• Title/Summary/Keyword: luminescence properties

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Preparation and Luminescence Properties of Y(P,V)O4:Eu3+ Phosphor using Impregnation Method (함침법에 의한 Y(P,V)O4:Eu3+ 형광체의 합성 및 발광특성)

  • Han, Cheong-Hwa;Kim, Soo-Jong
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.565-570
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    • 2011
  • The $Eu^{3+}$ doped $Y(P_x,V_{1-x})O_4$ (0 ${\leq}$ x ${\leq}$ 1) phosphors were synthesized by solid-state and impregnation method and investigated as potential red-emitting phosphors for a plasma display panel(PDP). The optimal substitution proportion of P for V was determined to be 60 mol%, for $Y(P_x,V_{1-x})O_4$ doped with 8 mol% $Eu^{3+}$. The VUV PL spectra and SEM for the synthesized phosphors were measured and compared against those of a commercial red-emission phosphor. The $Y(P_x,V_{1-x})O_4$:$Eu^{3+}$ phosphors exhibited strong red at around 592, 618 and 698 nm. The emission intensity and particle size of the phosphors were controlled by preparation conditions.

Luminescence Study of Eu3+ Ions Doped BaMoO4 Nanoparticles

  • Bharat, L. Krishna;Lee, Soo Hyun;Yu, Jae Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.415.2-415.2
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    • 2014
  • Cost-effective, robust devices for solid-state lighting industry that converts electricity to light revolutionize the current lighting industry. Phosphor materials used in these devices should be synthesized in a low-cost and effective method for use in WLEDs. In this presentation, the synthesis of Eu3+ ions doped BaMoO4 phosphor samples by a facile synthesis process for red component of WLEDs will be shown. The tetragonal phase of the host lattice was substantiated by the X-ray diffraction patterns. The morphological studies were carried out by using a field-emission scanning electron microscope and transmission electron microscope. These confirmed the formation of a shuttle like particles with perpendicular protrusions in the middle of the particle. The photoluminescence (PL) properties exhibited good emission with a high asymmetry ratio when excited with ultraviolet B wavelengths (~ 280-315 nm). The cathodoluminescence (CL) spectra showed similar results to the PL spectra, indicating the rich red emission. The results suggest that this phosphor is a good material as red region component in the development of tri-band UV excitation based WLEDs.

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Morphological Variation and Luminescence Properties of ZnO Micro/Nanocrystals Synthesized by Thermal Evaporation Method

  • Lee, Won-Jae;Lee, Geun-Hyoung
    • Korean Journal of Materials Research
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    • v.27 no.10
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    • pp.530-533
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    • 2017
  • ZnO micro/nanocrystals with different morphologies were synthesized by thermal evaporation of various zinc source materials in an air atmosphere. Zinc acetate, zinc carbonate and zinc iodide were used as the source materials. No catalysts or substrates were used in the synthesis of the ZnO crystals. The scanning electron microscope(SEM) image showed that the morphology of ZnO crystals was strongly dependent on the source materials, which suggests that source material is one of the key factors in controlling the morphology of the obtained ZnO crystals. Tetrapods, nanogranular shaped crystals, spherical particles and crayon-shaped crystals were obtained using different source materials. The X-ray diffraction(XRD) pattern revealed that the all the ZnO crystals had hexagonal wurtzite crystalline structures. An ultraviolet emission was observed in the cathodoluminescence spectrum of the ZnO crystals prepared via thermal evaporation of Zn powder. However, a strong green emission centered at around 500 nm was observed in the cathodoluminescence spectra of the ZnO crystals prepared using zinc salts as the source materials.

