• Title/Summary/Keyword: low dimensional materials

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Interfacial Charge and Mass Transfer at Graphene-SiO2 Substrates: Raman Spectroscopic Studies

  • Ryu, Sun-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.115.1-115.1
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    • 2014
  • Atom-thick 2-dimensional materials such as graphene, h-BN and MoS2 hold substantial potential for applications in future molecular-scale integrated electronics, transparent conducting membranes, nanocomposites, etc. From a fundamental point of view, 2-dim crystal-solid substrates can also serve as a unique system to study various physicochemical phenomena occurring at low dimensions or interfaces. In this talk, I will present our recent Raman spectroscopy studies on the surface science problems of graphene: interfacial charge transfer, molecular diffusion in confined space and structural deformation.

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Design and Preparation of High-Performance Bulk Thermoelectric Materials with Defect Structures

  • Lee, Kyu Hyoung;Kim, Sung Wng
    • Journal of the Korean Ceramic Society
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    • v.54 no.2
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    • pp.75-85
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    • 2017
  • Thermoelectric is a key technology for energy harvesting and solid-state cooling by direct thermal-to-electric energy conversion (or vice versa); however, the relatively low efficiency has limited thermoelectric systems to niche applications such as space power generation and small-scale or high-density cooling. To expand into larger scale power generation and cooling applications such as ATEG (automotive thermoelectric generators) and HVAC (heating, ventilation, and air conditioning), high-performance bulk thermoelectric materials and their low-cost processing are essential prerequisites. Recently, the performance of commercial thermoelectric materials including $Bi_2Te_3$-, PbTe-, skutterudite-, and half-Heusler-based compounds has been significantly improved through non-equilibrium processing technologies for defect engineering. This review summarizes material design approaches for the formation of multi-dimensional and multi-scale defect structures that can be used to manipulate both the electronic and thermal transport properties, and our recent progress in the synthesis of conventional thermoelectric materials with defect structures is described.

Technology Trend of the additive Manufacturing (AM) (적층식 제조(Additive manufacturing) 기술동향)

  • Oh, Ji-Won;Na, Hyunwoong;Choi, Hanshin
    • Journal of Powder Materials
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    • v.24 no.6
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    • pp.494-507
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    • 2017
  • A three-dimensional physical part can be fabricated from a three-dimensional digital model in a layer-wise manner via additive manufacturing (AM) technology, which is different from the conventional subtractive manufacturing technology. Numerous studies have been conducted to take advantage of the AM opportunities to penetrate bespoke custom product markets, functional engineering part markets, volatile low-volume markets, and spare part markets. Nevertheless, materials issues, machines issues, product issues, and qualification/certification issues still prevent the AM technology from being extensively adopted in industries. The present study briefly reviews the standard classification, technological structures, industrial applications, technological advances, and qualification/certification activities of the AM technology. The economics, productivity, quality, and reliability of the AM technology should be further improved to pass through the technology adoption lifecycle of innovation technology. The AM technology is continuously evolving through the introduction of PM materials, hybridization of AM and conventional manufacturing technologies, adoption of process diagnostics and control systems, and enhanced standardization of the whole lifecycle qualification and certification methodology.

Validation of a low-cost portable 3-dimensional face scanner

  • Liu, Catherine;Artopoulos, Andreas
    • Imaging Science in Dentistry
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    • v.49 no.1
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    • pp.35-43
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    • 2019
  • Purpose: The goal of this study was to assess the accuracy and reliability of a low-cost portable scanner (Scanify) for imaging facial casts compared to a previously validated portable digital stereophotogrammetry device (Vectra H1). This in vitro study was performed using 2 facial casts obtained by recording impressions of the authors, at King's College London Academic Centre of Reconstructive Science. Materials and Methods: The casts were marked with anthropometric landmarks, then digitised using Scanify and Vectra H1. Computed tomography (CT) scans of the same casts were performed to verify the validation of Vectra H1. The 3-dimensional (3D) images acquired with each device were compared using linear measurements and 3D surface analysis software. Results: Overall, 91% of the linear Scanify measurements were within 1 mm of the corresponding reference values. The mean overall surface difference between the Scanify and Vectra images was <0.3mm. Significant differences were detected in depth measurements. Merging multiple Scanify images produced significantly greater registration error. Conclusion: Scanify is a very low-cost device that could have clinical applications for facial imaging if imaging errors could be corrected by a future software update or hardware revision.

