• Title/Summary/Keyword: low temperature composition

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A study on the Effect of Heat Treatment of Co-bused Amorphous Ribbons (Co-계비정질 리본의 열처리 효과에 관한 연구)

  • 진성빈;임재근;문현욱;신용진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.149-151
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    • 1994
  • This thesis describes the effect of heat treatment on the magnetic properties of Co-bsaed Amorphous. A sample was chosen as basic composition with Co$\_$82//Si$\_$2//B$\_$16/ of zero magnetostriction. It was made by single roll method with quartz orifice 0.5[mmø], Ar gas pressure 0.6 [kg/cm$^2$] and roll speed 28 (m/sec) and atmosphere is ,Ar gas. We obtained the sample of width 2.4(mm), thickness 45[$\mu\textrm{m}$]. Made sample annealed for the improvement of magnetic propertics at at annealing temperature 325,350,375 and 400$^{\circ}C$ and annealing time 15, 30, 45, 60 and 120min respectiveily. Amorphous ribbon of co-based showed high permeab- ility ${\mu}$=8000∼14000, and became improvement of magnetic properties according to anneal ins temperature and time. Especially. Amorphous sample at 325$^{\circ}C$ ,45min appearanced high permeability ${\mu}$=13, 589 at frequency f= 100Hz. and loss factor was reduced at low frequency with rising anneal ins ti me and temperature more annealed sample than basic sample.

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Movpe Growth of InP/GaAs and GalnAs/GaAs from EDMln, TBP and TBAs (EDMln, TBP와 TBAs를 이용한 InP/GaAs와 GalnAs/GaAs의 MOVPE 성장)

  • 유충현
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.1
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    • pp.12-17
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    • 1998
  • The heteroepitaxial growth of InP and GaInAs on GaAs substrates has been studied by using a new combination of source materials: ethyldimethylindium (EDMIn) and trimethylgallium (TMGa) as group III sources, and tertiarybutylarsine (TBAs) and tertiarybutylphosphine (TBP) as group V sources. Device quality InP heteroepitaxial layers were obtained by using a two-step growth process under atmospheric pressure, involving a growth of an initial nucleation layer at low temperature followed by high temperature annealing and the deposition of epitaxial layer at a growth temperature. The continuity and thickness of nucleation layer were important parameters. The InP layers deposited at 500$^{\circ}$- 55$0^{\circ}C$ are all n-type, and the electron concentration decreases with decreasing TBP/EDMIn molar ratio. The excellent optical quality was revealed by the 4.4 K photoluminescence (PL) measurement with the full width at half maximum (FWHM) of 4.94 meV. Epitaxial Ga\ulcorner\ulcorner\ulcornerIn\ulcorner\ulcorner\ulcornerAs layers have been deposited on GaAs substrates at 500$^{\circ}$ - 55$0^{\circ}C$ by using InP buffer layers. The composition of GaInAs was determined by optical absorption measurements.

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A Study On electrical Properties of $Ba_{0.5}/Sr_{0.5}/TiO_3$thin-film capacitor ($Ba_{0.5}/Sr_{0.5}/TiO_3$ 박막 커패시터의 전기적 특성에 관한 연구)

  • 이태일;송재헌;박인철;김홍배;최동환
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.33-36
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    • 1999
  • In this paper, $Ba_{0.5}$Sr$_{0.5}$TiO$_3$ thin-films were prepared on Pt/Ti/Si0$_2$/Si substrates by RF magnetron sp-uttering method. We investigated electric and dielectric properties of BST thin-films with various ann-ealing temperature using in-sute RTA. Deposition conditions of BST films were set substrate temperat-ure, 30$0^{\circ}C$ and working gas ratio, Ar:O$_2$=90:10. After BST films deposited, we fabricated a capacitor of MIM structure with Al top electrode for measurement. Post-annealing using RTA performed at 40$0^{\circ}C$, $600^{\circ}C$, 80$0^{\circ}C$ for 60 sec, respectively. Also we exacted crystallization and composition of BST thin-films by XRD analysis. In measurement result, this capacitors showed a dielectric constant of about 200 at 1MHz and leakage current density of 5$\times$10$^{-8}$ A/$\textrm{cm}^2$ at 1.5V Microstructure of BST thin-films exhibited effective quality in low-temperature annealed 71ms than high-temperature annealed 71ms.s.s.

