• 한국세라믹학회지
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• 제44권1호
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• pp.43-51
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• 2007

Fluidity, setting time, hydration heat, bond water ratio, compressive strength, SEM and BET of OPC were measured by adding 1.0 wt% KCl and replacing 20 wt% mineral admixture in order to examine effects of blast furnace slag (BFS), limestone powder (LSP), and fly ash (FA) on fluidity and strength development of the cement contained much chloride. In general, the cement contained much chloride was high in heat of hydration, short in its setting time, low in its fluidity and low in its strength at 28 days due to the rapid hydration in its initial stage. As a result of the experiment, it has been demonstrated that fluidity became improved but the compressive strength at 28 days was decreased as replaced LSP to the cement contained much chloride. the fluidity and compressive strength at 28 days was improved as replaced BFS, the initial compressive strength development was improved due to the activation of initial reaction by KCl. Fluidity, initial compressive strength and late compressive strength at 28 days of cement contained much chloride replaced 5 wt% LSP and 15 wt% BFS concurrently was better than OPC, but the hydration heat was lower.

• 한국세라믹학회지
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• 제55권3호
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• pp.224-229
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• 2018

OPC production requires high calorific value and emits a large amount of $CO_2$ through decarbonation of limestone, accounting for about 7% of $CO_2$ emissions. To reduce $CO_2$ emissions during the Ordinary Portland Cement (OPC) production process, there is a method of reducing the consumption of cement or lower temperature calcination for OPC product. In this study, for energy consumption reduction, we prepared Hauyne-belite cement by calcination at a low temperature compared to that used for OPC and studied the early hydration properties of the synthesized Hauyne-belite cement. We set the ratios of Hauyne and belite to 8 : 2, 5 : 5 and 3 : 7. For the hydration properties of the synthesized Hauyne-belite cement, we tested heat of hydration of paste and the compressive strength of mortar, using XRD and SEM for analysis of hydrates. As for our results, the temperature for optimum synthesis of Hauyne-belite is $1,250^{\circ}C$. Compressive strength of synthesized Hauyne-belite cement is lower than that of OPC, but it is confirmed that compressive strength of synthesized Hauyne-belite cement with mixing in of some other materials can be similar to that of OPC.

• 한국구조물진단유지관리공학회 논문집
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• 제21권5호
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• pp.141-147
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• 2017

최근 온실가스 감축을 위해 시멘트 클링커를 대체하여 고로슬래그 미분말을 다량 치환한 하이볼륨 슬래그 시멘트에 대한 연구 활발히 진행되고 있다. 하지만, 수화열 및 내구성 등 다양한 장점에도 불구하고 초기 재령에서의 낮은 강도 발현 등의 문제점으로 인해 실제 현장의 적용에 한계점을 가지고 있다. 본 연구는 이러한 점을 극복하고자 GGBFS 혼입률에 따른 페이스트의 압축강도, 수화열 등의 특성을 분석하였다. GGBS 분말도에 따른 4종류와 치환율 35%, 50%, 65%, 80% 4수준으로 하여 총 16개의 배합에 대해 실험을 수행하였다. 실험결과 낮은 물-바인더 비에 의한 고성능 하이볼륨 슬래그 시멘트 페이스트 배합은 초기 재령에서의 낮은 압축강도의 한계점을 극복할 수 있을 것으로 판단된다. 또한 GGBS의 분말도는 고성능 하이볼륨 슬래그 시멘트 페이스트의 초기 재령에서의 압축강도 증진에는 효과가 있지만, 28일 이후의 장기 강도에는 큰 영향이 없는 것으로 나타났다.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2009년도 정기 학술대회
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• pp.315-318
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• 2009

본 논문에서는 해상 기초 교각 매스 콘크리트의 수화열 저감 방안을 다루었다. 저발열 콘크리트, Mesh형 거푸집 공법 등에 대한 실험을 수행하여 각각의 수화열 저감효과를 평가하였다. 현장 실험은 사용 시멘트와 거푸집의 종류, 거푸집의 사용 면수에 따라 총 4 type으로 구성하였으며, 이에 대한 실험 결과와 유한 요소 해석 결과를 비교, 검증하여 최종적인 수화열 저감 성능을 도출하고자 하였다. 실험을 통해, 저발열 시멘트와 유로폼을 사용하는 것이 수화열 저감을 위해 효과적인 방법으로 판명되었으나 추가 공사비의 발생으로 효율성이 떨어질 것으로 판단된다. 또한 Mesh형 거푸집 적용 면 수와 온도 상승 저감 효과는 비례하는 것을 알 수 있었지만 내 외부 온도차가 다소 크게 나타나 수화열에 의한 균열 발생 확률면에서는 다소 불리하게 나타났다. 그러나 실험 단계에서 생략된 양생과 관리를 통하여 균열의 저감효과를 거둘 수 있을 것으로 판단되며, 추가적으로 거푸집 해체 단계를 생략함으로 공기단축 측면에서 유리할 것으로 판단된다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2000년도 봄 학술발표회 논문집
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• pp.47-52
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• 2000

