eun Hye;Sung, Min Ho;Ryu, Si Hong;Lee, Seong Eui
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.5
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    • pp.391-396
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    • 2013
  • Recently, microcavity is studied to reduce the optical loss of BLU and OLED. In this paper, we suggest applying microcavity to photo-luminescent lamp with plasma discharge technology to meet the display applications for a BLU for LCD. The structure of photo-luminescent lamp consists of SUS foil and ITO glass with microcavity. The opto-electric characteristics of photo-luminescent lamp with microcavity was evaluated. The brightness of photo-luminescent device was increased over $111cd/m^2$ with the adaptation of patterned microcavity at $30{\mu}m$. The 3D optical simulation verified the enhanced light outcoupling when microcavity applied to the device.

A Study on the Type of Light in Fashion Design (패션디자인에 활용된 빛의 유형 분석)

  • Jung, Hyun;Geum, Key-Sook
    • Journal of the Korean Society of Costume
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    • v.58 no.2
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    • pp.120-133
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    • 2008
  • The purpose of this study is to analysis types of light and to find the characteristics of light in contemporary fashion design. In a scientific context, light is electromagnetic radiation of a wavelength that has the characteristics of straightness, reflection, refraction, scattering and diffraction. But in philosophical speculations, light has been used as a metaphor of 'being', 'to-be' or 'enlightenment.' And through the ages, people have tried to represent and apply the light into plastic art like painting and architecture. The types of light in fashion design was categorized as those; reflective light from the surface of clothing which is the result of interaction between illumination and material, representative light as the pattern of light or light effect such as sun or its rays and optical or psychedelic patterns, luminescent light from light emitting material like phosphorescence or LED which combines into fashion design, projective light from a medium to reveal virtual patterns on the surface or a fashion design itself using holography. These lights in fashion design can be considered as reflection of emphasis of sexuality, longing for fantasy and mystique, visualization of interaction and communication and groping for the play.

Luminescent Lanthanide Complexes for Advanced Photonics Applications

  • Eom, Yu Kyung;Ryu, Jung Ho;Kim, Hwan Kyu
    • Rapid Communication in Photoscience
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    • v.1 no.1
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    • pp.1-9
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    • 2012
  • Luminescent lanthanide complexes have been overviewed for advanced photonics applications. Lanthanide(III) ions ($Ln^{3+}$) were encapsulated by the luminescent ligands such as metalloporphyrins, naphthalenes, anthracene, push-pull diketone derivatives and boron dipyrromethene(bodipy). The energy levels of the luminescent ligands were tailored to maintain the effective energy transfer process from luminescent ligands to $Ln^{3+}$ ions for getting a higher optical amplification gain. Also, key parameters for emission enhancement and efficient energy transfer pathways for the sensitization of $Ln^{3+}$ ions by luminescent ligands were investigated. Furthermore, to enhance the optophysical properties of novel luminescent $Ln^{3+}$ complexes, aryl ether-functionalized dendrons as photon antennas have been incorporated into luminescent $Ln^{3+}$ complexes, yielding novel $Ln^{3+}$-cored dendrimer complex such as metalloporphyrins, naphthalenes, and anthracenes bearing the Fr$\acute{e}$chet aryl-ether dendrons, namely, ($Er^{3+}-[Gn-Pt-Por]_3$ (terpy), $Er^{3+}-[Gn-Naph]_3$(terpy) and $Er^{3+}-[Gn-An]_3$(terpy)). These complexs showed much stronger near-IR emission bands at 1530 nm, originated from the 4f-4f electronic transition of the first excited state ($^4I_{13/2}$) to the ground state ($^4I_{15/2}$) of the partially filled 4f shell. A significant decrease in the fluorescence of metalloporphyrins, naphthalenes and anthracene ligand were accompanied by a strong increase in the near IR emission of the $Ln^{3+}$ ions. The near IR emission intensities of $Ln^{3+}$ ions in the lanthanide(III)-encapsulated dendrimer complexes were dramatically enhanced with increasing the generation number (n) of dendrons, due to the site-isolation and the light-harvesting(LH) effects. Furthermore, it was first attempted to distinguish between the site-isolation and the light-harvesting effects in the present complexes. In this review, synthesis and photophysical studies of inert and stable luminescent $Ln^{3+}$ complexes will be dealt for the advanced photonics applications. Also, the review will include the exploratory investigation of the key parameters for emission enhancement and the effective energy transfer pathways from luminescent ligands to $Ln^{3+}$ ions with $Ln^{3+}$-chelated prototype complexes.