• Title/Summary/Keyword: light scattering coefficient

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Measurement on the Methotrexate in L-${\alpha}$-Phosphatidylcholine Media by Light Sacttering (L-${\alpha}$-Phosphatidylcholine 매질에서 빔산란에 의한 Methotrexate의 측정)

  • Kim, Ki-Jun;Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.2
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    • pp.251-257
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    • 2013
  • The influences of Methotrexate as fluorophor, scatterer, absorber in turbid material by light scattering were interpreted for the scattered fluorescence intensity and wavelength, it has been studied the molecular properties by laser induced fluorescence spectroscopy. It has been found that the effects of optical properties in scattering media by the optical parameters((${\mu}_s$, ${\mu}_a$, ${\mu}_t$). The value of scattering coefficient ${\mu}_s$ is large by means of the increasing particles of L-${\alpha}$-Phosphatidylcholine, it has been found that the slope decays exponentially as a function of depth from laser source to detector. It may also aid in designing the best model for oil chemistry, laser medicine and application of medical engineering.

Modeling of Smog Characteristics in Seoul during the Fall,1993 (서울시의 1993년 가을 스모그 특성모사)

  • 백남준;이성준;김용표;문길주;조영일
    • Journal of Korean Society for Atmospheric Environment
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    • v.10 no.2
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    • pp.137-145
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    • 1994
  • A visibility analysis model based on the Mie theory is applied to the measurements during the fall, 1993 in Seoul. Model estimations of the total extinction coefficient $b_{ext}$, and the particle scattering coefficient, $b_{sp}$ are in good agreement with the measured values by a transmissometer and a nephelometer, respectively. These values show strong dependency on the mass loading of fine particles( $D_{p}$ <3.0${\mu}{\textrm}{m}$) but show no apparent relation with that of coarse particles(3.0${\mu}{\textrm}{m}$$D^{p}$ <10${\mu}{\textrm}{m}$). Relative humidity plays an important role in determining the size of particles which in turn, affects the optical efficiency of aerosol. Based on the composition analysis with cut size nitrate concentration is higher than the sulfate concentration in PM3-10 but they are comparable to each other in PM3. Considering in 1985, it demonstrates a drastic increase of nitrate concentration between 1985 and 1993. It is found that measured and estimated light extinction budget were in good agreement within 10% and that scattering by particles is responsible for about 50-55% and 70-80 % of total extinction during clear and smoggy periods respectively.y.

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[Ru(phen)2(dppz)]2+ Assemble on the Surface of the SDS Micelle and Its Application for the Determination of DNA

  • Chen, Fang;Huang, Jianping;He, Zhike
    • Bulletin of the Korean Chemical Society
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    • v.27 no.10
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    • pp.1655-1658
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    • 2006
  • The solution of $[Ru(phen)_2(dppz)]^{2+}$ and SDS has high Resonance Light Scattering (RLS) signals due to $[Ru(phen)_2(dppz)]^{2+}$ assemble on the surface of the SDS micelle. Because of the high affinity ($KB\geq10^6\;L\;mol^{-1}$) between $[Ru(phen)_2(dppz)]^{2+}$ and DNA, the adding of DNA in the solution of $[Ru(phen)_2(dppz)]^{2+}$-SDS makes the dissociation of $[Ru(phen)_2(dppz)]^{2+}$-SDS, and results in decreasing of the RLS signals and increasing of the absorbance. Based on this, a novel method is proposed for DNA assay. Under optimum condition, good linear relationship was obtained within the concentration range of 0.018-1.26 $\mu g\;mL^{-1}$, the linear equation is $I_{RLS}$ = 504.8-348.8 c (c: $\mu g\;mL^{-1}$) and the correlation coefficient (r) is 0.9992. The detect limit for calf thymus DNA is 8.6 ng $mL^{-1}$. The proposed method was successful applied to determine the extracted colibacillus plasmid DNA.

Physico-Chemical Characteristics of Visibility Impairment by Airborne Pollen (공중화분에 의한 시정장애 현상의 물리적 및 화학적 특성 규명)

