• 한국표면공학회지
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• 제45권4호
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• pp.174-180
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• 2012

Low pressure inductively coupled plasma characteristics of argon and oxygen are numerically simulated for a 400 mm rectangular type system with a plasma fluid model. The results showed lower power absorption profile at the corner than a circular one in a 13.56 MHz driven 1.5 turn antenna system with a drift-diffusion and quasi-neutrality assumption. Ions controlled by electric field are more non-uniform than metastables and the power absorption profile of oxygen plasma is affected by horizontal gas flow pattern to show 25% lower power absorption at the pumping flange side. Oxygen negative ions which are generated in electron collisional dissociation of oxygen molecules was calculated as 0.1% of oxygen atoms with similar spatial profile.

• 한국재료학회:학술대회논문집
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• 한국재료학회 1993년도 추계 학술발표 강연 및 논문 개요집
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• pp.69-71
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• 1993

Fluoride compound potentiometric cell oxygen sensors were fabricated for the measurement of oxygen pressure in the low temperature range (300。K-500。K). The disk type sensors consist of a reference Air(0$_2$):Ag, a solid electrolyte SrF$_2$, and a sensing metel Ag electrode. And the buried reference electrode type sensor have a NiO/Ni reference electrode. The open circuit emf of the cell showed high sensivity to oxygen gas (60mv) at the measuring temperature 20$0^{\circ}C$. Also, The buried reference electrode type sensor showed 30mv from 1% to 10% oxygen pressure range.

• Bulletin of the Korean Chemical Society
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• 제18권6호
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• pp.640-643
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• 1997

Pure titanium dioxide $(TiO_2)$ films were prepared by pulsed laser deposition on a single crystal Si(100) substrate. We have investigated the growth of crystalline titanium dioxide films with respect to substrate temperature and ambient oxygen pressure. The structural properties of the films were analyzed by X-ray diffraction. We found that the anatase as well as the rutile phases could be formed from the original rutile phase of the target $TiO_2$. At 0.75 torr of ambient oxygen pressure, the structure of $TiO_2$ film was amorphous at room temperature, anatase between 300 and 600 ℃, a mixture of anatase and rutile between 700 and 800 ℃, and only rutile at 900 ℃ and above. However, at a low ambient oxygen pressure, the rutile phase became dominant; the only rutile phase was obtained at the ambient oxygen pressure of 0.01 torr and the substrate temperature of 800 ℃. Therefore, the film structures were largely influenced by substrate temperature and ambient oxygen pressure.

• Bulletin of the Korean Chemical Society
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• 제20권3호
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• pp.281-284
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• 1999

Two La1.82Ca1.18Cu2O6+δ (2126) compounds exhibited different properties depending upon how they were synthesized. The compound prepared under high oxygen pressure showed superconductivity. But the compound prepared under low oxygen pressure did not exhibit superconductivity, and showed a metal-insulator transition. Our study on these compounds shows that a small amount of additional oxygen intercalated into the superconducting phase plays an important role for superconductivity. The Fermi surface of non-superconducting 2126 compound possesses nesting phenomena, which is the reason for the M-1 transition. On the other hand, the superconducting 2126 compound does not show Fermi surface nesting. This is because the additional oxygen removes some electrons from Cu d-orbitals, thereby bradking the Fermi surface nesting.

• 센서학회지
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• 제21권3호
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• pp.229-234
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• 2012

The existing permeability measurements based on pressure differential between the polymer membrane that is permeable to measure the amount of oxygen used, but these methods must be kept in a vacuum, and the measurement of the membrane with low permeability in the membrane is too time consuming. In recent years by using electrochemical method polymer membrane currents caused by the amount of oxygen is a measure of how much is used. In this study, apparatus consisting of one anode and six cathodes for multi-oxygen permeability tester used the same number of membranes produced by electrochemical oxygen permeation characteristics. In this study, one silver/silver chloride anode electrochemical method with a hexagonal sensor to put various kinds of polymer membranes with the six oxygen permeability for simultaneous measurement in real-time systems. Six cathodes (Pt), and one of the coil-shaped anode (Ag/AgCl) to form a hexagonal one of the polarographic oxygen sensor in a single measurement system by six sensors. Each sensor for making hexagonal specificity of the sensor to compensate for the conditions obtained in a pure nitrogen gas and pure oxygen gas conditions. With this study, self-developed hexagonal sensor capable of measuring sensors and oxygen permeability tester, for a multi-six different oxygen permeability characteristics of the membrane measured at the same time.

