• Title/Summary/Keyword: liquid-phase

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Application of Reversed-Phase Solid Phase Extraction for the HPLC Analysis of Microcystins in Water (다량 시료중 마이크로시스틴의 농축 및 분석)

  • Kim, Myeong-Hee;Kim, Tae-Seung;Kim, Tae-Keun;Park, Sun Ku
    • Analytical Science and Technology
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    • v.13 no.3
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    • pp.399-402
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    • 2000
  • To determine the concentrations of microcystins present in lake water or in tap water using high performance liquid chromatography, it is necessary to concentrate a large volume of water samples (about 20 L) into very small volume (0.1-0.3 mL). Concentration can be conveniently done when disc type solid phase extraction (SPE) apparatus is used. Using this apparatus we have investigated the recovery rates of three kinds of microcystins, RR, YR, LR. The recovery rates were relatively low and the reproducibilities were not good either. It is expected, however, that the appropriate selection of the disc conditioning and eluting solvents and reproducible reconcentration process after SPE will improve both the recovery rates and the reproducibilities.

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Finite Element Analysis on Phase-Change Process of Pure Water (유한요소법을 이용한 순수 물의 상변화 과정에 대한 수치해석)

  • Hong Y. D.;Cha K. S.;Seo S. J.;Park C. G.
    • Journal of computational fluids engineering
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    • v.7 no.4
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    • pp.1-7
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    • 2002
  • The phase-change transformation processes are relevant in many engineering applications. In particular, this phenomenon plays an important role in the extraction and fabrication operations in the metallurgical industry. The control of the heat transfer and fluid flow patterns is important to achieve casting quality and competitive production times. In the present study, a simple finite-element algorithm is developed for solid-liquid phase change problems. Natural convection in the liquid phase due to the temperature dependency of water density is considered by a numerical model. The predictions are compared with measurements by the particle image velocimetry(PIV). to show that the calculation results are in good agreement with the experiment results.

Computer Simulations of two kinds of Polydisperse Hard-Sphere Systems; Atomic Systems and Colloidal Suspensions

  • Shimura Tsutomu;Yamazaki Hiroyuki;Terada Yayoi;Tokuyama Michio
    • 한국전산유체공학회:학술대회논문집
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    • 2003.10a
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    • pp.21-22
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    • 2003
  • We perform two kinds of computer simulations on polydisperse hard-sphere systems; a molecular-dynamics simulation on atomic systems and a Brownian-dynamics simulation on colloidal suspensions. Analyses of the mean square displacement, the radial distribution function, and the pressure suggest that there exist three phase regions, a liquid phase region, a metastable phase region, and a crystal phase region, where the freezing and melting points are shifted to the values higher than in monodisperse case. It is also shown that the long-time behavior of colloidal suspensions is exactly the same as that of atomic systems.

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NUMERICAL METHOD FOR THE TWO-FLUID THREE-FIELD MODEL ON AN UNSTRUCTURED MESH (비정렬격자 2-유체 3-상 유동 해석 기법)

  • Kim, J.;Park, I.K.;Cho, H.K.;Yoon, H.Y.;Jeong, J.J.
    • 한국전산유체공학회:학술대회논문집
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    • 2007.10a
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    • pp.243-248
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    • 2007
  • A three-dimensional (3D) unstructured hydrodynamic solver for transient two-phase flows has been developed. A two-fluid three-field model was adopted for the two-phase flows. The three fields represent a continuous liquid, an entrained liquid, and a vapour field. The hydrodynamic solver is for the 3D component of a nuclear system code and the component-scale analysis tools for transient two-phase flows. The finite volume method and unstructured grid are adopted, which are useful for the flows in a complicated geometry. The semi-implicit ICE (Implicit Continuous-fluid Eulerian) numerical scheme has been adapted to the unstructured non-staggered grid. This paper presents the numerical method and the preliminary results of the calculations. The results show that the numerical scheme is robust and predicts the phase change and the flow transitions due to boiling and flashing problems well.

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A Study on the Characteristics of Flow with Polymer Additives (고분자물질 첨가에 의한 유동특성에 관한 연구)

  • 차경옥;김재근
    • Transactions of the Korean Society of Automotive Engineers
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    • v.4 no.3
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    • pp.176-186
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    • 1996
  • The phenomena of drag reduction using small quantities of a liner macromolecules has attracted the attention of many experimental investigations. On the other hand drag reduction in two phase flow can be applied to the transport of crude oil, phase change system such as chemical reactor, pool and boiling flow, and to flow with cavitation which occurs pump impellers. But the research on dragreduction in two phase flow is not sufficient. The purpose of the present work is to evaluate the drag reduction by measuring pressure drop, void fraction, mean liquid velocity and turbulent intensity whether polymer additives a horizontal single and two phase system or not. Flow pattern of air-water two phase flow was classified by electrical conductivity probe signal. Velocities and turbulent intensities of signal were measured simultaneously with a Hot-film anemometer.

