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High Temperature Gas Leak Behavior of Glass-Ceramic Fiber Composite Seals for SOFC Applications (SOFC용 유리-세라믹섬유 복합기밀재의 고온 기체누설 거동)

  • Lee, Jae-Chun;Kwon, Hyuk-Chon;Kwon, Young-Pil;Park, Sung;Jang, Jin-Sik;Lee, Jongho;Kim, Joosun;Lee, Hae-Won
    • Journal of the Korean Ceramic Society
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    • v.42 no.12 s.283
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    • pp.842-845
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    • 2005
  • Glass composites containing ceramic fiber have been developed for Solid Oxide Fuel Cell (SOFC) seals. Effect of glass type, loading pressure and thermal cycle the leak rates of composite seals was investigated. Seal performance of two commercial glasses was compared with that of $SiO_2BaO-B_2O_3$ glass synthesized in this work. The leak rate for seals made of pyrex(R) increases from $\~0.0005\;to\;\~0.004sccm/cm$ as the gas pressure increases from 10 to 50 kPa. The soda lime silicate glass seal shows the leak rate two times higher than the one made of pyrex(R) or $SiO_2BaO-B_2O_3$ glass. The viscosity of glass at the seal test temperature is presumed to affect the leak rate of the glass seal. As the applied loading pressure increases from 0.4 to 0.8 MPa at $750^{\circ}C$, the leak rate decreases from 0.038 to 0.024 sccm/cm for composite seals. It has been found that during 50 thermal cycles between $450^{\circ}C\;to\;700^{\circ}C$ leak rates remained almost constant, ranging from 0.025 to 0.03sccm/cm. The results showed an excellent thermal cycle stability as well as sealability of the glass matrix ceramic fiber composite seals.

A Study on Performance Improvement of Whirling Machines (Whirling machine의 성능 개선을 위한 연구)

  • Lee Jung-Ki;Yang Woo-suk;Son Jea-seok;Han Hui-duck;Kim Han-soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.29 no.10 s.241
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    • pp.1416-1429
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    • 2005
  • In order to meet the increasing competitive pressures coupled with higher demands for component quality, whirling machines have been at the cutting edge of the automobile industry for more than 25 years. The hard whirling process can save on machining time and operation elimination. Hard whirling is done dry, without coolant. The chips carry away nearly all of the heat during cutting, leaving the workpiece cool and minimizing any thermal geometry variations. The surface finish and profile accuracy are close to grinding quality. Whirling machines usually consist of four major parts; 1) loading system that requires the necessary axial speeds, 2) head stock that needs high precision clamping and positioning system at the chuck and tailstock, 3) whirling unit that demands the high cutting speeds and cutting power fer cutting deep thread profiles and 4) unloading system that requires an easy workpiece unloading. Also, capabilities of the whirling machine can be improved by attaching a vision system to the machine. Most of whirling machines in Korean automobile industry are imported from the Leistritz company, Germany and the Hasegawa company, Japan. Tn this paper, a basic research will be performed to improve and enhance the existing whirling machines. Finally, a new Korean whirling machine will be proposed and developed.

Fabrication and characterization of polymer-based carbon nanomaterial composites for thermal conductive adhesive application (열전도성 점착제 응용을 위한 고분자 기반 탄소나노소재 복합체 제조 및 특성 평가)

  • Lee, Byeong-Joo;Jo, Sung-Il;Yoon, Eun-Hye;Lee, Ae-Ri;Lee, Woo-Young;Heo, Sung-Gyu;Hwang, Jae-Sung;Jeong, Goo-Hwan
    • Journal of Surface Science and Engineering
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    • v.53 no.4
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    • pp.160-168
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    • 2020
  • A polymer-based carbon nanomaterial composite was fabricated and characterized for the application of a thermal conductive adhesive. Low-dimensional carbon nanomaterials with excellent thermal conductivity such as carbon nanotube (CNT) and graphene were selected as a filler in the composite. Thermal, electrical and adhesive properties of the composite were investigated with respect to the morphology and content of the low-dimensional carbon nanomaterials. As a result, the composite-based adhesive fabricated by the loading of surface-treated MWCNTs of 0.4 wt% showed uniform dispersion, moderate adhesion and effective heat dissipation properties. Finally, it was confirmed through the thermal image analysis of LED module that the temperature reduction of 10℃ was achieved using the fabricated composite adhesive with MWCNT-6A. Expecially, heat dissipation performance of the optimized composite adhesive was evident at the hot spot in the module compared to other samples mixed with graphene or different MWCNT loading ratios.