• 한국군사과학기술학회지
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• 제20권5호
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• pp.620-632
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• 2017

A chemical vapor curing method(CVC) was developed to cure polycarbosilane(PCS) fibers by using cyclohexene vapour as a non-oxygen active reactant, instead of air in oder to prepare the silicon carbide(SiC) fiber with low oxygen content. A cross-linked PCS fibers by cyclohexene vapor showed a completely different variation in IR spectra in comparison to the air-cured PCS fiber. CVC method resulted in less than 3 wt% in oxygen content. In this experiment conditions, The average tensile strength and modulus of SiC fiber obtained by CVC had 1995 MPa and 183 GPa respectively, which is higher than that of SiC fiber prepared by air-curing process.

• 한국환경과학회지
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• 제11권6호
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• pp.577-582
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• 2002

Selective catalytic reduction and selective non-catalytic reduction processes are mainly used to treat nitrogen oxidants generated from fossil-fuel combustion. Especially, the selective non-catalytic reduction process can be operated more economical and designed more simply than the selective catalytic reduction. For this reason, many researchers carried out to increase the removal efficiency of nitrogen oxidants in the condition of low oxygen concentration by using the selective non-catalytic reduction process. However, this study was flue gas contained high oxygen concentration of 20(v/v%) with ammonia as a reducing agent. Moreover, it carried out experiment with many factors that are reaction temperature, retention time, initial NO concentration, NSR(normalized stoichiometric ratio). It was determined optimal operating conditions to improve NO removal efficiency with SNCR process. The De-NOx efficiency was increased with NSR, initial NO concentration and retention time increasement. This study has NO removal efficiency over 80% in the high oxygen concentration as well as low oxygen concentration. The injection of reducing agent may be considered for SNCR process and facility operation in 850$\^{C}$ of optimal condition.

• 한국해양학회지
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• 제22권4호
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• pp.246-256
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• 1987

鎭海灣一帶 海域에서 夏季 底層 溶存酸素표의 缺乏현상과 底棲生物量과의 關 係를 밝히기 위하여 1983年 9月 底棲生物의 生態學的 調査를 실시하였다. 일반적으 로 底層의 溶存酸素量이 낮은 地域에서는 底棲生物量과 個體數가 현저히 감소하였 다. 底層의 溶存酸素量이 2.0$m\ell$/$\ell$이하 그리고 酸素飽和度 40% 이하인 貧酸素 海域 이 전체 調査海域 497km$^{2}$의 54%를 차지하는 266km$^{2}$에 걸쳐 광범위하 게 발달하고 있음이 밝혀졌으며, 특히 馬山灣, 行岩灣, 古縣域灣, 加助島 西側의 元 門灣, 鎭海灣 中央部등이 영향을 받는 것으로 나타났다.

• Journal of Magnetics
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• 제13권2호
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• pp.61-64
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• 2008

We studied the effect of the variation of the lattice constant on the electrical properties of $SrRuO_3$ thin films. In order to obtain films with different volumes, we varied the substrate temperature and oxygen pressure during the growth of the films on $SrTiO_3$ (001) substrates. The films were grown using a pulsed laser deposition method. The X-ray diffraction patterns of the grown films at low temperature and low oxygen pressure indicated the elongation of the c-axis lattice constant compared to that of the films grown at a higher temperature and higher oxygen pressure. The in-plane strain states are maintained for all of the films, implying the expansion of the unit-cell volume by the oxygen vacancies. The variation of the electrical resistance reflects the temperature dependence of the resistivity of the metal, with a ferromagnetic transition temperature inferred form the cusp of the curve being observed in the range from 110 K to 150 K. As the c-axis lattice constant decreases, the transition temperature linearly increases.

• 한국수소및신에너지학회논문집
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• 제23권2호
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• pp.173-182
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• 2012

Effects of temperature, pressure, and gas residence time on methane combustion characteristics of mass produced oxygen carrier particle (OCN706-1100) were investigated in a pressurized fluidized bed reactor using methane and air as reactants for reduction and oxidation, respectively. The oxygen carrier showed high fuel conversion, high $CO_2$ selectivity, and low CO concentration at reduction condition and very low NO emission at oxidation condition. Moreover OCN706-1100 particle showed good regeneration ability during successive reduction-oxidation cyclic tests up to the 10th cycle. Fuel conversion and $CO_2$ selectivity decreased and CO emission increased as temperature increased. These results can be explained by trend of calculated equilibrium CO concentration. However, $CO_2$ selectivity increased as pressure increased and fuel conversion increased as gas residence time increased.