• Progress in Superconductivity
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• 제7권1호
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• pp.69-76
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• 2005

Complex single buffer composed of yttrium and samarium oxide was deposited on the metallic substrates by MOCVD (metal organic chemical vapor deposition) method using single liquid source. Two different types of the substrates with in-plane textures of about $8{\sim}10$ degree of Ni and $3at.\%W-Ni$ alloy were used. Y(tmhd: 2,2,6,6-tetramethyl-3,5-heptane dionate)$_3$:Sm(tmhd)$_3$ of liquid source was adjusted to 0.4:0.6 to minimize the lattice mismatch between the complex single buffer and the YBCO. The epitaxial growth of $(Y_{x}Sm_{1-x})_{2}O_3$ was achieved at the temperature higher than $500^{\circ}C$ in $O_2$ atmosphere. However, it was found that the formation of NiO accelerated with increasing deposition temperature. By supplying $H_{2}O$ vapor, this oxidation of the substrate could be suppressed throughout the deposition temperatures. We could get the epitaxial growth on pure Ni substrate without the formation of NiO. The competitive (222) and (400) growths were observed at the deposition temperatures of $650\~750^{\circ}C$, but the (400) growth became dominant above $800^{\circ}C$. The $(Y_{x}Sm_{1-x})_{2}O_3$-buffered metallic substrates can be used as the buffer for YBCO coated conductor.

• 한국주조공학회지
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• 제6권1호
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• pp.12-19
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• 1986

This study was undertaken to understand the formation mechanism of the hard spots in high strength brass. To investigate the behavior of the hard spots in the isothermal liquid state with varying silicon content, the rapidly quenched specimens were obtained by suctioning the melt into the silica tube and water quenching. To examine the growth process of the hard spots with holding time, the unidirectional solidification technique was used. The results of this study are summarized as follows: 1) With the addition of Fe in order to get the effects of grain refinement in high strength brass, the two different type of Fe-rich phases are occurred, which are defined as dendritic and globular phase. The chemical composition of the globular phase was different from that of the dendritic phase in that the globular phase contained Si. 2) With increasing Si content, the Fe-rich phase had a tendency to form globular phase. 3) As the holding time increased in the liquid state, globular was also prone to coalesce. The further growth of globular phase to large size was due to reducing the interfacial energy. 4) The primary phase of copper alloy was nucleated preferentially on the dendritic phase. It was noticeable that the dendritic phase acted as a grain refiner. However, the agglomerate (hard spots) which was composed of the globular phase decreased the mechanical properties of high strength brass. 5) Once the hard spots formed in the high strength brass casting, it was very difficult to remove them. This is due to the fact that their meting temperature is higher than the pouring temperature of high strength brass.

• 대한치과보철학회지
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• 제41권6호
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• pp.732-746
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• 2003

Statement of problem. Soft lining materials, also referred to as tissue conditioning materials, tissue heating materials, relining materials, soft liners or tissue conditioners, were first introduced to dentistry by a plastic manufacturer in 1959. Since the introduction of the materials to the dental field, their material properties have been continually improved through the effort of many researchers. Soft lining materials have become widely accepted, particularly by prosthodontists, because of their numerous clinical advantages and ease of manipulation. Unfortunately, few reports have been issued upon the topic of increasing the bond strength between the base metal alloy used in cast denture bases and PMMA soft liner modified with 4-META, nor upon the pattern of debonding and material change in wet environment like a intra oral situation. Purpose. The purposes of this study were comparing the bond strength between base metal alloy used for the cast denture bases and PMMA soft liner modified with 4-META, and describing the pattern of debonding and material property change in wet environment like the intraoral situation. Material and Methods. This study consisted of four experiments: 1. The in vitro measurement of shear bond strength of the adhesive soft liner. 2. The in vitro measurement of shear bond strength of the adhesive soft liner after 2 weeks of aging. 3. A comparison of debonding patterns. 4. An evaluation the Relation time of modified soft liner. The soft liner used in this study was commercially available as Coe-soft (GC America.IL.,USA), which is provided in forms of powder and liquid. This is a PMMA soft liner commonly used in dental clinics. The metal primer used in this study was 4-META containing primer packed in Meta fast denture base resin (Sun Medical Co., Osaka, Japan). The specimens were formed in a single lap joint desist which is useful for evaluating the apparent shear bond strength of adhesively bonded metal plate by tensile loading. Using the $20{\times}20mm$ transparent grid, percent area of adhesive soft liner remaining on the shear area was calculated to classify the debonding patterns. To evaluate the change of the initial flow of the modified adhesive soft liner, the gelation time was measured with an oscillating rheometer (Haake RS150W/ TC50, Haake Co., Germany). It was a stress control and parallel plate type with the diameter of 35mm. Conclusion. Within the conditions and limitations of this study, the following conclusions were drawn as follows. 1. There was significant increase of bond strength in the 5% 4-META, 10% 4-META containing groups and in the primer coated groups versus the control group(P<0.05). 2. After 2 weeks of aging, no significant increase in bond strength was found except for the group containing 10% 4-META (P<0.05). 3. The gelation times of the modified soft liner were 9.3 minutes for the 5% 4-META containing liner and 11.5 minutes for the 10% 4-META liner. 4. The debonding patterns of the 4-META containing group after 2 weeks of aging were similar to those of immediaely after preparation, but the debonding pattern of the primer group showed more adhesive failure after 2 weeks of aging.

