• Title/Summary/Keyword: low iridium

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Polymer Phosphorescent Light-Emitting Devices Doped with Iridium Complex (이리듐 합성물 기반의 인광 고분자 발광 소자)

  • Kim, Sung-Jin
    • Journal of the Korean Vacuum Society
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    • v.18 no.4
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    • pp.254-258
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    • 2009
  • We herein report on polymer phosphorescent light-emitting devices doped with iridium complex. The emitting layer of poly(N-vinylcabazole) and tris(2-phenylpyridine)iridium was fabricated by low speed dip-coating of 10, $20{\mu}m$/s. The devices showed stable current increasing leakage current at turn-on voltage. Compared to conventional spin-coating based organic light-emitting devices, the driving voltage by dip-coating observed lower values of 5.8 and 6.7 V at the luminance of 100 Cd/$cm^2$.

Feasibility Study of Communication Access via Iridium Constellation for Small-Scale Magnetospheric Ionospheric Plasma Experiment Mission

  • Song, Hosub;Lee, Jaejin;Yi, Yu
    • Journal of Astronomy and Space Sciences
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    • v.39 no.3
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    • pp.109-116
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    • 2022
  • The small-scale magnetospheric and ionospheric plasma experiment (SNIPE) is a mission initiated by the Korea Astronomy and Space Science Institute (KASI) in 2017 and comprises four 6U-sized nano-satellites (Korea Astronomy and Space Science Institute Satellite-1, KASISat-1) flying in formations. The main goal of the SNIPE mission is to investigate the space environment in low Earth orbit at 500-km. Because Iridium & GPS Board (IGB) is installed on the KASISat-1, a communication simulation is required to analyze the contact number and the duration. In this study, communication simulations between the Iridium satellite network and KASISat-1 are performed using STK Pro (System Tool Kit Pro Ver 11.2) from the AGI (Analytical Graphics, Inc.). The contact number and durations were analyzed by each orbit and date. The analysis shows that the average access number per day is 38.714 times, with an average of 2.533 times per orbit for a week. Furthermore, on average, the Iridium satellite communication is linked for 70.597 min daily. Moreover, 4.625 min is the average duration of an individual orbit.

Visibility Analysis of Iridium Communication for SNIPE Nano-Satellite (SNIPE 초소형위성용 Iridium 통신 모듈의 가시성 분석)

  • Cho, Dong-Hyun;Kim, Hongrae;Kim, Hae-Dong
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.50 no.2
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    • pp.127-135
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    • 2022
  • Compared to the continuous increase of domestic nano-satellite development cases, the initial communication success rate is relatively low. In a situation where communication cases of LEO satellites using commercial satellite communication networks are increasing recently. In this situation, the SNIPE project developed by the KASI(Korea Astronomy and Space Science Institute), KARI(Korea Aerospace Research Institute), and Yonsei University apply an Iridium module for communication test to the SNIPE nano-satellites. Therefore, in this paper, the visibility analysis of the iridium module on the SNIPE satellite was analyzed under considering the orbital and communication environment of the iridium satellite constellation and the attitude control mode. In the case of LEO satellites, the communication possibility was limited due to the relatively small iridium communication coverage for high altitude and the high doppler shift considered in the iridium communication network. For this reason, in this paper, it could be simulated that there was a more performance difference according to the difference in relative RAAN(Right Ascension of Ascending Node) angle with the Iridium constellation. Finally, by checking the visibility of communication module under the tumbling situation that occurred during the initial deployment of the nano-satellite, the possibility of using the iridium communication technology was analyzed.

New Phosphorescent Cyclometalated Iridium(III) Complexes with Diphenyl-1,3-oxazolic and 2-(3-Thienyl)pyridine Ligands for LED Applications

