• Korean Journal of Metals and Materials
• /
• v.47 no.3
• /
• pp.155-168
• /
• 2009

In this study, microstructural investigation was conducted on the separation phenomenon occurring during Charpy impact tests of API X80 linepipe steels. Particular emphasis was placed on the role of microstructural phases present in the API X80 steels such as acicular ferrite, bainite, and hard secondary phases. Detailed microstructural analysis of fractured impact specimens showed that highly elongated bainite worked as prior initiation sites for separations, and that the number and length of separations increased with increasing volume fraction of bainite. In the steels having high work hardenability, tearing-shaped separations were found because the hammer-impacted region was seriously hardened during the impact test, which led to the reduction in the impact toughness. As the test temperature decreased, the tendency of separations increased, but separations were not observed when the cleavage fracture prevailed at very low temperatures. Thus, the minimization of the formation of bainite and secondary phases in the steels would be beneficial for preventing or minimizing separations because separations deteriorated low-temperature impact toughness.

• Journal of the Korean Society for Heat Treatment
• /
• v.13 no.5
• /
• pp.346-354
• /
• 2000

Effect of Nb addition on the phase transformation behavior was studied through continuous cooling transformation tests after reheating(reheating CCT) and deforming(deforming CCT) the 0.07%C-1.3%Mn-0.015%Ti-(0~0.08)% Nb steels. Transformation temperatures for deforming CCT were lower than those for reheating CCT, and the critical cooling rate for bainite transformation during deforming CCT was lower than that during reheating CCT. These enhanced hardenability for deforming CCT was considered to come from the sufficient solid solution of Nb in austenite during high temperature reheating before deformation. With Nb addition, the phase transformation temperature decreased, the bainite formation was enhanced, and the hardness of steel increased. Furthermore, these phenomena were more remarkable for deforming CCT than for reheating CCT. From the results, Nb-Ti bearing low carbon steel was considered to be a very favorable alloy system with good strength/toughness balance by recrystallization control rolling process.

• Journal of the Korean Ceramic Society
• /
• v.46 no.5
• /
• pp.534-539
• /
• 2009

Reaction Bonded Silicon Carbide(RBSC) has been used for engineering ceramics due to low-temperature fabrication and near-net shape products with excellent structural properties such as thermal shock resistance, corrosion resistance and mechanical strength. Recently, attempts have been made to develop hot gas filter with gradient pore structure by RBSC to overcome weakness of commercial clay-bonded SiC filter such as low fracture toughness and low reliability. In this study a fabrication process of porous RBSC with multi-layer pore structure with gradient pore size was developed. The support layer of the RBSC with multi-layer pore structure was fabricated by conventional Si infiltration process. The intermediate and filter layers consisted of phenolic resin and fine SiC powder were prepared by dip-coating of the support RBSC in slurry of SiC and phenol resin. The temperature of $1550^{\circ}C$ to make Si left in RBSC support layer infiltrate into dip-coated layer to produce SiC by reacting with pyro-carbon from phenol resin.

• International Journal of Highway Engineering
• /
• v.10 no.3
• /
• pp.239-246
• /
• 2008

In this study, the influence of reaction temperatures, mixing time and flexible modifier for crumb rubber modified asphalt(CRMA) as processing conditions were investigated. The temperature susceptibility and adhesion properties of neat and modified asphalts at low temperature measured using the penetration and tensile adhesion test. It was found that processing temperatures and flexible modifier were important factors for tensile adhesion strength and toughness energy at low temperature. The CRMA in the higher processing temperature and flexible modifier exhibited improved tensile adhesion properties which indicated the flexible structure of neat and modified asphalt binder. In general, the improvements of the physical properties in the CRMAs were due to the improvements of miscibility between CR and asphalt binder. It was found that the adhesion properties of the flexible agent modified CRMA were higher than CRMA were related to the flexible agent tend to penetrate into CR particles and asphalt binder.

• Korean Journal of Metals and Materials
• /
• v.48 no.2
• /
• pp.122-132
• /
• 2010

Higher strength and fracture toughness of reactor pressure vessel steels can be obtained by changing the material specification from that of Mn-Mo-Ni low alloy steel (SA508 Gr.3) to Ni-Mo-Cr low alloy steel (SA508 Gr.4N). However, the operation temperature of the reactor pressure vessel is more than $300^{\circ}C$ and the reactor operates for over 40 years. Therefore, we need to have phase stability in the high temperature range in order to apply the SA508 Gr.4N low alloy steel for a reactor pressure vessel. It is very important to evaluate the temper embrittlement phenomena of SA508 Gr.4N for an RPV application. In this study, we have performed a Charpy impact test and tensile test of SA508 Gr.4N low alloy steel with changing impurity element contents such as Mn and P. And also, the mechanical properties of these low alloy steels after longterm heat treatment ($450^{\circ}C$, 2000hr) are evaluated. Further, evaluation of the temper embrittlement by fracture analysis was carried out. Temper embrittlement occurs in KL4-Ref and KL4-P, which show a decrease of the elongation and a shifting of the transition curve toward high temperature. The reason for the temper embrittlement is the grain boundary segregation of the impurity element P and the alloying element Ni. However, KL4-Ref shows temper embrittlement phenomena despite the same contents of P and Ni compared with SC-KL4. This result may be caused by the Mn contents. In addition, the behavior of embrittlement is not largely affected by the formation of $M_3P$ phosphide or the coarsening of Cr carbides.

