• 제목/요약/키워드: liquid alloy

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Refining of Silicon by Fractional Melting Process (Fractional Melting에 의한 Si 정련에 관한 연구)

  • Kim, Kwi-Wook;Yoon, Woo-Young
    • Journal of Korea Foundry Society
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    • v.17 no.6
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    • pp.598-607
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    • 1997
  • Fractional melting process involves heating an alloy within its liquid-solid region simultaneously ejecting liquid from the solid-liquid mixture. The extent of the purification obtained is comparable to that obtained in multi-pass zone refining. The new fractional melting process in which centrifugal force was used for separating the liquid from the mixture has been developed and applied to the purification of the metallic grade. Refining ratio depends on partition ratio, cake wetness and diffusion in the solid, and it was controlled by various processing parameters such as rotating speed and heating rate. The new parameter called "refining partition coefficient" has been suggested to estimate the effects of processing variables on the refining ratio. Because major impurities in MG-silicon such as Fe, Al, Ni have a low segregation coefficient, good purification effect is expected. The results of refining MG-silicon(98%) showed that 3N-Si was obtained in refined solid of 50% of the original sample.

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True Sedimentation and Particle Packing Rearrangement during Liquid Phase Sintering

  • Lee, Jong-K.;Xu, Lei;Lu, Shu Zu
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.68-69
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    • 2006
  • When an alloy such as Ni-W is liquid phase sintered, heavy solid W particles sedimentate to the bottom of the container, provided that their volume fraction is less than a critical value. The sintering process evolves typically in two stages, diffusiondriven macrosegregation sedimentation followed by true sedimentation. During macrosegregation sedimentation, the overall solid volume fraction decreases concurrently with elimination of liquid concentration gradient. However, in the second stage of true sedimentation, the average solid volume fraction in the mushy zone increases with time. It is proposed that the true sedimentation results from particle rearrangement for higher packing efficiency.

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Study on the Soldering of Off-eutectic Pb-Sn Solders in Partial Melting State

  • Park, Jae-Yong;Ha, Jun-Seok;Kang, Choon-Sik;Shin, Kyu-Sik;Kim, Moon-Il;Jung, Jae-Pil
    • Journal of the Microelectronics and Packaging Society
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    • v.7 no.2
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    • pp.63-68
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    • 2000
  • This paper introduces the partial melting process for solder application and characterization of its possibility using off-eutectic Pb-Sn alloy. In order to show that the liquid phase in the semi-liquid state maintains the wettability as the single-phase liquid, the wetting balance test are conducted with varying temperatures and compositions. The results are then compared with the surface tension of liquid, both measured and calculated, to examine the correlation. The results from this investigation indicate that the partial melting can yield satisfactory solder joints as long as the liquid phase acquires sufficient chemical activity. At a condition where the partial melting is effective, a direct correlation between the wettability and the surface tension is found to exist. All alloys are found to show a reasonable wettability in semi-liquid state.

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Process Analysis for Rheology Forming Considering Flow and Solidification Phenomena in Lower Solid Fraction (저고상율 소재의 유동 및 응고현상을 고려한 레올로지 성형공정해석)

  • Jung, Young-Jin;Cho, Ho-Sang;Kang, Chung-Gil
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.9
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    • pp.156-164
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    • 2001
  • Two-dimensional solidification analysis during rheology forming process of semi-solid aluminum alloy has been studied. Two-phase fluid flow model to investigate the velocity field and temperature distribution is proposed. The proposed mathematical model is applied to the die shape of the two types. To calculate the velocity and temperature fields during rheology forming process, the earth governing equation correspondent to the liquid and solid region are adapted. Therefore, each numerical models considering the solid and liquid region existing within the semi-solid material have been developed to predict the deflect of rheology forming gnarls. The Arbitrary Boundary Maker And Cell (ABMAC) method is employed to solve the two-phase flow model of the Navier-Stokes equation. Theoretical model on the basis of the two-phase flow model is the mixture rule of solid and liquid phases. This approach is based on the liquid and solid viscosity. The liquid viscosity is pure liquid state value, however solid viscosity is considered as a function of the shear rate, solid fraction and power law curves.

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An analysis on the solidification process of alloy casting with a contact resistance (접촉 열저항을 고려한 합금주조의 응고과정 해석)

  • Kim, W.S.;Lee, K.S.;Im, I.T.;Kim, K.S.
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.1
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    • pp.57-67
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    • 1997
  • The solidification process of Al 4.5%Cu alloy is numerically studied in the presence of contact resistance between mold and cast. Natural convection is considered in the liquid and mushy regions. The porosity approach is applied to the mushy zone modeling and linear variation of the solid fraction on the temperature is assumed. Results show that the mushy region is wider in the case with a contact resistance compared to the perfect contact condition. The temperature of the cast with a temporal variation in the contact heat transfer coefficient changes very rapidly in the early stage of the casting process compared to that with constant contact heat transfer coefficient.

