• Title/Summary/Keyword: line complex

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Electronic Spectroscopy and Ligand Field Analysis of cis-$>[Cr(cycb)Cl_2]$Cl

  • Choi, Jong-Ha;Oh, In-Gyung;Subodh Kumar;Ryoo, Keon-Sang
    • Journal of Photoscience
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    • v.11 no.1
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    • pp.19-23
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    • 2004
  • The sharp-line absorption spectrum of microcrystalline samples of cis-[Cr(cycb)$Cl_2$]Cl (cycb=rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) has been measured between 13000 and $16000 cm^{-1}$ at temperatures down to 5K. The 77K emission and excitation spectra, and 298 K infrared and visible absorption spectra have also been measured. The nine electronic bands due to spin-allowed and spin-forbidden transitions were assigned. Using the observed transitions, a ligand field analysis has been performed to probe the ligand field properties of coordinated atoms in the title chromium(III) complex. The zero-phonon line in the sharp-line absorption spectrum splits into two components by $240 cm^{-1}$ , and the $large ^2$$_E{g}$ splitting can be reproduced by the modem ligand field theory. It is confirmed that nitrogen atoms of the macrocyclic cycb ligand have a strong $\sigma$-donor character, but chloride ligand has weak $\sigma$- nd $\pi$-donor properties toward chromium(III) ion.n.

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Identification of hRad21-Binding Sites in Human Chromosome

  • Chin Chur;Chung Byung-Seon
    • Genomics & Informatics
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    • v.4 no.1
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    • pp.11-15
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    • 2006
  • The aim of this study is to identify hRad21-binding sites in human chromosome, the core component of cohesin complex that held sister chromatids together. After chromatin immunoprecipitation with an hRad21 antibody, it was cloned the recovered DNA and sequenced 30 independent clones. Among them, 20 clones (67%) contained repetitive elements including short interspersed transposable elements (SINE or Alu elements), long terminal repeat (LTR) and long interspersed transposable elements (LINE), fourteen of these twenty (70%) repeats clones had Alu elements, which could be categorized as the old and the young Alu Subfamily, eleven of the fourteen (73%) Alu elements belonged to the old Alu Subfamily, and only three Alu elements were categorized as young Alu subfamily. There is no CpG island within these selected clones. Association of hRad21 with Alu was confirmed by chromatin immunoprecipitation-PCR using conserved Alu primers. The primers were designed in the flanking region of Alu, and the specific Alu element was shown in the selected clone. From these experiments, it was demonstrated that hRad21 could bind to SINE, LTRs, and LINE as well as Alu.

Damage Cause Analysis of Phaya-Thon-Zu Temple in Myanmar Using Thrust Line Analysis (추력선 해석을 이용한 미얀마 파야톤주 사원의 손상 원인 분석)

  • Hong, Souk-Il;Jeon, Geon-Woo;Jung, In-Ki;Han, Wuk-Bean;Kim, Ho-Soo
    • Journal of Korean Association for Spatial Structures
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    • v.20 no.2
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    • pp.95-104
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    • 2020
  • Phaya-Thon-Zu temple has a unique architectural style connected by the three temples, and cultural values are highly as murals remain on some of the walls. However, various damages in internal walls and vaults have occurred due to earthquake and environmental influences. In order to analyze these damages, accurate structural analysis is required, but structural modeling is difficult, because Phaya-Thon-Zu temple is the complex masonry structure which is stacked with small bricks. Therefore, this study intends to analyze the causes of damages by examining collapse mechanism for cross section and longitudinal section of vaults in the entrance hall and shrine by using thrust line analysis, which is a geometric method, and to compare it with the actual damage situation.

