• Title/Summary/Keyword: liquid-phase

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The Effects of Additives on the Cooling Characteristic of a Clathrate Compound (포접화합물의 냉각특성에 대한 첨가제의 영향)

  • Kim Jin Heung;Chung Nak Kyu;Kim Suk Hyun;Kim Chang Oh
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.2
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    • pp.125-130
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    • 2005
  • This study was peformed to investigate the phase change temperature, the supercooling, the maintenance time of liquid phase and the change rate of volume of TMA 30 $wt\% clathrate compound with additives. TMA 30 $wt\% clathrate compound with additive was cooled at heat source temperature of $-6^{circ}C$. The additives are ethylene glycol and chloroform. Their concentration are 0.1$wt\% respectively. The experimental results showed that the phase change temperature was not affected by additives and this was average $5.3^{circ}C$. Also the supercooling and the maintenance time of liquid phase were decreased by additives. Especially, the average value of supercooling showed by $8.8^{circ}C$ and the maintenance time of liquid phase was by 19 minutes in the case of chloroform 0.1$wt\%. Additionally, the average change rate of volume showed by $1.26{\~}1.31\%$ according to additives and the volume was decreased by the phase change from liquid to solid.

GAS-LIQUID TWO-PHASE HOMOGENEOUS MODEL FOR CAVITATING FLOW (캐비테이션 유동해석을 위한 기-액 2상 국소균질 모델)

  • Shin, Byeong-Rog
    • Journal of computational fluids engineering
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    • v.12 no.2
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    • pp.53-62
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    • 2007
  • A high resolution numerical method aimed at solving cavitating flow is proposed and applied to gas-liquid two-phase shock tube problem. The present method employs a finite-difference 4th-order Runge-Kutta method and Roe's flux difference splitting approximation with the MUSCL TVD scheme. By applying the homogeneous equilibrium cavitation model, the present density-based numerical method permits simple treatment of the whole gas-liquid two-phase flow field, including wave propagation and large density changes. The speed of sound for gas-liquid two-phase media is derived on the basis of thermodynamic relations and compared with that by eigenvalues. By this method, a Riemann problem for Euler equations of one dimensional shock tube was computed. Numerical results such as detailed observations of shock and expansion wave propagations through the gas-liquid two-phase media at isothermal condition and some data related to computational efficiency are made. Comparisons of predicted results and exact solutions are provided and discussed.

CFD Analysis on Two-phase Flow Behavior of Liquid Water in Cathode Channel of PEM Fuel Cell (PEM 연료전지 공기극 유로에서 물의 가동에 대한 CFD 해석)

  • Kim, Hyun-Il;Nam, Jin-Hyun;Shin, Dong-Hoon;Chung, Tae-Yong;Kim, Young-Gyu
    • New & Renewable Energy
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    • v.3 no.4
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    • pp.8-15
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    • 2007
  • Liquid water in flow channel is an important factor that limits the steady and transient performance of PEM fuel cells. A computational fluid dynamics study based on the volume-of-fluid [VOF] multi-phase model was conducted to understand the two-phase flow behavior of liquid water in cathode gas channels. The liquid water transport in $180^{\circ}{\Delta}$ bends was investigated, where the effects of surface characteristics (hydrophilic and hydrophobic surfaces], channel geometries (rectangular and chamfered corners], and air velocity in channel were discussed. The two-phase flow behavior of liquid water with hydrophilic channel surface and that with hydrophobic surface was found very different; liquid water preferentially flows along the corners of flow channel in hydrophilic channels while it flows in rather spherical shape in hydrophobic channels. The results showed that liquid water transport was generally enhanced when hydrophobic channel with rounded corners was used. However, the surface characteristics and channel geometries became less important when air velocity was increased over 10m/s. This study is believed to provide a useful guideline for design optimization of flow patterns or channel configurations of PEM fuel cells.

