• Title/Summary/Keyword: low tin

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Study on the Copper Electro-refining from Copper Containing Sludge (저품위 동(Cu) 함유 슬러지로부터 동 전해정련에 관한 연구)

  • Lee, Jin-Yeon;Son, Seong Ho;Park, Sung Cheol;Jung, Yeon Jae;Kim, Yong Hwan;Han, Chul Woong;Lee, Man-seung;Lee, Ki-Woong
    • Resources Recycling
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    • v.26 no.6
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    • pp.84-90
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    • 2017
  • The electro-refining process was performed to recovery high purity copper from low grade copper containing sludge in sulfuric acid. The surface morphologies and roughness of electro-refining copper were analyzed with variation of the type and concentration of organic additives, the best surface morphology was obtained 5 ppm of the gelatin type and 5 to 10 ppm of the thiol type organic additive. The crude metal consisted of copper with 86.635, 94.969 and 99.917 wt.%, several impurity metals of iron, nickel, cobalt and tin by pyro-metallurgical process. After electro-refining process, the purity of copper increases to 3N or 4N grade. The impurity concentrations and copper purities of copper crude metals, electrolyte and electro-refining copper were analyzed using ICP-OES, the electro-refining time and purity of copper crude metal to recover 4N grade copper were deduced.

Luminous Characteristics of Transparent Field Emitters Produced by Using Ultra-thin Films of Single Walled Carbon Nanotubes

  • Jang, Eun-Soo;Goak, Jeung-Choon;Lee, Han-Sung;Lee, Seung-Ho;Lee, Nae-Sung
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.31.1-31.1
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    • 2009
  • Carbon nanotubes (CNTs) are attractive material because of their superior electrical, mechanical, and chemical properties. Furthermore, their geometric features such as a large aspect ratio and a small radius of curvature at tip make them ideal for low-voltage field emission devices including backlight units of liquid crystal display, lighting lamps, X-ray source, microwave amplifiers, electron microscopes, etc. In field emission devices for display applications, the phosphor anode is positioned against the CNT emitters. In most case, light generated from the phosphor by electron bombardment passes through the anode front plate to reach observers. However, light is produced in a narrow depth of the surface of the phosphor layer because phosphor particles are big as much as several micrometers, which means that it is necessary to transmit through the phosphor layer. Hence, a drop of light intensity is unavoidable during this process. In this study, we fabricated a transparent cathode back plate by depositing an ultra-thin film of single walled CNTs (SWCNTs) on an indium tin oxide (ITO)-coated glass substrate. Two types of phosphor anode plates were employed to our transparent cathode back plate: One is an ITO glass substrate with a phosphor layer and the other is a Cr-coated glass substrate with phosphor layer. For the former case, light was radiated from both the front and the back sides, where luminance on the back was ~30% higher than that on the front in our experiments. For the other case, however, light was emitted only from the cathode back side as the Cr layer on the anode glass rolled as a reflecting mirror, improving the light luminance as much as ~60% compared with that on the front of one. This study seems to be discussed about the morphologies and field emission characteristics of CNT emitters according to the experimental parameters in fabricating the lamps emitting light on the both sides or only on the cathode back side. The experimental procedures are as follows. First, a CNT aqueous solution was prepared by ultrasonically dispersing purified SWCNTs in deionized water with sodium dodecyl sulfate (SDS). A milliliter or even several tens of micro-liters of CNT solution was deposited onto a porous alumina membrane through vacuum filtration. Thereafter, the alumina membrane was solvated with the 3 M NaOH solution and the floating CNT film was easily transferred to an ITO glass substrate. It is required for CNT film to make standing CNTs up to serve as electron emitter through an adhesive roller activation.

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Electrical Properties of Al3+ and Y3+ Co-doped SnO2 Transparent Conducting Films (Al3+와 Y3+ 동시치환 SnO2 투명전극 박막의 전기적 특성)

