• Environmental Analysis Health and Toxicology
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• 제20권4호통권51호
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• pp.311-325
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• 2005

A chemical ranking and scoring system, CRS - Korea, has recently been developed and proposed to use to prioritize on a screening level the toxic chemicals for monitoring and risk assessment. As CRS-Korea requires rigorous assessments prior to its wide application, an assessment was conducted in this study by examining the contribution of individual parameter score to the final chemical score or ranking. The sensitivity of the system to the default values for various parameters of missing data was also tested. The chemical ranking/score was round to depend primarily on the score of a single parameter, i. e., the chemical release, while toxicity scores show little correlation with the priority Further analysis indicated that the dominating effect of the chemical release results from i) its multiplicative relationship with the other two exposure parameters (biodegradation and persistent) and ii) the fact that a maximum score of 10 was assigned to the chemical release parameter while 5 was assigned for all others. AE the fraction of the data that are missing exceeded $70\%$ for various toxicity parameters at compared to less than $10\%$ for exposure parameters, the sensitivity of the ranking to the default value was not significant (rank correlation coefficient = 0.98) for toxicity parameters. Bated on this assessment, an improved CRS system (CRS - Korea II) was proposed in which the impact of the chemical release was properly adjusted by changing the multiplicative relationship to additive one and the maximum score to 5. Chemical priority was derived for each of 16 provinces by using CRS-Korea II. The chemical priority was found to significantly vary among the provinces. It was concluded that not only the national chemical priority but the local chemical priority should be taken into account in setting the nationwide chemical monitoring and risk assessment strategy.

• Environmental Analysis Health and Toxicology
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• 제19권1호
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• pp.81-91
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• 2004

Although it is suggested that risk -based management plan is needed to manage air pollution effectively, we have no resources enough to evaluate all aspects of substances and set priorities. So we need to develop a logical and easy risk-based priority setting method. However, it if impossible that only one generic system that is consistent with all the use is developed. In this study, we proposed a human health risk based priority-setting method for hazardous air pollutants, and ranked priorities for this method. First of all, after investigating previous chemical ranking and scoring systems, we chose appropriate indicators and logics to goal of this study and made a chemical priority ranking method using these. As results, final scores in priority ranking method were derived for 25 substances, and ethylene oxide, acrylonitrile and vinyl chloride were included in high ranks. In addition, same substances were highly ranked when using default values like when using no default, but the scores of hydrofluoric acid and ryan and compounds were sensitive to default values. This study could be important that priorities were set including toxicity type and quality and local inherent exposure conditions and we can set area-specific management guidelines and survey plans as a screening tool.

• 한국산업융합학회 논문집
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• 제24권5호
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• pp.609-615
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• 2021

Chemical accidents can happen anywhere in the world. To prevent chemical accidents, Korea introduced the Chemicals Control Act. However, Small and medium-sized businesses do not meet these regulations. Accordingly, the Ministry of Environment is providing a chemical safety management support project for Small and medium-sized businesses. However, there are many small and medium-sized businesses, and businesses that need support need priority. In this study, the risk of the plants was classified into hig h, medium, and low risk based on four methods. As a result, out of 90 plants subject to the study, high risk was 30% and medium risk was 70%. The industries with the high risk were chemical products manufacturing and paint manufacturing. The plating and printing industries showed relatively medium risk. This risk classification has the advantage that it can obtain intuitive and quick results. These studies can be used as basic data for chemical safety management of local governments and Ministry of Environment.

• 무역학회지
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• 제41권5호
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• pp.63-87
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• 2016

최근 노동비용 상승 등에도 불구하고 세계 최고수준의 외국인 직접투자 및 대다수 글로벌 기업의 현지법인 진출 등으로 중국은 여전히 세계의 공장으로서 역할을 수행하고 있다. 또한 글로벌 기업의 중국현지 공장에서 생산하는 제품에 대해서는 원산지규정에 충족할 경우 2015년 발효된 한중 FTA 혜택을 누릴 수 있다. 이러한 이유로, 대표적인 한중 FTA 수혜산업인 화학산업을 한국과 중국의 관점이 아닌, 글로벌 관점에서 분석할 경우 우리나라 화학산업에 부정적인 결과를 초래할 수 있음을 화장품 기타제품을 사례로 분석해보았다. 분석결과 한국은 해당 제품군에서 중심국가에 위치하지 못하고 주변국에 속하여, 중국내 기초화장품 및 메이크업 등의 공장을 보유하고 있는 다국적 기업에 의한 한국 수출이 증가할 가능성이 있음을 확인하였다. 마지막으로 한중 FTA를 헤쳐 나가기 위한 화학산업계의 정책적 대안으로 첫째, 중국시장으로 직접진출을 꺼려하는 글로벌 화학기업들의 적극적 유치와 둘째, 향후 성장성이 높은 화학제품군에 대한 지속적인 투자를 제시하였다.

