• Journal of Powder Materials
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• v.27 no.1
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• pp.63-71
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• 2020

It is necessary to fabricate uniformly dispersed nanoscale catalyst materials with high activity and long-term stability for polymer electrolyte membrane fuel cells with excellent electrochemical characteristics of the oxygen reduction reaction and hydrogen oxidation reaction. Platinum is known as the best noble metal catalyst for polymer electrolyte membrane fuel cells because of its excellent catalytic activity. However, given that Pt is expensive, considerable efforts have been made to reduce the amount of Pt loading for both anode and cathode catalysts. Meanwhile, the atomic layer deposition (ALD) method shows excellent uniformity and precise particle size controllability over the three-dimensional structure. The research progress on noble metal ALD, such as Pt, Ru, Pd, and various metal alloys, is presented in this review. ALD technology enables the development of polymer electrolyte membrane fuel cells with excellent reactivity and durability.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.319.1-319.1
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• 2013

Solid oxide fuel cells (SOFCs) have been recognized as one of emerging renewable energy sources, due to minimized pollutant production and high efficiency in operation. The performance of SOFCs is largely dependent on the electrode polarization which involves the oxidation/reduction in cathodes and anodes along with the charge transport of ions and electronic carriers. Atomic layer deposition is based on the alternate chemical surface reaction occurring at low temperatures with high uniformity and superior step coverage. Such features can be extended into the coating of metal oxide and/or metal layer onto the porous materials. In particular, the atomic layer deposition is can manipulated in controlling the charge transport in terms of triple phase boundaries, in order to control artificially the electrochemical polarization in electrodes of SOFC. The current work applied atomic layer deposition of metal oxides intro the electrodes of SOFCs. The corresponding effect was monitored in terms of the electrochemical characterization. The roles of atomic layer deposition in solid oxide fuel cells are discussed towards optimized towards long-term durability at intermediate temperature.

• Journal of Wetlands Research
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• v.15 no.4
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• pp.493-500
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• 2013

Comparisons of surface sediment distributions in summer 1997 and 2011 and elevations on the tidal flats in April 1998 and March 2013 had been used for understanding the long-term changes of sedimentary environments at southern Kanghwa tidal flat, west coast of Korea. The mud sediments dominated in the eastern part and sandy mud sediments dominated in the western part of the tidal flat in 1997. In 2011, the surface sediments were dominant mud and sandy mud at Sunduri and Tonggum in the eastern part, sandy mud at Tongmakri in the middle part, and sand and muddy sand at Yeochari and Changhwari tidal flats in the western part. The area of mud sediments had decreased, but that of sand-mud mixed sediments extended to eastward tidal flat for 14 years. The long-term topographic changes showed that deposition occurred at Tongmakri and Yeochari and erosion occurred at Changhwari tidal flat during 15 years. These changes should be effected the local hydrodynamic changes by several constructions near the tidal flat since the 1990s.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.675-675
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• 2013

CIGS thin films have received a great attention as a promising material for solar cells due to their high absorption coefficient, appropriate bandgap, long-term stability, and low cost production. CIGS thin films have been deposited by various methods such as co-evaporation, sputtering, spray pyrolysis and electro-deposition. In this study, Cu(In,Ga)Se2(CIGS) thin films were prepared using a single quaternary target by rf magnetron sputtering. The effect of sulfurization on the structural, compositional and electrical properties of the films was examined in order to develop the deposition process. An optimal sulfurization process will be selected for the preparation of CIGS thin films with good structural, optical and electrical properties by applying various sulfurization processes. In addition, the electrical properties of CIGS thin films were investigated by post-deposition annealing process. The carrier concentration of CIG(SSe) thin films after sulfurization was increased from $10^{14}cm^{-3}$ to $10^{16}cm^{-3}$ and the resistivity was increased from 10 ${\Omega}cm$ to $10^3$ ${\Omega}cm$. It is confirmed that CIG(SSe) thin films prepared at optimal deposition condition have similar atomic ratio to the target value after sulfurization.