Recently, it is very necessary the development of the manufacturing techniques for high strength concrete(HSC) for the large-scale size and good quality of civil structure. But, the manufacture and quality control of HSC of which shrinkage, heat of hydration and workability at construction filed are considered, is very difficult due to its low water-cement ratio and high quantity of unit cement content. In the present study, we tried to know and assess the influences of chemical and physical properties of cement on the material properties of HSC. We analyzed basic properties of 4 kinds of cement whose chemical and physical properties are different each other through various tests such as chemical analysis and mortal test. Also, we performed the assessment of the material properties of HSC for each dement by the test for the conditions of same mix design and similar compressive strength. From the results in the study, the assessment of the important quality factors of cement influencing the properties of HSC may be utilized to quality control of applied cement to manufacture the HSC of high quality.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1997년도 가을 학술발표회 논문집
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• pp.293-298
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• 1997

Corrosion of steel reinforcing in concrete deteriorated by freezing/thawing and carbonation was characterized. Concrete specimens were prepared using various kinds of cements such as ordinary portland cement (type I), low heat portland cement (type IV, belite rich cement), sulphate resistance portland cement (type V), blast furnace slag portland cement and ternary blended cement. Of various cements, type V and type IV with lower $C_3A$ content revealed better steel corrosion resistance after freezing/thawing and carbonation. $C_3A$ content in cement might affect freezing/thawing resistance in sea water.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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• pp.305-308
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• 2004

Cold weather concrete is the concrete which is used during construction under low-temperature' environment, and this kind of concrete has to be taken care not to be frozen in early ages of setting-hardening, It is specified in the Concrete Standard Specification(2003) as 'the cold weather concrete must be used on the weather condition under the average daily outdoor temperature below $4^{\circ}C$.' In this research, the mechanical characteristics and hydration heat on the cold weather concrete using high early strength portland cement were studied. As a result, the excellent quality was obtained and high early strength portland cement is expected to be used widely as the cold weather concrete.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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• pp.457-460
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• 2006

Recently ultra high strength concrete is actively being developed and studied, and this trend is explained with the following effects. Technological effects expected from the application of ultra high strength concrete include the reduction of section, the decrease of structure mass and the improvement of workability. Belite cement has properities like low heat of hydration, excellent long term strength, and durablity without admixture. so, Belite cement is suitable for mass structure which is needed high strenghth, high fluidity and heat property. The objective of this study is to examine the suitability of mixture ratio through experiment of basic physical properties and provide materials for the field application of ultra high strength concrete.

• Computers and Concrete
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• 제13권6호
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• pp.695-707
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• 2014

This study investigated the chloride binding isotherms of various cement types, especially the contributions of C-S-H and AFm hydrates to the chloride binding isotherms were determined. Ordinary Portland cement (OPC), Modified cement (MC), Rapid-hardening Portland cement (RHC) and Low-heat Portland cement (LHC) were used. The total chloride contents and free chloride contents were analyzed by ASTM. The contents of C-S-H, AFm hydrates and Friedel's salt were determined by X-ray diffraction Rietveld (XRD Rietveld) analysis. The results showed that OPC had the highest chloride binding capacity, and, LHC had the lowest binding capacity of chloride ions. MC and RHC had very similar capacities to bind chloride ions. Experimental equations which distinguish the chemically bound chloride and physically bound chloride were formulated to determine amounts of the bound chloride basing on chloride binding capacity of hydrates.

• 한국건축시공학회지
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• 제12권3호
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• pp.284-290
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• 2012

시멘트 입도계수(CFM)란 시멘트의 입자크기 분포를 정수로 표현하는 방법으로서 시멘트의 화학성분이나 광물조성은 변화시키지 않고, 시멘트 분쇄과정의 조정으로 CFM을 변화시킨다면 조강, 중용열 및 저열 등의 다양한 시멘트로의 접근이 가능할 것으로 추측된다. 따라서 본 연구에서는 CFM 변화를 활용한 특수 시멘트의 제조 가능성을 분석하기 위한 기초적 연구로서 CFM이 콘크리트의 기초적 특성에 미치는 영향에 대하여 검토하고자 하였다. 그 결과를 요약하면 굳지 않은 콘크리트의 배합특성으로 CFM이 커질수록 목표 유동성을 확보하기 위해 잔골재율 및 단위수량은 증가시켜 주어야 하고, AE제 및 SP제 사용량은 감소시켜 주어야 했다. 응결시간은 CFM이 커질수록 지연되었고, 압축강도는 초기재령에서는 상대적으로 낮았으나, 후기재령으로 갈수록 압축강도의 차이는 작아져 3년 정도가 되면 동등한 수준의 압축강도가 발현되었다.