• 한국재료학회:학술대회논문집
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• 한국재료학회 2000년도 추계학술발표강연 및 논문개요집
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• pp.119-119
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• 2000

• Bulletin of the Korean Chemical Society
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• 제34권2호
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• pp.505-509
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• 2013

A low temperature ($65^{\circ}C$) thermal deposition process was developed for depositing a silver coating on thermally sensitive polymeric substrates. This low temperature deposition was achieved by chemical reduction of a silver alkylcarbamate complex with latent reducing agent. The effects of acetol as a latent reducing agent for the silver 2-ethylhexylcarbamate (Ag-EHCB) complex and their blend solutions were investigated in terms of reducing mechanism, and the size and shape of silver nanoparticles (Ag-NPs) as a function of reduced temperature and time, and PVP stabilizer concentration were determined. Low temperature deposition was achieved by combining chemical reduction with thermal heating at $65^{\circ}C$. A range of polymer film, sheet and molding product was coated with silver at thicknesses of 100 nm. The effect of process parameters and heat treatment on the properties of silver coatings was investigated.

• 콘크리트학회논문집
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• 제23권4호
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• pp.521-528
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• 2011

이 논문은 최근 가속진행 되고 있는 에너지 고갈 및 이산화탄소($CO_2$) 배출 방지대책에 대한 하나의 방안으로서 우수한 잠열 성능을 가진 PCM(phase change materials)을 모르타르에 혼입하고 실험을 통해 PCM의 적정 혼입량 및 모르타르 물성, 성능, 바닥 방식에서의 냉 난방식 적용에 대한 PCM의 효율적인 용융점 등 을 파악하였으며 자체 열적 성능 실험을 통해 열 전달 및 잠열 성능을 확인하였다. 또한 실험에서 도출해 낸 결과에 의해 Fourier의 열법칙을 이용하여 PCM 혼입량별 열전달량과 온도 구배 식을 제안하고 이를 분석하였다. 따라서 이 논문의 결과를 근거로 PCM의 건축물에서의 적용성을 파악하고 냉 난방 에너지 저감 효과를 기대할 수 있는 기초적 자료로서의 근거를 도출하는데 큰 의미를 두었다. 이 실험 결과 PCM 모르타르의 우수한 냉 온 축열 성능을 도출 할 수 있었으며 이를 통해 냉 난방기 On-Off 작동 조절에 의한 에너지 저감 및 그에 따른 $CO_2$ 저감에 대한 가능성을 확인 할 수 있었다.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2011년도 춘계학술발표대회 논문집
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• pp.162-167
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• 2011

Thermal storage plays an important role in building energy saving, which is greatly assisted by the incorporation of latent heat storage in building materials. A phase change material is a substance with a high heat of fusion which, melting and solidifying at a certain temperature, can be storing and releasing large amount of energy. Heat is stored or released when the material changes from solid to liquid. Integration of building materials incorporating PCMs into the building envelope can result in increased efficiency of the built environment. The aim of this research is to identify thermal performance of PCMs impregnated building materials which is applied to interior of building such as gypsum and red clay. In order to analyze thermal performance of phase change materials, test-cell experiments and simulation analysis were carried out. The results show that micro-encapsulated PCM has an effect to maintain a constant indoor temperature using latent heat through the test-cell experiments. PCM wallboard makes it possible to reduce the fluctuation of room temperature and heating and cooling load by using EnergyPlus simulation program. Phase change material can store solar energy directly in buildings. Increasing the heat capacity of a building is capable of improving human comfort by decreasing the frequency of indoor air temperature swings so that the interior air temperature is closer to the desired temperature for a long period of time.

• 한국자동차공학회논문집
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• 제15권1호
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• pp.23-28
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• 2007

This study aims to find out cooling characteristics of TMA(Tri-Methyl-Amine, $(CH_3)_3N$) 25wt%-water clathrate compound with ethanol($CH_3CH_2OH$) such as supercooling, phase change temperature and specific heat. For this purpose, ethanol is added as per weight concentration and cooling experiment is performed at $-6{\sim}-8^{\circ}C$, cooling heat source temperature, and it leads the following result. (1) Phase change temperature is decreased due to freezing point depression phenomenon. Especially, it is minimized as $3.8^{\circ}C$ according to cooling source temperature in case that 0.5wt% of ethanol is added. (2) If 0.5wt% of ethanol is added, average supercooling degree is $0.9^{\circ}C$ and minimum supercooling is 0.8, $0.7^{\circ}C$ according to cooling heat source temperature. The restraint effect of supercooling is shown. (3) Specific heat shows tendency to decrease if ethanol is added. It is $3.013{\sim}3.048\;kcal/kg^{\circ}C$ according to cooling heat source temperature if 0.5wt% of ethanol is added. Phase change temperature higher than that of water and inhibitory effect against supercooling can be confirmed through experimental study on cooling characteristics of TMA 25wt%-water clathrate compound by adding additive, ethanol. This can lead to shorten refrigerator operation time of low temperature latent heat storage system and improve COP of refrigerator and efficiency of overall system. Therefore energy can be saved and efficiency can be improved much more.