• Korean Journal of Materials Research
• /
• v.31 no.3
• /
• pp.139-149
• /
• 2021

In this study, three kinds of bainitic steels are fabricated by controlling the contents of vanadium and boron. High vanadium steel has a lot of carbides and nitrides, and so, during the cooling process, acicular ferrite is well formed. Carbides and nitrides develop fine grains by inhibiting grain growth. As a result, the low temperature Charpy absorbed energy of high vanadium steel is higher than that of low vanadium steel. In boron added steel, boron segregates at the prior austenite grain boundary, so that acicular ferrite formation occurs well during the cooling process. However, the granular bainite packet size of the boron added steel is larger than that of high vanadium steel because boron cannot effectively suppress grain growth. Therefore, the low temperature Charpy absorbed energy of the boron added steel is lower than that of the low vanadium steel. HAZ (heat affected zone) microstructure formation affects not only vanadium and boron but also the prior austenite grain size. In the HAZ specimen having large prior austenite grain size, acicular ferrite is formed inside the austenite, and granular bainite, bainitic ferrite, and martensite are also formed in a complex, resulting in a mixed acicular ferrite region with a high volume fraction. On the other hand, in the HAZ specimen having small prior austenite grain size, the volume fraction of the mixed acicular ferrite region is low because granular bainite and bainitic ferrite are coarse due to the large number of prior austenite grain boundaries.

• Journal of the Korean Society of Industry Convergence
• /
• v.23 no.1
• /
• pp.25-32
• /
• 2020

Generally, high-temperature, high-pressure, high-priced sintering equipment is used for diamond sintering, and conductivity is a problem for improving the surface modification of the sintered body. In this study, to improve the efficiency of diamond sintering, we identified a new process and material that can be sintered at low temperature, and attempted to develop a composite thin film that can be discharged by doping boron gas to improve the surface modification of the sintered body. Sintered bodies were sintered by mixing Si and two diamonds in different particle sizes based on CIP molding and HIP molding. In CVD deposition, CVD was performed using WC-Co cemented carbide using CH₄ and H₂ gas, and the specimen was made conductive using boron gas. According to the experimental results of the sintered body, as the Si content is increased, the Vickers hardness decreases drastically, and the values of tensile strength, Young's modulus and fracture toughness greatly increase. Conductive CVD deposited diamond was boron deposited and discharged. As the amount of boron added increased, the strength of diamond peaks decreased and crystallinity improved. In addition, considering the release processability, tool life and adhesion of the deposition surface according to the amount of boron added, the appropriate amount of boron can be confirmed. Therefore, by solving the method of low temperature sintering and conductivity problem, the possibility of solving the existing sintering and deposition problem is presented.

• Proceedings of the KWS Conference
• /
• v.43
• /
• pp.141-143
• /
• 2004

The experimental simulation welds using 3kinds of 70ksi titania based flux-cored consumables were performed on 24 inches 24.6-thick API 5L Gr. B pipe with relatively high current, over 300A and four different Post Weld Heat Treaonent(PWHT) conditions at $625^{circ}C$ were applied to each consumable test coupon. It is well known that, in common welding processes such as Submerged Arc Welding(SAW) or Flux Cored A.c Welding(FCAW), the cooling rates in as-deposited weld bead are normally so ,apid that actual precipitation of microalloy carbonitrides, Nb(C,N) or V(C,N) is not likely to occur in the as-welded weld metal, however, during stress relief or PWHT the operation of precipitation can reduce the impact properties of the weld metal. As results of mechanical testing, it is concluded that PWHT at $625^{circ}C$ is detrimental to weld metal impact toughness of Ti-B type flux- cored (FC) welding consumables regardless of the amount of Nb and V, but two optima were exhibited, one at 800ppm Ti, 75ppm 5 and another 360ppm Ti, 54ppm 5.

• Journal of the Korean Society for Heat Treatment
• /
• v.27 no.3
• /
• pp.121-126
• /
• 2014

High-nitrogen Fe-18Mn-18Cr-N austenitic steels with higher yield strength have been recently developed and used for generator retaining rings because they have non-magnetic, high strength, high ductility, and good corrosion resistance. In the present study, a high-nitrogen Fe-18Mn-18Cr-0.61N austenitic steel was fabricated and then tensile and Charpy impact tests were conducted on them in order to investigate the effect of cold working on the mechanical properties. Although the yield and tensile strengths usually increased with cold working, the ductility and impact toughness significantly decreased after cold working. On the other hand, the high-nitrogen austenitic steel exhibited a ductile-brittle transition due to unusual brittle fracture at low temperatures despite having a face-centered cubic structure. The ductile-brittle transition temperature obtained from Charpy impact tests could be remarkably increased by $60^{\circ}C$ after 20% cold working because of the enhanced cleavage-like brittle fracture.

• Journal of the Korean Ceramic Society
• /
• v.35 no.7
• /
• pp.659-664
• /
• 1998

Densification behavior of $Si_3N_4$ ceramics by two step gas pressure sintering was compared with pres-sureless sintering one step gas pressure sintering or hot isostatic pressing. While it was difficult to get the highly interlocked ${\beta}-Si_3N_4$ microstructure during the pressureless sintering due to decomposition above $1800^{\circ}C$ gas pressure sintering could solve this problem by increasing the densification temperature 2MPa of nitrogen pressure was enough to inhibit the decomposition up to $1890^{\circ}C$ and especially two step gas pres-sure sintering applying comparatively low pressure(2MPa) until the closed pore stage and then high pres-sure(10MPa) after pore closure could increase the hardness and the toughness.