Synthesis and Characterization of Poly(9,9-dioctylfluorene-2,7-vinylene) for Light Emitting Diode Application

  • Jin, Sung-Ho;Park, Hye-Jin;Kim, Jin-Young;Lee, Kwang-Hee;Gal, Yeong-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.336-339
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    • 2002
  • Fluorenevinylene-based EL polymers, poly(9,9-dioctylfluorene-2,7-vinylene) (PFV) and poly[(9,9-dioctylfluorene-2,7-vinylene)-co-{2-methoxy-5-(2 ethylhexyloxy)-1,4-phenylenevinylene}] (PFV-co-MEH-PPV), have been synthesized by Gilch polymerization method. The resulting polymers were soluble in common organic solvents and easily spin cast onto the indium-tin oxide (ITO) substrate. The weight average molecular weight and polydispersity of PFV and PFV-co-MEH-PPV were in the range of 22.2 - 43.2 x $10^4$ and 1.9 - 3.0, respectively. Double-layer light-emitting diodes with ITO/PEDOT/Polymer/Al configuration were fabricated. PFV-co-MEH-PPV showed better EL properties than those of PFV and MEH-PPV The turn-on voltage of poly(9,9dialkylfluorene) derivatives were dramatically decreased to the 2.5 V compared to fluorene-based EL polymers. The maximum brightness and luminescence efficiency were up 7 to 1350 cd/$m^2$ and 0.51 Cd/A.

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Photodarkening and Thermal Bleaching Effect in Ge-doped Multicomponent Oxide Glasses by UV Irradiation (자외선 조사에 따른 게르마늄 함유 다성분계 산화물 유리의 광흑화와 열표백화 현상)

  • 이회관;오영석;강원호
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.3 no.3
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    • pp.161-165
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    • 2002
  • Ge-doped rnulticomponent oxide glasses were prepared by a conventional melting method. The change of micro structure in glasses was investigated by using PL (photoluminescence) and ESR (electron spin resonance). Before UV irradiation, the PL intensity increased according to germanium contents, but decreased the intensity as soon as UV irradiation. A changed property was recovered near it original properties when it was annealed. These photodarkening and thermal bleaching effect were observed by ESR intrument. These effect did not change the glass phase but vary only change of micro structure.

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Thermoluminescence Characteristics of Smart Phone Tempered Glass (스마트폰 강화유리의 열형광 특성)

  • Je, Jaeyong
    • Journal of the Korean Society of Radiology
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    • v.14 no.4
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    • pp.433-437
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    • 2020
  • Principles of Radiation Detection and measurement include luminescence, ionization and chemical reactions. In this study, thermoluminescent properties were analyzed by exposure radiation on the glass for protective glass of smart phone. In order to analyze the thermoluminescent characteristics by radiation, 6 MV X-ray 100 cGy was irradiated to the powder annealing at 300 ℃ by grinding the tempered glass and original tempered glass. As a result of measuring the amount of thermoluminescent respectively irradiated material, the thermoluminescent increased by 3 times in the tempered glass, and when the tempered glass was grinding by powder the thermoluminescent was 2.4 times increased. Based on these results, the liquid crystal protective glass of the smart phone is evaluated as a tracer material to evaluate the radiation exposure and dose of the personal radiation monitoring.

A Study for Luminescence Properties of OLEDs Using $Alq_2-Ncd$ as an Emitting Layer ($Alq_2-Ncd$를 이용한 유기 전기 발광 소자의 발광특성에 관한 연구)

  • Yoon, Hee-Chan;Shin, Hoon-Kyu;Kim, Byoung-Sang;Kim, Chung-Kyun;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.518-521
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    • 2002
  • New luminescent material, 6,11-Dihydroxy-5,12-naphthacenedione$(Alq_2-Ncd)$ was synthesized. And extended efforts have been made to obtain high-performance electro-luminescent(EL) devices, since the first report of organic light-emitting diodes(OLEDs) based on tris-(8-hydroxy-quinoline)aluminum$(Alq_3)$ Current-voltage characteristics, brightness-voltage characteristics, luminous efficiency and quantum efficiency were measured at room temperature. The maximum wavelength of the EL is at around 504nm and the brightness is up to $2702[cd/m^2]$ with the maximum efficiency up to 3.91 [1m/W]. This study indicates not only the sterical effect but also some other effect would be responsible for the change of the emission wavelength.

