• Title/Summary/Keyword: layer approach

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Sorption of $UO^{2+}_2$ onto Goethite and Kaolinite: Mechanistic Modeling Approach

  • Jinho Jung;Lee, Jae-Kwang;Cho, Young-Hwan;Keum, Dong-Kwon;Hahn, Pil-Soo
    • Nuclear Engineering and Technology
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    • v.31 no.2
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    • pp.182-191
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    • 1999
  • The sorption of UO$_{2}$$^{2+}$ onto goethite and kaolinite under various experimental conditions was successfully interpreted using surface complexation modeling (SCM). The SCM approach used in this work is the triple-layer model (TLM) in which weakly bonded ions are modeled as outer-sphere (ion-pair) complexes and strongly bonded ions as inner-sphere (surface coordination) complexes. The change of ionic strength did not affect the U(VI) sorption onto goethite, thus the formation of inner-sphere surface complexes, (FeO)$_2$UO$_2$ and (FeO)$_2$(UO$_2$)$_3$OH$_{5}$ was assumed to simulate the effects of ionic strength and goethite concentration. On the other hand, the U(VI) sorption onto kaolinite showed ionic strength dependence, thus the formation of AlO-UO$_{2}$$^{2+}$(outer-sphere complex) and SiO(UO$_2$)$_3$OH$_{5}$ (inner-sphere complex) was assumed to simulate the experimental data. In the presence of carbonates, the sorption of U(VI) onto kaolinite decreased in the weakly alkaline pH range. This was well simulated assuming the formation of a outer-sphere surface complex, A1OH$^{2+}$- (UO$_2$)$_2$CO$_3$OH$_3$. Since SCM approach uses thermodynamic data such as surface complexation constants, it is more predictive than empirical modeling approach in which conditional values such as partition coefficient are used. used.

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Modeling and Interoperability Test Case Generation of a Real-Time QoS Monitoring Protocol

  • Chin, Byoung-Moon;Kim, Sung-Un;Kang, Sung-Won;Park, Chee-Hang
    • ETRI Journal
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    • v.21 no.4
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    • pp.52-64
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    • 1999
  • QoS monitoring is a kind of real-time systems which allows each level of the system to track the ongoing QoS levels achieved by the lower network layers. For these systems, real-time communications between corresponding transport protocol objects is essential for their correct behavior. When two or more entities are employed to perform a certain task as in the case of communication protocols, the capability to do so is called interoperability and considered as the essential aspect of correctness of communication systems. This paper describes a formal approach on modeling and interoperability test case generation of a real-time QoS monitoring protocol. For this, we specify the behavior of flow monitoring of transport layer QoS protocol, i.e., METS protocol, which is proposed to address QoS from an end-to-end's point of view, based on QoS architecture model which includes ATM net work in lower layers. We use a real-time Input/Output finite State Machine to model the behavior of real-time flow monitoring over time. From the modeled real-time I/OFSM, we generate interoperability test cases to check the correctness of METS protocol's flow monitoring behaviors for two end systems. A new approach to efficient interoperability testing is described and the method of interoperability test cases generation is shown with the example of METS protocol's flow monitoring. The current TTCN is not appropriate for testing real-time and multimedia systems. Because test events in TTCN are for message-based system and not for stream-based systems, the real-time in TTCN can only be approximated. This paper also proposes the notation of real-time Abstract Test Suite by means of real-time extension of TTCN. This approach gives the advantages that only a few syntactical changes are necessary, and TTCN and real-time TTCN are compatible. This formal approach on interoperability testing can be applied to the real-time protocols related to IMT-2000, B-ISDN and real-time systems.