  • Kim, Kyung-Won
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.6
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    • pp.863-875
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    • 2006
  • Intensive visibility monitoring was conducted to investigate physical and chemical characteristics of visibility impairment by airborne pollen. Light attenuation coefficients were optically measured by a transmissometer, a nephelometer, and an aethalometer. Elemental, ionic, and carbonaceous species were chemically analyzed on the filters collected by $PM_{2.5}$ and $PM_{10}$ samplers. Aerosol size distribution was analyzed using a cascade impactor during airborne pollen period. Airborne pollen count was calculated using a scanning electron microscope. Airborne pollen was emitted into the atmosphere in springtime and funker degraded visibility through its scattering and absorbing the light. Average light extinction coefficient was measured to be $211{\pm}36Mm^{-1}$ when airborne pollen was not observed. But it increased to $459{\pm}267Mm^{-1}$ during the airborne pollen period due to increase of average $PM_{2.5}$ and $PM_{10}$ mass concentration and relative humidity and airborne pollen count concentration for $PM_{10}$, which were measured to be $46.5{\pm}29.1{\mu}g\;m^{-3},\;97.0{\pm}41.7{\mu}g\;m^{-3},\;54.1{\pm}11.6%$, and $68.2{\pm}89.7m^{-3}$, respectively. Average light extinction efficiencies for $PM_{2.5}$ and $PM_{10}$ were calculated to be $5.9{\pm}0.9$ and $4.5{\pm}0.8m^2 g^{-1}$ during the airborne pollen period. Light extinction efficiency for $PM_{10}$ increased further than that for $PM_{2.5}$. The average light extinction budget by airborne pollen was estimated to be about 24% out of the average measured light extinction coefficient during the airborne pollen period.

A Study on the Measurements of Beam Wave Propagation and Fluorescence Spectroscopy in Particles Media (입자매질에서 빔파동전파와 형광분광 측정에 관한 연구)

  • Kim, Ki-Jun;Lee, Jou-Youb;Sung, Wan-Mo
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.2
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    • pp.167-175
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    • 2014
  • The influences of fluorescence, scattering, and flocculation in turbid material were interpreted for the scattered fluorescence intensity and wavelength, it has been studied the molecular properties by the spectroscopy of laser induced fluorescence(LIF). The effects of optical properties in scattering media have been found by the optical parameters(${\mu}_s$, ${\mu}_a$, ${\mu}_t$). Flocculation is an important step in many solid-liquid separation processes and is widely used in Photodynamic therapy. The interactions of several colloid particles can come into play which have major effect on the flocculation and LIF process. We measured scattering and fluorescence spectra of the sample for in vitro as function of concentration from lase source to detector. The value of scattering coefficient ${\mu}_s$ is large by means of the increasing particles of scatterer. Therefore, Phorphyrin A is larger than Phorphyrin C in scattering intensity ${\mu}_s$, but Phorphyrin A is smaller than Phorphyrin C in penetration depth ${\delta}$.

A Study on Wave Propagation and Scattering in Purple Membrane and β-carotene (Purple Membrane과 β-carotene에서 산란과 파동전파에 관한 연구)

  • Kim, Ki-Jun;Park, Tae-Sul;Sung, Wan-Mo
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.1
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    • pp.136-142
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    • 2016
  • The influences of fluorescence, scattering, and flocculation in random media were interpreted for the scattered fluorescence intensity and wavelength, it has been studied the molecular properties by the spectroscopy of laser induced fluorescence(LIF). The effects of optical properties in scattering media have been found by the optical parameters(${\mu}_s$, ${\mu}_a$, ${\mu}_t$). Flocculation is an important step in many solid-liquid separation processes and is widely used in Photodynamic therapy. The interactions of several colloid particles can come into play which have major effect on the flocculation and LIF process. We measured scattering and fluorescence spectra of the sample in vitro as function of distance from lase source to detector. The value of scattering coefficient ${\mu}_s$ is and ${\beta}$-carotene were measured as larger values(I, ${\delta}$) by means of closer distance from source to detector.

Effect of Particle Shape and Size of Calcium Carbonate on Physical Properties of Paper (탄성칼슘에 성상이 종이물성에 미치는 영향)

  • 한영림;서영범
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.1
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    • pp.7-12
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    • 1997
  • This study was intended to investigate the proper shape and size of calcium carbonate for the improvement of paper properties and its end use performance. We loaded calcium carbonate of various shapes and size in the handsheet and measured their physical and optical properties. Results obtained from the study are summarized as follows : 1. Due to different particle shapes and sizes, precipitated calcium carbonate (PCC) contributed greater to bulk improvement than ground calcium carbonate (GCC). Scalenohedral form of PCC produced the bulkiest sheet, GCC made the sheet bulkier as average particle size increases. 2. Tensile strength increased as average particle size was increasing. GCC kept tensile strength more effectively than PCC. The effect of particle size on tensile strength was much more pronounced as filler addition level was increasing. 3. Over the average particle size of 6.99$\mu$m, GCC gave much higher burst strength and internal bond than PCC did. In the filler levels of 20% and 30%, GCC by using bigger size fillers showed 50~100% improvement in some cases than PCC at the same filler content. 4. Tear strength increased as average particle size was increasing. At the filler level of 30%, PCC decreased tear greatly. 5. Over the average particle size of 13.56$\mu$m, GCC kept bending stiffness greater than PCC. Due to its shape, Scalenohedral form of PCC showed higher stiffness than others at the same particle size. 6. Cubic and acicular form of PCC improved light scattering coefficient very effectively. Light scattering coefficient of GCC decreased as average particle size increased. 7. Both of particle shape and size of filler were important factor in developing optical properties and bending stiffness. Particle size was the only important factor in developing other strength properties

