• Title/Summary/Keyword: low-temperature-active

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Simulation Experiment of PEMFC Using Insulation Vessel at Low Temperature Region (저온영역에서 단열용기를 이용한 연료전지 모의 실험)

  • Jo, In-Su;Kwon, Oh-Jung;Kim, Yu;Hyun, Deok-Su;Park, Chang-Kwon;Oh, Byeong-Soo
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.5
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    • pp.403-409
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    • 2008
  • Polymer electrolyte membrane fuel cell (PEMFC) is very interesting power source due to high power density, simple construction and operation at low temperature. But it has problems such as high cost, improvement of performance, effect of temperature and initial start at low temperature. These problems can be approached to be solved by using experiment and mathematical method which are general principles for analysis and optimization of control system for heat and hydrogen detecting management. In this paper, insulation vessel and control system for stable operation of fuel cell at low temperature were developed for experiment. The constant temperature capability and the heating time at sub-zero temperatures with insulation control system were studied by using a heating bar of 60W class. PEMFC stack which was made by 4 cells with $50\;mc^2$ active area in each cell is a thermal source. Times which take to reach constant temperature by the state of insulation vacuum were measured at variable environment temperatures. The test was performed at two conditions: heating mode and cooling mode. Constant temperature capability was better at lower environment temperature and vacuum pressure. The results of this experiment could be used as basis data about stable operation of fuel cell stack in low temperature zone.

An Extremely Low Temperature Properties of Austenite Stainless Steels (오스테나이트 스테인리스강의 극저온 특성)

  • Jung, Chan-Hoi;Kim, Soon-Kook;Lee, Jun-Hee;Jeong, Se-Jin;Kim, Ik-Soo
    • Korean Journal of Materials Research
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    • v.17 no.1
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    • pp.37-42
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    • 2007
  • The effects of immersion time in the liquid nitrogen and deformation-induced martensitic transformation on the behavior of austenite stainless steels used for the hydrogen storage tank of auto-mobile at cryogenic temperature were investigated. With increasing of immersion time in the liquid nitrogen, the tensile strength of all austenite stainless steels at cryogenic temperature was increased because the martensite transformation of unstable austenite. The restraint of crack generation ana transmission also increased the tensile strength by the active ${\alpha}'$ transformation. The elongation decreasing of 321 steel is not the mechanical deformation of austenite phase but the stress induced martensite phase during the tensile test.

Low-temperature Synthesis of Graphene-CdLa2S4 Nanocomposite as Efficient Visible-light-active Photocatalysts

  • Zhu, Lei;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.52 no.3
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    • pp.173-179
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    • 2015
  • We report the facile synthesis of graphene-$CdLa_2S_4$ composite through a facile solvothermal method at low temperature. The as-prepared products were characterized by X-ray diffraction (XRD) and by Scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis and BET analysis, revealing the uniform covering of the graphene nanosheet with $CdLa_2S_4$ nanocrystals. The as-prepared samples show a higher efficiency for the photocatalytic degradation of typical MB dye compared with P25 and $CdLa_2S_4$ bulk nanoparticles. The enhancement of visible-light-responsive photocatalytic properties by decolorization of Rh.B dye may be attributed to the following causes. Firstly, graphene nanosheet is capable of accepting, transporting and storing electrons, and thus retarding or hindering the recombination of the electrons with the holes remaining on the excited $CdLa_2S_4$ nanoparticles. Secondly, graphene nanosheet can increase the adsorption of pollutants. The final cause is that their extended light absorption range. This work not only offers a simple way to synthesize graphene-based composites via a one-step process at low temperature but also a path to obtain efficient functional materials for environmental purification and other applications.

A Study on Exhaust Gas Characteristics of Heavy-duty Diesel Engines through Actual Vehicle Application of Non-influenced Temperature Condition Type Active Regeneration Method (온도조건 비영향형 복합재생방식 DPF의 실차적용을 통한 대형디젤기관의 배출가스 특성 연구)

  • Yun chul Lee;Sang ki Oh
    • Journal of ILASS-Korea
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    • v.29 no.2
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    • pp.53-59
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    • 2024
  • Cars are one of the main causes of air pollution in large cities, and 34.6% of domestic air pollution emissions come from mobile sources, of which cars account for 69.6%. In particular, the importance of nitrogen oxides (NOx) and particulate matter (PM), which are major pollutants in diesel vehicles, is increasing due to their high contribution to emissions. Therefore, in this study, the problem of natural regeneration caused by low exhaust gas temperature during low speed and low load operation was solved by applying a complex regeneration DPF that is not affected by temperature conditions to large diesel vehicles with higher driving time and engine displacement than small and medium-sized vehicles. And the feasibility of application to large diesel vehicles was reviewed by measuring the emission reduction efficiency. As a result of the reduction efficiency test on the actual vehicle durability product, PM showed a reduction efficiency of 84% to 86%, and the reduction efficiency of gaseous substances showed a high reduction efficiency of over 90%. The actual vehicle applicability test was completed with three driving patterns: village bus vehicle, police car, and road-going construction equipment vehicle, and no device problems occurred until the end of the test. Both load and no-load smoke measurement results showed a smoke reduction efficiency of over 96%.