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Mechanistic Analysis of Pavement Damage and Performance Prediction Based on Finite Element Modeling with Viscoelasticity and Fracture of Mixtures

  • Rahmani, Mohammad;Kim, Yong-Rak;Park, Yong Boo;Jung, Jong Suk
    • Land and Housing Review
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    • v.11 no.2
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    • pp.95-104
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    • 2020
  • This study aims to explore a purely mechanistic pavement analysis approach where viscoelasticity and fracture of asphalt mixtures are considered to accurately predict deformation and damage behavior of flexible pavements. To do so, the viscoelastic and fracture properties of designated pavement materials are obtained through experiments and a fully mechanistic damage analysis is carried out using a finite element method (FEM). While modeling crack development can be done in various ways, this study uses the cohesive zone approach, which is a well-known fracture mechanics approach to efficiently model crack initiation and propagation. Different pavement configurations and traffic loads are considered based on three main functional classes of roads suggested by FHWA i.e., arterial, collector and local. For each road type, three different material combinations for asphalt concrete (AC) and base layers are considered to study damage behavior of pavement. A concept of the approach is presented and a case study where three different material combinations for AC and base layers are considered is exemplified to investigate progressive damage behavior of pavements when mixture properties and layer configurations were altered. Overall, it can be concluded that mechanistic pavement modeling attempted in this study could differentiate the performance of pavement sections due to varying design inputs. The promising results, although limited yet to be considered a fully practical method, infer that a few mixture tests can be integrated with the finite element modeling of the mixture tests and subsequent structural modeling of pavements to better design mixtures and pavements in a purely mechanistic manner.

Upper Bound Limit Analysis of Bearing Capacity for Surface Foundations on Sand Overlying Clay (점토층위의 모래지반에 위치한 얕은 기초의 지지력에 대한 상한 한계해석)

  • 김대현;야마모토켄타로
    • Journal of the Korean Geotechnical Society
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    • v.20 no.3
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    • pp.85-96
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    • 2004
  • The ultimate bearing capacity of surface foundations on a sand layer overlying clay has been theoretically investigated. First, a review of previous studies on the bearing capacity problems for this type of foundation was performed and a discussion was presented concerning the practical application. Second, the kinematic approach of limit analysis was used to calculate the upper bound of the true ultimate bearing capacity. The kinematic solutions are upper bounds and their accuracy depends primarily on the nature of the assumed failure mechanism. This approach makes it convenient to create design charts, and it is possible to trace the influence of parameters. Third, the commercial finite element program ABAQUS was applied to obtain the ultimate bearing capacity based on the elasto-plastic theory. Results obtained from the kinematic approach were compared with those from the program ABAQUS and the limit equilibrium equations proposed by Yamaguchi, Meyerhof and Okamura et al. Finally, the validities of the results from the kinematic approach, the results from the program ABAQUS and the limit equilibrium equations were examined.

A new analytical approach to estimate the seismic tensile force of geosynthetic reinforcement respect to the uniform surcharge of slopes

  • Motlagh, Ali Tafreshi;Ghanbari, Ali;Maedeh, Pouyan Abbasi;Wu, Wei
    • Earthquakes and Structures
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    • v.15 no.6
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    • pp.687-699
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    • 2018
  • This paper investigates the pseudo-static analysis of reinforced slopes with geosynthetics under the influence of the uniform surcharge to evaluate the maximum tensile force of reinforcements. The analytical approach has basically been used to develop the new practical procedure to estimate both tensile force and its distribution in the height of the slope. The base of developed relationships has been adapted from the conventional horizontal slice method. The limit equilibrium framework and the assumptions of log-spiral failure surface have directly been used for proposed analytical approach. A new analytical approach considering a single layer of non-cohesion soil and the influence of uniform surcharge has been extracted from the 5n equation and 5n unknown parameters. Results of the proposed method illustrated that the location of the surcharge, amount of internal friction and the seismic coefficient have the remarkable effect on the tensile force of reinforcement and might be 2 times increasing on it. Furthermore, outcomes show that the amount of tensile force has directly until 2 times related to the amount of slope angle and its height range. Likewise, it is observed that the highest value of the tensile force in case of slope degree more than 60-degree is observed on the lower layers. While in case of less degree the highest amount of tensile force has been reported on the middle layers and extremely depended to the seismic coefficient. Hence, it has been shown that the tensile force has increased more than 6 times compared with the static condition. The obtained results of the developed procedure were compared with the outcomes of the previous research. A good agreement has been illustrated between the amount results of developed relationships and outcomes of previous research. Maximum 20 and 25 percent difference have been reported in cases of static and seismic condition respectively.