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Low Temperature sintering of $Al_2O_3-TiO_2$ ceramics (저온소결 $Al_2O_3-TiO_2$ 세라믹의 마이크로파 유전특성에 관한 연구)

  • Lim, Eun-Kyeong;Kim, Chang-Il;Park, Yong-Jun;Lee, Young-Jin;Nahn, Shan;Paik, Jong-Hoo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.252-252
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    • 2007
  • $Al_2O_3-TiO_2$(AT)ceramics shows great promise as a dielectric material for millimeter-wave use. The sintering temperature of AT ceramics was approximately $1450^{\circ}C$ and decreased to $900^{\circ}C$ with the addition of BaCu(B2O5) (BCB) ceramic powder. The presence, of the liquid phase was responsible for the decrease of the sintering temperature. The liquid phase is considered to have a composition similar to the BaO-deficient BCB. The Q-value initially increased with the addition of BCB, but decreased considerably when a large amount of BCB was added, because of the presence of the liquid phase. Good microwave dielectric properties of $Q{\times}f\;=\;16,200\;GHz$, ${\varepsilon}_r\;=\;9$ and ${\tau}_f\;=\;-4\;ppm/^{\circ}C$ were obtained for the 20.0 mol% BCB-added AT ceramics sintered at $900^{\circ}C$ for 2 h.

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The Effect of Calcium on Microstructure of AZ61 Magnesium Alloy during Annealing Heat Treatment (AZ61 마그네슘 합금의 어닐링 중 Ca의 첨가에 따른미세조직 변화에 미치는 영향)

  • Kim, Kibeom;Jeon, Joonho;Kim, Kwonhoo
    • Journal of the Korean Society for Heat Treatment
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    • v.34 no.2
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    • pp.53-59
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    • 2021
  • Due to high specific strength and low density, AZ series magnesium alloys have been receiving high interest as a lightweight material. However, their industrial application is limited due to the phenomenon that the strength decreases at elevated temperature by the occurrence of softening effect because of the Mg17Al12 phase decomposition. To solve this problem, many research were conducted to increase the high-temperature strength by forming a thermal stable second-phase component by adding new elements to the AZ magnesium. Especially, adding Ca to AZ magnesium has been reported that Ca forms the new second-phase. However, studies about the analysis of decomposition or precipitation temperature, formation composition, and components to understand the formation behavior of these precipitated phases are still insufficient. Therefore, the effect of Ca addition to AZ61 on the phase change and microstructure of the alloy during annealing was investigated. As a result of analysis of the initial and heat-treated specimen, AZ61 formed α-Mg matrix and precipitated phase of Mg17Al12, and AZX611 formed one more type of precipitated phase, Al2Ca. Also, Al2Ca was thermal stable at high temperatures. And after annealing, the laves phase was decomposed to under 10 ㎛ size and distributed in matrix.

Studies on the Processing of Rapid- and Low Salt-Fermented Liquefaction of Anchovy(Engrulis japonica) (I) -Changes in Free Amino Acids during Fermentation and Quality Indices- (저식염 속성 멸치 발효액화물 가공에 관한 연구(I) -숙성 중 유리아미노산 변화 및 품질지표-)

