• Geomechanics and Engineering
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• v.35 no.4
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• pp.449-464
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• 2023

Advanced nonlinear effective stress constitutive models are started to be frequently used in one-dimensional (1D) and two-dimensional (2D) site response analysis for assessment of porewater generation and liquefaction potential in soft soil deposits. The emphasis of this research is on the assessment of the implementation of this category of models at the element stage. Initially, the performance of a coupled porewater pressure (PWP) and constitutive models were evaluated employing a catalogue of 40 unidirectional cyclic simple shear tests with a variety of relative densities between 35% and 80% and effective vertical stresses between 40 and 80 kPa. The authors evaluated three coupled constitutive models (PDMY02, PM4SAND and PDMY03) using cyclic direct simple shear tests and for decide input parameters used in the model, procedures are recommended. The ability of the coupled model to capture dilation as strength is valuable because the studied models reasonably capture the cyclic performance noted in the experiments and should be utilized to conduct effective stress-based 1D and 2D site response analysis. Sandy soils may become softer and liquefy during earthquakes as a result of pore-water pressure (PWP) development, which may have an impact on seismic design and site response. The tested constitutive models are mathematically coupled with a cyclic strain-based PWP generation model and can capture small-strain stiffness and large-strain shear strength. Results show that there are minor discrepancies between measured and computed excess PWP ratios, indicating that the tested constitutive models provide reasonable estimations of PWP increase during cyclic shear (r_u) and the banana shape is reproduced in a proper way indicating that dilation and shear- strain behavior is well captured by the models.

• Membrane Journal
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• v.22 no.1
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• pp.72-76
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• 2012

$SF_6$ has an extremely high global worming potential (GWP). Therefore, there has been an effort to reduce the use of $SF_6$ and its emission into atmosphere. One possible solution for minimizing the use of $SF_6$ in electrical equipments is utilization of gas mixtures such as $SF_6/N_2$. The $SF_6$ concentration in the gas mixture varies from 10 to 60%. However, when the apparatus is repaired or dismantled, we have to recover $SF_6$ from the gas mixture. Since the boiling point of $SF_6$is low (${\sim}-60^{\circ}C$), the liquefaction method is difficult to apply. One possible alternative is the membrane separation technology. In this study, we investigated the $SF_6$ and $N_2$ permeation properties of 5 polymeric membranes. For example, permeability of $N_2$ in BOPP membrane at $25^{\circ}C$was 0.19 barrer, whereas that of $SF_6$ was only 0.0012 barrer, resulting in the selectivity of 158. An upper bound for $SF_6/N_2$ gas pair was suggested for the first time with n = -1.33 and k = 160 (barrer).

• Korean Chemical Engineering Research
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• v.52 no.4
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• pp.467-474
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• 2014

Preliminary design in chemical process furnishes economic feasibility through calculation of both mass balance and energy balance and makes it possible to produce a desired product under the given conditions. Through this design stage, the process possesses unchangeable characteristics, since the materials, reactions, unit configuration, and operating conditions were determined. Unique characteristics could be very economic, but it also implies various potential risk factors as well. Therefore, it becomes extremely important to design process considering both economics and safety by integrating process simulation and quantitative risk analysis during preliminary design stage. The target of this study is LNG liquefaction process. By the simulation using Aspen HYSYS and quantitative risk analysis, the design variables of the process were determined in the way to minimize the inherent explosion risks and operating cost. Instead of the optimization tool of Aspen HYSYS, the optimization was performed by using stochastic optimization algorithm (Covariance Matrix Adaptation-Evolution Strategy, CMA-ES) which was implemented through automation between Aspen HYSYS and Matlab. The research obtained that the important variable to enhance inherent safety was the operation pressure of mixed refrigerant. The inherent risk was able to be reduced about 4~18% by increasing the operating cost about 0.5~10%. As the operating cost increases, the absolute value of risk was decreased as expected, but cost-effectiveness of risk reduction had decreased. Integration of process simulation and quantitative risk analysis made it possible to design inherently safe process, and it is expected to be useful in designing the less risky process since risk factors in the process can be numerically monitored during preliminary process design stage.