• Korean Chemical Engineering Research
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• 제60권2호
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• pp.175-183
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• 2022

자동차 시장의 확대에 따라 자동차 모터의 필수 소재로 희토류금속인 Nd에 대한 수요가 급증하고 있다. Nd를 제조하기 위하여 Nd₂O₃와 Ca계 합금의 열 환원반응에 관한 연구가 활발히 진행되어 왔다. 본 연구에서는 Nd₂O₃의 환원제로 사용되는 Ca계 합금인 Ca-Cu를 CaCl₂ 용융염에서 전기분해반응을 통해 제조하였다. 전기분해반응의 작업 전극과 상대전극으로는 Cu 와이어와 흑연을 각각 사용하였다. 기준전극은 AgCl:CaCl₂=1:99 mol%로 혼합한 혼합물에 Ag 와이어를 넣어 제작하였다. 순환전압 전류법 결과에 의하면 -1.8 V의 전위부터 작업전극의 표면에 Ca²⁺의 증착이 관찰되었으며, CaCl₂ 염의 온도가 증가할수록 Ca²⁺의 환원전위가 감소하였다. 시간대전류법 실험을 통해 계산된 Ca²⁺의 확산계수는 5.4(±6.8)×10^-6 cm²/s으로 나타났다. 또한, Cu 전극에 일정한 전위를 가해 Ca-Cu 액상합금을 제조하였으며 제조된 합금은 EDS line scan을 통해 인가 전위의 증가에 따라 Ca의 전기화학적 삽입이 증가함을 확인하였다. -2.0 V보다 음의 전위를 인가하여 제조한 Ca-Cu 합금의 조성비는 Ca:Cu=1:4임을 확인하였다.

• 에너지공학
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• 제13권2호
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• pp.101-111
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• 2004

액체금속로 노심 열유체 설계의 기본 목표는 노심을 구성하는 집합체에서 발생하는 열량을 효과적으로 추출하기 위해 각각의 집합체 냉각재 유량을 적절히 분배하고, 이에 따른 온도분포가 적절하게 유지되도록 하는 것이다. 노심 열유체 설계 및 특성 분석은 전체노심에 대한 각 집합체의 유량영역을 구분하고, 집합체별 온도분포를 계산하여, 최종적으로 집합체에 대한 상세 부수로 해석을 하는 과정으로 진행된다. 본 논문에서는 이러한 액체금속로의 노심 열유체 설계 방법론을 기술하고, 이를 바탕으로 KALIMER의 증식특성 노심과 breakeven 노심에 대한 열유체 설계와 특성분석을 수행하였다. KALIMER는 원자력 중장기 과제로 개념설계가 진행 중인 전기출력 150MWe, 열출력 392MWth의 금속핵연료를 사용하는 액체 금속로이다.

