• Title/Summary/Keyword: limiting processes

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Channel Electrode Voltammetric and In Situ Electrochemical ESR Studies of Comproportionation of Methyl Viologen in Acetonitrile

  • Lee, Ji U;John C. Eklund;Robert A. W. Dryfe;Richard G. Compton
    • Bulletin of the Korean Chemical Society
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    • v.17 no.2
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    • pp.162-167
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    • 1996
  • Two redox processes of methyl viologen (+2/+, +/0) in acetonitrile were investigated by using channel electrode voltammetric and in situ electrochemical ESR methods. Two separated unequal plateau currents of the first (+2/+) and second (+/0) redox processes of the viologen were observed in the channel electrode voltammograms and showed a cube-root depedndence on the electrolyte flow rate, respectively. The simple Levich analysis resulted in two different diffusion coefficients of $D_{+2}=2.2{\times}10^{-5}\;cm^2/s$ and $D_+=3.0{\times}10^{-5}cm^2/s$ from the limiting currents. In situ electrochemical ESR studies were performed for the monocation radicals generated at the potentials of the two plateau currents in the electrolyte flow range $1.3{\times}10^{-1}{\geq}v_f{\geq}2.7{\times}10^{-3}\;cm^3/s$. Backward implicitfinite difference method was employed to simulate the electrochemical kinetic problem of two sequential electron transfers ($MV^{+2}+e{\leftrightarrows}MV^+,\;MV^{+}+e{\leftrightarrows}MV^0$) coupled with reversible comproportionation ($MV^{2+}+MV^0{{\leftrightarrows}^{k_f}_{k_b}}2MV^+$). $k_f$ was found to be greater than ($10^6M^{-1}s^{-1}.

A Study on the Establishment of CDE Workflow and Information Container System for the Development of a Korean Common Data Environment (CDE) Based on ISO 19650 (ISO 19650 기반의 한국형 공통데이터환경(CDE) 개발을 위한 CDE 워크플로우와 정보컨테이너 체계 수립 연구)

  • Lee, Il-Gon;Kim, Hyun-Min;An, Joon-Sang;Choi, Jae-Woong
    • Journal of KIBIM
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    • v.13 no.4
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    • pp.74-84
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    • 2023
  • Modern construction projects have stakeholders from various construction fields, highlighting the importance of efficient information sharing and collaboration. The expanding scope of Building Information Modeling (BIM), particularly in the domestic construction sector, necessitates a Common Data Environment (CDE). However, applying foreign commercial CDE solutions within the domestic context is challenging due to the difficulty of aligning them with the unique organizational structures and characteristics prevalent in the country. Furthermore, the information review and approval processes specified by ISO 19650 often fail to harmonize adequately with the domestic design procedures, limiting the full utilization of CDE advantages. This study endeavors to develop a Korean CDE collaborative platform based on ISO 19650, with a focus on adapting workflows and information container systems to the domestic context. Building upon the requirements of ISO 19650-based CDE workflows and information containers, this research involves an in-depth analysis of information generation, sharing, review, and approval processes within domestic design organizations, offering tailored CDE workflows and information container systems that align with the specific needs of the Korean construction industry.

Service Identification of Configuration and Data Management System for Weapon System R&D Processes Based on Service Oriented Architecture (서비스 지향 아키텍처에 기반한 무기체계 연구개발 형상/정보관리시스템의 서비스 식별)

  • Kim, Hyung-Jun;Lee, Bu-Kweon;Seo, Yeong-Geon
    • Journal of Digital Contents Society
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    • v.10 no.1
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    • pp.147-157
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    • 2009
  • Configuration and data management system to support processes for the weapon system should support the concurrent engineering and collaborative activities for various documents, drawings, part informations and structural informations, etc. which are produced through R&D processes for a long time. This thesis attempts to identify major functions in the configuration and data management system to support processes for the weapon system R&D into services based on a service oriented architecture. In order to identify major services in the configuration and data management system to support processes for the weapon system R&D, a configuration and data management system to support processes for the weapon system R&D was proposed with a service oriented architecture with four layers including a service consumer layer, a business service layer, an application service layer and a application layer, and major services were identified for each layer. In order to identify major services in four layers, this thesis adopted a bottom-up approach to identify the necessary business services from a well-defined domain implementation system rather than a top-down identification method in general. This thesis tried to identify the essential services in implementing the configuration and data management system to support processes for the weapon system R&D as a system based on the service oriented architecture using such a bottom-up service identification method while limiting those services to the general PDM system aspects and the business areas of the configuration and data management system to support processes for the weapon system R&D.