A Study on Characteristics of Flexural Behavior of High-strength Polymer Concrete Beams Using Recycled PET (PET 재활용 고강도 폴리머 콘크리트보의 휨거동에 관한 연구)

  • Cho Byung-Wan;Park Jong-Hwa;Park Seung-Kook;Bea Sung-Wan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05a
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    • pp.483-486
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    • 2005
  • The polymer concrete is drawing a strong interest as high-performance materials in the construction industry. Resins using recycled PET offer the possibility of a lower source cost of materials for making useful polymer concrete products. Also the recycling of PET in polymer concrete would help solve some of the solid waste problems posed by plastics and save energy. Polymer concrete beams using unsaturated polyester resins based on recycled polyethylene terephthalate (PET) plastic waste were used in our study for grasping its structural behavior of static and fatigue. As a result of static test, Compression stress distribution of Polymer concrete indicates linear behavior such as triangles. Although polymer concrete is high strength materials, its ductility capacity is excellent. From the fatigue test results, There was almost no difference on flexural characteristics between before and after fatigue loading. Therefore, recycled PET polymer concrete remains excellent structural ability after fatigue loading.

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Dynamic Characteristics of the Box Structure in Multi-layered Ground Under Earthquake Load (지진하중을 받는 다층지반내 박스구조물의 동적 특성)

  • Kim, In Dae;Shin, Eun Chul;Park, Jeong Jun
    • Journal of the Korean Geosynthetics Society
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    • v.19 no.1
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    • pp.55-63
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    • 2020
  • In this study, a scaled model test of the shaking table and a seismic analysis considering effective stresses were performed to reveal the dynamic behavior characteristics of box structures deep located in multi-layered soils upon seismic loading. The input seismic wave was operated below the ground using five seismic waves, including long period wave (Hachinohe), short period wave (Ofunato), artificial wave and real earthquakes that occurred in Gyeong-ju and Po-hang. As a result of model test and numerical analysis, the vertical displacement of box structures upon seismic loading was greater than that of horizontal direction, and it was confirmed that an increase of excess pore water pressure below the foundation ground caused a displacement. In addition, behavior of the ground and structures during artificial seismic wave appeared to be larger than real earthquake wave.

Study on the possible application of Vibrated and Rolled reinforced concrete pipe to vertical.crossing water distribution system (진동 및 전압 철근 콘크리트관의 종.횡단배수관 적용성 검토에 관한 연구)

  • Park Do-Kyong;Lee Myung-Kue;Yang Keek-Young
    • Journal of the Korea Institute of Building Construction
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    • v.6 no.2 s.20
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    • pp.111-117
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    • 2006
  • In case of carrying out vortical crossing water distribution system in expressways or general roads construction, VR(Vibrated and Rolled reinforced concrete) pipes are restricted because of their specification of reinforced spun concrete pipe or on-site made pipe. Therefore, in order to apply VR pipes to those constructions, through the structural behavior experiments of the pipes, VR pipes are compared and verified with reinforced spun concrete pipe and the results are obtained as the following. From the experiments and analyses of Pipe Stiffness(PS) of the pipes, cracking loading is approved to satisfy the KS regulations. Through a direct load test, the cracking loading strength and the maximum load test of VR pipe is larger compared with reinforced spun concrete pipe. Particularly, even if side weld is thin, there is no little change in the cracking strength of VR pipe. The results of the direct load test analysis show that the structural behavior of VR pipe is equivalent or higher compared with reinforced spun concrete pipe in performance and VR pipe could be used as the water distribution pipe for roads. In this study, through pipe stiffness, direct load test and load teat on earth, reinforced spun concrete pipe and VR pipe are compared. And as a result, the structural behavior of VR pipe is comprehensively excellent. From the structural behavior tests, VR pipe's section shows more thickness and has uniform characteristics so that VR pipe is considered more favorable than reinforced spun concrete pipe.

Evaluation of structural safety reduction due to water penetration into a major structural crack in a large concrete project

  • Zhang, Xiangyang;Bayat, Vahid;Koopialipoor, Mohammadreza;Armaghani, Danial Jahed;Yong, Weixun;Zhou, Jian
    • Smart Structures and Systems
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    • v.26 no.3
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    • pp.319-329
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    • 2020
  • Structural damage to an arch dam is often of major concern and must be evaluated for probable rehabilitation to ensure safe, regular, normal operation. This evaluation is crucial to prevent any catastrophic or failure consequences for the life time of the dam. If specific major damage such as a large crack occurs to the dam body, the assessments will be necessary to determine the current level of safety and predict the resistance of the structure to various future loading such as earthquakes, etc. This study investigates the behavior of an arch dam cracked due to water pressure. Safety factors (SFs), of shear and compressive tractions were calculated at the surfaces of the contraction joints and the cracks. The results indicated that for cracking with an extension depth of half the thickness of the dam body, for both cases of penetration and non-penetration of water load into the cracks, SFs only slightly reduces. However, in case of increasing the depth of crack extension into the entire thickness of the dam body, the friction angle of the cracked surface is crucial; however, if it reduces, the normal loading SFs of stresses and joints tractions reduce significantly.