Development of Sleeve Parts for Continuous Hot Zinc Plating Roll Applied to Wear-Resistant Alloy Cast Steel

  • Park, Dong-Hwan;Hong, Jin-Tae;Kwon, Hyuk-Hong
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.26 no.4
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    • pp.357-364
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    • 2017
  • Metal casting is a process in which molten metal or liquid metal is poured into a mold made of sand, metal, or ceramic. The mold contains a cavity of the desired shape to form geometrically complex parts. The casting process is used to create complex shapes that are difficult to make using conventional manufacturing practices. For the optimal casting process design of sleeve parts, various analyses were performed in this study using commercial finite element analysis software. The simulation was focused on the behaviors of molten metal during the mold filling and solidification stages for the precision and sand casting products. This study developed high-life sleeve parts for the sink roll of continuous hot-dip galvanizing equipment by applying a wear-resistant alloy casting process.

Evaluation of Cavitation Characteristics of 5083-O Al Alloy with Amplitude (5083-O 알루미늄 합금의 진폭에 따른 캐비테이션 침식 특성 평가)

  • Lee, Seung Jun;Kim, Seong Jong
    • Corrosion Science and Technology
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    • v.11 no.5
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    • pp.205-212
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    • 2012
  • With recent advances in engineering and technology, a damage on industrial machineries performing high-speed and high-power requirements has become a problem. There is an increasing possibility of cavitation damage, especially in pumps, propellers and high-speed vessels in a flowing liquid accordingly. There are several factors affecting cavitation damage on materials, including viscosity, pressure, temperature, amplitude applied. In this study, effects of cavity pressure in seawater on the damage for 5083-O aluminium alloy were evaluated by modulating amplitude. Trend of the damage with respect to time and amplitude was analyzed comparatively, and surface degradation of specimens was investigated by using Scanning Electron Microscope(SEM) and 3D microscope. The result reveals that the amount of the damage increased consistently with the increase in time and amplitude while the plastic deformation zone where no appreciable damage occurred was in less than 30 minutes.

Effect of Bonding Condition on High Temperature Mechanical Properties of TLP Bonded Joints of FE-35Ni-26Cr Alloy (Fe-35Ni-26Cr 주강 액상확산접합부의 고온기계적 특성에 미치는 접합조건의 영향)

  • 김대업
    • Journal of Welding and Joining
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    • v.18 no.4
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    • pp.96-103
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    • 2000
  • This study investigated the effects of bonding temperature and bonding atmosphere on high temperature mechanical properties of transient liquid phase(TLP) bonded joints of heat resistant alloy using MBF-50 insert metal. Specimens were bonded at 1,423~1,468K for 600s. Microconstituents of {TEX}$Cr_{7}(C,B)_{3}${/TEX}were formed in the bonded region when the bonding temperature was low. The amount of microcostituents in the bonded layer decreased with increasing the bonding temperature, and the microconstituents in the bonded layer disappeared at the bonding temperature above 1,468K. The tensile strength of the joints at elevated temperatures increased with the increase the bonding temperature and was the same level as one of the base metal in the bonding temperature over 1,453K. Microstructure and alloying element distributions of the bonded region bonded in Ar and $N_2$atmosphere were similar to those of the bonded in vacuum. The creep rupture strength and rupture lives of joints were almost identical to those of base metal.

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A Study on the Solidified Structures of Al-Pb Alloy Solidified by Rapid Cooling (급냉응고 시킨 Al-Pb 합금의 응고조직에 관한 연구)

  • Kim, Yong-Kil;Kim, Tong-Hoon
    • Journal of Korea Foundry Society
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    • v.2 no.1
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    • pp.12-18
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    • 1982
  • The present investigation was made to abtain a fine distribution of Pb Particles in AL - Pb binary alloys , which have a broad miscibility gap and large specific difference, by means of rapid Cooling of the molten alloys. Al-2.4% Pb, Al-5.5wt% Pb and Al-8.0wt % Pb alloy were used. The rapid cooling operation was performed by free falling of homogeneous liquid Al-Ph alloys into the water-cooled copper mold, and thermal analysis was made. Microstructures were observed, and variations of size and number of Pb particles were analysicle analyzer. By the result of examination with the varing cooling rates 100 to $210^{\circ}C/sec$ fine distributions of Pb particles were obtained with high cooling rate. Under same cooling condition, the best rapid cooling effect was recognized in Al-5.5wt% Pb alloy.

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Characteristics of Cryolite as an Electrolyte for Reduction of Nd$_2$O$_3$ (네오디뮴 산화물의 전해환원시 전해질로서 빙정석의 특성)

  • 남상욱;백영현
    • Journal of the Korean institute of surface engineering
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    • v.26 no.2
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    • pp.82-86
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    • 1993
  • An attempt was made to reduce directly Nd2O3 in a cryolited based fluoride bath. Neodymium metal was electrodeposited on the iron cathode to produce the Fe-Nd eutectic alloy in a liquid state at 90$0^{\circ}C$. Graphite was adopted for the anode and pure iron for the cathode. Electrolyte was composed of Na3AlF6 50wt.%. AlF3 34wt.% and Nd2O3 16wt.%. Analysis of typical alloy product showed Al 63.4wt.% Fe 26.9wt.% and Nd 7.0 wt.% The enrichment of neodymium in the alloy couldn't be obtained because aluminum codeposited with ne-odydmium. Experimental results proved that the cryolited based electrolyte was unstable for the electrolysis of rare earth oxides even though their prominent solubilities.

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