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Developing a New BNR (Parallel BNR) Process by Computer Simulation (컴퓨터 시뮬레이션을 이용한 신 생물학적 고도처리 (병렬 고도처리) 공법 개발)

  • Lee, Byonghi;Lee, Yong-Woon
    • Journal of Korean Society of Water and Wastewater
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    • v.16 no.6
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    • pp.670-678
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    • 2002
  • Since Korean government imposed a stricter regulation on effluent T-N and T-P concentrations from wastewater treatment plant, a new process has to be developed to meet these rules and this process should remove T-N and T-P, economically, from weak wastewater that is typical for Korea's combined sewer system sewage. In this study, a computer simulator, BioWin from EnviroSim, Inc. was used. Three processes - A2/O, Modified Johannesburg, UCT- had been simulated under same operational conditions and a new process - Parallel BNR Process - had been developed based on these simulation results. The Parallel BNR process consists of two rows of reactors: One row has anaerobic and aerobic reactors in series, and the other row has RAS anoxic1 and RAS anoxic2 reactors in series. In order to ensure anaerobic state in anaerobic tank, a part of influent is fed to RAS anoxic1 tank in second row. This process had been simulated under same conditions of other three processes and the simulation results were compared. The results showed that three existing processes could not perform biological phosphorus removal when the average influent was fed at any operation temperatures. However, the Parallel BNR process was found that biological phosphorus removal could be performed when both design and average influent were fed at any operation temperatures. This process showed the T-N concentration in effluent had a maximum value of 15mg/L when design influent was fed at $13^{\circ}C$ and a minimum value of 14mg/L when average influent was fed at $20^{\circ}C$. Also, T-P concentrations had a maximum value of 1.3mg/L when average influent was fed at $20^{\circ}C$ and a minimum value of 1.1mg/L when design influent was fed at $13^{\circ}C$. Based on these results, we found that this process can remove nitrogen and phosphorus biologically under any operational conditions.

Cusum of squares test for discretely observed sample from diusion processesy

  • Lee, Sang-Yeol;Lee, Tae-Wook;Na, Ok-Young
    • Journal of the Korean Data and Information Science Society
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    • v.21 no.1
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    • pp.179-183
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    • 2010
  • In this paper, we consider the change point problem in diusion processes based on discretely observed sample. Particularly, we consider the change point test for the dispersion parameter when the drift has unknown parameters. In performing a test, we employ the cusum of squares test based on the residuals. It is shown that the test has a limiting distribution of the sup of a Brownian bridge. A simulation result as to the Ornstein-Uhlenbeck process is provided for illustration. It demonstrates the validity of our test.

Electrochemically Fabricated Alloys and Semiconductors Containing Indium

  • Chung, Yonghwa;Lee, Chi-Woo
    • Journal of Electrochemical Science and Technology
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    • v.3 no.3
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    • pp.95-115
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    • 2012
  • Although indium (In) is not an abundant element, the use of indium is expected to grow, especially as applied to copper-indium-(gallium)-selenide (CI(G)S) solar cells. In future when CIGS solar cells will be used extensively, the available amount of indium could be a limiting factor, unless a synthetic technique of efficiently utilizing the element is developed. Current vacuum techniques inherently produce a significant loss of In during the synthetic process, while electrodeposition exploits nearly 100% of the In, with little loss of the material. Thus, an electrochemical process will be the method of choice to produce alloys of In once the proper conditions are designed. In this review, we examine the electrochemical processes of electrodeposition in the synthesis of indium alloys. We focus on the conditions under which alloys are electrodeposited and on the factors that can affect the composition or properties of alloys. The knowledge is to facilitate the development of electrochemical means of efficiently using this relatively rare element to synthesize valuable materials, for applications such as solar cells and light-emitting devices.