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Aerosol Synthesis of Gd2O3:Eu/Bi Nanophosphor for Preparation of Photofunctional Pearl Pigment as Security Material

  • Jung, Kyeong Youl;Han, Jang Hoon;Kim, Dae Sung;Choi, Byung-Ki;Kang, Wkang-Jung
    • Journal of the Korean Ceramic Society
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    • v.55 no.5
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    • pp.461-472
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    • 2018
  • $Gd_2O_3:Eu/Bi$ nanoparticles were synthesized via spray pyrolysis and applied for the preparation of a luminescent pearl pigment as an anti-counterfeiting material. The luminescence properties were optimized by changing the $Eu^{3+}$ and $Bi^{3+}$ concentration. Ethylene glycol was used as an organic additive to prepare the $Gd_2O_3:Eu/Bi$ nanoparticles. The highest emission intensity was achieved when the total dopant content was 10.0 at.% and the mole fraction of Bi was 0.1. The concentration quenching was mainly due to dipole-dipole interactions between the same activators, and the critical distances were 9.0 and $19.6{\AA}$ for $Eu^{3+}$ and $Bi^{3+}$, respectively. The prepared $Gd_2O_3:Eu/Bi$ powder exhibited an average size of approximately 82.5 nm and a narrow size distribution. Finally, the $Gd_2O_3:Eu/Bi$ nanophosphor coated on the surface of the pearl pigment was confirmed to have good red emission under irradiation from a portable ultraviolet light-emitting diode lamp (365 nm).

Indium Tin Oxide Thin Films Grown on Polyethersulphone (PES) Substrates by Pulsed-Laser Deposition for Use in Organic Light-Emitting Diodes

  • Kim, Kyung-Hyun;Park, Nae-Man;Kim, Tae-Youb;Cho, Kwan-Sik;Sung, Gun-Yong;Lee, Jeong-Ik;Chu, Hye-Yong
    • ETRI Journal
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    • v.27 no.4
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    • pp.405-410
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    • 2005
  • High quality indium tin oxide (ITO) thin films were grown by pulse laser deposition (PLD) on flexible polyethersulphone (PES) substrates. The electrical, optical, and surface morphological properties of these films were examined as a function of substrate temperature and oxygen pressure. ITO thin films, deposited by PLD on a PES substrate at room temperature and an oxygen pressure of 15 mTorr, have a low electrical resistivity of $2.9{\times}10^{-4}{\Omega}cm$ and a high optical transmittance of 84 % in the visible range. They were used as the anode in organic light-emitting diodes (OLEDs). The maximum electro luminescence (EL) and current density at 100 $cd/m^2$ were 2500 $cd/m^{2}$ and 2 $mA/m^{2}$, respectively, and the external quantum efficiency of the OLEDs was found to be 2.0 %.

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Synthesis of Eu3+ Doped (Y,Gd)BO3 Powder by Mechanochemical Process (기계 화학적 방법을 통한 Eu3+ 도핑된 (Y,Gd)BO3 형광체의 분말제조)

  • Won, Hee-Sub;Lee, Wan-Jae;Kim, Je-Seok;Hong, Gun-Young;Lee, Kun-Jae;Choa, Yong-Ho
    • Journal of Powder Materials
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    • v.15 no.2
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    • pp.136-141
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    • 2008
  • The mechanochemical process were employed to prepare the red phosphors (Y,Gd)$BO_3:Eu^{3+}$. The main factors affecting particle size, particle distribution, and luminescent properties of the product were investigated in details. Particles sized around 200-600 nm are formed after intensive milling. The phosphors were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and photoluminescence spectrum. Results revealed that phosphors with different morphology, small particle size and high luminescence intensity could be obtained by mechanochemical process.