  • Kim, Geun-Woo;Seo, Yong-Jun;Sung, Chang-Hoon;Park, Keun-Young;Cho, Ho-Je;Heo, Si-Nae;Koo, Bon-Heun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.10
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    • pp.805-810
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    • 2012
  • Transparent conducting oxides (TCOs) have wide range of application areas in transparent electrode for display devices, Transparent coating for solar energy heat mirrors, and electromagnetic wave shield. $SnO_2$ is intrinsically an n-type semiconductor due to oxygen deficiencies and has a high energy-band gap more than 3.5 eV. It is known as a transparent conducting oxide because of its low resistivity of $10^{-3}{\Omega}{\cdot}cm$ and high transmittance over 90% in visible region. In this study, co-doping effects of Al and Y on the properties of $SnO_2$ were investigated. The addition of Y in $SnO_2$ was tried to create oxygen vacancies that increase the diffusivity of oxygen ions for the densification of $SnO_2$. The addition of Al was expected to increase the electron concentration. Once, we observed solubility limit of $SnO_2$ single-doped with Al and Y. $\{(x/2)Al_2O_3+(x/2)Y_2O_3\}-SnO_2$ was used for the source of Al and Y to prevent the evaporation of $Al_2O_3$ and for the charge compensation. And we observed the valence changes of aluminium oxide because generally reported of valence changes of aluminium oxide in Tin - Aluminium binary system. The electrical properties, solubility limit, densification and microstructure of $SnO_2$ co-doped with Al and Y will be discussed.

A Study on the Sound Amplitude and Decaying Time of the Jing Depending on the Depth of Rim (징악기의 RIM 깊이에 따른 음향 증폭 및 음향 지속 시간에 관한 연구)

  • Sohn Jung-ho;Bae Myung-Jin
    • Journal of Broadcast Engineering
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    • v.9 no.4 s.25
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    • pp.424-433
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    • 2004
  • Jing(gong) is one of the most well known Korean traditional Samulnori instruments to the general public. Samulnori is consisted of four instruments, them being : the jingo the janggu (hour-glass drum). the kkwaenggwari, and the buk(drum). Of the four instruments, the jing with its deep, and yet soft and beautiful long lingering sound embraces the sounds of the other three. The jing is a brassware instrument, a compound of $70{\%}\;copper\;and\;22{\%}\;tin.$\;A high quality brassware is used when the jing is made. The jing is shaped with a 39-40cm circular plate and a rim that gives 7.0-7.5cm of depth to the instrument. Even with its most simple structure, when the circular plate is hit during performance, the rim which supports the circular plate gives resonance to the sound making low-frequency sounds. Therefore the range of the representative frequency of the full rim jing is between $118.4{\~}366.0[Hz],$\;the lingering sound lasts for more than 20 seconds afterwards. When the jing with half of its rim cut off is hit the basic frequency is $139.9{\~}387.5[Hz].$\;And the sound lasted for ten more seconds. The jing of its rimless frequencies are distributed between $990.5{\~}1,372[Hz].$\;And the lingering sound lasts for 5seconds afterwards. Therefore, different thickness and depth of the rim may give new resonance frequencies and alter the longing time of the sound. This thesis paper will try to reveal the relationship between the thickness or depth of the rim (which holds the bending circular plate) and the frequency or the lasting time of the sound.

SUITABILITY OF SHELLFISHES FOR PROCESSING 1. Suitability of Baby Clam for Processing (패류의 가공적성 1. 바지락의 가공적성)

  • LEE Eung-Ho;PYEUN Jae-Hyeung;KIM Soo-Hyeun;CHUNG Seung-Yong
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.8 no.1
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    • pp.20-30
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    • 1975
  • It is matter of fact processing technology must affects the quality and yield of final product and these also depend on the selection of raw material directly or indirectly. So that the estimation of tile preprocessing condition of shellfish is of great importance for distributors and processors. This study was attempted to establish the basic data for evaluating the processing suitability of baby clam, which is one of the five important shellfishes for domestic use and export. The important results are as follows: 1. The ratio of meat volume and meat weight to the holding capacity by shells may be useful for measuring the condition index of baby clams. 2. Baby clams grown in the beds with the composition of a large quantity of gravel were low in condition index value than in sand and mud. 3. If the green feed phenomenon was the prime consideration for canned baby clams, tile most suitable harvest season if October. In this period, the digestive tract in body was almost colorless. 4. As a whole, seasonal changes of moisture and fat content in baby clams were reversely correlated. Protein content increased from April and slightly decreased for a while from July to August and increased again from September. In March, the content of glycogen was 6.3 to 6.8 percent. From this period to October, glycogen was rapidly decreased. In October, it was only 0.1 to 0.2 percent but increased from November. There were little seasonal changes in pH value and crude ash content. The pH value of meat was 6.0 to 6.2 and crude ash content was about 2 percent. 5. By the results of condition index and chemical composition of baby clams, the suitable harvest season as raw materials for processing was from March to June and from September to October. 6. The steamed baby clam meat was packed with 2 percent salt solution containing 0.15 percent, citric acid or 0.5 percent $Na_2$ EDTA in a round sanitary tin can coated with C-enamel that is 203.9 ml by volume and sterilized for 60 minutes at $112^{\circ}C$. The canned product has shown a good result to reserve the natural characteristics of baby clam through six month storage at room temperature.