The Fine Structure of Collar Cell in Tentacles of Chinese Mystery Snail, Cipangopaludina chinensis malleata Reeve (논우렁이 촉수(觸手) 칼라세포(Collar Cell)의 미세구조(微細構造)에 관한 연구(硏究))

  • Song, Yong-Jik;Kim, Woo-Kap;Kim, Chang-Whan
    • Applied Microscopy
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    • v.17 no.2
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    • pp.23-30
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    • 1987
  • There are groups of large monopolar cells containing numerous secretory inclusions in the muscular and connective tissue. These cells contain the electron-lucent vesicles in the size of $0.5{\sim}0.9{\mu}m$, which are secreted to the exterior of the tentacle through their cytoplasmic processes projected to the epithelial layer. Secretory material can be seen accumulating in swollen portions of the granular endoplasmic reticulum. It is postulated that this material is transported to the Golgi-complex and thus the limiting membrane of the inclusions is derived from the Golgi-membrane. An electron lucent material secreted from these cells seems to be similar to fibrous electron lucent material filled in the brush border of the epidermis.

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Weak Convergence of Processes Occurring in Statistical Mechanics

  • Jeon, Jong-Woo
    • Journal of the Korean Statistical Society
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    • v.12 no.1
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    • pp.10-17
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    • 1983
  • Let $X^{(n)}_j, j=1,2,\cdots,n, n=1,2,\cdots$ be a triangular array of random variables which arise naturally in a study of ferromagnetism in statistical mechanics. This paper presents weak convergence of random function $W_n(t)$, an appropriately normalized partial sum process based on $S^{(n)}_n = X^{(n)}_i+\cdot+X^{(n)}_n$. The limiting process W(t) is shown to be Gaussian when weak dependence exists. At the critical point where the change form weak to strong dependence takes place, W(t) turns out to be non-Gaussian. Our results are direct extensions of work by Ellis and Newmam (1978). An example is considered and the relation of these results to critical phenomena is briefly explained.

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A law of large numbers for maxima in $M/M/infty$ queues and INAR(1) processes

  • Park, Yoo-Sung;Kim, Kee-Young;Jhun, Myoung-Shic
    • Journal of the Korean Statistical Society
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    • v.23 no.2
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    • pp.483-498
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    • 1994
  • Suppose that a stationary process ${X_t}$ has a marginal distribution whose support consists of sufficiently large integers. We are concerned with some analogous law of large numbers for such distribution function F. In particular, we determine a weak law of large numbers for maximum queueing length in $M/M\infty$ system. We also present a limiting behavior for the maxima based on AR(1) process with binomial thining and poisson marginals (INAR(1)) introduced by E. Mckenzie. It turns out that the result of AR(1) process is the same as that of $M/M/\infty$ queueing process in limit when we observe the queues at regularly spaced intervals of time.

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A Study on the Manufacture of the Cu Powder from Electrochemical Recovery of Waste Rinse Water at the Cu Electroplating Process (동 도금 수세 폐수로부터 구리 분말 제조에 관한 연구)

  • 김영석;한성호
    • Journal of the Korean institute of surface engineering
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    • v.36 no.2
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    • pp.194-199
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    • 2003
  • Polarization measurements were peformed to investigate the electrochemical behavior of copper ions and limiting current density in waste rinse water from copper electroplating processes. A newly designed cyclone type electrolyzer was tested to recover the copper powder. Synthetic solutions were prepared using analytical grade $CuSO_4$ to the desired waste water concentration and pH was adjusted with $H_2$$SO_4$. Electrowinning was peformed at room temperature and the solution was cycled with a pump. Results showed that more than 99 percent of Cu was recovered and the size of the recovered Cu powder ranges from 0.1 - $0.5\mu\textrm{m}$. The chemical composition of the Cu powder mainly consists of $Cu_2$O and Cu and can be easily reduced to pure Cu powder.