• Toxicological Research
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• 제18권1호
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• pp.23-29
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• 2002

Disodium disulphite, the HPV chemical, was assigned to Korea in order to implement OECD SIDS program in 1999. It was produced about 3,200 ton/year in 1998. This report evaluates the toxic potency of disodium disulphite based on the environmental and mammalian effects as well as human exposure. Oral $LD_{50}$ in rats is 1,540 mg/kg b.w. and effects was observed to the stomach, liver and the GI track that was filled with blood. For repeated dose toxicity, the predominant effect was the induction of stomach lesion due to local irritation. The no observed adverse effect lever for local (stomach irritation) was about 217 mg/kg bw/day. There is no evidence that disodium disulphite is genotoxic in vivo. No reproductive or developmental toxicty of disodium disulphite was observed for the period up to 2 yr and over three generation. In humans, urticaria and asthma with itching, edema, rhinitis, and nasal congestion were reported. Disodium disulphite is unlikely to induce respiratory sensitization but may enhance symptom of asthma in sensitive individuals. This chemical would be mainly transported to water compartment when released to environmental compartments since it is highly water soluble (470 g/l at 20). Low K oc (2.447) indicates disodium disulphite is so mobile in soil that it may not stay in the terrestrial compartment. The chemical has been tested in a limited number of aquatic species. hem acute toxicity test to fish, 96 hr-$LC_{50}$ was > 100 mg/1. For algae, 72 hr-$XC_{50}$ was 48.1 mg/1. For daphnid, the acute toxicity value of 48 hr-$EC_{50}$ was 88.76 mg/1, and chronic value of 21day-NOEC was > 10 mg/1. Therefore, PNEC of 0.1 mg/l for the aquatic organism was obtained from the chronic value of daphnid using the assessment factor of 100. Based on these data the disodium disulphite was recommended as low priority for further post-SIDS work in OECD.

• 공업화학
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• 제17권2호
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• pp.210-216
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• 2006

광양만 연안 표면 퇴적토를 대상으로 미국 EPA가 선정한 유해성 우선물질 16종 PAHs 화합물에 대한 특성 및 모니터링 조사를 수행하였다. 선정된 23개 지점에 대한 PAHs 조사결과 농도 수준은 최소 0.01에서 최고 171.39 mg/kg 수준이었으며, 평균값은 $8.13{\pm}24.8mg/kg$ 이었다. 광양만 PAHs의 주요 유입원은 광양제철 옆 태인도, 수어천, 그리고 여수산업단지 내의 월래천이었으며, 오염수준은 각각 114.81 mg/kg, 38.37 mg/kg, 19.05 mg/kg로 측정되었다. 또한, 세부분으로 나뉜 퇴적토 입자크기에 따른 PAHs 분석결과 입자크기가 작고 퇴적토 내 유기물함량과의 관계에서는 함량이 높을수록 PAHs의 오염도도 증가하는 양의 상관관계를 보였다. LMW/HMW, Phe/Ant, Fle/Pyr PAHs 농도비를 이용한 PAHs 발생원에 대한 연구 결과는 광양만 전역에서 열분해 산물의 특성을 나타냈고, 일부 지역에서 열분해 산물과 유류산물의 혼합된 구성형태를 관찰할 수 있었다. 이외에 광양만 PAHs 고정 유입원으로 보이는 세 지점에대한 저서생태계에 미치는 독성영향평가에서는 발암가능성이 높은 PAHs가 주로 축척된 태인도가 ERM 수준이상으로 나타났고, 수어천과 월래천은 ERL 수준이었다.

• Toxicological Research
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• 제18권1호
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• pp.13-22
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• 2002