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An Asian Dust Compensation Scheme of Light-Scattering Fine Particulate Matter Monitors by Multiple Linear Regression (다중 선형 회귀에 의한 광산란 초미세먼지 측정기의 황사 보정 기법)

  • Baek, Sung Hoon
    • Journal of Convergence for Information Technology
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    • v.11 no.8
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    • pp.92-99
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    • 2021
  • Light-scattering fine particulate matter monitors can measure particulate matter (PM) concentrations in every second and can be designed in a portable size. They can measure the concentrations of various PM sizes (PM1.0, PM2.5, PM4.0 and PM10) with a single sensor. They measure the number and size of particulate matters and convert them to weight per volume (concentration). These devices show a large error for asian dust. This paper proposes a scheme that compensates the PM2.5 concenstration error for asian dust by multiple linear regression machine learning in light-scattering PM monitors. This scheme can be effective with only two or three types of PM sizes. The experimental results compare a beta-ray PM monitor of national institute of environmental research and a light-scattering PM monitor during a month. The correlation coefficient (R2) of theses two devices was 0.927 without asian dust, but it was 0.763 due to asian dust during the entire experimental period and improved to 0.944 by the proposed machine learning.

An Analysis of the Characteristics of Aerosol Light Scattering Coefficients at Seoul and Baengnyeongdo (서울과 백령도의 에어로솔 산란계수 특성 분석)

  • Eun, Seung-Hee;Nam, Hyoung-Gu;Kim, Byung-Gon;Park, Jin-Soo;Ahn, Jun-Young;Lee, Seok-Jo
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.3
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    • pp.264-274
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    • 2013
  • This study investigates long-term trends and characteristics of aerosol light scattering coefficient at Seoul and Baengnyeongdo in order to understand aerosol optical and radiative properties around Korea. The analysis period is limited to one year of 2011. First, the aerosol scattering coefficients (${\sigma}_{sp}$) of both sites show strong linear dependence on the $PM_{2.5}$ mass concentrations with significant correlations between both. Further, correlations and sensitivity between ${\sigma}_{sp}$ and $PM_{2.5}$ increase with relative humidity, implying both relationships are strongly dependent upon moisture amounts in the atmosphere. This study applied 3-step careful quality control procedures to the analysis of ${\sigma}_{sp}$ for the insurance of data confidence. For the relationship analysis of extinction coefficients (${\sigma}_{ext}$) to visibility and aerosol optical depth, ${\sigma}_{sp}$ observed at 3 p.m. have been used with help of aerosol absorption coefficients (${\sigma}_{ap}$) in order to remove its dependence upon relative humidity, and also those of rainy period have been excluded. As expected, ${\sigma}_{ext}$ estimated are inversely proportional to visibility observation by eye. Finally, aerosol extinction coefficients have been vertically integrated with an assumption of nearly well-mixed within an e-folding height to determine aerosol optical depth, and compared with those retrieved from sunphotometer. The results show a reasonable agreement in spite of an inherent difference of each definition. We expect these findings would help to eventually understand aerosol radiative forcing and its effect on the regional climate change around Korea.

Angular Dispersion-type Nonscanning Fabry-Perot Interferometer Applied to Ethanol-water Mixture

  • Ko, Jae-Hyeon;Kojima, Seiji
    • Journal of the Optical Society of Korea
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    • v.13 no.2
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    • pp.261-266
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    • 2009
  • The angular dispersion-type non-scanning Fabry-Perot was applied to an ethanol-water mixture in order to investigate its acoustic properties such as the sound velocity and the absorption coefficient. The scattered light from the mixture was analyzed by using the charge-coupled-device area detector, which made the measurement time much shorter than that obtained by using the conventional scanning tandem multi-pass Fabry-Perot interferometer. The sound velocity showed a deviation from ultrasonic sound velocities at low temperatures accompanied by the increase in the absorption coefficient, indicating acoustic dispersion due to the coupling between the acoustic waves and some relaxation process. Based on a simplified viscoelastic theory, the temperature dependence of the relaxation time was obtained. The addition of water molecules to ethanol reduced the relaxation time, consistent with dielectric measurements. The present study showed that the angular dispersion-type Fabry-Perot interferometer combined with an area detector could be a very powerful tool in the real-time monitoring of the acoustic properties of condensed matter.