Dimensional Change of Melamine Sheet Laminated MDF Flooring by Heating (멜라민시트 적층 MDF 마루판재의 가열에 의한 치수변화)

  • Min, Ill-Hong;Kim, Eui-Sik;Han, Gyu-Seong
    • Journal of the Korean Wood Science and Technology
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    • v.24 no.4
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    • pp.32-39
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    • 1996
  • The overall purpose of this study was to investigate the dimensional changes of melamine sheet laminated medium density fiberboard(MDF) floorings by sub-heating system(Ondol). This study was also conducted to improve the properties of melamine sheet laminated MDF floorings. The effects of density, resin content, manufacturing speed of MDF and types of melamine sheet on dimensional and weight changes of floorings were investigated. The results were as followings. 1. Dimensional and weight change of melamine sheet laminated MDF flooring by heating decreased with decreasing the density of MDF. 2. Dimensional and weight change of melamine sheet laminated MDF flooring by heating decreased with increasing the resin content of MDF. 3. Dimensional and weight change of melamine sheet laminated MDF flooring by heating decreased with decreasing the manufacturing speed of MDF. 4. Dimensional change of melamine sheet laminated MDF flooring in width direction by heating was doubled than that in machine direction. 5. Dimensional change and curling of high pressure melamine laminate(HPM) laminated MDF flooring by heating was less than those of low pressure melamine laminate(LPL) flooring. 6. Weight loss of melamine sheet laminated MDF flooring by heating has linear relationship with shrinkage.

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Reduced graphene oxide field-effect transistor for biomolecule detection and study of sensing mechanism

  • Kim, D.J.;Sohn, I.Y.;Kim, D.I.;Yoon, O.J.;Yang, C.W.;Lee, N.E.;Park, J.S.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.431-431
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    • 2011
  • Graphene, two dimensional sheet of sp2-hybridized carbon, has attracted an enormous amount of interest due to excellent electrical, chemical and mechanical properties for the application of transparent conducting films, clean energy devices, field-effect transistors, optoelectronic devices and chemical sensors. Especially, graphene is promising candidate to detect the gas molecules and biomolecules due to the large specific surface area and signal-to-noise ratios. Despite of importance to the disease diagnosis, there are a few reports to demonstrate the graphene- and rGO-FET for biological sensors and the sensing mechanism are not fully understood. Here we describe scalable and facile fabrication of rGO-FET with the capability of label-free, ultrasensitive electrical detection of a cancer biomarker, prostate specific antigen/${\alpha}1$-antichymotrypsin (PSA-ACT) complex, in which the ultrathin rGO sensing channel was simply formed by a uniform self-assembly of two-dimensional rGO nanosheets on aminated pattern generated by inkjet printing. Sensing characteristics of rGO-FET immunosensor showed the highly precise, reliable, and linear shift in the Dirac point with the analyte concentration of PSA-ACT complex and extremely low detection limit as low as 1 fg/ml. We further analyzed the charge doping mechanism, which is the change in the charge carrier in the rGO channel varying by the concentration of biomolecules. Amenability of solution-based scalable fabrication and extremely high performance may enable rGO-FET device as a versatile multiplexed diagnostic biosensor for disease biomarkers.

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Experimental and Numerical Simulation Studies of Low-Velocity Impact Responses on Sandwich Panels for a BIMODAL Tram

  • Lee, Jae-Youl;Shin, Kwang-Bok;Jeong, Jong-Cheol
    • Advanced Composite Materials
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    • v.18 no.1
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    • pp.1-20
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    • 2009
  • This paper describes the results of experiments and numerical simulation studies on the impact and indentation damage created by low-velocity impact subjected onto honeycomb sandwich panels for application to the BIMODAL tram. The test panels were subjected to low-velocity impact loading using an instrumented testing machine at six energy levels. Contact force histories as a function of time were evaluated and compared. The extent of the damage and depth of the permanent indentation was measured quantitatively using a 3-dimensional scanner. An explicit finite element analysis based on LS-DYNA3D was focused on the introduction of a material damage model and numerical simulation of low-velocity impact responses on honeycomb sandwich panels. Extensive material testing was conducted to determine the input parameters for the metallic and composite face-sheet materials and the effective equivalent damage model for the orthotropic honeycomb core material. Good agreement was obtained between numerical and experimental results; in particular, the numerical simulation was able to predict impact damage area and the depth of indentation of honeycomb sandwich composite panels created by the impact loading.