• International Journal of Precision Engineering and Manufacturing
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• 제4권2호
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• pp.49-56
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• 2003

As semi-solid forging (SSF) is compared with conventional casting such as gravity die-casting and squeeze casting, the product without inner defects can be obtained from semi-solid forming and globular microstructure as well. Generally, SSF consists of reheating, forging, and ejecting processes. In the reheating process, the materials are heated up to the temperature between the solidus and liquidus line at which the materials exists in the form of liquid-solid mixture. The process variables such as reheating time, reheating temperature, reheating holding time, and induction heating power has large effect on the quality of the reheated billets. It is difficult to consider all the variables at the same time for predicting the quality. In this paper, Taguchi method, regression analysis and neural network were applied to analyze the relationship between processing conditions and solid fraction. A356 alloy was used for the present study, and the learning data were extracted from the reheating experiments. Results by neural network were in good agreement with those by experiment. Polynominal regression analysis was formulated using the test data from neural network. Optimum processing condition was calculated to minimize the grain size and solid fraction standard deviation or to maximize the specimen temperature average. Discussion is given about reheating process of row material and results are presented with regard to accurate process variables fur proper solid fraction, specimen temperature and grain size.

• 한국분말재료학회지
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• 제13권3호
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• pp.199-204
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• 2006

We manufactured the metal hydrides of $(Ti_{0.88}Mg_{0.12})H_2$ using a very easy and cheap way that Ti-12%Mg blending powder was mechanically milled with liquid milling media such as isopropyl alcohol ($C_3H_8O$, containing oxygen) and hexane ($C_6H_{14}$, no oxygen) as hydrogen source. The $(Ti_{0.88}Mg_{0.12})H_2$ synthesized in isopropyl alcohol contained the high oxygen of 11.2%, while one in hexane had the low oxygen content of 0.7%. Such a difference of oxygen content affected the dehydriding behavior, phase transformation, and microstructural evolution at high temperature, which was investigated through X-ray diffraction and DSC measurements, and electron microscope observations.

• 한국산학기술학회논문지
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• 제10권4호
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• pp.740-746
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• 2009

본 논문에서는 공진형 유도가열기를 이용한 2단 직렬 부하형 유도가열 과열증기 발생장치를 제안하였다. 발열방식은 외부의 가열코일로부터 특수 합금 발열체에 비접촉 상태로 전자유도 와전류를 구조체에 흐르게 하였다. 인버터는 풀-브리지 고주파 직렬 부하 공진형 이며, LC 공진 설계에서 부하자체를 인덕터로 선정하여 효율을 최대화 하였다. 개발된 장치는 전자유도가열 발열체와 유체이동에 의한 새로운 열교환 방식으로 일체의 연소과정 없이 기체, 액체 및 증발체 등을 상온에서 고온에 이르기까지 고정도의 가열이 가능하다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1995년도 추계학술대회 논문집
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• pp.302-305
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• 1995

ITO(indium tin oxide) that is both conductive in electricity and transparent to the visible ray is called transparent conducting thin film. Nowaday, according to the development of flat panel display such as LCD(Liquid Crystal display, EL(electolumine- scence display), PDP(plasma display panel), ECD(electrocromic display), the higher quality in the low temperature process has been asked to reduce the production cost and to have a good uniformity on a large substrate. In this study, we prepared indium tin oxide(ITO) by a cylindrical DC magnetron sputtering with Indium-tin (9:1) alloy target instead of indium-tin oxide target. To reduce the defact in ITO, the effect on ITO by varing the magnetic field intensity and the applied voltage ares studied. the resistivity of the film deposited in oxygen partial pressure of 5% and substrate temperature of 140$^{\circ}C$. is 1.6${\times}$10$\^$-1/$\Omega$$.$cm with 85% optical transmission in viaible ray.

• 한국재료학회지
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• 제13권5호
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• pp.297-302
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• 2003

The effects of risering design and alloying element on the formation of defects such as external depression, primary and secondary shrinkage cavity in gray cast iron were investigated. Two types of risering design for the cylindrically step-wise specimen, No. 1(progressive solidification) and No. 2(directional solidification) risering designs, were prepared and five different alloy compositions were casted. In the No. 1 risering design, external depression or primary shrinkage cavity due to liquid contraction was observed in all the specimens from ISO 150 to ISO 350. The primary shrinkage cavity was located right under the top surface or connected to the top surface, and was characterized by smooth surface. Its size increased with an increase in ISO number. However, neither secondary shrinkage cavity nor swollen surface was observed in all the castings. In the No.2 risering design, neither primary shrinkage cavity nor secondary shrinkage cavity was observed in all the specimens due to proper risering design. A swollen surface was also not observed in all the castings with the application of pep-set mold.