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The Effect of Freshwater Inflow on the Spatio-temporal Variation of water Qualify of Yeongil Bay (영일만 수질의 시ㆍ공간 변동에 미치는 담수유입의 효과)

  • 김영숙;김영섭
    • Korean Journal of Environmental Biology
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    • v.22 no.1
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    • pp.57-65
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    • 2004
  • In order to determine the effect of fresh water inflow from the Heongsan river on the changes of water quality in the Yeongil Bay (Korea), the seasonal changes of water temperature, salinity, chemical oxygen demand (COD), dissolved inorganic nitrogen(DIN) and phosphate phosphorus ($PO_4$-P) concentrations were examined using the data set obtained five fixed points of Yeongil Bay from 1998 to 2000. The distributions and changes of COD and concentrations of total inorganic phosphorous (TIP) and nitrogen (TIN) at three points Heongsan river, were also compared with those of Yeongil Bay. Based on the correlations of DIN and $PO_4$-P, it was found that the inflow of freshwater affected on the water quality of Yeongil Bay. Such a complicacy was confirmed by the prominent differences in n few water quality measures between Site 1(the innermost area) and Site 5 (the mouth of the bay). The negative correlations in $\Delta N/\Delta P $ at sites 1, 2 and 3 of the inner-part of the bay also indicated a large effect of freshwater inflow on the water quality of the bay. The extremely low atomic ratio of an average of 6.4 in $\Delta N/\Delta P $ compared to the Redfild ratio suggested that the DIN was depleted in the overall bay system. In contrast, it was inferred that the excessive PO$_4$-P concentration was due to the inflow of freshwater from the Heongsan river.

Long-term Survival Analysis of Bronchioloalveolar Cell Carcinoma (기관세지폐포암의 장기결과분석)

  • Lee Seung Hyun;Kim Yong Hee;Moon Hye Won;Kim Dong Kwan;Kim Jong Wook;Park Seung Il
    • Journal of Chest Surgery
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    • v.39 no.2 s.259
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    • pp.106-110
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    • 2006
  • Background: Bronchioloalveolar carcinoma (BAC) is an uncommon primary malignancy of the lung, and it accounts for $2{\~}14\%$ of all pulmonary malignancies. According to World Health Organization (WHO) categorisation, BAC is a subtype of adenocarcinoma. The current definition of BAC includes the following: malignant neoplasms of the lung that have no evidence of extrathoracic primary adenocarcinoma, an absence of a central bronchogenic source, a peripheral parenchymal location, and neoplastic cells growing along the alveolar septa. Previous reports had demonstrated a better prognosis following surgery for patients affected by BAC than those affected by other type of non-small cell lung cancer (NSCLC). We aim to analyse Asan Medical Center experiences of BAC. Material and Method: Between 1990 and 2002, 31 patients were received operations for BAC. We analyse retrosepectively sex, age, disease location, preoperative clinical stage, postoperative pathologic stage & complications, survival according to medical record. Result: There were 12 men and 19 women, the average age was 61.09$\pm$10.63 ($31{\~}79$) years. Tumor locations were 7 in RUL, 1 in RML, 4 in RLL, 8 in LUL, 11 in LLL. Operations were 28 lobectomies, 2 pneumonectomies. Postoperative pathologic stage were 12 T1N0M0, 15 T2N0M0, 1 T1N1M0, 1 T1N2M0, 1 T2N2M0, 1 T1N0M1. Mortality were 4 cases ($12.9\%$) and there were no early mortality. Cancer free death was 1 cases, other 3 were cancer related deaths. All of them were affected by distal metastasis and received chemotherapy and each metastatic locations were right rib, brain, and both lung field. The average follow up periods were 50.87$\pm$24.77 months. The overall 3, 5-year survival rate among all patients was $97.1\%,\;83.7\%$, stage I patients overall 2, 5year survival rate was $96.3\%$. The overall disease free 1, 2, 5-year survival rate among all patients was $100\%,\;90\%,\;76\%$ and 2, 5-year survival rate in cases of stage I was $96.4\%,\;90.6\%$. 7 cases ($22.58\%$) were chemotherapies, 1 case ($3.22\%$) was radiation therapy, and 2 cases ($6.45\%$) were chemoradiation therapies. Metastatic locations were 3 cases in lung, 1 case in bone, 1 cases in brain. Conclusion: BAC has a favourable survival and low recurrence rate compare with reported other NSCLC after operative resections.