• 에너지공학
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• 제7권1호
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• pp.122-130
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• 1998

A simplified heat transfer model for the cooling capability of the AP 600 PCCS is proposed I this paper. As the PCCS domain is covered with very thin and long water film, it is phenomenologically divided into 3 regions; water entrance effect region, asymptotic region, and air entrance effect region. As the length of the asymptotic region is estimated to be over 90% of the whole domain, the phenomena in the asymptotic region is focused. Using the analogy between heat and mass transfer phenomena in a turbulent situation, a new dependent variable combining temperature and vapor mass fraction was defined. The similarity between the PCCs phenomena in the asymptotic region and the buoyant air flow phenomena on a vertical heated plate is derived. Using the similarity, the simplified heat transfer correlations for the interfacial heat fluxes and the ratios of latent heat transfer to sensible heat transfer were established. To verify the accuracy of the correlation, the results of this study were compared with those of other numerical analyses performed for the same configuration and they are well within the range of 15% difference.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2011년도 추계 학술논문 발표대회
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• pp.245-246
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• 2011

In recent research in this emerging and latent heat storage material features an innovative temperature - controlled Phase Change Materials to evaluate the superior thermal performance would like to calculate the thermal conductivity. Specified in KS F 4040 test specimen dimensions were equivalent in specifications, test methods according to KS L 9016 was an experiment in progress. As a result, the thermal conductivity of plain cement mortar mixed with more PCM came out with low thermal conductivity of mortar, thermal performance was excellent.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2008년도 하계학술발표대회 논문집
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• pp.414-418
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• 2008

The effects of paper properties such as density, air permeability, water vapor transmission rate on the thermal performance of plate-type enthalpy exchanger were experimentally investigated. Three enthalpy exchanger samples having different properties were made, and were tested according to the standard test procedure (KS B 6879). Effective efficiencies were defined, which accounted for the air leakage between supply and exhaust streams. Results showed that paper density affected the sensible heat transfer of the samples. Sensible heat transfer increased with density of the paper. It was also shown that water vapor transmission rate alone was not a proper indicator for the efficiency of latent heat transfer. Air permeability should also be considered for adequate evaluation of the latent heat transfer. Best performance was obtained for the sample having highest paper density and moderate water vapor transmission ratio.

• 한국습지학회지
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• 제11권1호
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• pp.105-113
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• 2009

연안습지 생태계에서 열에너지 교환 과정은 매우 중요하다. 지표 열에너지 평형을 이루는 요소인 순복사플럭스, 현열 플럭스, 잠열 플럭스 그리고 토양열 플럭스를 전라남도 고흥에 위치한 수평적으로 균질하다고 판단되는 지역인 고흥만 간척지에서 관측하고 분석하였다. 열의 수송을 평가하기 위해서 5회의 집중관측 기간에 대기 난류를 측정하였고, 특히 갈대로 덮여있는 간척지에서 지표층 열에너지 수지를 분석하기 위해서는 물과 매우 미세한 입자로 구성된 토양 그리고 계절에 따라 색깔과 밀도가 변하는 식생캐노피를 고려하였다. 순복사 플럭스, 현열 플럭스, 잠열 플럭스, 토양열 플럭스를 기존의 에너지 수지방정식에 적용하여 식생과 토양과 같은 지표면 특성에 따른 열 플럭스의 특징을 조사하여 습지의 기온조절 효과에 대해 알아보았다. 에너지 수지비로 식생 성장기에는 주로 잠열 플럭스에 의해 열이 대기로 전달되는 것을 알 수 있었다. 또한 식생층은 열을 저장하여 기온의 일교차를 줄이는 역할을 한다. 여름철에 집중관측지의 기온이 주변 지역의 기온보다 보다 낮고 겨울철에는 다소높게 나타난 결과는 식생층을 포함하는 연안습지가 열환경을 조절함을 보여주었다.

• 공업화학
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• 제21권5호
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• pp.522-526
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• 2010

축열이용기술은 열저장효과를 이용하여 냉난방 부하가 적을 때 남는 열을 저장하였다가 부하가 증가할 때 이용하는 방법으로써, 열저장 물질의 온도이용 특성에 따라 현열축열과 잠열축열로 구분한다. 잠열축열은 특정 온도 범위에서 상변화 할 때 높은 잠열을 갖는 물질을 이용하여 열을 저장하는 방법으로 동일한 열저장을 위해 소요되는 공간 크기가 현열 축열에 비하여 작아지게 되고 일정한 온도범위에서 열의 흡수 및 방출이 가능한 특성이 있다. 본 연구는 건축물의 냉난방시 소요되는 에너지를 절약하기 위하여 상온 상변화물질을 축열재로 사용하여, 건축자재로 범용적으로 사용되고 있는 시멘트, 석고 등에 적용하고자 하였다. 제조된 물질이 에너지절약성능은 물론 건축자재로서 필요한 물성을 갖추기 위하여 최적배합 방법 및 비율을 도출하고자 하였다. 그에 따라 중량비로 3% 들어간 축열모르타르의 냉각지연효과는 약 19%로 나타났다.