• 대한화학회지
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• 제57권3호
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• pp.365-369
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• 2013

With the wide application of ASP (alkaline-surfactant-polymer) flooding, the scaling becomes more and more serious, which is harmful to the oilfield and environment. In order to investigate the effects of HPAM on calcium carbonate crystallization, the crystallization behaviors of $CaCO_3$ in HPAM (Hydrolyzed polyacrylamide) solutions were studied and the composition and morphology of $CaCO_3$ crystal were investigated in different concentrations of polyacrylamide solutions. The crystal forms and morphologies of $CaCO_3$ were characterized by Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy. The results show that the crystallization of $CaCO_3$ is strongly influenced by the HPAM. The paper analyzed the internal cause, and the results show: The reasons leading to the change of morphology are carboxyl groups in polyacrylamide molecule and $Ca^{2+}$ in solution form chelates by coordination bond. And the chelates are adsorbed on the calcium hydroxide surfaces of solid-liquid interfaces so as to change the formation rate of calcium carbonate crystal nucleus. The research provides a reliable basis for the mechanism research of the scaling problem in the oil extraction process of ASP flooding and the adoption of scale inhibition and scale inhibitor.

• 한국연소학회지
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• 제4권2호
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• pp.43-50
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• 1999

Liquefied petroleum gas (LPG) has been used as motor fuel due to its low emissions and low cost. The fuel feeding system has been improved with stringent requirement for exhaust emissions. LPG carburetion system was first introduced, then the system has been changed to a precisely controlled gas injection system, but this gas feeding system has a limitation on improving power output. In order to improve an engine performance, a multi-point port injection system was introduced recently, and a liquid direct injection system into a cylinder was suggested as a next generation system to maximize a fuel economy as well as a power. This study addresses the analysis of the LPG spray from diesel injectors. The spray images are visualized and compared with diesel sprays in a wide injection pressure range. The photographs show much wider dispersion of LPG sprays.

• 한국연소학회:학술대회논문집
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• 한국연소학회 1999년도 제19회 KOSCO SYMPOSIUM 논문집
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• pp.21-26
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• 1999

Liquefied petroleum gas(LPG) has been used as motor fuel due to its low emissions and low cost. The fuel feeding system has been improved with stringent requirement for exhaust emissions. LPG carburation system was firstly introduced, then the system changed into a gas injection system controlled precisely, but those gas feeding system has a limitation on improving power output. In order to improve an engine performance, a multi-point port injection system was introduced recently, and a liquid direct injection system into a cylinder was suggested as a next generation system to maximize a fuel economy as well as a power. This study addresses the analysis of the LPG spray from diesel injectors. The spray images are visualized and compared with diesel sprays in a wide injection pressure range. The photographs show much wider dispersion of LPG sprays.

• 대한기계학회논문집B
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• 제28권9호
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• pp.1075-1080
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• 2004

In this study, performance and emissions characteristics of an liquefied petroleum gas (LPG) engine converted from a diesel engine were examined by using mixer system and liquid propane injection (LPi) system fuel supply methods. A compression ratio for the base diesel engine, 21, was modified into 8, 8.5, 9 and 9.5. The cylinder head and the piston crown were modified to roe the LPG in the engine. Ignition timing was controlled to be at minimum spark advance for best torque (MBT) each case. Engine performance and emissions characteristics are analyzed by investigating engine power, brake mean effective pressure (BMEP), brake specific fuel consumption (BSFC), volumetric efficiency, CO, THC and NOx. Experimental results showed that the LPi system generates higher power and lower emissions than the conventional mixer fuel supply method.

• 한국가스학회지
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• 제13권4호
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• pp.1-7
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• 2009

최근 연료경제성 및 강화되는 배출가스 규제를 만족하기 위하여 대체연료의 하나인 LPG에 대한 수요가 증가하고 있다. 현재 LPG 차량에 적용되고 있는 제3세대 LPG 연료공급방식인 LPLi(Liquid Phase LPG Injection) 시스템은 가솔린 차량과 비교하여 배출가스는 적게 배출하면서 동등한 출력을 낼 수 있게 하는 핵심 기술이다. LPG 연료를 고압의 액상 상태로 공급하기 위해서는 LPG 펌프가 필요하다. 연료펌프의 성능을 저하 시킬 수 있는 연료 내 불순물을 제거하기 위하여 연료펌프에는 연료필터가 장착되어 있으며 장착되는 연료필터의 종류에 따라서 연료펌프의 성능도 변하게 된다. 본 연구에서는 임펠라 방식을 채택한 LPG 연료펌프에서 극세사, 이중메쉬, 외장형 필터의 세 가지 필터에서 부하별 토출성능 및 효율을 파악하였으며 온도 변화에 따른 펌프유량 변화를 측정하였다.

