• Title/Summary/Keyword: long electrode

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Improved Conversion Efficiency of Dye-sensitized Solar Cells Based on TiO2 Porous Layer Coated TiO2 Nanotubes on a Titanium Mesh Substrate as Photoanode

  • Lim, Jae-Min;He, Weizhen;Kim, Hyung-Kook;Hwang, Yoon-Hwae
    • Current Photovoltaic Research
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    • v.1 no.2
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    • pp.90-96
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    • 2013
  • We report here flexible dye-sensitized solar cells (DSSC) based on Ti-mesh electrodes that show good mechanical flexibility and electrical conductivity. $TiO_2$ nanotube arrays prepared by electrochemical anodizing Ti-mesh substrate were used as photoanode. A Pt-coated Ti-mesh substrate was used as counter electrode. The photoanodes were modified by coating a $TiO_2$ porous layer onto the $TiO_2$ nanotubes in order to increase the specific surface area. To increase the long term stability of the DSSCs, a gel type electrolyte was used instead of a conventional liquid type electrolyte. The DSSC based on $33.2{\mu}m$ long porous $TiO_2$ nanotubes exhibited a better energy conversion efficiency of ~2.33%, which was higher than that of the DSSCs based on non-porous $TiO_2$ nanotubes.

Study on Automatic Mixing of Nutrient Solution Using ion Electrodes for Closed-Loop Hydroponics (이온전극을 이용한 순환식 양액 자동 조제에 관한 연구)

  • 김민규;류관희;장유섭;김기영
    • Journal of Biosystems Engineering
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    • v.27 no.5
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    • pp.425-432
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    • 2002
  • This study was carried out to develop an automatic mixing system of nutrient solution for closed-loop hydroponics using ion electrodes. The results of the study are summarized as follows: 1. It appeared that ion-electrodes had not to be soaked into nutrient solution for a long time since it was much less durable than EC or PH sensors. Once ion-electrodes were soaked into real nutrient solution for a long time, they became unstable. 2. ion measurement modules, which were able to sample recirculated nutrient solution and easily wash and dry ion-electrodes, were developed in order to use ion-electrodes continuously. 3. The results of calibration tests on three kinds of ion electrodes presented that the time required to read measurement data was over 30 seconds. Using the calibration data the regression equations for the ion electrodes were developed. 4. An automatic nutrient-solution mixing system using the three kinds of ion electrodes was developed and then its accuracy was examined. The control errors of the mixing system using ion electrodes were in the range of 9.8 to 12%.

Effect of Moisture on Cu(In,Ga)Se2 Solar Cell with (Ga,Al) Co-doped ZnO as Window Layer ((Ga,Al)이 도핑된 ZnO를 투명전극으로 가진 Cu(In,Ga)Se2 태양전지에 수분이 미치는 영향)

  • Yang, So Hyun;Bae, Jin A;Song, Yu Jin;Jeon, Chan Wook
    • Current Photovoltaic Research
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    • v.5 no.4
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    • pp.135-139
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    • 2017
  • We fabricated two different transparent conducting oxide thin films of ZnO doped with Ga ($Ga_2O_3$ 0.9 wt%) as well as Al ($Al_2O_3$ 2.1 wt%) (GAZO) and ZnO doped only with Al ($Al_2O_3$ 3 wt%) (AZO). It was investigated how it affects the moisture resistance of the transparent electrode. In addition, $Cu(In,Ga)Se_2$ thin film solar cells with two transparent oxides as front electrodes were fabricated, and the correlation between humidity resistance of transparent electrodes and device performance of solar cells was examined. When both transparent electrodes were exposed to high temperature distilled water, they showed a rapid increase in sheet resistance and a decrease in the fill factor of the solar cell. However, AZO showed a drastic decrease in efficiency at the beginning of exposure, while GAZO showed that the deterioration of efficiency occurred over a long period of time and that the long term moisture resistance of GAZO was better.

