This study reviews recent advancements in Ni-based catalysts for CO2 methanation, emphasizing high thermal stability and catalytic performance at elevated temperatures. Ni catalysts are preferred for their strong hydrogen adsorption, high activity, and methane selectivity. Strategies such as optimizing metal loading, using efficient supports, and introducing promoters enhance thermal stability by preventing sintering and carbon deposition. The produced methane serves as a valuable feedstock for synthetic fuels and chemicals, improving the economic feasibility of the CO2 methanation process. These findings underscore the importance of thermal stability in developing effective Ni catalysts for large-scale CO2 methanation.
Journal of Korean Society of Environmental Engineers
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v.22
no.11
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pp.2047-2058
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2000
The effects of operating parameters on performance of upflow anaerobic sludge blanket(UASB). anaerobic filter(AF), and two-stage anaerobic sludge bed filter (ASBF) bioreactors in treating swine wastewater were evaluated by operating the lab-scale bioreactors upto hydraulic retention time(HRT) of 1 day and organic loading rate (OLR) of $5.1kg-COD/m^3{\cdot}d$ for 200 days. Swine wastewaters of which characteristics were affected by types of hog raising and seasons contained high concentrations of COD, SS, and ammonia. Inoculation of the bioreactors with waste sludge from anaerobic treatment facility of local municipal wastewater treatment plant was effective in developing biomass in the bioreactors. Acclimation period of the bioreactors with swine wastewaters required approximately 40 days, but that for AF and two-stage ASBF, which were filled with media, was faster than VASB. The bioreactors showed high and stable COD removal efficiency of 77~91% at influent T-N concentrations of 370~800mg/L but low and unstable COD removal efficiency of 24~94% at influent T-N concentrations of 760~1,310mg/L. It is essential to remove ammonia prior to anaerobic treatment since the concentrations of ammonia in swine wastewaters showed toxic effects to methanogenic bacteria. The bioreactors were effective in treating swine wastewaters with COD removal efficiency of 78.9~81.5% and biogas generation rate of $0.39{\sim}0.59m^3/kg-COD_r$ at OLR of $1.1{\sim}2.2kg-COD/m^3{\cdot}d$: however, an increase of OLR by reducing HRT and increasing influent COD caused decrease of COD removal efficiency. The extent of decrease in COD removal efficiency was higher in UASB than AF and two-stage ASBF. AF and two-stage ASBF anaerobic bioreactors were effective in treating varing characteristics of swine wastewaters since they showed high and stable COD removal efficiency at high OLR due to effective retention of biomass by media and staging.
Journal of Korean Society of Environmental Engineers
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v.31
no.11
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pp.1007-1018
/
2009
Hydrocyclone is widely used in industry, because of its simplicity in design, high capacity, low maintenance and operational cost. The separation action of a hydrocyclone treating particulate slurry is a consequence of the swirling flow that produces a centrifugal force on the fluid and suspended particles. In spite of hydrocyclone have many advantage, the application for treatment of urban stormwater case study were rare. We conducted a laboratory scale study on treatable potential of micro particles using hydrocyclone filter (HCF) that was a combined modified hydrocyclone with perlite filter cartridge. Since it was not easy to use actual storm water in the scaled-down hydraulic model investigations, it was necessary to reproduce ranges of particles sizes with synthetic materials. The synthesized storm runoff was made with water and addition of particles; ion exchange resin, road sediment, commercial area manhole sediment, and silica gel particles. Experimental studies have been carried out about the particle separation performance of HCF-open system and HCF-closed system. The principal structural differences of these HCFs are underflow zone structure and vortex finder. HCF was made of acryl resin with 120 mm of diameter hydrocyclone and 250 mm of diameter filter chamber and overall height of 800 mm. To determine the removal efficiency for various influent concentrations of suspended solids (SS) and chemical oxygen demand (COD), tests were performed with different operational conditions. The operated maximum of surface loading rate was about 700 $m^3/m^2$/day for HCF-open system, and 1,200 $m^3/m^2$/day for HCF-closed system. It was found that particle removal efficiency for the HCF-closed system is better than the HCF-open system under same surface loading rate. Results showed that SS removal efficiency with the HCF-closed system improved by about 8~20% compared with HCF-open system. The average removal efficiency difference for HCF-closed system between measurement and CFD particle tracking simulation was about 4%.