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Experimental and Numerical Study on Characteristics of Air-assisted Spray and Spray Flames (2유체 분무의 연소특성에 관한 실험 및 수치 해석적 연구)

  • Kim, Dong-Il;Oh, Sang-Huen
    • Journal of the Korean Society of Combustion
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    • v.3 no.2
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    • pp.51-63
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    • 1998
  • Air-assisted atomizer flames are investigated numerically to study spray structures in nonburning and burning conditions based on experimental data. A PDA is used to measure droplet size, velocity, and number density for both nonburning and burning spray. Computations utilize time-averaged gas-phase equations and $k-{\varepsilon}$ turbulence model for simplicity. The major features of the liquid-phase model are that a SSF approach is used to represent the effect of gas-phase turbulence on droplet trajectories and vaporization, an infinite-diffusion model is employed to represent the transient liquid-phase process. Computation and experiment results show that the droplet acceleration and evaporation proceed quickly in near the atomizer, characterizing high number densities and a strong convective effect. The primary combustion zone, however, is dorminated by the gas phase reaction and exhibits a sheath combustion.

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Studies of Molecular Orientation for Ferrielectric Liquid Crystal by Phase Transitions

  • Kim, S.W.;Choi, H.;Song, J.H.;KIm, J.H.;Kumar, S.;Choi, J.W.;Kim, Y.B.;Shin, S.T.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.61-62
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    • 2000
  • We have studied the molecular orientation by the phase transitions of the chiral smectic liquid crystals, 4-(1-Trifluoromethyl-6-ethoxy-hexyloxycarbonlphenyl)-4-nonyloxybiphenyl-4-carbo-xylate (R-TFMEOHPNBC) to seek the original solution of the zig-zag defect using two different experimental techniques; optical system and x-ray scattering. The phase sequence is gamma ferroelectric $(SmC{\gamma}\;^*)$ ${\rightarrow}$ smectic A (SmA) ${\rightarrow}$ isotropic (I). Existence of two layer spacing at chiral smectic phase gives a possibility of the molecular orientation in two different tilt angles, ${\theta}\;_1$ and ${\theta}\;_2$, which are separated each other to the layer normal at a given temperature. The gamma ferroelectric-like phase is, first, discovered in the single compound.

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Implementation of multi-level phase gratings for the optical interconnection using liquid crystal television (LCTV를 이용한 광연결용 다위상 격자의 구현)

  • Lee, Yeon-Seon;Kim, Nam;Park, Seong-Gyoon;Ihm, Jong-Tae
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.33A no.3
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    • pp.152-162
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    • 1996
  • Diffraction gratings were designed to generate multiple beams for the real-time optical interconnection in free-space using a liquid crsytal television. Multi-level phase gratings consisted of stepped phase value, 0 to 2$\pi$, and generate a 5$\times$5 spot array, and V-shaped spot patterns which have a maximum diffraction efficiency of 78.84%. Simulated annealing technique was used to determine phase states of each pixel having uniform intensity and high diffraction efficiency. Through the optical interconnection experiments, we compared the diffraction characteristics of beam paterns obtained by binary-level, four-level, and eight-level phase gratings.

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The Effect of the precursor powder composition for Bi-system superconducting thick films on Cu tapes (동테이프 위의 Bi-계 초전도 후막에서 전구체분말 조성의 영향)

  • 한상철;성태현;한영희;이준성;김상준
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.65-68
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    • 1999
  • A well oriented Bi2212 superconductor thick films were fabricated by screen printing with a Cu-free Bi-Sr-Ca-O mixture powder on a copper plate and heat-treating at 820-88$0^{\circ}C$ for several minute in air. During the heat-treatment, the printing layer partially melted by reaction between the Cu-free precursor and CuO of the oxidizing copper plate. In the partial melting state, it is believed that the solid phase is Bi-free phase and Cu-rich phase and the composition of the liquid is around Bi : Sr : Ca : Cu = 2 : 2 : 0 : 1. Following the partial melting, the Bi2212 superconducting phase is formed at Bi-free phase/liquid interface by nucleation and grows. With decreasing the Bi composition in the precursor powder, the critical temperature(T$_{c}$) of the fabricated Bi2212 thick film increased to about 79 K.K.

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A Convective Heat Transfer Correlation for Turbulent Gas-Liquid Two-Phase Flow in Vertical Pipes

  • Kim, Dong-Woo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.9 no.4
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    • pp.27-36
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    • 2001
  • A new two-phase non-boiling convective heat transfer correlation for turbulent flow $(Re_{SL}>4000)$ in vertical tubes with different fluid flow patterns and fluid combinations was developed using experimental data available from the literature. The correlation presented herein originates from a careful analysis of the major non-dimensional parameters affecting two-phase heat transfer. This model takes into account the appropriate contributions of both the liquid and gas phases using the respective cross-sectional areas occupied by the two phases. A total of 255 data points from three available studies (which included the four sets of data) were used to determine the curve-fitted constants in the improved correlation. The performance of the new correlation was compared with two-phase correlations from the literature, which were developed for specific fluid combinations.

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