• 한국응용과학기술학회지
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• 제26권3호
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• pp.279-287
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• 2009

Fisher-Tropsch synthesis for the production of hydrocarbon from syngas was investigated on 20% cobalt-based catalysts (20% Co/HSA, 20% Co/Si-MMS), which were prepared by home-made supports with high surface areas such as high surface alumina (HSA) and silica mesopores molecular sieve (Si-MMS). In the gas phase reaction by syngas only, 20% Co/Si-MMS catalyst was shown in higher CO conversion and lower carbon dioxide formation than 20% Co/HSA, whereas the olefin selectivity was higher in 20% Co/HSA than in 20% Co/Si-MMS. In the effect of n-hexane added in syngas, the selectivities of $C_{5+}$ and olefin were increased by comparing the supercritical phase reaction with the gas phase reaction in addition to reduce unexpected methane and carbon dioxide.

• 한국자동차공학회논문집
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• 제13권1호
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• pp.28-35
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• 2005

Fuel injection rate of an injector is affected by various injection conditions such as injection duration, fuel temperature, injection pressure, and voltage in LPG liquid injection systems for either a port-fuel-injection(PFI) or a direct injection(DI) in a cylinder. Even fuel injection conditions are changed, the air-fuel ratio should be accurately controlled to educe exhaust emissions. In this study, correction factor for the fuel injection rate of an injector is derived from the density ratio and the pressure difference ratio. A voltage correction factor is researched from injection test results on an LPG liquid injection engine. A compensation method of the fuel injection rate is proposed for a fuel injection control system. The experimental results for the LPG liquid injection system in a SI-engine show that this system works well on experimental range of engine speed and load conditions. And the fuel injection rate is accurately controlled by the proposed compensation method.

• 한국자동차공학회논문집
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• 제10권5호
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• pp.90-97
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• 2002

The interaction between airflow and liquid phase LfG (Liquefied Petroleum Gas) sprays was investigated in a steady flow system embodied in a wind tunnel to simulate the variety of flow inside intake port of LPG engines with liquid injection system. The spray developments in flowing fields with the mean velocities of 5.4, 21.5 and 42.4m/s were identified by spray visualization techniques such as Mie scattering and shadowgraph. The microscopic visualization using a telescopic lens system was performed to investigate the shape and size of liquid droplets in the spray. PDA measurement was used to get 1-dimensional velocity and diameter of liquid droplets. The fast co-flows make the spray field be compact and be lead upward to the injection direction. SMD of the spray was smaller at the fast flowing field. Spray width got bigger and SMD of the spray was smaller with higher injection pressure.

• 대한화학회지
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• 제7권2호
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• pp.128-132
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• 1963

A study has been made on the applicability of gas-liquid partition chromatography to the qualitative and quantitative analysis of complex mixture of gaseous hydrocarbons. While phthalate columns are widely used for this $purpose^9$, they separates neither saturated hydrocarbons from the unsaturated nor n-butane from isobutene or butene-1, therefore combined columns such as phthalate and dimethylsulfolane have been used for the perfect separation of gaseous hydrocarbons. It is shown by this study, however, that hydrocarbons having $C_1$ through $C_4$ can be separated with a 2-meters tetraethyleneglycol dimethylether column except ethane from ethylene, and trans-from cis-2-butene especially operated at $15^{\circ}C$$ using helium as the carrier gas. The column effluents were in order of methane, (ethane, ethylene), propane, propylene, isobutane, n-butane, isobutylene, butene-1, (trans-& cis-2-butene, isopentane), (butadiene-1, 3, n-pentane). Two kinds of liquified petroleum gases in market are analysed qualitatively and quantitatively. The results indicate that use of this 2-meters TEGDE column permits the separation and identification of all the commonly encountered aliphatic gaseous hydrocarbons.

• 대한기계학회논문집B
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• 제38권2호
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• pp.155-163
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• 2014

주유소에서 거래되는 액체 연료인 석유류는 온도 변화에 따라 팽창과 수축하게 된다. 석유류의 체적팽창계수는 약 $0.1%/^{\circ}C$이고, 우리나라의 기온은 겨울철에는 $-15^{\circ}C$, 여름철에는 $35^{\circ}C$까지 변한다. 온도 변화에 따른 체적의 변화가 석유류 거래에 미치는 영향을 조사하기 위해 주유소에 저장된 연료와 주유되는 연료의 온도 변화를 측정하였다. 또 우리나라의 지난 50 년간의 일간, 월간, 년간 온도 변화를 고찰하였다. 지하 저장탱크의 유류 온도는 계절에 관계없이 하루 중 안정되게 유지되었다. 주유소 주위의 환경 조건과 위치, 주유 빈도등이 주유되는 유류의 온도에 영향을 미치는 것을 알 수 있었다. 이러한 연구 결과는 건전한 석유류의 거래와 관련 법령의 제정에 활용될 것이다.