Journal of the Korea Academia-Industrial cooperation Society
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v.18
no.5
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pp.708-715
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2017
Recently, in order to meet the stricter emission regulations, the proportion of after-treatments for vehicles and vessels has been increasing gradually. The objective of this study is to investigate the improvement of $CH_4$ reduction ability of natural gas oxidation catalyst (NGOC), which reduces toxic gases emitted from CNG buses. Thirteen NGOCs were prepared, and the conversion performance of noxious gases according to the type of supports, the loading amount of noble metal, and surfactant and aging were determined. Support Zeolite supported on No. 3 $NGOC(1Pt-1Pd-3MgO-3CeO_2/(46TiO_2+23Al_2O_3+23Zeolite)$ is an anionic alkali metal/earth metal component that improved the oxidation reactivity between CO and NO and noble metal dispersion, and thus enhanced the $CH_4$ reduction ability. As the loading amount of Pd, a noble metal with a high selectivity to $CH_4$, was increased, the number of reaction sites was increased and the ability to reduce $CH_4$ was improved. No. 11 $NGOC(1Pt-1Pd-3MgO-3CeO_2/(Z20+Al80)$(pH=8.5), to which nitrate surfactant had been added, exhibited well dispersed catalyst particles with no agglomeration and improved the $CH_4$ reduction ability by 5-15%. The $NGOC(2Pt-2Pd-3Cr-3MgO/90Al_2O_3)$(48h aging), which was mildly thermal aged for 48h, increased the $CH_4$ reduction ability to about 10% or less as compared with No. 12 NGOC(Fresh).
A laser docking system provides a centimeter-level accuracy distance from jetty mounted laser sensors in order to help a vessel to approach to a pier. It is very accurate & useful, whereas there are too many considerable problems. Laser sensors of the laser docking system need to be correctly positioned and installed on a jetty to allow for full range of vessels to be berthed and to consider loading condition and tidal variations. Above all, the laser docking system is expensive and its service coverage is limited. In order to solve these problems, CDGPS positioning method using GPS satellites has been proposed. This paper presents that, through RHDOP simulation, the previous CDGPS positioning method using only GPS satellites is not able to provide the continuous service with centimeter-level positioning accuracy. And this paper proposes a pseudolite-augmented positioning method for vessel docking in order to solve the problem of the continuous service on the previous CDGPS positioning method. In this paper, pseudolite is used to aid in CDGPS positioning. This paper shows that the proposed method can provides the continuous service through comparison analysis of RHDOP simulation results between the GPS satellite constellation and the pseudolite-augmented GPS satellite constellation. Furthermore, it is shown that the proposed positioning method satisfies the positioning performance required for vessel automatic docking at a test bed designed for performance evaluation.
Japanese restaurant owners seek to secure their competitive advantage by implementing a unique competition strategy that may overcome hostile environment. Brand power, aggressive expansion and the partnership strategy with other businesses may be suggested. The present study is to find out the competitive advantages of Japanese restaurants, to compare the importance and satisfaction by different customer factors of choices and then, to identify what kinds of factors affect customer satisfaction. Total 205 copies of questionnaire, out of 230 distributed, were used for analyses. Cronbarch's alpha coefficient of all 20 items was 0.911. In terms of importance, Cronbarch's alpha coefficients were 0.887(food), 0.796(menu), 0.851(employee), 0.815(service), and 0.730(physical environment). For satisfaction, the coefficients were 0.876(food), 0.860(menu), 0.880(employee), 0.851(service), 0.730(physical environment). In addition, the exploratory factor analysis showed an acceptable factor loading, supporting 20 items' validity. The result showed that customers' perceptions of the importance of Japanese restaurant service quality was higher than their level of satisfaction in general. In particular, IPA analysis revealed that food and service factors were well operated as located in the first quadrant. However, service factor located in the second quadrant was perceived to be important yet perceived as being satisfied poorly. So this study suggests that Japanese restaurant owners should concentrate on the attributes included in this quadrant to improve the quality of foodservice. Lastly, menu and physical environment factors were located in the third quadrant showing low level of importance and satisfaction. On the basic of the IPA analysis, Japanese restaurant owners should identify their strengths and weaknesses and draw up a plan to improve service quality and to maximize their profits.
