• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2002.11a
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• pp.171-184
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• 2002

Approx. 200,000 bpd vacuum residue oil is produced from oil refineries in Korea. These are supplying to use asphalt, high sulfur fuel oil, and upgrading at the residue hydro-desulfurization unit. Vacuum residue oil has high energy content, however high sulfur content and high concentration of heavy metals represent improper low grade fuel. To meet growing demand for effective utilization of vacuum residue oil from refineries, recently some of the oil refinery industries in Korea, such as SK oil refinery and LG Caltex refinery, have already proceeded feasibility study to construct 435-500 MWe IGCC power plant and hydrogen production facilities. Recently, KIER(Korea Institute of Energy Research) are studing on the Vacuum Residue gasification process using an oxygen-blown entrained-flow gasifier. The experiment runs were evaluated under the reaction temperature : 1,100~1,25$0^{\circ}C$, reaction pressure : 1~6kg/$\textrm{cm}^2$G, oxygen/V.R ratio : 0.8~0.9 and steam/V.R ratio : 0.4-0.5. Experimental results show the syngas composition(CO+H$_2$) : 85~93%, syngas flow rate : 50~110Mm$^3$/hr, heating value : 2,300~3,000 ㎉/Nm$^3$, carbon conversion : 65~92, cold gas efficiency : 60~70%. Also equilibrium modeling was used to predict the vacuum residue gasification process and the predicted values were compared reasonably well with experimental data.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.5
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• pp.507-516
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• 2010

Stationary combustion sources such as coal-fired power plants, waste incinerators, industrial manufacturing, etc. are recognized as major sources of mercury emissions. Due to rapid economic growth, zinc production in Korea has increased significantly during the last 30 years. Total zinc production in Korea exceeded 739,000 tons in 2008, and Korea is currently the third largest zinc producing country in the world. Previous studies have revealed that zinc smelting has become one of the largest single sectors of total mercury emissions in the World. However, studies on this sector are very limited, and a large gap in the knowledge regarding emissions from this sector needs to be bridged. In this paper, Hg emission measurements were performed to develop emission factors from zinc smelting process. Stack sampling and analysis were carried out utilizing the Ontario Hydro method and US EPA method 101A. Preliminary data showed that $Hg^0$ concentrations in the flue gas ranged from 4.56 to $9.90\;{\mu}g/m^3$ with an average of $6.40\;{\mu}g/m^3$, Hg(p) concentrations ranged from 0.03 to $0.09\;{\mu}g/m^3$ with an average of $0.04\;{\mu}g/m^3$, and RGM concentrations ranged from 0.23 to $1.17\;{\mu}g/m^3$ with an average of $6.40\;{\mu}g/m^3$. To date, emission factors of 7.5~8.0 g/ton for Europe, North America and Australia, and of 20 or 25 g/ton for Africa, Asia and South America are widely accepted by researchers. In this study, Hg emission factors were estimated using the data measured at the commercial facilities as emissions per ton of zinc product. Emission factors for mercury from zinc smelting pross ranged from 4.32 to 12.96 mg/ton with an average of 8.31 mg/ton. The emission factors that we obtained in this study are relatively low, considering Hg contents in the zinc ores and control technology in use. However, as these values are estimated by limited data of single measurement of each, the emission factor and total emission amount must be updated in future.

• Journal of Korea Water Resources Association
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• v.36 no.6
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• pp.1069-1082
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• 2003

The Cheongdocheon has the reaches under reduction of stream flow. We analysed the cause of the reduction. We investigated the current status of facilities for agricultural water use. We also compared the discharge measurements with the results from the continuous simulation of watershed runoff The satellite image was a tool to find some reaches of stream flow reduction under doubt. Agricultural reservoirs block up the stream and water does not flow over the reservoirs except by storm. They also discharge water through diversion channels and the water diverted does not flow through the natural stream. Farmers directly take water from the stream by weirs. The infiltration gallery of water below the stream ground makes the reach dryness perfect in Kamakchon. These are causes of the stream flow reduction. The discharge measurements are less than the simulation results of watershed runoff, and we guess that the reaches investigated have dried. We found the reaches of stream flow reduction that were under doubt from some KOMPSAT satellite images with the resolution of 6.6 m. Then, we confirmed the reduction of stream flow by a field investigation. All the above reaches have infiltration galleries of water below the stream ground. The research results are a case study on the cause analysis on the reduction of stream flow. One can obtain the KOMPSAT image for a low price and can get prior information to find the doubtful reach of stream flow reduction.