[ N2H+ ] OBSERVATIONS OF MOLECULAR CLOUD CORES IN TAURUS

  • TATEMATSU KEN'ICHI
    • Journal of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.279-282
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    • 2005
  • We report the millimeter-wave radio observations of molecular cloud cores in Taurus. The observed line is the $N_2H^+$ emission at 93 GHz, which is known to be less affected by molecular depletion. We have compared starless (IRAS-less) cores with star-forming cores. We found that there is no large difference between starless and star-forming cores, in core radius, linewidth, core mass, and radial intensity profile. Our result is in contrast with the result obtained by using a popular molecular line, in which starless cores are larger and less condensed. We suggest that different results mainly come from whether the employed molecular line is affected by depletion or not. We made a virial analysis, and found that both starless and star-forming cores are not far from the critical equilibrium state, in Taurus. Together with the fact that Taurus cores are almost thermally supported, we conclude that starless Taurus cores evolve to star formation without dissipating turbulence. The critical equilibrium state in the virial analysis corresponds to the critical Bonnor-Ebert sphere in the Bonnor-Ebert analysis (Nakano 1998). It is suggested that the initial condition of the molecular cloud cores/globules for star formation is close to the critical equilibrium state/critical Bonnor-Ebert sphere, in the low-mass star forming region.

Focal Length Control of Line-focus Ultrasonic Transducer Using Bimorph-type Bending Actuator (바이몰프형 밴딩 액츄에이터를 이용한 선집속형 초음파 트랜스듀서의 초점 거리 제어)

  • 채민구;하강열;김무준
    • The Journal of the Acoustical Society of Korea
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    • v.22 no.3
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    • pp.202-207
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    • 2003
  • For medical ultrasonic transducer, phase-weighting method has been used for controlling focal length with electric circuit at each vibrating element. However, the electric circuit is complex as the number of vibrating elements is increased. In this paper, we fabricated line-focus transducer with a bimorph-type piezoelectric actuator. The polyvinylidene fluoride (PVDF) piezoelectric type polymer film is used for transmitting and receiving of ultrasonic signal. Using this transducer, focal length of the transducer can be controlled mechanically by changing voltage of the actuator. It is confirmed that focal length of the transducer can be controlled in range of 1095 to radius of curvature.

An Analytical Study on the Thermal-Structure Stability Evaluation of Mill-Turn Spindle with Curvic Coupling (커빅 커플링을 적용한 밀-턴 스핀들의 열-구조 안정성 평가에 관한 해석적 연구)

  • Lee, Choon-Man;Jeong, Ho-In
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.1
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    • pp.100-107
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    • 2020
  • As demand for high value-added products with hard materials increases, the line center is used for producing high value-added products in many industries such as aerospace, automobile fields. The line center is a key device for smart factory automation that can improve the production efficiency and the productivity. Therefore, the development of a mill-turn line center is necessary to produce high value-added products with complex shapes flexibly. In the mill-turn process, a milling process and a turning process are combined. In particular, the turning process needs to increase the rigidity of the spindle. The purpose of this study is to analyze the thermal-structural stability through thermo-structural coupled analysis for a mill-turn spindle with a curvic coupling. The maximum temperature and thermal stability of the spindle were analyzed by thermal distribution. In addition, the thermal deformation and thermal-structural stability of the spindle were analyzed through thermo-structural coupled analysis.

Cu Line Fabricated with Inkjet Printing Technology for Printed Circuit Board (잉크젯 인쇄 기술을 이용한 인쇄회로기판용 나노구리배선 개발)

  • Seo, Shang-Hoon;Lee, Ro-Woon;Yun, Kwan-Soo;Joung, Jae-Woo;Lee, Hee-Jo;Yook, Jong-Gwan
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1806-1809
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    • 2008
  • Study that form micro pattern by direct ink jet printing method is getting attention recently. Direct ink jet printing spout fine droplet including nano metal particle by force or air pressure. There is reason which ink jet printing method is profitable especially in a various micro-patterning technology. It can embody patterns directly without complex process such as mask manufacture or screen-printing for existent lithography. In this study, research of a technology that ejects fine droplet form of Pico liter and forms metal micro pattern was carried with inkjet head of piezoelectricity drive system. Droplet established pattern while ejecting consecutively and move on the surface at the fixed speed. Patterns formed in ink are mixed with organic solvent and polymer that act as binder. So added thermal hardening process after evaporate organic solvent at isothermal after printing. I executed high frequency special quality estimation of CPW transmission line to confirm electrical property of manufactured circuit board. We tried a large area printing to confirm application possibility of an ink jet technology.