  • Kang, Tae-Jung;Cho, Kyu-Ok;Park, Choon-Kyu
    • Journal of the Korean Society of Food Culture
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    • v.17 no.2
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    • pp.197-213
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    • 2002
  • In order to establish the processing condition of rapid- and low salt-fermented liquefaction of anchovy (Engrulis japonica), effect of temperature on crude enzyme activity of anchovy viscera, pretreatment conditions, and the minimum content of adding NaCl were investigated. The minimum limitation of NaCl content for anchovy liquefaction was 10%. Sample A(water adding, heating, adding 10% NaCl): chopped whole anchovy adding 20% water and then heating for 9 hrs at $50^{\circ}C$ and then adding 10% NaCl and then fermented at room temperature$(8-29^{\circ}C)$ for 180 days. Sample B(water adding, heating, adding 13% NaCl): chopped whole anchovy adding 20% water and then heating for 9 hrs at $50^{\circ}C$ and then adding 13% NaCl and then fermented at room temperature for 180 days. Sample C(adding 13% NaCl): chopped whole anchovy and then adding 13% NaCl and then fermented at room temperature for 180 days. Sample D(adding 17% NaCl): whole anchovy adding 17% NaCl and then fermented at room temperature for 180 days. The content of free amino acids such as aspartic acid, serine and threonine fluctuated severely according to the pretreatment methods. Possibly they might be recommend quality indices of standardization for salt-fermented liquefaction of anchovy. As for the relation between fermentation period(X) and individual free amino acid(Y), five kinds of free amino acids such as glutamic acid, valine, glycine, lysine, and alanine showed highly significant in their coefficient of determination in most of samples. They might be recommend as quality indices for salt-fermented liquefaction of anchovy during fermentation. The difference of taste between products of the rapid- and low salt-fermented liquefaction and the traditional salt-fermented liquefaction were caused by their composition of the free amino acids ratios, in which were umami, sweet, and bitter taste in the extracts of anchovy during fermentation. The appropriate fermentation period of the sample A was shorten 30 days than the sample B and 60 days than the samples C and 90 days than the sample D in the processing of anchovy.

Mineralogy and Chemical Compositions of Dangdu Pb-Zn Deposit (당두 연-아연 광상의 산출광물과 화학조성)

  • Lim, Onnuri;Yu, Jaehyung;Koh, Sang Mo;Heo, Chul Ho
    • Economic and Environmental Geology
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    • v.46 no.2
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    • pp.123-140
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    • 2013
  • The Dangdu Pb-Zn deposit is located at approximately 10 km south of Jecheon, Korea. Geology of Dangdu deposit area consists of Pre-cambrian metamorphic rocks, Ordovician sedimentary rocks, Jurassic and Cretaceous igneous rocks. The ore deposit is developed along the fracture trending $N20{\sim}40^{\circ}W$ in Ordovician limestone and is considered to be a skarn type ore deposit. The shape of ore bodies developed in the Dangdu ore deposit can be divided into lens-form(two ore bodies of -30 m level adit and one ore body of -63 m level adit) and pocket-form developed in -30 m level adit. Ore minerals observed in the ore deposits are magnetite, pyrrhotite, pyrite, chalcopyrite, sphalerite, galena, cosalite, marcasite, hessite, native Bi and bismuthinite. Chemical composition of sphalerite ranges FeS 14.14~18.08 mole%, CdS 0.44~0.70 mole%, MnS 0.52~1.13, 1.53~2.09 mole%. Galena contains a small amount of silver with an average of 0.54 wt.%. An average composition of cosalite is Ag 2.43 wt.%, Bi 44.36 wt.%, Pb 35.05 wt.% which results the chemical formula of cosalite as $Pb_{1.7}Bi_{2.1}Ag_{0.2}S_5$. Skarn minerals consist of epidote, garnet, pyroxene, tremolite, quartz and calcite. The zoning pattern of the ore deposit can be subdivided into epidote-clinopyroxene zone, epidote-clinopyroxene-chlorite zone and epidote-garnet-clinopyroxene zone from the central part of the ore body towards the wall rocks. The chemical composition of garnet shows an increasing trend of grossular from epidote-clinopyroxene zone to epidote-garnet-clinopyroxene zone. Clinopyroxene occurs as a solid solution of diopside and hedenbergite, and the ratio of johannsenite increases from epidote-clinopyroxene zone to epidote-clinopyroxene-chlorite and epidote-garnet-clinopyroxene zones. The mineralization of the ore deposit is considered to be one stage event which can be separated into early skarn mineralization stage, middle ore mineralization stage and late low temperature mineralization stage. The temperature estimation from the low temperature mineralization range from $125{\sim}300^{\circ}C$ which is considered to be representing the temperature of late mineralization.