Synthesis and Characterization of The Electrolessly Deposited Co(Re,P) Film for Cu Capping Layer (무전해 도금법으로 제조된 Co(Re,P) capping layer제조 및 특성 평가)

  • Han, Won-Kyu;Kim, So-Jin;Ju, Jeong-Woon;Cho, Jin-Ki;Kim, Jae-Hong;Yeom, Seung-Jin;Kwak, Noh-Jung;Kim, Jin-Woong;Kang, Sung-Goon
    • Korean Journal of Materials Research
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    • v.19 no.2
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    • pp.61-67
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    • 2009
  • Electrolessly deposited Co (Re,P) was investigated as a possible capping layer for Cu wires. 50 nm Co (Re,P) films were deposited on Cu/Ti-coated silicon wafers which acted as a catalytic seed and an adhesion layer, respectively. To obtain the optimized bath composition, electroless deposition was studied through an electrochemical approach via a linear sweep voltammetry analysis. The results of using this method showed that the best deposition conditions were a $CoSO_4$ concentration of 0.082 mol/l, a solution pH of 9, a $KReO_4$ concentration of 0.0003 mol/l and sodium hypophosphite concentration of 0.1 mol/L at $80^{\circ}C$. The thermal stability of the Co (Re,P) layer as a barrier preventing Cu was evaluated using Auger electron spectroscopy and a Scanning calorimeter. The measurement results showed that Re impurities stabilized the h.c.p. phase up to $550^{\circ}C$ and that the Co (Re,P) film efficiently blocked Cu diffusion under an annealing temperature of $400^{\circ}C$ for 1hr. The good barrier properties that were observed can be explained by the nano-sized grains along with the blocking effect of the impurities at the fast diffusion path of the grain boundaries. The transformation temperature from the amorphous to crystal structure is increased by doping the Re.

Temporal Variation of Water Quality of the Western Chinhae Bay in Summer (진해만 서부해역의 하계 수질의 시간변동 특성)

  • Cho Hyeon-Seo;Lee Dae-In;Yoon Yang-Ho;Lee Moon-Ok;Kim Dong-Myung
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.7 no.1
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    • pp.13-21
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    • 2004
  • Temporal changes of Chl-α, physical and chemical factors were investigated by diurnal observation at 2-hour interval at three fixed stations in the western Chinhae Bay from 12 Aug. to 13 Aug. 1999. Difference of dissolved oxygen between surface and bottom layer was maximum when the thermocline were strong. Organic distribution such as COD was affected by the growth of phytoplankton. Limitting factor was nitrogen, that is, inorganic nitrogen plays a significant role on regulating the algal growth. Surface distribution of dissolved inorganic nitrogen was very low compared to bottom layer by uptake of organisms. Maximum value of Chl-α at station C2 and C11 were observed from subsurface layer, ranges of which exceeded possibility concentration of red tide outbreak, 10 mg/㎥. On the other hand, that of C15 exist at surface layer. In this area, DIN and DIP concentrations increased by input sources such as rainfall and benthic flux before the bloom of phytoplankton. Accumulation of phytoplankton occurred at subsurface layer by the rapid uptake of DIN, especially nitrate ion, when strong thermocline existed as approach to the afternoon, which led to the increase of organics in water column and oxygen deficiency water mass at bottom layer until late at evening. Since then, DIN increases gradually as water temperature decrease to minimum. The quantitative understanding of nitrogen of fluxed to and from the various sources is necessary for environmental management.

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Characteristics of MOCVD Cobalt on ALD Tantalum Nitride Layer Using $H_2/NH_3$ Gas as a Reactant