Acquired resistance of rock bream (Oplegnathus fasciatus) against rock bream iridovirus (RBIV) through undergoing low water temperature period

  • Zenke, Kosuke;Yoon, Ki Joon;Kim, Min Sun;Choi, Seung Hyuk;Kim, Ki Hong
    • Journal of fish pathology
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    • v.27 no.2
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    • pp.85-89
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    • 2014
  • Water temperature is a key environmental factor controlling the epizootics of viral diseases in fish. High water temperature is associated with the rapid spread of rock bream iridovirus (RBIV) disease and with high mortality of RBIV infected fish. Although protection of fish against iridoviral disease by active immunization has been reported, little information is available concerning whether fish survived from an epizootic of iridoviral disease can naturally acquire resistance against the viral disease. In the present study, we have demonstrated that juvenile rock bream, which survived from a natural epizootic of RBIV, acquired resistance against recurrence or reinfection of RBIV, and this resistance was established during the subsequent low water temperature period. Furthermore, the possible involvement of the adaptive humoral immune response in the resistance of the juvenile rock bream was suggested by in vivo neutralization experiment.

AKARI OBSERVATIONS OF DUSTY TORI OF ACTIVE GALACTIC NUCLEI

  • Oyabu, Shinki;Kaneda, Hidehiro;Izuhara, Masaya;Tomita, Keisuke;Ishihara, Daisuke;Kawara, Kimiaki;Matsuoka, Yoshiki
    • Publications of The Korean Astronomical Society
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    • v.32 no.1
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    • pp.157-161
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    • 2017
  • The dusty torus of Active Galactic Nuclei (AGNs) is one of the important components for the unification theory of AGNs. The geometry and properties of the dusty torus are key factors in understanding the nature of AGNs as well as the formation and evolution of AGNs. However, they are still under discussion. Infrared observation is useful for understanding the dusty torus as thermal emission from hot dust with the dust sublimation temperature (~ 1500 K) has been observed in the infrared. We have analyzed infrared spectroscopic data of low-redshift and high-redshift quasars, which are luminous AGNs. For the low-redshift quasars, we constructed the spectral energy distributions (SEDs) with AKARI near-infrared and Spitzer mid-infrared spectra and decomposed the SEDs into a power-law component from the nuclei, silicate features, and blackbody components with different temperatures from the dusty torus. From the decomposition, the temperature of the innermost dusty torus shows the range between 900-2000 K. For the high-redshift quasars, AKARI traced rest-frame optical and near-infrared spectra of AGNs. Combining with WISE data, we have found that the temperature of the innermost dusty torus in high redshift quasars is lower than that in typical quasars. The hydrogen $H{\alpha}$ emission line from the braod emission line region in the quasars also shows narrow full width at half maximum of $3000-4000km\;s^{-1}$. These results indicate that the dusty torus and the broad emission line region are more extended than those of typical quasars.

Differential Recovery of Photosystem II Complex from Low-Temperature Photoinhibition in Plants with Different Chilling Sensitivity

  • Moon, Byoung-Yong;Norio Murata
    • Journal of Photoscience
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    • v.7 no.2
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    • pp.39-44
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    • 2000
  • To examine the chilling tolerance lipids, we compared the chilling susceptibility of photosystem II of wild type tobacco plants with that of transgenic tobacco plants, in which the sensitivity to chilling had been enhanced by genetic modification of fatty acid unsaturation of chloroplast membrane lipids. The transgenic tobacco plants were found to contain reduced levels of unsaturated membrane fatty acids by being tansformed with cDNA for glycerol-3-phosphate acyltransferase from squash. For the purpose of studying on the functional integrity of photosystem II during low-temperature photoinhibition, the photochemical efficiency was measured as the ration of the maximun fluorescence of chlorophyll (Fv/Fm) of photosystem II. In parallel with an investigation on the transgenic plants, susceptibility of chilling-resistant species, such as spinah and pea, and of chilling-sensitive ones, such as squash and sweet potato, to low-temperature photoinhibition was also compared in terms of room temperature-induced chlorophyll fluorescence from photosystem II. When leaf disks from the two genotypes of tobacco plants were exposed to light at 5$^{\circ}C$, the transgenic plants showed more rapid decline in photochemical activity of photosysytme II than wild-type plants. When they were pretreated with lincomycin, an inhibitor of chloroplast-encoded protein synthesis, the extent of photoinhibition was even more accelerated. More impottantly, they showed a comparable extent of photoinhibition in the presence of lincomycin, making a clear contrast to the discrepancy observed in the discrepancy observed in the absence of lincomycin. Restoration of Fv/Fm during recovery from low-temperature photoinhibition occurred more slowly in the transgenic tobacco plants than the wild-type. These findings are discussed in relation to fatty acid unsaturation of membrane phosphatidylglycerol. It appears that the ability of plants to rapidly regenerate the active photosystem II complex from might explain, in part, why chilling-resistant plants can toleratlow-temperature photoinhibition.