• Fire Science and Engineering
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• v.33 no.6
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• pp.95-104
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• 2019

Smoke generated in a fire consists of gaseous substances and particulate matter, such as unburned carbon that adsorbed the gases. Human injury caused by inhalation of gaseous substances present in smoke is mostly short-term, whereas damage caused by inhalation of particulate matter is relatively a long-term phenomenon depending on the state of the gas-phase adsorption. The amount and location of the deposited smoke particles are important factors in estimating the damage caused to humans, which are affected by the breathing conditions as well as particle conditions, such as the size and concentration affected by the combustion conditions. In this study, in order to understand the characteristics of the deposition of smoke particles in the respiratory tract related to the study of human smoke inhalation injury, the number and mass concentration of smoke particles deposited in different areas of the respiratory tract for different fuel types, combustion conditions and breathing conditions were calculated. In addition, the amount of mass deposition of smoke in the respiratory tract for a certain period of inhalation was compared with the atmospheric standard of fine dust.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2009.10a
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• pp.446-447
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• 2009

• Ecology and Resilient Infrastructure
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• v.4 no.1
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• pp.12-23
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• 2017

The Naeseong Stream is a meandering sand-bed stream flowing through mountains and has so long maintained its geomorphological uniqueness characterized by extensive braided bare bars. Recently, its long-lasting landscape has been changed due to encroachment of vegetation. In this study being a part of long-term monitoring research morphological changes of the 56.8 km long study reach of the Naeseong Stream, which occurred during the period of 2012 - 2016 were analyzed. Airborne LiDAR and terrestrial cross-section surveys were carried out. Hydrological and on-site investigation data were also collected. Among the main four sites, two bend reaches showed point bars enlarged, while along the other two straight reaches mid-channel bars were either newly formed or increased in area and height. At the highest deposition point of each bar, vertical changes which were caused by one or two times of sediment deposition amounted to 0.6 - 1.4 m. On the contrary channel bed degradation was not obvious. Overall morphological changes in the study reach were attributed to deposition of sediment which occurred during the flood in July 2016 on the bar surfaces vegetated during the precedent dry seasons. These kind of geomorphological processes are thought to be the same as those related to the existing mid-channel islands along the mid- and downstream reach of the Naeseong Stream.

• Journal of Environmental Science International
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• v.11 no.6
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• pp.489-496
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• 2002

The purpose of this study was to investigate spatial distributions of total deposition. A total number 79 samples were collected at 17 sampling sites from September 1999 to January 2000. Total (=wet+dry) atmospheric depositions were collected by filtered deposition sampler at sampling site (the Western Part of Kyongsangnam Province). In addition, the deposition of soluble and insoluble fraction was also investigated to find a suitable simplified collection method for a long-term monitoring of total deposition. The total depositions were measured soluble amount(mm/month), insoluble amount(kg/km$^2$/month), pH, conductivity(E.C.) and eight ionic components. The spatial distribution of deposition flux was to estimated by using a kringing analysis. The 17 sites mean fluxes of water soluble ionic components; SO$_4$$\^$2-/, Cl$\^$-/, NO$_3$$\^$-/, Na$\^$+/, NH$_4$$\^$+/, K$\^$+/, Mg$\^$2+/, Ca$\^$2+/ were 100.7∼315.6kg/km$^2$/month, 30.1∼234.3kg/km$^2$/month, 64.4∼ 139.4kg/km$^2$/month, 7.5∼68.3kg/km$^2$/month, 10.7∼48.7kg/km$^2$/month, 5.6∼27.9kg/km$^2$/month, 4.5∼17.5kg/km$^2$/month, 27.6∼81.7kg/km$^2$/month, respectively.

• Korean Journal of Environmental Biology
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• v.19 no.4
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• pp.232-238
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• 2001

Effects of atmospheric nitrogen deposition on terrestrial ecosystems were reviewed and discussed in this paper. The amount of nitrogen deposition has increased rapidly in Europe, North America and Korean due to industrialization, increase in fossil fuel combustion(automobiles in particular), and intensive agricultural activities. Nitrogen input through such deposition may enhance primary productivity at early stage, but it could cause nitrogen saturation and hence deterioration of forests of disturbance of systems in the long term. Mechanisms of the deterioration of forests by nitrogen deposition include nutrients imbalance, soil acidification, and immobilization of toxic ions. In addition, nitrogen deposition may impede the decomposition rates of soil organic matter, and induce eutrophication in aquatic ecosystems by enhanced leaching of nitrate. Finally, I propose several topics in relation to nitrogen deposition, which warrant further studies in Korea.

• Proceedings of the KIEE Conference
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• 2011.07a
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• pp.1408-1409
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• 2011

Carbon nanotubes (CNTs) were grown on conical tip substrates by using various methods such as electrophoretic deposition, dip-coating, and spray. The scanning electron microscope measurement showed that the spray method ascertained the most uniform deposition of CNTs. The CNT-emitter that was fabricated by the spray method revealed the lowest turn on voltage of electron emission and the highest emission current. In addition, the spray-produced CNT emitter showed the most stable long-term emission characteristics.