Catalytic activities and performance enhancement of Ni catalysts for CO2 reforming (이산화탄소 개질반응을 위한 니켈 촉매의 활성 및 성능향상)

  • Jun, So-Youn;Kim, Dong-Sun;Kim, Kweon-Ill
    • Clean Technology
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    • v.9 no.3
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    • pp.125-132
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    • 2003
  • Activity improvement of Ni metal catalysts for carbon dioxide reforming was studied using HY-zeolite as the main supporter. As the reaction temperature increased, $CH_4$ and $CO_2$ conversions increased, and conversions higher than 80% was obtained above $700^{\circ}C$. As the Ni loading increased, the catalyst activity increased, and the highest activity was shown for the Ni loading of 13wt%. The HY-zeolite support showed the highest intial conversions of $CH_4$ and $CO_2$, but it showed faster deactivation than a ${\gamma}-Al_2O_3$ support. Nevertheless, it maintained the $CH_4$conversion higher than 80% after 24 hr reaction. The effect of promoters such as Mg, Mn, K, and Ca was also studied. It was observed that the Mg promotor exhibited the highest catalyst activity and less deactivation compared with Mn, K and Ca. After 24hr reaction, The optimum Mg content was found to be 5wt%.

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Hydrodynamic interactions and coupled dynamics between a container ship and multiple mobile harbors

  • Kang, H.Y.;Kim, M.H.
    • Ocean Systems Engineering
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    • v.2 no.3
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    • pp.217-228
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    • 2012
  • As the size of container ships continues to increase, not many existing harbors can host the super-container ship due to its increased draft and the corresponding dredging requires huge budget. In addition, the minimization of waiting and loading/offloading time is the most important factor in harbor competitiveness. In this regard, mobile-harbor concept has been developed in Korea to achieve much improved harbor capacity and efficiency. In developing the concept, one of the most important elements is the operability of crane between two or more floating bodies in side-by-side arrangement. The container ship is to be stationed through a hawser connection to an outside-harbor fixed-pile station with the depth allowing its large draft. The mobile harbors with smart cranes are berthed to the sides of its hull for loading/offloading containers and transportation. For successful operation, the relative motions between the two or more floating bodies with hawser/fender connections have to be within allowable range. Therefore, the reliable prediction of the relative motions of the multiple floating bodies with realistic mooring system is essential to find the best hull particulars, hawser/mooring/fender arrangement, and crane/docking-station design. Time-domain multi-hull-mooring coupled dynamic analysis program is used to assess the hydrodynamic interactions among the multiple floating bodies and the global performance of the system. Both collinear and non-collinear wind-wave-current environments are applied to the system. It is found that the non-collinear case can equally be functional in dynamics view compared to the collinear case but undesirable phenomena associated with vessel responses and hawser tensions can also happen at certain conditions, so more care needs to be taken.

Sonocatalytic Degradation of Rhodamine B in the Presence of TiO2 Nanoparticles by Loading WO3

  • Meng, Ze-Da;Sarkar, Sourav;Zhu, Lei;Ullah, Kefayat;Ye, Shu;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.24 no.1
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    • pp.6-12
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    • 2014
  • In the present work, $WO_3$ and $WO_3-TiO_2$ were prepared by the chemical deposition method. Structural variations, surface state and elemental compositions were investigated for preparation of $WO_3-TiO_2$ sonocatalyst. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX) and transmission electron microscopy (TEM) were employed for characterization of these new photocatalysts. A rhodamine B (Rh.B) solution under ultrasonic irradiation was used to determine the catalytic activity. Excellent catalytic degradation of an Rh.B solution was observed using the $WO_3-TiO_2$ composites under ultrasonic irradiation. Sonocatalytic degradation is a novel technology of treating wastewater. During the ultrasonic treatment of aqueous solutions sonoluminescence, cavitaties and "hot spot" occurred, leading to the dissociation of water molecules. In case of a $WO_3$ coupled system, a semiconductor coupled with two components has a beneficial role in improving charge separation and enhancing $TiO_2$ response to ultrasonic radiations. In case of the addition of $WO_3$ as new matter, the excited electrons from the $WO_3$ particles are quickly transferred to $TiO_2$ particle, as the conduction band of $WO_3$ is 0.74 eV which is -0.5 eV more than that of $TiO_2$. This transfer of charge should enhance the oxidation of the adsorbed organic substrate. The result shows that the photocatalytic performance of $TiO_2$ nanoparticles was improved by loading $WO_3$.