Wearable Approach of ECG Monitoring System for Wireless Tele-Home Care Application

  • Kew, Hsein-Ping;Noh, Yun-Hong;Jeong, Do-Un
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2009.05a
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    • pp.337-340
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    • 2009
  • Wireless tele-home-care application gives new possibilities for ECG (electrocardiogram) monitoring system with wearable biomedical sensors. Thus, continuously development of high convenient ECG monitoring system for high-risk cardiac patients is essential. This paper describes to monitor a person's ECG using wearable approach. A wearable belt-type ECG electrode with integrated electronics has been developed and has proven long-term robustness and monitoring of all electrical components. The measured ECG signal is transmitted via an ultra low power consumption wireless sensor node. ECG signals carry a lot clinical information for a cardiologist especially the R-peak detection in ECG. R-peak detection generally uses the threshold value which is fixed thus it bring errors due to motion artifacts and signal size changes. Variable threshold method is used to detect the R-peak which is more accurate and efficient. In order to evaluate the performance analysis, R-peak detection using MIT-BIH databases and Long Term Real-Time ECG is performed in this research. This concept able to allow patient to follow up critical patients from their home and early detecting rarely occurrences of cardiac arrhythmia.

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Daily Amperometric Monitoring of Immunoglobulin E in a Mouse Whole Blood: Model of Ovalbumin Induced Asthma

  • Lee, Ju Kyung;Yoon, Sung-hoon;Kim, Sang Hee
    • Journal of the Korean Electrochemical Society
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    • v.25 no.1
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    • pp.13-21
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    • 2022
  • There is an increasing interest in monitoring of specific biomarker for determining progression of a disease or efficacy of a treatment. Conventional method for quantification of specific biomarkers as enzyme linked immunosorbent assay (ELISA) has high material costs, long incubation periods, requires large volume of samples and involves special instruments, which necessitates clinical samples to be sent to a lab. This paper reports on the development of an electrochemical biosensor to measure total immunoglobulin E (IgE), a marker of asthma disease that varies with age, gender, and disease in concentrations from 0.3-1000 ng/mL with consuming 20 µL volume of whole blood sample. The sensor provides rapid, accurate, easy, point-of-care measurement of IgE, also, sequential monitoring of total IgE with ovalbumin (OVA) induced mice is another application of sensor. Taken together, these results provide an alternative way for detection of biomarkers in whole blood with low volumes and long-term ex-vivo assessments for understanding the progression of a disease.

Electrochemical Characteristics of EDLC with various Organic Electrolytes (유기전해질에 따른 EDLC의 전기화학적 특성)

  • Yang Chun-Mo;Lee J.K.;Cho W.I.;Cho B.W.;Rim Byung-O
    • Journal of the Korean Electrochemical Society
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    • v.4 no.3
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    • pp.113-117
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    • 2001
  • Specific capacitance and charge-discharge rate of EDLC using activated carbon electrode were affected by the compositions of electrolytes, the conditions of charge-discharge and physical properties of activated carbon materials. The activated carbon electrode was prepared by dip coating method. Charge-discharge test and electrochemical experiments were carried out for various kinds of organic electrolytes. Effects of charge and discharge current density on the specific capacitance were studied. Characteristics of leakage current, self-discharge and time-voltage curves in optimum conditions of organic electrolytes were compared with conventional $1M-Et_4NBF_4/PC$ electrolyte. The EDLC using MSP-20(specific surface area: $2000m^2/g$) electrode and $1M-LiPF_6/PC-DEC(1:1)$ was exhibited th highest specific capacitance of 130F/g and low polarization resistances. The EDLC using MSP-20 electrode at $1M-LiPF_6/PC-DEC(1:1)$ was small leak current of 0.0004A for 15min, long voltage retention of 0.8V after 100h and linear time-voltage curves with small IR-drop.

Effect of the Sulfur Removal in Manufacturing Pt/C Electrocatalysts on the Performance of Phosphoric Acid Fuel Cell (인산형 연료전지용 백금촉매제조에서 황의 제거에 따른 전극 성능)

  • Shim, Jae-Cheol;Lee, Kyung-Jik;Lee, Ju-Seong
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.486-490
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    • 1998
  • Pt/C powder which was used as electrocatalyst in a Phosphoric Acid Fuel Cell(PAFC) was fabricated by colloid method. It was reported that the sulfur from reductant, $Na_2S_2O_4$, worked as a poison against catalyst during long term operation. To remove these sulfurs, we try to treat Pt/C powder by three different methods. First, we tried to remove the sulfur according to temperature and time in $H_2$ atmosphere. As the heat treatment temperature is raised up, the effect of the removal is increased but the electrode performance is decreased because of the growth of Pt particle size. The optimal heat treatment temperature is $400^{\circ}C$, the size of Pt particle is approximately $35{\sim}40{\AA}$ and the electrode performance is $360mA/cm^2$ at 0.7 V. At $400^{\circ}C$, even though the time of heat treatment is extended, size of Pt, amounts of remaining sulfur and electrode performance is almost constant. Secondly, when we removed in a crucible at $900^{\circ}C$ the removal of the sulfur was not better, but the size of Pt particle, approximately $80{\AA}$, was smaller than that of heat treatment in $H_2$ atmosphere at $900^{\circ}C$. Lastly we treated with solvents such as acetone, benzene, and carbon disulfide. It was observed that sulfur components were removed partly by extraction with solvents, the electrode performances were similar each other.