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A Study of Identifyign and Organizing Modules for Skirt Pattern Making Program (스커트 원형 자동제도 프로그램을 위한 기본단위의 체계화에 관한 연구)

  • 임남영
    • The Research Journal of the Costume Culture
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    • v.2 no.1
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    • pp.93-104
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    • 1994
  • Nowadays computer technology is being applied in various areas of apparel design. In particular, since the task of pattern making is to be performed by a set of predefined drawing rules, the effect of computer application in pattern making will be significant, There have been a large number of studies on pattern making program. For instance, the previous studies have developed computer programs for pattern making of women's wear, men's wear, children's wear, Han-Bok, etc. Most of them have focused on the development of computer program for a particular kind of apparel only and, however, have disregarded the feasibility of developing a multi-purposed computer program so that is just can be modified to adopt for various styles. For example, by widening the hem-wide of the basic H-Line skirt and then connecting its waist line and widened hem-wide, we can draw the A-Line skirt. Therefore, we have developed a program which can make a pattern for the basic skirt and can mae, with a slight change of he program, other patterns for various style as well. The objective of this paper is to identify and organize modules which will be used for developing a general pattern making computer system. This general pattern making system is a computer program by which we can draw a variety of apparel styles. This system is restricted to skirt pattern making only. there presentation scheme used in organizing these modules is an AND-OR tree, the one being often used in representing a complex problem in artificial intelligence domain.

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Robust Lane Detection Method Under Severe Environment (악 조건 환경에서의 강건한 차선 인식 방법)

  • Lim, Dong-Hyeog;Tran, Trung-Thien;Cho, Sang-Bock
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.5
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    • pp.224-230
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    • 2013
  • Lane boundary detection plays a key role in the driver assistance system. This study proposes a robust method for detecting lane boundary in severe environment. First, a horizontal line detects form the original image using improved Vertical Mean Distribution Method (iVMD) and the sub-region image which is under the horizontal line, is determined. Second, we extract the lane marking from the sub-region image using Canny edge detector. Finally, K-means clustering algorithm classifi left and right lane cluster under variant illumination, cracked road, complex lane marking and passing traffic. Experimental results show that the proposed method satisfie the real-time and efficient requirement of the intelligent transportation system.

Spectroscopic Properties and Ligand Field Analysis of trans -Dibromo(2,2-dimethyl-1,3-diaminopropane)chromium(III) Moiety

  • Choi, Jong-Ha;Oh, In-Gyung;Lim, Woo-Taik;Ryoo, Keon-Sang;Kim, Dong-Il;Park, Yu-Chul
    • Bulletin of the Korean Chemical Society
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    • v.26 no.6
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    • pp.903-908
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    • 2005
  • The sharp-line absorption and emission spectra of $(H_{13}O_6)${$trans-[Cr(Me_2tn)_2Br_2]$}$_2Br_2(ClO_4)\;(Me_2$tn = 2,2-dimethyl-1,3-diaminopropane) have been measured between 13000 $cm^{-1}$ and 16000 $cm^{-1}$ at 5 K. The 298 K infrared and visible absorption spectra have also been measured. The nine electronic bands due to spin-allowed and spin-forbidden transitions were assigned. Using observed transitions, a ligand field analysis has been performed to probe the ligand field properties of coordinated atoms in the title chromium(III) complex ion. The zero-phonon line in the sharp-line absorption spectrum splits into two components by 286 $cm^{-1}$, and the large $^2E_g$ splitting can be reproduced by the modern ligand field theory. It is confirmed that nitrogen atoms of the Me2tn ligand have a strong $\sigma$-donor character, but the bromide has weak $\sigma$- and $\pi$-donor properties toward chromium(III) ion.