  • Kirsyuk, V. V.;Turgambaeva, A. E.;Shim, Jung-Jin;Rhee, Shi-Woo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.174-177
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    • 2003
  • We report four new phosphorescent iridium(III} complexes with 2,4-diphenyl-1,3-oxazole [$Ir(24dpo)_3$], 2,5-diphenyl-1,3-oxazole [$Ir(25dpo)_3$], 2-(3-thienyl) pyridine [$Ir(3thpyh)_3$] and [Ir(3thpy)2(acac)]. Three of them demonstrate good photophysical properties to be used as dopants to organic polymer matrix or to be used "as is" without a host matrix to fabricate OLEDs. Green and yellow light emission was observed for the photoluminescence: 569/525, 549/498 nm and 557,604/533 (solid state/$CH_2Cl_2$ solution) for $Ir(24dpo)_3$, $Ir(3thpyh)_3$ and $Ir(3thpyh)_2$acac respectively. Room temperature luminescent lifetimes are 2.5 and 1.8 ${\mu}s$ and quantum efficiencies 37 and 53%for $Ir(24dpo)_3$ and $Ir(3thpyh)_3$. The complexes are stable in air and sublimable at low pressure without considerable decomposition. Comparison of physicochemical properties of the reported iridium(III) cyclometalated compounds with that known from literature is carried out.

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High sensitivity determination of iridium contents in ultra-basic rocks by INAA with coincidence gamma-ray detection

  • Ebihara, Mitsuru;Shirai, Naoki;Kuwayama, Jin;Toh, Yosuke
    • Nuclear Engineering and Technology
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    • v.54 no.2
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    • pp.423-428
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    • 2022
  • Very low contents (in the range of 10-9 g/g) of Ir in mantle-derived rock samples (komatiites) were non-destructively determined by INAA coupled with coincidence gamma-ray spectrometry using 16 Ge detectors. Aliquots of the same samples were analyzed by NiS fire-assay ICP-MS for Ir and other platinum group elements. Because the INAA procedure used in this study is non-destructive and is almost free from spectral interference in gamma-ray spectrometry, the INAA values of Ir contents obtained in this study can be highly reliable. Iridium values obtained by ICP-MS were consistent with the INAA values, implying that the ICP-MS values of Ir obtained in this study are equally reliable. Under the present experimental conditions, detection limits were estimated to be 1 pg/g, which corresponds to 0.1 pg for a sample mass of 0.1 g. These levels can be even lowered by an order of magnitude, if necessary, which cannot be achieved by ICP-MS carried out in this study.

Thermal Stability Enhancement of Nickel Monosilicides by Addition of Iridium (이리듐 첨가에 의한 니켈모노실리사이드의 고온 안정화)

  • Yoon, Ki-Jeong;Song, Oh-Sung
    • Korean Journal of Materials Research
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    • v.16 no.9
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    • pp.571-577
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    • 2006
  • We fabricated thermal evaporated 10 nm-Ni/(poly)Si and 10 nm-Ni/1 nm-Ir/(poly)Si films to investigate the thermal stability of nickel monosilicide at the elevated temperatures by rapid annealing them at the temperatures of $300{\sim}1200^{\circ}C$ for 40 seconds. Silicides for salicide process was formed on top of both the single crystal silicon actives and the polycrystalline silicon gates. A four-point tester is used for sheet resistance. Scanning electron microscope and field ion beam were employed for thickness and microstructure evolution characterization. An x-ray diffractometer and an auger depth profile scope were used for phase and composition analysis, respectively. Nickel silicides with iridium on single crystal silicon actives and polycrystalline silicon gates showed low resistance up to $1200^{\circ}C$ and $800^{\circ}C$, respectively, while the conventional nickel monosilicide showed low resistance below $700^{\circ}C$. The grain boundary diffusion and agglomeration of silicides led to lower the NiSi stable temperature with polycrystalline silicon substrates. Our result implies that our newly proposed Ir added NiSi process may widen the thermal process window for nano CMOS process.

Low-iridium Doped Single-crystalline Hydrogenated Titanates (H2Ti3O7) with Large Exposed {100} Facets for Enhanced Oxygen Evolution Reaction under Acidic Conditions ({100} 단결정 수소화 티타네이트(H2Ti3O7)를 활용한 저함량 Irridium 수전해 양극 촉매 개발)

