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The Chemical Composition of the Nagdong River Downstream Water (낙동강 하류수의 수질조성에 대하여)

  • WON Jong Hun;LEE Bae Jung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.14 no.2
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    • pp.47-58
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    • 1981
  • Relationships between the electrical conductivity and the contents of the chloride, sulfate, calcium, magnesium, sodium, potassium and total major inorganic ions, and between each, chemical conservative constituents were calculated with the data which sampled at the lesions of Mulgeum and between Namji and Wondong from March 1974 to April 1980. Semilogarithmic relations were found between the electrical conductivity and the contents of monovalent ions, and logarithmic relations were found between the electrical conductivity and the contents of divalent ions at the both regions. The relational equations between the electrical conductivity $\lambda_{25}$and the contents of the major inorganic ions at Mulgeum are as follows: $log\;Cl(ppm)\;=\;2.37{\cdot}\lambda_{25}(m{\mho}/cm)+0.733{\pm}0.141$, $log\;SO_4(ppm)=1.12{\cdot}log\lambda_{25}(m{\mho}/cm)+2.14{\pm}0.18$, $log\;Ca(ppm)=0.615{\cdot}log\lambda_{25}(m{\mho}/cm)+1.67{\pm}0.12$, $log\;Mg(ppm)=0.756{\cdot}log\lambda_{25}(m{\mho}/cm)+1.27{\pm}0.11$, $log\;Na(ppm)=2.82{\cdot}\lambda_{25}(m{\mho}/cm)+0.551{\pm}0.133$, $log\;K(ppm)=1.33{\cdot}\lambda_{25}(m{\mho}/cm)+0.136{\pm}0.095$, and total inorganic ions $C(ppm)=399{\cdot}\lambda_{25}(m{\mho}/cm)-0.9{\pm}14.6$. The relational equations between the electrical conductivity ($\lambda_{25}$) and the contents of the major inorganic ions at the region between Namji and Wondong a.e as follows: $log\;Cl(ppm)=4.27{\cdot}\lambda_{25}(m{\mho}/cm)+0.380{\pm}0.138$, $log\;SO_4(ppm)=0.915{\cdot}log\lambda_{25}(m{\mho}/cm)+1.95{\pm}0.18$, $log\;Ca(ppm)=0.756{\cdot}log\lambda_{25}(m{\mho}/cm)+1.74{\pm}0.12$, $log\;Mg(ppm)=1.00{\cdot}log\lambda_{25}(m{\mho}/cm)+1.41{\pm}0.10$. $log\;Na(ppm)=2.47{\cdot}\lambda_{25}(m{\mho}/cm)+0.614{\pm}0.065$, $log\;K(ppm)=1.62{\cdot}\lambda_{25}(m{\mho}/cm)+0.030{\pm}0.060$, and total inorganic ions $C(ppm)=323{\cdot}\lambda_{25}(m{\mho}/cm)+11.7{\pm}9.3$. Logarithmic relations were found between each chemical conservative constituents at Mulgeum and the equations are as follows: $log\;Cl(ppm)=0.711{\cdot}log\;SO_4(ppm)+0.488{\pm}0.206$, $log\;Cl(ppm)=0.337{\cdot}log\;Ca(ppm)+0.822{\pm}0.130$, $log\;Cl(ppm)=0.605{\cdot}log\;Mg(ppm)-0.017{\pm}0.154$, $Cl(ppm)=0.676{\cdot}Na(ppm)+2.31{\pm}4.67$, $log\;Cl(ppm)=0.406{\cdot}log\;K(ppm)-0.092{\pm}0.112$, $log\;SO_4(ppm)=0.378{\cdot}log\;Ca(ppm)+0.721{\pm}0.125$, $log\;SO_4(ppm)=0.462{\cdot}log\;Mg(ppm)+0.107{\pm}0.118$, $log\;SO_4(ppm)=0.592{\cdot}log\;Na(ppm)+0.313{\pm}0.191$, $log\;SO_4(ppm)=0.308{\cdot}log\;K(ppm)-0.019{\pm}0.120$, $Ca(ppm)=0.262{\cdot}Mg(ppm)+0.74{\pm}1.71$. $log\;Ca(ppm)=1.10{\cdot}log\;Na(ppm)-0.243{\pm}0.239$, $Ca(ppm)=0.0737{\cdot}K(ppm)+1.26{\pm}0.73$, $log\;Mg(ppm)=0.0950{\cdot}Na(ppm)+0.587{\pm}0.159$, $log\;Mg(ppm)=0.0518{\cdot}K(ppm)+0.111{\pm}0.102$, and $Na(ppm)=0.0771{\cdot}K(ppm)+1.49{\pm}0.59$. Logarithmic relations were found between each chemical conservative constituents except a relationship between the chloride and calcium contents at the region between Namji and Wondong, and the equations are as follows : $log\;Cl(ppm)=0.312{\cdot}log\;SO_4(ppm)+0.907{\pm}0.210$, $log\;Cl(ppm)=0.458{\cdot}log\;Mg(ppm)+0.135{\pm}0.130$, $Cl(ppm)=0.484{\cdot}logNa(ppm)+0.507{\pm}0.081$, $Cl(ppm)=0.0476{\cdot}K(ppm)+1.41{\pm}0.34$, $log\;SO_4(ppm)=0.886{\cdot}log\;Ca(ppm)+0.046{\pm}0.050$, $log\;SO_4(ppm)=0.422{\cdot}log\;Mg(ppm)+0.139{\pm}0.161$, $log\;SO_4(ppm)=0.374{\cdot}log\;Na(ppm)+0.603{\pm}0.140$, $log\;SO_4(ppm)=0.245{\cdot}log\;K(ppm)+0.023{\pm}0.102$, $log\;Ca(ppm)=0.587{\cdot}log\;Mg(ppm)+0.003{\pm}0.088$, $log\;Ca(ppm)=0.892{\cdot}log\;Na(ppm)+0.028{\pm}0.109$, $log\;Ca(ppm)=0.294{\cdot}log\;K(ppm)-0.001{\pm}0.085$, $log\;Mg(ppm)=0.600{\cdot}log\;Na(ppm)+0.674{\pm}0.120$, $log\;Mg(ppm)=0.440{\cdot}log\;K(ppm)+0.038{\pm}0.081$, and $log\;Na(ppm)=0.522{\cdot}log\;K(ppm)-0.260{\pm}0.072$.

