• Title/Summary/Keyword: low temperature combustion method

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Fabrication of $Gd_2O_3:Eu^{3+}$ Nano Phosphor and Optical Characteristics for High Resolution Radiation Imaging (고해상도 방사선 영상을 위한 $Gd_2O_3:Eu^{3+}$ 나노 형광체 제조 및 광학적 특성)

  • Kim, So-Yeong;Kang, Sang-Sik;Park, Ji-Koon;Cha, Byung-Youl;Choe, Chi-Won;Lee, Hyung-Won;Nam, Sang-Hee
    • Journal of Biomedical Engineering Research
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    • v.28 no.1
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    • pp.148-152
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    • 2007
  • In this paper, we have synthesized $Gd_2O_3:Eu^{3+}$ nano phosphor particle using a low temperature solution-combustion method. We have investigated the structure and the luminescent characteristic as the sintering temperature and europium concentration. From XRD(X-ray diffraction) and SEM(scanning electron microscope) results, we have verified that the phosphor particle was fabricated a spherical shape with $30{\sim}40nm$ particle size. From the photoluminescence results, the strong peak exhibits at 611 um and the luminescent intensity depends on europium concentration. $Gd_2O_3:Eu$ fine phosphor particle has shown excellent luminescent efficiency at 5 wt% of europium concentration. The phosphors calcinated at $500^{\circ}C$ have possessed the x-ray peaks corresponding to the cubic phase of $Gd_2O_3$. As calcinations temperature increased to $700^{\circ}C$, the new monoclinic phase has identified except cubic patterns. From the luminescent decay time measurements, mean lifetimes were $2.3{\sim}2.6ms$ relatively higher than conventional bulk phosphors. These results indicate that $Gd_2O_3:Eu$ nano phosphor is possible for the operation at the low x-ray dose, therefore, the application as medical imaging detector.

Study on Fuel Consumption Improvement in SI Engine with EGR for Hybrid Electric Vehicle (하이브리드용 가솔린엔진의 EGR을 통한 연비향상에 관한 연구)

  • Park, Cheol-Woong;Choi, Young;Kim, Chang-Gi
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.2
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    • pp.128-135
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    • 2008
  • EGR(exhaust gas recirculation) is considered as a most effective method to reduce the NOx emissions. But high EGR tolerance is always pursued not only for its advantages of the pumping loss reduction and fuel economy benefit in Gasoline-Hybrid engine. However, the occurrence of excessive cyclic variation with high EGR normally prevents substantial fuel economy improvements from being achieved in practice. Therefore, the optimum EGR rate should be carefully determined in order to achieve low fuel consumption and low exhaust emission. In this study, 2 liters gasoline engine with E-EGR system was used to investigate the effects of EGR on fuel efficiency, combustion stability, engine performance and exhaust emissions. With optimal EGR rates, the fuel consumption was improved by 4%. This improvement was achieved while a reduction in NOx emissions of 75% was accomplished. Increase of EGR gas temperature causes the charge air temperature to affect the knock phenomenon and moreover, the EGR valve lift changes for the same control signal.

A Study on Ignition Probability and Combustion Characteristics of Low Pressure Direct Injection LPG according to a Function of Ambient Condition (분위기 조건 변화에 따른 저압 직접분사식 LPG의 점화성 및 연소특성 연구)

  • Chung, Sung-Sik;Hwang, Seong-Ill;Yeom, Jeong-Kuk;Jeon, Byong-Yeul
    • Journal of Power System Engineering
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    • v.20 no.2
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    • pp.32-42
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    • 2016
  • Under part load condition of spark-ignition engine, pumping loss had great effect on engine efficiency. To reduce pumping loss, the study designed spark-ignited engines to make direct spray of gasoline to combustion chamber. In spark-ignited direct-injection engines, ignition probability is important for successful combustion and flame propagation characteristics are also different from pre-mixed combustion. This study designed a visualization testing device to study ignition probability of spark-ignited direct-injection LPG fuel and combustion flame characteristics. This visualization device consists of combustion chamber, fuel supply system, air supply system, electronic control system and data acquisition system. Ambient pressure, ambient temperature and ambient air flow velocity are important parameters on ignition probability of LPG-air mixture and flame propagation characteristics, and the study also found that sprayed LPG fuel can be directly ignited by spark-plug under proper ambient conditions. To all successful cases of ignition, the study recorded flame propagation image in digital method through ICCD camera and its flame propagation characteristics were analyzed.

