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Decomposition of Low-toxic Propellant by Cu-La-Al/honeycomb Catalysts (Cu-La-Al/honeycomb 촉매를 이용한 저독성 추진제 분해)

  • Kim, Munjeong;Yoo, Dalsan;Lee, Jeongsub;Joen, Jong-Ki
    • Korean Chemical Engineering Research
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    • v.59 no.2
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    • pp.296-303
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    • 2021
  • The objective of this study is to investigate the applicability of a Cu-supported honeycomb catalyst as a catalyst for decomposition of a low toxic liquid propellant based on ammonium dinitramide (ADN). A mixture of copper, lanthanum, and alumina was supported on the honeycomb support by wash coating to prepare a Cu-La-Al/honeycomb catalyst. We elucidated that the effect of metal loading on the physicochemical properties of Cu-La-Al/honeycomb catalyst and catalytic performance in decomposition of the ADN-based liquid propellant. As the number of wash coatings increased, the amount of active metal Cu was increased to 4.1 wt%. The BET surface area of the Cu-La-Al/honeycomb catalyst was in the range of 3.1~4.1 ㎡/g. The micropores were hardly present in Cu-La-Al/honeycomb catalysts, however, the mesopores and macropores were well developed. The Cu (2.7 wt%)-La-Al/honeycomb catalyst exhibited the highest activity in the decomposition of the ADN-based liquid propellant, which is attributed to the largest surface area, the largest pore volume, and the well-developed mesopores and macropores.

Experimental Study on the Strengthening Effect of External Prestressing Method Considering Deterioration (구조물 노후도를 반영한 외부긴장 보강 효과에 관한 실험적 연구)

  • Kim, Sang-Hyun;Jung, Woo-Tai;Kang, Jae-Yoon;Park, Hee-Beom;Park, Jong-Sup
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.1
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    • pp.1-6
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    • 2021
  • Concrete structures gradually age due to deterioration of materials or excess loads and environmental factors, and their performance decreases, affecting the usability and safety of structures. Although external tension construction methods are widely used among the reinforcement methods of old bridges, it is insufficient to identify the effects and effects of reinforcement depending on the level of aging. Therefore, in this study, a four-point loading experiment was conducted on the subject with the non-reinforced and external tensioning method to confirm the reinforcement effect of the external tensioning method, assuming the aging of the structure as a reduction in the compressive strength and tensile reinforcement of concrete, to analyze the behavior of the reinforcement and confirm the reinforcement effect. As a result of the experiment, it was difficult to identify the amount of reinforcement in the extreme condition due to early elimination of the anchorage. Therefore, compliance with the regulations on anchor bolts is required when applying the external tension reinforcement method. Crack load and yield load increased depending on whether external tension was reinforced, but before the crack, the stiffness before and after reinforcement was similar, making it difficult to confirm the reinforcement effect.

Structural Stability Analysis of Medical Waste Sterilization Shredder (의료폐기물 멸균분쇄용 파쇄기의 구조적 안정성 분석)

  • Azad, Muhammad Muzammil;Kim, Dohoon;Khalid, Salman;Kim, Heung Soo
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.34 no.6
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    • pp.409-415
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    • 2021
  • Medical waste management is becoming increasingly important, specifically in light of the current COVID-19 pandemic, as hospitals, clinics, quarantine centers, and medical research institutes are generating tons of medical waste every day. Previously, a traditional incineration process was utilized for managing medical waste, but the lack of landfill sites, and accompanying environmental concerns endanger public health. Consequently, an innovative sterilization shredding system was developed to resolve this problem. In this research, we focused on the design and numerical analysis of a shredding system for hazardous and infectious medical waste, to establish its operational performance. The shredding machine's components were modeled in a CAD application, and finite element analysis (FEA) was conducted using ABAQUS software. Static, fatigue, and dynamic loading conditions were used to analyze the structural stability of the cutting blade. The blade geometry proved to be effective based on the cutting force applied to shred medical waste. The dynamic stability of the structure was verified using modal analysis. Furthermore, an S-N curve was generated using a high cycle fatigue study, to predict the expected life of the cutting blade. Resultantly, an appropriate shredder system was devised to link with a sterilization unit, which could be beneficial in reducing the volume of medical waste and disposal time, thereof, thus eliminating environmental issues, and potential health hazards.