• Journal of the Mineralogical Society of Korea
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• v.26 no.1
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• pp.27-34
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• 2013

X-ray powder diffraction is one of the most powerful techniques for qualitative and quantitative analysis of crystalline compounds. Thus, there exist a number of different methods for quantifying mineral mixtures using X-ray diffraction pattern. We present here the use of Rietveld and PONKCS (partial or no known crystal structure) methods for quantification of amorphous and crystallized mineral phases in synthetic mixtures of standard minerals (amorphous silica, quartz, mullite and corundum). Pawley phase model of amorphous silica was successfully built from the pattern of 100 wt% amorphous silica and internal standard-spiked samples by PONKCS approach. The average of absolute bias for quantities of amorphous silica was 1.85 wt%. The larger bias observed for lower quantities of amorphous silica is probably explained by low intensities of diffraction pattern. Averages of absolute bias for minerals were 0.53 wt% for quartz, 0.87 wt% for mullite and 0.57 wt% for corundum, respectively. The PONKCS approach achieved improved quantitative results compared with classical Rietveld method by using an internal standard.

• Journal of Energy Engineering
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• v.12 no.1
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• pp.49-57
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• 2003

Approx. 200.000 bpd vacuum residue oil is produced from oil refineries in Korea, and is supplied to use asphalt, high sulfur fuel oil and for upgrading at the residue hydro-desulfurization unit. Vacuum residue oil has high energy content, however its high sulfur content and high concentration of heavy metals represent improper low grade fuel. To meet growing demand for effective utilization of vacuum residue oil from refineries, recently some of the oil refinery industries in Korea, such as SK oil refinery and LG Caltex refinery, have already proceeded feasibility study to construct 435~500 MWe IGCC power plant and hydrogen production facilities. Recently, KIER (Korea Institute of Energy Research) are studying on the Vacuum Residue gasification process using an oxygen-blown entrained-flow gasifier. The experiment runs were evaluated under the reaction temperature: 1.100~l,25$0^{\circ}C$, reaction pressure: 1~6 kg/$\textrm{cm}^2$G, oxygen/V.R ratio: 0.8~0.9 and steam/V.R ratio: 0.4~0.5. Experimental results show the syngas composition (CO+H$_2$): 85~93%, syngas flow rate: 50~l10 Nm$^3$/hr, heating value: 2,300~3,000 k㎈/Nm$^3$, carbon conversion: 65~92, cold gas efficiency: 60~70%. Also equilibrium modeling was used to predict the vacuum residue gasification process and the predicted values were compared reasonably well with experimental data.

• The Journal of Engineering Geology
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• v.27 no.3
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• pp.293-304
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• 2017

This study was performed in order to hydrogeological analysis of aquifer, which is a necessary part for evaluating the efficiency of the combined well and open-closed loops geothermal (CWG) systems. CWG systems have been proposed for the effective utilization of geothermal energy by combining open loop geothermal systems and closed loop geothermal systems. Small aperture CWG systems and large aperture CWG systems were installed at a green house land with water curtain facilities in Chungju City. Aquifer tests include pumping tests and step-drawdown tests were conducted to analyse hydrogeological characteristics of aquifer in the study area. The transmissivity was estimated in the range of $13.49{\sim}58.99cm^2/sec$, and the storativity was estimated in the range of $1.13{\times}10^{-5}{\sim}5.20{\times}10^{-3}$. The geochemical analysis showed $Ca^{2+}$ ion and ${HCO_3}^-$ ion were dominant in groundwater. The Langelier Saturation Index and the Ryznar Stability Index showed low scaling potential of groundwater. In the analysis of vertical water temperature change, the geothermal gradient was estimated as $2.1^{\circ}C/100m$, which indicated the aquifer was enough for geothermal systems. In conclusion, groundwater is rich, can stably use geothermal heat, and it is less likely to cause deterioration of thermal energy efficiency by precipitation of carbonate minerals in study area. Therefore, the study area is suitable for installation of the combined geothermal system.