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Application of DFB Diode Laser Sensor to Reacting Flow (II) - Liquid-Gas 2-Phase Reacting Flow -

  • Park, Gyung-Min;Masashi Katsuki;Kim, Duck-Jool
    • Journal of Mechanical Science and Technology
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    • v.17 no.1
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    • pp.139-145
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    • 2003
  • Diode laser sensor is conducted to measure the gas temperature in the liquid-gas 2-phase counter flow flame. C$\_$10/H/ sub 22/ and city gas were used as liquid fuel and gas fuel, respectively. Two vibrational overtones of H$_2$O were selected and measurements were carried out in the spray flame region stabilized the above gaseous premixed flame. The path-averaged temperature measurement using diode laser absorption method succeeded in the liquid fuel combustion environment regardless of droplets of wide range diameter. The path-averaged temperature measured in the post flame of liquid-gas 2-phase counter flow flame showed qualitative reliable results. The successful demonstration of time series temperature measurement in the liquid-gas 2-phase counter flow flame gave us motivation of trying to establish the effective control system in practical combustion system. These results demonstrated the ability of real-time feedback from combustor inside using the non-intrusive measurement as well as the possibility of application to practical combustion system. Failure case due to influence of spray flame was also discussed.

A Study of the Behavior of Liquid Phase Spray Considering Critical Condition of the Fuel (연료의 임계조건을 고려한 디젤 액상분무거동에 관한 연구)

  • Park, Jong-Sang;Kim, Si-Pom;Chung, Sung-Sik;Ha, Jong-Yul;Yeom, Jeong-Kuk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.5
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    • pp.467-472
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    • 2007
  • In this study the penetration distance of liquid phase fuel(i.e. liquid phsae length) was investigated in evaporative field. An exciplex fluorescence method was applied to the evaporative fuel spray to measure and investigate both the liquid and the vapor phase of the injected spray. For accurate investigation, images of the liquid and vapor phase regions were recorded using a 35mm still camera and CCD camera, respectively. Liquid fuel was injected from a single-hole nozzle (l/d=1.0mm/0.2mm) into a constant-volume chamber under high pressure and temperature in order to visualize the spray phenomena. Experimental results indicate that the liquid phase length decreased down to a certain constant value in accordance with increase in the ambient gas density and temperature. The constant value, about 40mm in this study the, is reached when the ambient density and temperature of the used fuel exceed critical condition.

Preparation and Stabilization of an O/W Emulsion Using Liquid Crystalline Phases (액정상을 이용한 O/W형 에멀젼의 제조 및 제형 안정화에 관한 연구)

  • An, Bong-Jeun;Lee, Jin-Tae;Lee, In-Chol;Kwak, Jae-Hoon;Park, Jung-Mi;Park, Chan-Ik
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.1
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    • pp.31-36
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    • 2004
  • Liquid crystalline phases were formed from acylglutamate; polyglyceryl-10 myristate and glycerine mixture and they were used as a base material for preparing an O/W emulsion. When an oil phase is added into the liquid crystalline phases, it was inserted into the dispersed liquid crystal droplets rather than stayed outside the liquid crystals, which can be known by the fact that the size of liquid crystal droplets increases with the increasing oil phase content. Along with the increase in the droplet size, the complex modulus increases from 100 to 350 pascals and the loss angle decreases from 60 to 24 degrees, from which it can be known that the increase in the internal phase volume results in the increase in the elastic property of oil in liquid crystalline-phases (O/LC). When the water phase was lastly added into the O/LC phase, the emulsification occurred to form a O/W emulsion and the averaged particle size of the O/W emulsion changes from 22.5nm to 538nm with the addition of water phase. The results from the droplet size measurements and stability tests under accelerated conditions such as high temperature show that the obtained O/W emulsion is very consistent with time.