Development of CanSat System for Collecting Weather Information With Autorotating Science Payload Ejection Function (자동회전 과학 탑재체 사출 기능을 갖춘 기상정보 수집용 캔위성 체계 개발)

  • Kim, Youngjun;Park, Junsoo;Nam, Jaeyoung;Lee, Junhyuck;Choi, Yunwon;Yoo, Seunghoon;Lee, Sanghyun;Lee, Younggun
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.50 no.8
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    • pp.573-581
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    • 2022
  • This paper deals with the development of CanSat system, which ejects two maple seed-type autorotating science payloads and collects weather information. The CanSat consists of two autorotating science payloads and a container. The container is equipped with devices for launching science payloads and communication with the ground station, and launches science payloads one by one at different designated altitudes. The science payload consists of a space for loading and a large wing, and rotates to generate lift for slowing down the fall speed. Specifically, after being ejected, it descends at a speed of 20 m/s or less, measures the rotation rate, atmospheric pressure, and temperature, and transmits the measured value to the container at a rate of once per second. The communication system is a master-slave structure, and the science payload transmits all data to the master container, which aggregates both the received data and its own data, and transmits it to the ground station. All telemetry can be checked in real time using the ground station software developed in-house. A simulation was performed in the simulation environment, and the performance of the CanSat system that satisfies the mission requirements was confirmed.

Hysteretic behaviors and calculation model of steel reinforced recycled concrete filled circular steel tube columns

  • Ma, Hui;Zhang, Guoheng;Xin, A.;Bai, Hengyu
    • Structural Engineering and Mechanics
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    • v.83 no.3
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    • pp.305-326
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    • 2022
  • To realize the recycling utilization of waste concrete and alleviate the shortage of resources, 11 specimens of steel reinforced recycled concrete (SRRC) filled circular steel tube columns were designed and manufactured in this study, and the cyclic loading tests on the specimens of columns were also carried out respectively. The hysteretic curves, skeleton curves and performance indicators of columns were obtained and analysed in detail. Besides, the finite element model of columns was established through OpenSees software, which considered the adverse effect of recycled coarse aggregate (RA) replacement rates and the constraint effect of circular steel tube on internal RAC. The numerical calculation curves of columns are in good agreement with the experimental curves, which shows that the numerical model is relatively reasonable. On this basis, a series of nonlinear parameters analysis on the hysteretic behaviors of columns were also investigated. The results are as follows: When the replacement rates of RA increases from 0 to 100%, the peak loads of columns decreases by 7.78% and the ductility decreases slightly. With the increase of axial compression ratio, the bearing capacity of columns increases first and then decreases, but the ductility of columns decreases rapidly. Increasing the wall thickness of circular steel tube is very profitable to improve the bearing capacity and ductility of columns. When the section steel ratio increases from 5.54% to 9.99%, although the bearing capacity of columns is improved, it has no obvious contribution to improve the ductility of columns. With the decrease of shear span ratio, the bearing capacity of columns increases obviously, but the ductility decreases, and the failure mode of columns develops into brittle shear failure. Therefore, in the engineering design of columns, the situation of small shear span ratio (i.e., short columns) should be avoided as far as possible. Based on this, the calculation model on the skeleton curves of columns was established by the theoretical analysis and fitting method, so as to determine the main characteristic points in the model. The effectiveness of skeleton curve model is verified by comparing with the test skeleton curves.