Surface of fine-size exposed aggregate portland cement concrete pavements(FS-EAPCC) is consist by exposed coarse aggregate to remove upper 2~3mm mortar of concrete slabs. Advantages of FS-EAPCC are maintaining low-noise and adequate skid-resistance level during the performance period. However, FS-EAPCC is required rational management criteria for field application, since it is early stage for application. Design construction and quality control criteria of FS-EAPCC was temporary laboratory tests which including optimum mix and exposing method, selection of adequate aggregate, resistance against, environmental loading and etc. However, these criteria need to be validated base on field application. In this study, experimental constructions were performed and construction procedure and quality control criteria were suggested based on the performance of the FS-EAPCC.
Usage of bicycle has been supported the universal reduction of energy consumption and $CO_2$. For the same purpose, new constructions for long length bike roads are planned in Korea. Recently, laboratory tests of physical properties and resistance against environmental loading about optimum mix design of roller compacted concrete, that have advantages of high structural performance by cement hydration and aggregate interlocking, simple construction procedure and low construction cost, are performed for the effective construction of new bike roads. However, properties of roller compacted concrete had different results between laboratory and field tests since it had different compaction method. Also, construction method of roller compacted concrete are not defined for the application of bike roads since it had different demand performance such as thin pavement thickness, low strength and etc with road pavements. Thus, in this experimental research was launched to evaluate the core properties, visual inspection, compaction ratio, water content, thickness reduction rate of roller compaction, skid resistance and roughness by experimental construction about variable mix proportion and compaction method based on laboratory test results. And construction method of roller compacted concrete pavement were suggested for the application of bike roads.
OMTP (Open Mobile Terminal Platform) is a global forum made by telecommunications providers to promote user-oriented mobile services and data business. Devised by OMTP, BONDI is a browser-based application or a mobile web run-time platform to help widgets make good use of functions of mobile devices in a secure way. BONDI enables applications programmed with web standard technologies such as HTML, JavaScript, CSS, and AJAX to reach the internal functions of mobile devices. Since BONDI, which is not just a simple network application, can reach the internal resources of devices in standard ways, it enables the application and widgets to be developed regardless of tile OS or platform. Web browser-based widgets are vulnerable to the network environment, and their exeeution speed can be slowed as the operations of the widgets or applications become heavy. However, those web widgets will be continuously used thanks to the user-friendly simple interface and the faster speed in using web resources more than the native widgets inside the device. This study suggested a method to effectively operate and manage the resource of OMTP BONDI web widget and then provided an improved result based on a running performance evaluation experiment. The experiment was carried to improve the entire operating time by enhancing the module-loading speed. In this regard, only indispensable modules were allowed to be loaded while the BONDI widget was underway. For the purpose, the widget resource list, able to make the operating speed of the BONDI widget faster, was redefined while a widget cache was employed. In addition, the widget box, a management tool for removed widgets, was devised to store temporarily idle widgets.
Chung Young Soo;Park Chang Kyu;Lee Beom Gi;Song Hee Won
Journal of the Korea Concrete Institute
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v.17
no.1
s.85
/
pp.121-128
/
2005
A RC column-bent pier represents one of the most popular piers used in highway bridges. Seismic performance of reinforced concrete (RC) column-bent piers under bidirectional seismic loadings was experimentally investigated. Six column bent-piers were constructed with two circular supporting columns which were made in 400 mm diameter and 2,000 mm height. One single column specimen was additionally made to comparatively evaluate the seismic response of RC column-bent piers. Test parameters are different transverse reinforcement and loading pattern. These piers were tested under lateral load reversals with the axial load of $0.1 f_{ck}A_g$. Three specimens were subjected to bidirectional lateral load cycles which consisted of two main longitudinal loads and two sub transverse loads in one load cycle. Other three specimens were loaded in the opposite way. Test results indicated that lateral strength and ductility of the latter three specimens were generally bigger than those of the former three specimens. Plastic hinges were formed with the spall of cover concrete and the fracture of the longitudinal reinforcing steels in the bottom plastic hinge of two supporting columns for the former three specimens. Similar behavior was observed in the top and bottom parts of two supporting columns for the latter three specimens.
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