Synthesis of ZnS:Cu,Cl phosphor by combustion method

  • Han, Sang-Do;Kim, Byeong-Kwon;Park, Jo-Yong;Khatkar, S.P.;Taxak, V.B.;Singh, Ishwar
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.759-761
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    • 2002
  • A new method for the preparation of copper activated zinc sulfide phosphors by combustion method has been proposed. Copper nitrate was decomposed with an organic fuel to give fine sized particles in presence of alkali metal halides at low temperature than the conventional synthesis. Organic compound also acted as fuel at 500 $^{\circ}C$ with rapid heating. The phosphors thus obtained were then heated at 900 $^{\circ}C$ in an inert atmosphere for 2-5 hrs to get better luminescent properties.

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A Study on the Effects of Induced Mixture Flows and the Stratified Charge for a Lean Burn (희박연소를 위한 혼합기의 성층급기와 유동에 관한 연구)

  • 전대수;이태원;윤수한;하종률
    • Transactions of the Korean Society of Automotive Engineers
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    • v.8 no.1
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    • pp.1-9
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    • 2000
  • In the present study, the IDI-type constant volume chamber, which utilizes the indirect injection stratified charge method, is used to solve several problems including misfires and cycle-variations caused by unstable initial ignitions. A subchamber has been used to make an ignitable mixture under the low mean equivalence ratio. After burned in the subchamber, the flame jet getting through the passage hode enters the main chamber and burns the lean charge. There are many factors which affect the combustion characteristics of the indirect injection stratified engine. The passage hole angle is the most important since it determines the direction of flame flows into the main chamber. In the present study, we measured the combustion pressure, and the wall temperature, and computed the heat flux through the cylinder wall in order to understand the combustion characteristics depending on passage hole angle and the equivalence ratio.

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A Study on the Synthesis of Titanium Carbonitride by SHS(Self-propagating High-temperature Synthesis) Method (자체반응열 고온합성법을 이용한 Titanium Carbonitride의 합성에 관한 연구)

  • Ha, Ho;Hwang, Gyu-Min;Lee, Hee-Cheol
    • Journal of the Korean Ceramic Society
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    • v.31 no.6
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    • pp.637-642
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    • 1994
  • Using SHS(Self-propagating High-temperature Synthesis) method, the optimum synthetic condition of titanium carbonitride was established by controlling the parameters such as relative density of mixture (Ti+C), nitrogen pressure, additive amounts of titanium hydride(TiH1.924) and protecting heat loss. Under 1 atm nitrogen pressure, nitridation ratio with changing relative density of the sample compacts has a maximum (87.2%) at about 55%, and in the case of enveloping the pellet with a quartz tube, the highest nitridation ratio of 90% was obtained at about 68%. At relative density of 55%, nitridation ratio with the nitrogen pressure has a miximum (87.3%) at 7 atm. As the amounts of additive titanium hydride increased, nitridation ratio decreased at below 7 atm nitrogen pressure and, increased at above this pressure until percent of addition percent reached 15 wt% and decreased abruptly upon futher increases in titanium hydride. In the synthesis of TiCxNy by combustion reaction, heat transfer from combustion zone to preheating zone and nitrogen gas penetration into the compact were found to be important factors affecting the TiCxNy formation. It was difficult to obtain high nitridation ratio when the conbustion temperature was either too high or too low, and it seems that the retention of high temperature after a combustion wave sweeped through the reactant mixture pellet is critical to obtain a satisfactory nitridation ratio.

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Soot Formation and Combustion in Turbulent Flames (난류 화염 내에서의 매연 입자의 생성및 재연소)

  • 정종수;신현동;이춘식
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.5
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    • pp.962-978
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    • 1989
  • A new model of the combustion rates of soot particle in turbulent flames has been suggested. This model applies the combustion rate of soot particles in laminar flames and uses local time-averaged quantities in order to consider the effect of the chemical reaction on the soot combustion in turbulent flames. The proposed rate equation has been tested for two propane-air turbulent round-jet diffusion flames and gives better predictions for the soot concentration field of two flames than the model previously used, especially in low temperature regions. A modified Monte carlo Method for analyzing radiative heat transfer of a flame also has been suggested and tested, which reveals good results.