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Synthesis, Protonation Constants and Stability Constants for $Co^{2+}$, $Ni^{2+}$, $Cu^{2+}$, and $Zn^{2+}$ Ions of 1,15-bis(2-pyridyl)-2,5,8,11,14-pentaazapentadecane

  • Kim, Sun-Deuk;Kim, Jun-Kwang;Jung, Woo-Sik;Chung, Koo-Chun
    • Analytical Science and Technology
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    • v.9 no.4
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    • pp.411-415
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    • 1996
  • The new potentially heptadentate $N_7$ ligand 1, 15-bis(2-pyridyl)-2, 5, 8, 11, 14-pentaazapentadecane(pytetren) has been synthesized and characterized by EA, IR, NMR, and mass spectrometry. Its proton association constants (log $K{_H}^n$) and stability constants(log $K_{ML}$) for $Co^{2+}$, $Ni^{2+}$, $Cu^{2+}$, and $Zn^{2+}$ ions were determined at 298.1K and ionic strength=0.100M($KNO_3$) by potentiometry: log $K{_H}^1=9.36$, log $K{_H}^2=9.12$, log $K{_H}^3=8.09$, log $K{_H}^4=6.62$, log $K{_H}^5=4.02$, log $K{_H}^6=2.54$: log $K_{ML}(CO^{2+})=22.67$, log $K_{ML}(Ni^{2+})=26.25$. log $K_{ML}(Cu^{2+})=28.46$, log $K_{ML}(Zn^{2+})=19.90$.