Nanofibers Comprising Mo2C/Mo2N Nanoparticles and Reduced Graphene Oxide as Functional Interlayers for Lithium-Sulfur Batteries (Mo2C/Mo2N 나노 입자와 환원된 그래핀 옥사이드가 복합된 나노 섬유 중간층이 적용된 리튬-황 전지)

  • Lee, Jae Seob;Yang, Ji Hoon;Cho, Jung Sang
    • Korean Chemical Engineering Research
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    • v.60 no.4
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    • pp.574-581
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    • 2022
  • Nanofibers comprising reduced graphene oxide (rGO) and Mo2C/Mo2N nanoparticles (Mo2C/Mo2N rGO NFs) were prepared for a functional interlayer of Li-S batteries (LSBs). The well-dispersed Mo2C and Mo2N nanoparticles in the nanofiber structure served as active polar sites for efficient immobilization of dissolved lithium polysulfide. The rGO nanosheets in the structure also provide conductive channels for fast ion/electron transport during charging-discharging and ensured reuse of lithium polysulfide during redox reactions through a fast charge transfer process. As a result, the cell assembled with Mo2C/Mo2N rGO NFs-coated separator and pure sulfur electrode (70 wt% of sulfur content and 2.1 mg cm-2 of sulfur loading) showed a stable discharge capacity of 476 mA h g-1 after 400 charge-discharge cycles at 0.1 C. Furthermore, it exhibited a discharge capacity of 574 mA h g-1 even at a high current density of 1.0 C. Therefore, we believe that the proposed unique nanostructure synthesis strategy could provide new insights into the development of sustainable and highly conductive polar materials as functional interlayers for high performance LSBs.

Burn-back Analysis for Propellant Grains with Embedded Metal Wires (금속선이 삽입된 추진제 그레인의 Burn-back 해석)

  • Lee, Hyunseob;Oh, Jongyun;Yang, Heesung;Lee, Sunyoung;Khil, Taeock
    • Journal of the Korean Society of Propulsion Engineers
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    • v.26 no.2
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    • pp.12-19
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    • 2022
  • Propellant grains with embedded metal wires have been used for enhancement of burning rate while maintaining high loading density. For the performance design of a solid rocket motor using propellant grain with embedded metal wires, burn-back analysis is required according to number, location, arrangement angle of metal wires, and augmentation ratio of the propellant burning rate near a wire region. In this study, a numerical method to quickly calculate a burning surface area was developed in response to the design change of the propellant grain with embedded metal wires. The burning surface area derived from the developed method was compared with the results of a CAD program. Error rate decreased as the radial size of the grid decreased. Analysis for characteristics of burning surface area was performed according to the number and location of metal wires, the initial and final phases were shortened and the steady-state phase was increased when the number of metal wires increased. When arranging the metal wires at different radii, the burning surface area rapidly increased in the initial phase and sharply decreased in the final phase compared to the case where the metal wires were disposed in the same radius.

Biomechanical Analysis of Lower Extremity Joints According to Landing Types during Maximum Vertical Jump after Jump Landing in Youth Sports Athletes (유소년 스포츠 선수들의 점프착지 후 수직점프 동작 시 착지 유형에 따른 하지관절의 운동역학적 분석)

  • Jiho Park;Joo Nyeon Kim;Sukhoon Yoon
    • Korean Journal of Applied Biomechanics
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    • v.33 no.3
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    • pp.110-117
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    • 2023
  • Objective: The purpose of this study was to find out kinematic and kinetic differences the lower extremity joint according to the landing type during vertical jump movement after jump landing, and to present an efficient landing method to reduce the incidence of injury in youth players. Method: Total of 24 Youth players under Korean Sport and Olympic Committee, who used either heel contact landing (HCG) or toe contact landing (TCG) participated in this study (HCG (12): CG height: 168.7 ± 9.7 cm, weight: 60.9 ± 11.6 kg, age: 14.1 ± 0.9 yrs., career: 4.3 ± 2.9 yrs., TCG height: 174.8 ± 4.9 cm, weight: 66.9 ± 9.9 kg, age 13.9 ± 0.8 yrs., career: 4.7 ± 2.0 yrs.). Participants were asked to perform jump landing consecutively followed by vertical jump. A 3-dimensional motion analysis with 19 infrared cameras and 2 force plates was performed in this study. To find out the significance between two landing styles independent t-test was performed and significance level was set at .05. Results: HCG showed a significantly higher dorsi flexion, extension and flexion angle at ankle, knee and hip joints, respectively compared with those of TCG (p<.05). Also, HCG revealed reduced RoM at ankle joint while it showed increased RoM at knee joint compared to TCG (p<.05). In addition, HGC showed greater peak force, a loading rate, and impulse than those of TCG (p<.05). Finally, greater planta flexion moment was revealed in TCG compared to HCG at ankle joint. For the knee joint HCG showed extension and flexion moment in E1 and E2, respectively, while TCG showed opposite results. Conclusion: Compared to toe contact landing, the heel contact landing is not expected to have an advantage in terms of absorbing and dispersing the impact of contact with the ground to the joint. If these movements continuously used, performance may deteriorate, including injuries, so it is believed that education on safe landing methods is needed for young athletes whose musculoskeletal growth is not fully mature.