Kinetic and Thermodynamic Features of Combustion of Superfine Aluminum Powders in Air

  • Kwon, Young-Soon;Park, Pyuck-Pa;Kim, Ji-Soon;Gromov, Alexander;Rhee, Chang-Kyu
    • Journal of Powder Materials
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    • v.11 no.4
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    • pp.308-313
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    • 2004
  • An experimental study on the combustion of superfine aluminum powders (average particle diameter, a$_{s}$: ∼0.1 ${\mu}{\textrm}{m}$) in air is reported. The formation of aluminum nitride during the combustion of aluminum in air and the influence of the combustion scenario on the structures and compositions of the final products are in the focus of this study. The experiments were conducted in an air (pressure: 1 atm). Superfine aluminum powders were produced by the wire electrical explosion method. Such superfine aluminum powder is stable in air but once ignited it can burn in a self-sustaining way due to its low bulk: density (∼0.1 g/㎤) and a low thermal conductivity. During combustion, the temperature and radiation were measured and the actual burning process was recorded by a video camera. Scanning electron microscopy (SEM), X-ray diffraction (XRD) and chemical analysis were performed on the both initial powders and final products. It was found that the powders, ignited by local heating, burned in a two-stage self-propagating regime. The products of the first stage consisted of unreacted aluminum (-70 mass %) and amorphous oxides with traces of AlN. After the second stage the AlN content exceeded 50 mass % and the residual Al content decreased to ∼10 mass %. A qualitative discussion is given on the kinetic limitation for AlN oxidation due to rapid condensation and encapsulation of gaseous AlN.N.

Study on the Characteristics of Performance and Exhaust Emissions of 3-Chamber GDI Engine (3-연소실형 GDI Engine의 성능 및 배기 배출물 특성에 관한 연구)

  • 김봉수;정남훈;진선호;배종욱
    • Journal of Advanced Marine Engineering and Technology
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    • v.26 no.1
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    • pp.37-47
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    • 2002
  • Recently gasoline direct injection method has been applied to gasoline engine to reduce fuel consumption rate by controlling fuel air mixture on lean condition by means of stratified charging, and to reduce simultaneously. Pollutant emissions especially NOx and CO by lowering the combustion temperature. But difficulty of controling local fuel air ratio at ignition area in flammability limit unavoidably appeared, because it is merely controlled by injection timing with spatial and temporal distribution of fuel mixture. In this study, the authors devised a uniquely shaped combustion chamber so called three-chamber GDI engine, intended to keep the more reliable fuel air ratio at ignition area. The combustion chamber is divided into three regions. The first region is in the rich combustion division, where the fuel is injected from the fuel injection valve and ignited by the spark plug. The second region is in the lean combustion division, where the combustion gas from the rich combustion division flows out and burns on lean condition. And the last region is in the main combustion division ie in the cylinder, where the gas from the above two combustion divisions mixed together and completes the combustion during expansion stroke. They found that the stable range of operation of three-chamber GDI engine on low-load condition exists in the lean area of average equivalence ratio. And they also found that the reformed engine reveals less specific fuel consumption and less pollutant emissions compared with conventional carburettor type gasoline engine.

A Study of $NO_x$ Reduction in Stage Combustion (단계적 연소의 $NO_x$ 저감에 대한 연구)

  • 채재우;전영남;이운영
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.6
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    • pp.1556-1571
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    • 1993
  • Nitrogen oxides ($NO_x$) are air pollutants which are generated from the combustion of fossil fuels. Stage combustion is an effective method to reduce $NO_x$ emissions. The effects of $NO_x$ reduction by stage combustion in a pilot scale combustor(6.6kW) have been investigated using propane gas flames laden with NH$_{3}$ as Fuel-N. The results in this study are follows; (1) $NO_x$ emissions are dependent on the reducing environment of fuel-rich zone regardless of total air ratio. The maximum $NO_x$ reduction is at the stoichiometric ratio of 0.8 to 0.9 in the reducing zone. (2) $NO_x$ reduction is maximum when burnout air is injected at the point where the oxygen in reducing zone is almost consumed. (3) $NO_x$ reduction is dependent upon the temperature of reducing zone with best effect above 950.deg. C in the reducing zone. (4) The fuel stage combustion is more effective to reduce $NO_x$ formation in the wide range of stoichiometric ratio than two stage combustion. (5) The results of this study could be utilized mainly in a design strategy for low $NO_x$ emission from the combustion of high fuel-nitrogen in energy sources ratio than as an indication of the absolute levels of $NO_x$ which can be achieved by stage combustion techniques in large scale facilities.