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Identification of Tetrachloroethylene Sorption Behaviors in Natural Sorbents Via Sorption Models

  • Al Masud, Md Abdullah;Choi, Jiyeon;Shin, Won Sik
    • Journal of Soil and Groundwater Environment
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    • v.27 no.6
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    • pp.47-57
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    • 2022
  • A number of different methods have been used for modeling the sorption of volatile organic chlorinated compounds such as tetrachloroethylene/perchloroethylene (PCE). In this study, PCE was adsorbed in several natural sorbents, i.e., Pahokee peat, vermicompost, BionSoil®, and natural soil, in the batch experiments. Several sorption models such as linear, Freundlich, solubility-normalized Freundlich model, and Polanyi-Manes model (PMM) were used to analyze sorption isotherms. The relationship between sorption model parameters, organic carbon content (foc), and elemental C/N ratio was studied. The organic carbon normalized partition coefficient values (log Koc = 1.50-3.13) in four different sorbents were less than the logarithm of the octanol-water partition coefficient (log Kow = 3.40) of PCE due to high organic carbon contents. The log Koc decreased linearly with log foc and log C/N ratio, but increased linearly with log O/C, log H/C, and log (N+O)/C ratio. Both log KF,oc or log KF,oc decreased linearly with log foc (R2 = 0.88-0.92) and log C/N ratio (R2 = 0.57-0.76), but increased linearly with log (N+O)/C (R2 = 0.93-0.95). The log qmax,oc decreased linearly as log foc and log C/N increased, whereas it increased with log O/C, log H/C and log (N+O)/C ratios. The log qmax,oc increased linearly with (N+O)/C indicating a strong dependence of qmax,oc on the polarity index. The results showed that PCE sorption behaviors were strongly correlated with the physicochemical properties of soil organic matter (SOM).

Protonation and Stability Constants for $Co^{2+},\;Ni^{2+},\;Cu^{2+},\;and\;Zn^{2+}$ of the Open-Chain Polyamine 1-Amino-13-(2-pyridyl)-3,6,9,12-tetraaza-tridecane. Crystal Structure of Its Nickel(Ⅱ) Complex

  • 김선덕;김준광;정우식
    • Bulletin of the Korean Chemical Society
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    • v.18 no.6
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    • pp.653-656
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    • 1997
  • The new unsymmetric $N_6$ ligand 1-amino-13-(2-pyridyl)-3,6,9,12-tetraazatridecane (aptatd) containing one pyridyl group has been synthesized and characterized by EA, IR, and NMR. Its proton association constants $(log K_H^n)$ and stability constants $(log K_{ML})$ for Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ), and Zn(Ⅱ) ions were determined at 298.1 K and ionic strength 0.100 mol $dm^{-3}$ (KNO₃) in aqueous solution by potentiometry: log $K_H^1$=8.80, log $K_H^2$=8.49, log $K_H^3$=6.84, log $K_H^4$=4.17, log $K_H^5$=3.47; log $K_{ML}(Co^{2+})$=18.00, log $K_{ML}(Ni^{2+})$=21.31, log $K_{ML}(Cu^{2+})$=23.62, log $K_{ML}(Zn^{2+})$=15.60. The X-ray structure of its nickel(Ⅱ) complex [Ni(aptatd)]$(ClO_4)_2$ are reported: orthorhombic space group Pbca, a=15.715(1) Å, b=14.280(2) Å, c=19.443(2) Å, V=4363.4 (9) ų with Z=8. The geometry around nickel is a distorted octahedron with the pyridine nitrogen atom being cis to the nitrogen atom of the terminal primary amine.