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An Experimental Study on Installation Effects of Pipe Elbow on the Electromagnetic Flowmeter Characteristics (Turbulent Flow) (곡관의 하류에 설치된 전자기유량계의 유량신호 특성에 관한 실험적 연구(난류 유동))

  • Lim, Ki-Won
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.11
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    • pp.1613-1621
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    • 2002
  • An electromagnetic flowmeter(EMF) essentially averages the velocity distribution over the pipe cross- sectional area, and the measured value is dependent on the velocity profiles. In this study, installation effects of 90$^{\circ}$long elbow(KS B 1522, ISO 3419) on the EMF characteristics was investigated. A commercial EMF was adopted and the distribution of magnetic field in the electrodes cross section was measured. In the experiment, the national flow standard system, of which measurement uncertainty was evaluated in accordance with ISO 17025 recommendation, was used fur characterization of EMF. The leading line has 150D long straight pipe to established a fully developed flow before entering into the elbow and the elbow was installed downstream of it. then the flowmeter was tested within 50 D from the elbow. The installation effects of the flowmeter were investigated by varying the mean velocity(Reynolds No.)in pipe section, the locations and the direction of electrodes plane.($\phi$) From the experimental results, we find the optimal conditions to get most accurate measurements. Generally, the deviations from the calibration value were less than 0.5 % in farther than 10D distance from the elbow and the direction of electrode plane. $\phi$ = 90$^{\circ}$yielded the smallest measurement deviation. These characteristics were shown consistently in turbulent region regardless of the mean Reynolds number.

Long-term AC Electrical Treeing Behaviors of Epoxy/Layered Silicate Nanocomposites Prepared by a 3-Roll Mill

  • Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.2
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    • pp.85-88
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    • 2012
  • Studies on the effects of layered silicate content on the AC electrical treeing and breakdown behaviors of epoxy/layered silicate nanocomposites were carried out in needle-plate electrode geometry. Wide-angle X-ray diffraction (WAXD) analysis and transmission electron microscopy (TEM) observation showed that 1 wt% of the multilayered silicate was fully exfoliated into nano-sized monolayers in the epoxy matrix however, over 3 wt% of the silicate was in an intercalated state. When 1 wt% layered silicates were incorporated, an electrical tree was initiated in 439 min and propagated at a speed of 2.3 ${\mu}m$/min after applying 781.4 kV/mm, representing a decreased in starting initiation time by a factor of 11.0 and increase in propagation speed by a factor 8.2 in comparison with neat epoxy resin. These values were in great decline after the layered silicate content was increased to 3wt% which implies that the exfoliated silicate blocked the tree initiation and propagation processes effectively. However the effect was largely decreased in the intercalated state.

Zundel- and Eigen-like Surface Hydrated Protons on Pt(111)

  • Kim, Youngsoon;Park, Youngwook;Shin, Sunghwan;Kang, Heon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.167.1-167.1
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    • 2016
  • The interaction between adsorbed water and hydrogen on metallic surfaces is important for fundamental understanding of heterogeneous catalysis and electrode surface reactions in acidic environment. Here, we explore a long-standing question of whether hydronium ion can exist or not on a Pt surface coadsorbed with atomic hydrogen and water. Studies based on mass spectrometry and infrared spectroscopy show clear evidence that hydrogen atoms are converted into hydrated protons on a Pt(111) surface. The preferential structures of hydrated protons are identified as multiply hydrated $H_5O_2{^+}$ and $H_7O_3{^+}$ species rather than as hydronium ions. The multiply hydrated protons may be regarded as two dimensional zundel ($H_5O_2{^+}$) and Eigen cation ($H_7O_3{^+}$) in water-metal interface. These surface-bound hydrated protons may be key surface intermediates of the electrochemical interconversion between adsorbed hydrogen atoms and solvated protons.

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