Structural and electrical properties of perovskite Ba(Sm1/2Nb1/2)O3-BaTiO3 ceramic

  • Nath, K. Amar;Prasad, K.
    • Advances in materials Research
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    • v.1 no.2
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    • pp.115-128
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    • 2012
  • The structural and electrical properties of $(1-x)Ba(Sm_{1/2}Nb_{1/2})O_3-xBaTiO_3$; ($0{\leq}x{\leq}1$) ceramics were prepared by conventional ceramic technique at $1375^{\circ}C$/7 h in air atmosphere. The crystal symmetry, space group and unit cell dimensions were derived from the X-ray diffraction (XRD) data using FullProf software whereas crystallite size and lattice strain were estimated from Williamson-Hall approach. XRD analysis of the compound indicated the formation of a single-phase cubic structure with the space group Pm m. Dielectric study revealed that the compound $0.75Ba(Sm_{1/2}Nb_{1/2})O_3-0.25BaTiO_3$ is having low and ${\varepsilon}^{\prime}$ and ${\varepsilon}^{{\prime}{\prime}}$ a low $T_{CC}$ (< 5%) in the working temperature range (up to+$100^{\circ}C$) which makes this composition suitable for capacitor application and may be designated as 'Stable Low-K' Class I material as per the specifications of the Electronic Industries Association. The correlated barrier hopping model was employed to successfully explain the mechanism of charge transport in the system. The ac conductivity data were used to evaluate the density of states at Fermi level, minimum hopping length and apparent activation energy of the compounds.

Analysis on the Combustion Characteristics of Low-Btu Synthetic Gases in Gas Engine (저발열량 합성가스의 가스엔진 내 연소 특성에 대한 해석)

  • Lee, Chan;Cho, Sang Mok
    • Clean Technology
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    • v.12 no.2
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    • pp.78-86
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    • 2006
  • Computational analyses are conducted on the combustion characteristics of the coal- and the biomass-derived synthetic gases with low-Btu heating value in gas engine. Using thermochemical analyses on the synthetic gases, combustion pressure, temperature, exhaust gas composition, NO emission and engine power are predicted and the predicted results are compared with small-scale pilot engine test results. In order to investigate the unsteady combustion phenomena in gas engine combustion chamber, CFD analyses are carried out on the coal and the biomass synthetic gases and their computed results are compared to provide the guidelines for the design modification and the tuning of the gas engine burning the synthetic gases as alternative fuels.

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Analysis of Glass Composition on Low k Materials (저유전율 소재에서의 유리조성에 대한 분석)

  • Na, Yoon-Soo;Hwang, Jong-Hee;Lim, Tae-Young;Shin, Hyo-Soon;Kim, Jong-Hee;Cho, Yong-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.177-177
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    • 2008
  • The effect of several $SiO_2-B_2O_3-Al_2O_3$-R(R;Ca, Sr, Ba) borosilicate glass system on sintering behavior, dielectric properties and mechanical properties of glass/ceramic composites were investigated. The amount of '+2 valency' metal elements(Ca, Sr, Ba) were examined in LTCC composite of low k glass with cordierite filler. It was sintered for 60minutes in temperature range from 850C to 950. Properties of frit and glass/ceramic composites were analyzed by DTA, XRD, SEM, Network Analyzer, UTM and so on. Dielectric constant ($\varepsilon_r$) and $Q{\times}f_0$ (Q) of the composite with 50% glass contents demonstrated $\varepsilon_r$ = 5.4 $Q{\times}f_0$ = 1600 GHz. Sintering was complete and maximum bending strength of 160MPa was obtained.

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