  • Sun Young Jung;HyukSu Han
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.1
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    • pp.79-89
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    • 2023
  • Development of efficient and stable electrocatalysts for oxygen evolution reaction (OER) under acidic conditions is desirable goal for commercializing proton exchange membrane (PEM) water electroyzer. Herein, we report iridium-doped hydrogenated titanate (Ir-HTO) nanobelts as a promising catalyst with a low-Ir content for the acidic OER. Addition of low-Ir (~ 3.36 at%) into the single-crystalline HTO nanobelts with large exposed {100} facets significantly boost catalytic activity and stability for OER under acidic conditions. The Ir-HTO outperforms the commenrcial benchmark IrO2 catalyst; an overpotential for delivering 10 mA cm-2 current density was reduced to about 25% for the Ir-HTO. Moreover, the catalytic performance of Ir-HTO is positioned as the most efficient electrocatalyst for the acidic OER. An improved intrinsic catalytic activity and stability are also confirmed for the Ir-HTO through in-depth electrochemical characterizations. Therefore, our results suggest that low-Ir doped single-crystalline HTO nanobelts can be a promising catalyst for efficient and durable OER under acidic conditions.

Microstructure Characterization for Nano-thick Ir-inserted Nickel Silicides (나노급 Ir 삽입 니켈실리사이드의 미세구조 분석)

  • Song, Oh-Sung;Yoon, Ki-Jeong;Lee, Tae-Hyun;Kim, Moon-Je
    • Korean Journal of Materials Research
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    • v.17 no.4
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    • pp.207-214
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    • 2007
  • We fabricated thermally-evaporated 10 -Ni/(poly)Si and 10 -Ni/1 -Ir/(poly)Si structures to investigate the microstructure of nickel monosilicide at the elevated temperatures required for annealing. Silicides underwent rapid at the temperatures of 300-1200 for 40 seconds. Silicides suitable for the salicide process formed on top of both the single crystal silicon actives and the polycrystalline silicon gates. A four-point tester was used to investigate the sheet resistances. A transmission electron microscope(TEM) and an Auger depth profile scope were employed for the determination of vertical section structure and thickness. Nickel silicides with iridium on single crystal silicon actives and polycrystalline silicon gates shoed low resistance up to 1000 and 800, respectively, while the conventional nickle monosilicide showed low resistance below 700. Through TEM analysis, we confirmed that a uniform, 20 -thick silicide layer formed on the single-crystal silicon substrate for the Ir-inserted case while a non-uniform, agglomerated layer was observed for the conventional nickel silicide. On the polycrystalline silicon substrate, we confirmed that the conventional nickel silicide showed a unique silicon-silicide mixing at the high silicidation temperature of 1000. Auger depth profile analysis also supports the presence of thismixed microstructure. Our result implies that our newly proposed iridium-added NiSi process may widen the thermal process window for the salicide process and be suitable for nano-thick silicides.

Highly Efficient Simple-Structure Red Phosphorescent OLEDs with an Extremely Low Doping Technology

  • Jeon, Woo-Sik;Park, Tae-Jin;Kwon, Jang-Hyuk
    • Journal of Information Display
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    • v.10 no.2
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    • pp.87-91
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    • 2009
  • Highly efficient red phosphorescent OLEDs (PHOLEDs) with a simple, organic, triple-layer structure was developed using the narrow-bandgap fluorescent host material bis(10-hydroxybenzo[h] quinolinato)beryllium complex (Bebq2) and the deep-red dopant tris(1-phenylisoquinoline)iridium (Ir(piq)3). The maximum current and power efficiency values of 12.71 cd/A and 16.02 lm/W, respectively, with an extremely low doping technology of 1%, are demonstrated herein. The results reveal a practical, cost-saving host dopant system for the fabrication of highly efficient PHOLEDs involving the simple structure presented herein, with a reduction of expensive Ir dopants.

Brachytherapy for Head and Neck Cancer (두경부암의 근접방사선 치료)

  • Yoo Seong-Yul
    • Korean Journal of Head & Neck Oncology
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    • v.7 no.1
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    • pp.3-9
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    • 1991
  • Brachytherapy is a method of radiotherapy in advantage to achieve better local control with minimum radiation toxicity in comparison with external irradiation because radiation dose is distributed according to the inverse square low of gamma-ray emitted from the implanted sources. The main characteristics of brachytherapy are delivering of higher dose to target volume shortening of total treatment period and sparing of normal tissue. Recent development of iridium ribbons for low dose rate implant provides improvement of technology of brachytherapy in terms of safety and efficiency. High dose rate method. on the other hand, is effective to avoid unnecessary expoure of medical personnel.

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