Optical and Electrical Properties of ZnO Hybrid Structure Grown on Glass Substrate by Metal Organic Chemical Vapor Deposition (유기금속화학증착법으로 유리기판 위에 성장된 산화아연 하이브리드 구조의 광학적 전기적 특성)

  • Kim, Dae-Sik;Kang, Byung Hoon;Lee, Chang-Min;Byun, Dongjin
    • Korean Journal of Materials Research
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    • v.24 no.10
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    • pp.543-549
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    • 2014
  • A zinc oxide (ZnO) hybrid structure was successfully fabricated on a glass substrate by metal organic chemical vapor deposition (MOCVD). In-situ growth of a multi-dimensional ZnO hybrid structure was achieved by adjusting the growth temperature to determine the morphologies of either film or nanorods without any catalysts such as Au, Cu, Co, or Sn. The ZnO hybrid structure was composed of one-dimensional (1D) nanorods grown continuously on the two-dimensional (2D) ZnO film. The ZnO film of 2D mode was grown at a relatively low temperature, whereas the ZnO nanorods of 1D mode were grown at a higher temperature. The change of the morphologies of these materials led to improvements of the electrical and optical properties. The ZnO hybrid structure was characterized using various analytical tools. Scanning electron microscopy (SEM) was used to determine the surface morphology of the nanorods, which had grown well on the thin film. The structural characteristics of the polycrystalline ZnO hybrid grown on amorphous glass substrate were investigated by X-ray diffraction (XRD). Hall-effect measurement and a four-point probe were used to characterize the electrical properties. The hybrid structure was shown to be very effective at improving the electrical and the optical properties, decreasing the sheet resistance and the reflectance, and increasing the transmittance via refractive index (RI) engineering. The ZnO hybrid structure grown by MOCVD is very promising for opto-electronic devices as Photoconductive UV Detectors, anti-reflection coatings (ARC), and transparent conductive oxides (TCO).

Heating Characteristics of Planar Heater Fabricated with Different Mixing Ratios of MXene-CNT-WPU Composites (MXene-CNT-WPU 복합소재 기반 면상발열체의 배합 비율에 따른 발열 특성)

  • Hyo-Jun, Oh;Quy-Dat, Nguyen;Yoonsik, Yi;Choon-Gi, Choi
    • Clean Technology
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    • v.28 no.4
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    • pp.278-284
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    • 2022
  • This study presents an excellent planar heater based on low-dimensional composites. By optimizing the ratio of 1D carbon nanotubes (CNT) and 2D MXene (Ti3C2TX), it is possible to create a planar heater that has superior electrical conductivity and high heat generation characteristics. Low-dimensional composites were prepared by mixing CNT paste and MXene solution with eco-friendly waterborne polyurethane (WPU). In order to find the optimal mixing ratio for the MXene-CNT-WPU composites, samples with MXene to CNT weight ratios of 3:1, 1:1, 1:3, 1:7, and 1:14 were investigated. In addition to these different weight ratios, 5 wt% WPU was equally applied to each sample. It was confirmed that the higher the weight ratio of CNT, the lower the sheet resistance and the higher the heating temperature. In particular, when the MXene-CNT-WPU planar heater was fabricated by mixing MXene and CNT at a weight ratio of 1:7 and 1:14, the heating temperature was higher than the heating temperature of a CNT-WPU planar heater. These characteristics are due to the optimized mixture of the 1D materials (CNT) and the 2D materials (MXene) causing the formation of a flat surface and a dense network structure. The low-dimensional composites manufactured with the optimized mixing ratios found in this study are expected to be applied in flexible electronic devices.

The reflection characteristic of one-dimensional photonic crystal using by chalcogenide thin films (칼코게나이드 박막을 이용한 일차원 photonic crystal의 반사 특성)

  • Lee, Jung-Tae;Shin, Kyung;Yeo, Cheol-Ho;Ku, Dae-Sung;Kim, Jong-Bin;Chung, Hong-Bay
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.120-123
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    • 2002
  • In this study it had an excellent optical characteristic, it followed in the creation rate and the refractive index regulation to the ease. Chalcogenide produced the $As_{45}Se_{45}Te_{10}$ thin film and the $MgF_{2}$ thin film. It measured thin film plan simulation, and the thin film has a 1 -dimensional photonic band gap. The chalcogenide $As_{45}Se_{45}Te_{10}$ thin film was measured with the fact that it has a high refractive index (2.6~2.9). The $As_{45}Se_{45}Te_{10}$ and $MgF_{2}$ thin film, have a high refractive index and a low refractive index, it used a simulation and planed period 5-pairs structure, the result was from 500nm to 800nm. It will be able to confirm the characteristic which most of the incidence light reflects, the He-Ne (632.8nm) laser was irradiated in the thin film which stabilized the thin film. $As_{45}Se_{45}Te_{10}$ (high refractive index layer: H) and $MgF_{2}$ (low refractive index layer: L) results which plans the thin film with glass/LHLHLLHLHL/air structure, 632.8nm against transmitance, increased a lot. An application possibility with the filter against a specific wave length was confirmed.

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