Auto Configuration Module for Logstash in Elasticsearch Ecosystem

  • Ahmed, Hammad;Park, Yoosang;Choi, Jongsun;Choi, Jaeyoung
    • Proceedings of the Korea Information Processing Society Conference
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    • 2018.10a
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    • pp.39-42
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    • 2018
  • Log analysis and monitoring have a significant importance in most of the systems. Log management has core importance in applications like distributed applications, cloud based applications, and applications designed for big data. These applications produce a large number of log files which contain essential information. This information can be used for log analytics to understand the relevant patterns from varying log data. However, they need some tools for the purpose of parsing, storing, and visualizing log informations. "Elasticsearch, Logstash, and Kibana"(ELK Stack) is one of the most popular analyzing tools for log management. For the ingestion of log files configuration files have a key importance, as they cover all the services needed to input, process, and output the log files. However, creating configuration files is sometimes very complicated and time consuming in many applications as it requires domain expertise and manual creation. In this paper, an auto configuration module for Logstash is proposed which aims to auto generate the configuration files for Logstash. The primary purpose of this paper is to provide a mechanism, which can be used to auto generate the configuration files for corresponding log files in less time. The proposed module aims to provide an overall efficiency in the log management system.

Dynamic Compressed Representation of Texts with Rank/Select

  • Lee, Sun-Ho;Park, Kun-Soo
    • Journal of Computing Science and Engineering
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    • v.3 no.1
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    • pp.15-26
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    • 2009
  • Given an n-length text T over a $\sigma$-size alphabet, we present a compressed representation of T which supports retrieving queries of rank/select/access and updating queries of insert/delete. For a measure of compression, we use the empirical entropy H(T), which defines a lower bound nH(T) bits for any algorithm to compress T of n log $\sigma$ bits. Our representation takes this entropy bound of T, i.e., nH(T) $\leq$ n log $\sigma$ bits, and an additional bits less than the text size, i.e., o(n log $\sigma$) + O(n) bits. In compressed space of nH(T) + o(n log $\sigma$) + O(n) bits, our representation supports O(log n) time queries for a log n-size alphabet and its extension provides O(($1+\frac{{\log}\;{\sigma}}{{\log}\;{\log}\;n}$) log n) time queries for a $\sigma$-size alphabet.

Retention Behavior of Lanthanide Complexes with $\alpha$ -hydroxyisobutyric Acid on Cation Exchanger (양이온 교환체에서 희토류원소와 $\alpha$-Hydroxyisobutyric Acid 착물들의 머무름 거동에 관한 연구)

  • Jo, Gi Su;Han, Seon Ho;Seo, Mu Yeol;Eom, Tae Yun;Kim, Yeon Du
    • Journal of the Korean Chemical Society
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    • v.34 no.6
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    • pp.582-592
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    • 1990
  • Retention behavior of lanthanide-$\alpha$HiBA complexes was studied on the cation exchanger (LC-18 coated with $C_{20}H_{41}SO_4^-$). An equation predicting retention of lanthanides in isocratic or gradient elution with sodium ion and $\alpha$-HiBA concentration was derived from ion exchange equilibria of metal-ligand complex system, respectively. The relations between log k' and log [Na$^+$] /log [$\alpha$-HiBA) showed non-linearity in isocratic elution. In gradient elution a good linearity between log k' vs log R was obtained. The values of slopes (log k / log R) gave good agreements between calculation and experiment. Individual capacity factors ($k'_{Ln}^{3+}, k'_{LnL}^{2+}, k'{LnL2+}) and stability constant (${\beta}_1$, ${\beta}_2$, ${\beta}_3$) of lanthanide-$\alpha$HiBA complexes were calculated by the non-linear least square fittings using the retention equation. The correlation coefficients of lanthanides were shown better than 0.9996 between experiment and calculation.