The effect of grain shape on grain growth behavior of oxide system during liquid phase sintering (산화물계의 액상소결에서 입자 형상이 입자성장 거동에 미치는 영향)

  • 조동희;박상엽
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.3
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    • pp.127-131
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    • 2001
  • The effect of grain shape on the grain growth behavior of oxide system was investigated as afunction of liquid content during liquid phase sintering. As a model system, the solid grains of $Al_{2}O_{3}$ and MgO were selected during liquid phase sintering, i.e. faceted shape of $Al_{2}O_{3}$ in $CaAl_{2}Si_{2}O_{8}$ liquid phase and spherical shape of MgO in $CaMgSiO_{4}$ liquid phase. The average grain size of MgO with spherical shape was decreased with increasing the liquid phase content, whereas that of $Al_{2}O_{3}$ with faceted shape was independent of liquid phase content. In the case of $Al_{2}O_{3}$ grains with faceted shape, which interfaces are expected to be atomically flat, are likely to grow by the interfacial reaction controled process. Whereas, in the case of MgO grains with spherical shape, which interface are expected to be atomically rough, are likely to grow by the diffusion controlled process.

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Recovery of Golden yellow and Cibacron LSG dyes from aqueous solution by bulk liquid membrane technique

  • Muthuraman, G;Ali, P. Jahfar
    • Membrane and Water Treatment
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    • v.3 no.4
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    • pp.243-252
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    • 2012
  • Tri-n-butyl phosphate (TBP) was used as carrier for the transport of Golden yellow and Cibacron LSG dyes through a hexane bulk liquid membrane. The transport efficiency of dyes by TBP was investigated under various experimental conditions such as pH of the feed phase (dyes solution), concentration of the receiving phase (NaOH solution), concentration of TBP in membrane, rate of stirring, effect of transport time, type of solvent, dye concentration in feed phase, effect of temperature.. The maximum transport dyes occurs at ratio of 1:1 TBP-hexane At pH 3.0 0.1 (feed phase) the transport dyes decreased. At high stirring speed (300 rpm) the dyes transport from the feed phase to the strip phase was completed within 60 minutes at $27^{\circ}C$. Under optimum conditions: Feed phase 100 mg/L dyes solution at pH 1.0 0.1, receiving phase 0.1 mol/L NaOH solution, membrane phase 1:1 TBP-hexane , Stirring speed 300 rpm and temperature $27^{\circ}C$, the proposed liquid membrane was applied to recover the textile effluent.

A Study on Friction and Wear Characteristics of Sintered W/C-35%Ni Tappets for Diesel Engine Application (디젤엔진용 소결(W/C35%Ni) 태핏의 마멸거동에 관한 연구)

  • 류병진;오세일;박맹로;양승호
    • Tribology and Lubricants
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    • v.16 no.1
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    • pp.33-38
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    • 2000
  • Abstract- In this paper tribological characteristics of solid and liquid phase sintered W/C-35%Ni tappets were investigated. Three test methods were performed to investigate the wear and surface damage mechanism of sintered tappets. First, block-on-ring wear test was performed to investigate the wear characteristics under pure sliding condition. Second, simplified cam and tappet tests (called component wear test hereafter) were carried out to simulate the real contact history of cam and tappet. Also, after the test, contact surfaces were analyzed with scanning electron microscope to study the wear mechanism. As a final screening, engine dynamo tests were performed. Results showed that in the block on ring sliding wear test, solid phase sintered specimens showed superior wear resistance to liquid phase sintered specimens. The component wear tests and engine dynamo tests also showed the same results. Therefore, in these tests, solid phase sintered tappet material revealed superior wear resistant properties to liquid phase sintered one.

Bonding Phenomena during Transient Liquid Phase Bonding of CMSX-4, High Performance Single Crystal Superalloy (고성능 단결정 초내열합금 CMSX-4의 액상확산접합현상)

  • 김대업
    • Journal of Welding and Joining
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    • v.19 no.4
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    • pp.423-428
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    • 2001
  • The bonding phenomena of Ni base single crystal superalloy. CMSX-4 during transient liquid phase(TLP) bonding was investigated using MBF-80 insert metal. Bonding of CMSX-4 was carried out at 1,373∼1,548K for 0∼19.6ks in vacuum. The (001) orientation of each test specimen was aligned perpendicular to the bonding interface. The dissolution width of base metal was increased when the bonding temperature and holding time were increased. The eutectic width diminished linearly with the square root of holding time during isothermal solidification process. Borides were formed in the bonded layer during TLP bonding operation. The solid phase grew epitaxially into the liquid phase from substrates and single crystallization could be readily achieved during the isothermal solidification.

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