  • Park, Jae-Hyeong;Han, Dong-Seok;Mun, Dae-Yong;Yun, Don-Gyu;Park, Jong-Wan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.377-377
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    • 2012
  • Microprocessor technology now relies on copper for most of its electrical interconnections. Because of the high diffusivity of copper, Atomic layer deposition (ALD) $TaN_x$ is used as a diffusion barrier to prevent copper diffusion into the Si or $SiO_2$. Another problem with copper is that it has weak adhesion to most materials. Strong adhesion to copper is an essential characteristic for the new barrier layer because copper films prepared by electroplating peel off easily in the damascene process. Thus adhesion-enhancing layer of cobalt is placed between the $TaN_x$ and the copper. Because, cobalt has strong adhesion to the copper layer and possible seedless electro-plating of copper. Until now, metal film has generally been deposited by physical vapor deposition. However, one draw-back of this method is poor step coverage in applications of ultralarge-scale integration metallization technology. Metal organic chemical vapor deposition (MOCVD) is a good approach to address this problem. In addition, the MOCVD method has several advantages, such as conformal coverage, uniform deposition over large substrate areas and less substrate damage. For this reasons, cobalt films have been studied using MOCVD and various metal-organic precursors. In this study, we used $C_{12}H_{10}O_6(Co)_2$ (dicobalt hexacarbonyl tert-butylacetylene, CCTBA) as a cobalt precursor because of its high vapor pressure and volatility, a liquid state and its excellent thermal stability under normal conditions. Furthermore, the cobalt film was also deposited at various $H_2/NH_3$ gas ratio(1, 1:1,2,6,8) producing pure cobalt thin films with excellent conformality. Compared to MOCVD cobalt using $H_2$ gas as a reactant, the cobalt thin film deposited by MOCVD using $H_2$ with $NH_3$ showed a low roughness, a low resistivity, and a low carbon impurity. It was found that Co/$TaN_x$ film can achieve a low resistivity of $90{\mu}{\Omega}-cm$, a low root-mean-square roughness of 0.97 nm at a growth temperature of $150^{\circ}C$ and a low carbon impurity of 4~6% carbon concentration.

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Fast Mode Decision Algorithm for Scalable Video Coding (SVC) Using Directional Information of Neighboring Layer (스케일러블 비디오 코딩에서 방향성 정보를 이용한 모드 결정 고속화 기법)

  • Jung, Hyun-Ki;Hong, Kwang-Soo;Kim, Byung-Gyu;Kim, Chang-Ki;Yoo, Jeong-Ju
    • Journal of Broadcast Engineering
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    • v.17 no.1
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    • pp.108-121
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    • 2012
  • As Scalable Video Coding (SVC) is a video compression standard extended from H.264/AVC, it is a way to provide scalability in terms of temporal, spatial and quality. Although the compression efficiency of SVC is increased due to the scalability in many aspect, it is essential to reduce the complexity in order to efficiently use because the complexity is relatively increased. To reduce the complexity of SVC in the paper, we propose fast mode decision algorithm to reduce the complexity of encoding process using direction information of B-picture by efficiently performing inter-layer prediction. The proposed algorithm is a fast mode decision algorithm that makes different from detection mode number of forward and backward, bi-direction in the way using best mode of base-layer up-sampled after simply SKIP mode detection using the direction information of best mode of base-layer up-sampled. The experimental results show that the proposed algorithm approach can achieve the maximum computational time saving about 53% with almost no loss of rate distortion (RD) performance in the enhancement layer.

Side Channel Analysis with Low Complexity in the Diffusion Layer of Block Cipher Algorithm SEED (SEED 블록 암호 알고리즘 확산계층에서 낮은 복잡도를 갖는 부채널 분석)

  • Won, Yoo-Seung;Park, Aesun;Han, Dong-Guk
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.27 no.5
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    • pp.993-1000
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    • 2017
  • When the availability of embedded device is considered, combined countermeasure such as first-order masking and hiding countermeasures is quite attractive because the security and efficiency can be provided at the same time. Especially, combined countermeasure can be applied to the confusion and diffusion layers of the first and last rounds in order to provide the efficiency. Also, the middle rounds only employs first-order masking countermeasure or no countermeasure. In this paper, we suggest a novel side channel analysis with low complexity in the output of diffusion layer. In general, the attack target cannot be set to the output of diffusion layer owing to the high complexity. When the diffusion layer of block cipher is composed of AND operations, we show that the attack complexity can be reduced. Here, we consider that the main algorithm is SEED. Then, the attack complexity with $2^{32}$ can be reduced by $2^{16}$ according to the fact that the correlation between the combination of S-box outputs and that of the outputs of diffusion layer. Moreover, compared to the fact that the main target is the output of S-box in general, we demonstrate that the required number of traces can be reduced by 43~98% in terms of simulated traces. Additionally, we show that only 8,000 traces are enough to retrieve the correct key by suggested scheme, although it fails to reveal the correct key when performing the general approach on 100,000 traces in realistic device.