• Journal of Korean Tunnelling and Underground Space Association
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• v.14 no.1
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• pp.1-22
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• 2012

This paper tried to verify whether the fixed fire fighting system (FFFS) that is installed in road tunnel improves evacuation performance or not. Verification was performed according to the Disaster Prevention Facilities Installation and Management Guide at Road Tunnel. Twenty seven different fire scenarios were set up for the verification and the cases that FFFS was installed were compared with the cases that FFFS was not installed. The result of the comparison showed that the average equivalent death was reduced in 26 cases out of 27 cases when water spray extinguishing system was installed. It was confirmed that the risk when was not installed was unacceptable in Hong Kong and the Netherlands. On the other hand, it was confirmed that the risk was reduced to as low as reasonably practicable (ALARP) when was installed. The cumulative frequency of average death in case with FFFS was compared against the frequency of death without FFFS: death of one or more is about 50 times less; 10 or more is about 100 times less; and the death of more than 100 is four times less. It was verified that FFFS makes improved conditions to escape from the fires in road tunnel.

• Journal of Wetlands Research
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• v.18 no.2
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• pp.201-207
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• 2016

In LID facilities treating stormwater runoff, various kinds of plants are applied for water circulation recovery and pollutant reduction. However, rapid changes of soil moisture due to the use of porous media and spread of deicing material during winter season cause slow plant growth that detrimentally leads to many problems including death of plants. Therefore, this study was performed to evaluate the salt resistance of plants, its effects on pollutants removal, and water circulation recovery. Eight different kinds of plants applicable to an LID facility were selected for the experiment, which were Bridal wreath (Spiraea japonica, S.J), Azalea (Rhododendron indicum, R.I), Dawn Redwood (Metasequoia glyptostroboides, M.G), Sweet flag (Acorus calamus A.C), Dwarf fan-shape columbine(Aquilegia flabellata, A.F), Pink (Dianthus chinensis, D.C), Pratia pedunculata (Pratia pedunculata, P.B) and Marigold (Tagetes patula, T.P). Woody plants such as S.P, R.I, and M.G appear to have less salt resistance compared to the other herbaceous plants. Specifically, M.G achieved the highest salt resistance among the other woody plants being followed by S.P, and R.I, respectively. For herbaceous plants, T.L and D.C have the higher salt resistances than that of A.C, P.B, and A.F, respectively. Regardless of the influence of salt to most of the plants, TN and TP were reduced more than 60% and the study suggests the M.G showed high pollutant removal efficiency and provided better water circulation by means of active photosynthesis and respiration due to higher growth.

• KDI Journal of Economic Policy
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• v.34 no.1
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• pp.135-168
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• 2012

This study analyzes ways to detect protest responses (hereafter, PR zero-bid) in the contingent valuation method (CVM). In order to distinguish PR zero-bids from true zero-bids (non-PR zero bids), this study adopts the concept of the implicit willingness to pay employing the Hicksian compensating surplus and the Taylor's 1st order approximation. When a respondent proposes a zero-bid (i.e., WTP=0) and chooses a PR filtering item to indicate that her implicit WTP is not necessary zero, her response is identified as a PR zero bid. PR filtering items falling into the PR zero bids category include the uncertainty of information, distrust in the government and project achievement, disagreement to project plans, discontent with the fairness of public works and their payment method and animosity against the CVM itself. The empirical analysis shows that PR zero bids take place systematically in particular respondent groups: respondents who have never used similar facilities before nor plans to use the facility provided by the public project, the employed, and low income groups. In conclusion, the study suggests that a CVM questionnaire needs to be designed carefully to minimize problems associated with PR zero bids and the potential risks of having sample selection bias should be concerned.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.10
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• pp.777-784
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• 2017

Energy harvesting through a thermoelectric module normally makes use of the temperature gradient in the system's operational environment. Therefore, it is difficult to obtain the desired output power when the system is subjected to an environment in which a low temperature gradient is generated across the module, because the power generation efficiency of the thermoelectric device is not optimized. The utilization of solar energy, which is a form of renewable energy abundant in nature, has mostly been limited to photovoltaic solar cells and solar thermal energy generation. However, photovoltaic power generation is capable of utilizing only a narrow wavelength band from the sunlight and, thus, the power generation efficiency might be lowered by light scattering. In the case of solar thermal energy generation, the system usually requires large-scale facilities. In this study, a simple and small size thermoelectric power generation system with a solar concentrator was designed to create a large temperature gradient for enhanced performance. A solar tracking system was used to concentrate the solar thermal energy during the experiments and a liquid circulating chiller was installed to maintain a large temperature gradient in order to avoid heat transfer to the bottom of the thermoelectric module. Then, the setup was tested through a series of experiments and the performance of the system was analyzed for the purpose of evaluating its feasibility and validity.