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Aboveground biomass estimation of Quercus glauca in evergreen forest, Kotzawal wetland, Cheju Island, Korea (제주도 곶자왈 상록활엽수 종가시나무의 생물량 추정을 위한 상대생장식)

  • Jeong, Heon-Mo;Kim, Hae-Ran;Cho, Kyu-Tae;Lee, Seung-Hyuk;Han, Young-Sub;You, Young-Han
    • Journal of Wetlands Research
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    • v.16 no.2
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    • pp.245-250
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    • 2014
  • This study developed allometry equation and estimated the aboveground-biomass of Quercus glauca, a warm-temperature, evergreen broad-leaved tree, growing in Kotzawal wetland located on Jeju Island. The allometric equations between DBH(diameter at breast height) and dry weights of stems (Ws), branches (Wb), leaves (Wl) and aboveground biomass (Wab) of Q. glauca were as follows: logWs=2.4042logDBH-1.3045, logWb=2.6436logDBH-1.6232, logWl =1.5428logDBH-1.3692 and logWab=2.3324logDBH-0.9181. The allometric equations between $D^2H$ and Ws, Wb, Wl, and Wab of Q.glauca were as follows : logWs=$0.853logD^2H-1.4252$, logWb=$0.8453logD^2H-1.5834$, logWl=$0.5328logD^2H-1.4073$ and logWab=$0.8453logD^2H-1.0327$. The $R^2$ between DBH and Ws, Wb, Wl and Wab were 0.9873, 0.9711, 0.7979 and 0.993, respectively. The $R^2$ between $D^2H$ and Ws,Wb,Wl and Wab were 0.9841, 0.9174, 0.7537 and 0.9876, respectively. There was no significant difference between observed and calculated values of the allomatric equations from DBH and $D^2H$(p>0.05, Kolmogorov-Smirnov test). Thus, to estimate the aboveground biomass of Q. glauca, use of DBH and $D^2H$ as an independent variables in the allometric equation is recommended.

LOG-SINE AND LOG-COSINE INTEGRALS

  • Choi, Junesang
    • Honam Mathematical Journal
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    • v.35 no.2
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    • pp.137-146
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    • 2013
  • Motivated essentially by their potential for applications in a wide range of mathematical and physical problems, the log-sine and log-cosine integrals have been evaluated, in the existing literature on the subject, in many different ways. The main object of this paper is to present explicit evaluations of some families of log-sine and log-cosine integrals by making use of the familiar Beta function.

Relationship of Somatic Cell Count, Physical, Chemical and Enzymatic Properties to the Bacterial Standard Plate Count in Different Breeds of Dairy Goats

  • Ying, Chingwen;Yang, Cheng-Bin;Hsu, Jih-Tay
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.4
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    • pp.554-559
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    • 2004
  • The objective of the present study was to investigate the accuracy of mastitis diagnostic indicators for different dairy goat breeds. Biweekly milk samples were collected from individual half mammary gland of seven Saanen and seven Alpine dairy goats in the period of 40 to 120 days in milk. With threshold value set at 2.8 and 3.1 for Alpine and Saanen dairy goats, respectively, log (SPC) offered good sensitivity (0.89, 0.93), specificity (0.88, 0.95), positive predictive value (0.75, 0.85) and negative predictive value (0.95, 0.98) as a mastitis diagnostic tool. The correlations of log (SPC) with milk yield, log (SCC), ALP, LDH, $Na^{+}$, $K^{+}$ and EC were significant in Saanen dairy goats (p<0.05), with the highest correlation coefficient (0.653) existing between log (SPC) and log (SCC). The correlations of log (SPC) with milk yield, milk fat, milk protein, log (SCC), $Na^{+}$, $K^{+}$, EC were significant in Alpine dairy goats (p<0.05), with the highest correlation coefficient (0.416) existing between log (SPC) and log (SCC). There were different best-fit regression equations with different multiple diagnostic indicators for Saanen and Alpine dairy goats. In conclusion, different breeds of dairy goats may have to adapt different mastitis diagnostic parameters for a better diagnosis.