In Korea, 2,320 tonnes of acetanilide were mostly wed as intermediates for synthesis in phar-maceuticals or additives in synthesizing hydrogen peroxide, varnishes, polymers and rubber. Only small amount of 120 kg were wed as a stabilizer for hydrogen peroxide solution for hair colouring agents in 1998. Readily available environmental or human exposure data do not exist in Korea at the present time. However, potential human exposures from drinking water, food, ambient water and in work places are expected to be negligible because this chemical is produced in the closed system in only one company in Korea and the processing factory is equipped with local ventilation and air filtering system. Acetanilide could be distributed mainly to water based on EQC model. This substance is readily biodegradable and its bioaccumulation is low. Acute toxicity of acetanilide is low since the L $D_{50}$ of oral exposure in rats is 1,959 mg/kg bw. The chemical is not irritating to skin, but slightly irritating to the eyes of rabbits. horn repeated dose toxicity, the adverse effects in rats were red pulp hyperplasia of spleen, bone marrow hyperplasia of femur and decreased hemoglobin, hematocrit and mean corpuscular hemoglobin concentration. The LOAEL for repeated dose toxicity in rats was 22 mg/kg/day for both sexes. Acetanilide is not considered to be genotoxic. In a reproductive/developmental toxicity study, no treatment-related changes in precoital time and rate of copulation, impregnation, pregnancy were shown in all treated groups. The NOAELs for reproduction and developmental toxicity (off-spring toxicity) are considered to be 200 mg/kg bw/day and 67 mg/kg bw/day, respectively. Ecotoxicity data has been generated in a limited number of aquatic species of algae (72 hr- $E_{b}$ $C_{50}$; 13.5 mg/l), daphnid (48hr-E $C_{50}$ > 100 mg/l) and fish (Oryzias latipes, 96hr-L $C_{50}$; 100 mg/l). Form the acute toxicity values, the predicted no effect concentration (PNEC) of 0.135 mg/1 was derived win an assessment factor of 100. On the basis of these data, acetanilide was suggested as currently of low priority for further post-SIDS work in OECD.in OECD.D.

• 한국항만경제학회지
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• 제37권3호
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• pp.19-34
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• 2021

여수광양항은 부산항, 인천항, 울산항, 평택당진항과 함께 국내 5대 항만으로써 남해안의 무역 거점의 역할을 담당하고 있다. 부산항에 이어 물동량 2위의 규모이며, 수출입 물동량 기준으로는 국내 최대의 항만이다. 세계 최대 규모의 화학산업단지인 여수화학산업단지를 주요 배후로 하여 고도성장을 거듭하여 왔으나, 최근에는 물동량의 증가세가 감소하고 있다. 이에 본 연구에서는 여수광양항의 발전을 위한 주요 발전전략을 발굴하고, 전략의 우선순위를 도출하고자 하였다. 이를 위해 AHP 분석기법을 이용하여 여수광양항의 발전전략을 운영 활성화, 인프라 구축, 정책지원의 3가지 대분류로 나누고 다시 기간별로 단·중기와 장기의 두 가지 측면에서 분석하였다. 분석결과, 단/중기정책에서는 '컨테이너부두 통합운영 및 경쟁력 강화'가 가장 중요한 것으로 평가되었다. 컨테이너 운영사의 통합 및 초대형 선박 입항에 대비한 항로개설, 대형크레인 설치 등이 필요할 것으로 판단된다. 장기정책에서는 '지역산업기반 고부가가치산업 육성'이 가장 중요한 것으로 평가되었다. 정착지원금제도 등을 통해 외부 지역의 기업 유치하기 위한 전략이 필요할 것으로 사료 된다. 본 연구의 결과는 여수광양항의 발전전략을 수립하고, 투자 우선순위를 정립하는데 활용될 수 있을 것으로 기대된다.

• 한국재난정보학회 논문집
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• 제19권3호
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• pp.656-664
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• 2023

연구목적: 고용노동부에서는 사업장 내 화재·붕괴 등의 대형재난이 발생하면 사업장 대규모 인적사고 위기관리 표준매뉴얼에 근거하여 재난을 관리하고 있다. 현재 운용중인 표준매뉴얼을 점검하고 미흡한 항목에 대해 개선방안을 제시하고자 한다. 연구방법:이에 따라, 재난관리 매뉴얼 내·외부 전문가, 본부·지방관서의 재난업무 담당자 등과 함께 표준매뉴얼을 점검하였고 우선적으로 개선해야 할 항목을 도출하였다. 연구결과: 붕괴사고의 경우에는 재난관리 주관부처 선정의 논란을 제거하기 위해 행정안전부에서 선정기준을 정확히 제시할 필요가 있으며, 인파밀집사고의 경우에는 표준매뉴얼 보다는 행동·실무 매뉴얼에 구체적으로 반영하여 유사시 근로자 대피 안전성을 확보해야 할 것이다. 이 외에도 재난안전 통신망 운영 및 대피요령에 대해 상세한 내용의 추가 보완이 필요해 보인다. 결론: 향후에도 국민의 눈높이에 부응하는 재난관리 제도 개선을 위해서 해당 분야별 전문가, 재난업무 담당자, 그리고 일반시민 등의 의견수렴을 통해 근로자의 생명과 안전을 보장하고 좀 더 현장감 있는 사업장 대규모 인적사고 위기 관리 표준매뉴얼 마련을 기대한다.