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Water-Assisted Synthesis of Carbon Nanotubes at Low Temperature and Low Pressure (물을 첨가한 탄소나노튜브의 저온 저압 합성)

  • Kim, Young-Rae;Jeon, Hong-Jun;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.395-395
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    • 2008
  • Water-assisted synthesis of carbon nanotubes (CNTs) has been intensively studied in recent years, reporting that water vapor enhances the activity and lifetime of metal catalyst for the CNT growth. While most of these studies has been focused on the supergrowth of CNTs at high temperature, rarely has the similar approach been made for the CNT synthesis at low temperature. Since the metal catalyst are much less active at lower temperature, we expect that the addition of water vapor may increase the activity of catalyst more largely at lower temperature. We synthesized multi-walled CNTs at temperature as low as $360^{\circ}C$ by introducing water vapor during growth. The water addition caused CNTs to grow ~3 times faster. Moreover, the water-assisted growth prolonged the termination of CNT growth, implying the enhancement of catalyst lifetime. In general, a thinner catalyst layer is likely to produce smaller-diameter, longer CNTs. In a similar manner, the water vapor had a greater effect on the growth of CNTs for a smaller thickness of catalyst in this study. To figure out the role of process gases, CNTs were grown in the first stage and then exposed to each of process gases in the second stage. It was shown that water vapor and hydrogen did not etch CNTs while acetylene led to the additional growth of CNTs even faster in the second stage. As-grown CNTs were characterized by scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), atomic force microscopy (AFM), and Raman spectroscopy.

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Electrochemical Properties of MnO$_2$electrode for supercapactor wish a Diffuser (Polyvinylalcohol) (분산제 PVA에 따른 수퍼커패시터용 이산화망간전극의 전기 화학적 특성)

  • 이상오;김한주;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.753-756
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    • 2001
  • This research made a study of MnO$_2$electrode for supercapacitor with a diffuser (Polyvinyl alcohol). Manganese dioxide was used as active material. We tried to increase specific surface area by adding PVA. Manganese dioxide was synthesized by a sol-gel method using fumaric acid and oxalic acid in low temperature with high yield. Therefore, We prepared Manganese dioxide powder. This powder was used by active materials. The electrode was made by a mixture of active material, ketjen-black which is a large specific surface area, and PVdF-co-HFP as binder agent with using Nickel mesh as current collector. Here we reported on the synthesis and electrochemical performance of a enhanced material. All active materials have been submitted to X-ray diffraction and Scanning electron microscopy.

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Physio-chemical studies on the seed browning in mature green peppers stored at low-temperature (Part 1) -Changes in between-step metabolites and substrates in the seed-browning effect- (녹숙(綠熟)고추의 저온저장(低溫貯藏)에 따른 종자갈변(種子褐變)에 관(關)한 생리화학적연구(生理化學的硏究) -제 1 보(第 1 報) 종자갈변(種子褐變)에 관계(關係)되는 기질(基質)과 중간대사성분(中間代謝成分)의 변화(變化)-)

  • Lee, Sung-Woo
    • Korean Journal of Food Science and Technology
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    • v.3 no.1
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    • pp.29-36
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    • 1971
  • When a low-temperature treatment was given to a small sweet pepper variety Zairaisisi, the seed browning effect appeared soon. This change attracted the studies to determine and discuss the browning metabolites, polyphenolic compounds, and changes in their between-step components. (1) Chlorogenic acids were found as a polyphenolic compound in seed, whereas no flavanol-type polyphenol was observed. (2) There was sharp increase in total polyphenol content and chlorogenic acid with a low-temperature treatment. The contents of these substrates dropped below that of room-temperature treatment after the browning effect took place. (3) A marked increase in between-step metabolites phenylalanine, tyrosine, shikimic acid contents, and thus assumed activated shikimate pathway in this process. (4) It was suggested by determining the effect of specific metabolic inhibition and respiratory inhibitor administrations on enzymes that active biosynthesis of polyphenolic compounds takes place in shikimate pathway with combination of phosphoenolpyruvate and erythrose-4-phosphate connected to TCA cycle jaming after an active EMP pathway was gone through with sugars in pepper seeds at a low-temperature. (5) It was also suggested from the observation of increased K ion flow-out in pepper seeds with a low-temperature treatment that there is an abnormality in the plasma membrance.

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