Carbon Nanosphere Composite Ultrafiltration Membranes with Anti-Biofouling Properties and More Porous Structures for Wastewater Treatment Using MBRs (분리막 생물반응기를 활용한 폐수처리를 위한 생물오염방지 특성 및 다공성 구조를 가진 탄소나노구체 복합 한외여과막)

  • Jaewoo Lee
    • Membrane Journal
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    • v.34 no.1
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    • pp.38-49
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    • 2024
  • Wastewater treatment using membrane bioreactors has been extensively used to alleviate water shortage and pollution by improving the quality of the treated water discharged into the environment. However, membrane biofouling persistently holds back an MBR process by reducing the process efficiency. Herein, we synthesized carbon nanospheres (CNSs) with many hydrophilic oxygen groups and utilized them as an additive to prepare high-performance ultrafiltration (UF) membranes with hydrophilicity and porous pore structure. CNSs were found to form crescent-shaped pores on the membrane surface, increasing the mean surface pore size by about 40% without causing significant defects larger than bubble points, as the CNS content increased by 4.6 wt%. In addition, the porous pore structure of CNS composite membranes was also attributable to the CNS's isotropic morphologies and relatively low particle number density because the aforementioned properties contributed to preventing the polymer solution viscosity from soaring with the loading of CNS. However, too porous structure compromised the mechanical properties, such that CNS2.3 was the best from a comprehensive consideration including the pore structure and mechanical properties. As a result, CNS2.3 showed not only 2 times higher water permeability than CNS0 but also 5 times longer operation duration until membrane cleaning was required.

Algorithm for a Minimum Linear Arrangement(MinLA) of Lattice Graph (격자 그래프의 최소선형배열 알고리즘)

  • Sang-Un Lee
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.24 no.2
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    • pp.105-111
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    • 2024
  • This paper deals with the minimum linear arrangement(MinLA) of a lattice graph, to which an approximate algorithm of linear complexity O(n) remains as a viable solution, deriving the optimal MinLA of 31,680 for 33×33 lattice. This paper proposes a partitioning arrangement algorithm of complexity O(1) that delivers exact solution to the minimum linear arrangement. The proposed partitioning arrangement algorithm could be seen as loading boxes into a container. It firstly partitions m rows into r1,r2,r3 and n columns into c1,c2,c3, only to obtain 7 containers. Containers are partitioning with a rule. It finally assigns numbers to vertices in each of the partitioned boxes location-wise so as to obtain the MinLA. Given m,n≥11, the size of boxes C2,C4,C6 is increased by 2 until an increase in the MinLA is detected. This process repeats itself 4 times at maximum given m,n≤100. When tested to lattice in the range of 2≤n≤100, the proposed algorithm has proved its universal applicability to lattices of both m=n and m≠n. It has also obtained optimal results for 33×33 and 100×100 lattices superior to those obtained by existing algorithms. The minimum linear arrangement algorithm proposed in this paper, with its simplicity and outstanding performance, could therefore be also applied to the field of Very Large Scale Integration circuit where m,n are infinitely large.