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Sensitive and Selective Electrochemical Glucose Biosensor Based on a Carbon Nanotube Electronic Film (탄소나노튜브 전자 필름을 이용한 고감도-고선택성 전기화학 글루코스 센서)

  • Lee, Seung-Woo;Lee, Dongwook;Seo, Byeong-Gwuan
    • Applied Chemistry for Engineering
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    • v.33 no.2
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    • pp.188-194
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    • 2022
  • This work presents a non-destructive and straightforward approach to assemble a large-scale conductive electronic film made of a pre-treated single-walled carbon nanotube (SWCNT) solution. For effective electron transfer between the immobilized enzyme and SWCNT electronic film, we optimized the pre-treatment step of SWCNT with p-terphenyl-4,4"-dithiol and dithiothreitol. Glucose oxidase (GOx, a model enzyme in this study) was immobilized on the SWCNT electronic film following the positively charged polyelectrolyte layer deposition. The glucose detection was realized through effective electron transfer between the immobilized GOx and SWCNT electronic film at the negative potential value (-0.45 V vs. Ag/AgCl). The SWCNT electronic film-based glucose biosensor exhibited a sensitivity of 98 ㎂/mM·cm2. In addition, the SWCNT electronic film biosensor showed the excellent selectivity (less than 4 % change) against a variety of redox-active interfering substances, such as ascorbic acid, uric acid, dopamine, and acetaminophen, by avoiding co-oxidation of the interfering substances at the negative potential value.

A Review on SEBS Block Copolymer based Anion Exchange Membranes for Water Electrolysis (SEBS 블록 공중합체를 기반으로 한 수전해용 음이온 교환막에 대한 총설)

  • Kim, Ji Eun;Park, Hyeonjung;Choi, Yong Woo;Lee, Jae Hun
    • Membrane Journal
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    • v.32 no.5
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    • pp.283-291
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    • 2022
  • Hydrogen energy has received much attention as a solution to the supply of renewable energy and to respond to climate change. Hydrogen is the most suitable candidate of storing unused electric power in a large-capacity long cycle. Among the technologies for producing hydrogen, water electrolysis is known as an eco-friendly hydrogen production technology that produces hydrogen without carbon dioxide generation by water splitting reaction. Membranes in water electrolysis system physically separate the anode and the cathode, but also prevent mixing of generated hydrogen and oxygen gases and facilitate ion transfer to complete circuit. In particular, the key to next-generation anion exchange membrane that can compensate for the shortcomings of conventional water electrolysis technologies is to develop high performance anion exchange membrane. Many studies are conducted to have high ion conductivity and excellent durability in an alkaline environment simultaneously, and various materials are being searched. In this review, we will discuss the research trends and points to move forward by looking at the research on anion exchange membranes based on commercial polystyrene-b-poly(ethylene-co-butylene)-b-polystyrene (SEBS) block copolymers.

A Data-driven Classifier for Motion Detection of Soldiers on the Battlefield using Recurrent Architectures and Hyperparameter Optimization (순환 아키텍쳐 및 하이퍼파라미터 최적화를 이용한 데이터 기반 군사 동작 판별 알고리즘)

  • Joonho Kim;Geonju Chae;Jaemin Park;Kyeong-Won Park
    • Journal of Intelligence and Information Systems
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    • v.29 no.1
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    • pp.107-119
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    • 2023
  • The technology that recognizes a soldier's motion and movement status has recently attracted large attention as a combination of wearable technology and artificial intelligence, which is expected to upend the paradigm of troop management. The accuracy of state determination should be maintained at a high-end level to make sure of the expected vital functions both in a training situation; an evaluation and solution provision for each individual's motion, and in a combat situation; overall enhancement in managing troops. However, when input data is given as a timer series or sequence, existing feedforward networks would show overt limitations in maximizing classification performance. Since human behavior data (3-axis accelerations and 3-axis angular velocities) handled for military motion recognition requires the process of analyzing its time-dependent characteristics, this study proposes a high-performance data-driven classifier which utilizes the long-short term memory to identify the order dependence of acquired data, learning to classify eight representative military operations (Sitting, Standing, Walking, Running, Ascending, Descending, Low Crawl, and High Crawl). Since the accuracy is highly dependent on a network's learning conditions and variables, manual adjustment may neither be cost-effective nor guarantee optimal results during learning. Therefore, in this study, we optimized hyperparameters using Bayesian optimization for maximized generalization performance. As a result, the final architecture could reduce the error rate by 62.56% compared to the existing network with a similar number of learnable parameters, with the final accuracy of 98.39% for various military operations.

A Study on the Method of Manufacturing Lactic Acid from Ginkgo Biloba Leaf Extraction Byproducts (은행잎 추출부산물로부터의 Lactic acid 제조법에 관한 연구)

  • Euisuk Ko;Hakrae Lee;Woncheol Shim;Soohyeon Lee;Sunjin Kim;Jaineung Kim
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.29 no.2
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    • pp.95-102
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    • 2023
  • Despite the easing of social distancing, demand for non-face-to-face services continues to rise. Recently, the EU is pursuing a comprehensive plastic use reduction by expanding the scope of plastic use regulations for packaging plastics according to the New Cyclical Economy Action Plan(NCEAP). In response to this trend, the packaging industry is moving away from conventional non-degradable/petroleum-based plastics and conducting research on packaging materials using biodegradable plastics such as PLA(Poly Lactic Acid), PBAT(Poly Butylene Adipate-co-butylene Terephthalate). On the other hand, ginkgo leaves occur in large quantities in Korea and act as a cause of slip accidents and flooding. In this study, a method to utilize ginkgo biloba leaf as a new alternative biomass resource was proposed by producing lactic acid through pretreatment, enzymatic saccharification, and fermentation processes. For the efficiency of lactic acid production, a comparative analysis of lignin content from before and after browning was performed. In addition, the degree of glucan extraction was evaluated by applying a pretreatment method using three catalysts: hot water, sulfuric acid, and sodium hydroxide. It is difficult to expect high production of lactic acid with single process. Therefore, an integrated process operation using both the pretreated hydrolyzate and the residual solid enzymatic saccharification solution must necessarily be applied.

Instrumentation Management of Differential Settlement of the Deep Soft Ground with Dredged Clay Reclaimed in the Upper (대심도 준설 매립지반에서의 층별침하 계측관리에 관한 사례 연구)

  • Tae-Hyung Kim;Seung-Chan Kang;Ji-Gun Chang;Soung-Hun Heo
    • Journal of the Korean Geosynthetics Society
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    • v.22 no.1
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    • pp.87-96
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    • 2023
  • There are a lot of difference between the surface settlement and the differential settlement measured at the Busan New Port, where the dredged and reclaimed clay layer exists and below the clay is originally thickly distributed. To find the cause and solution of this, the actual conditions of each differential settlement used for the soft ground improvement, characteristics, installation method, measurement frequency, measurement data management, and data analysis of each type were considered. In the deep soft ground improvement work where large deformation occurs, the bending deformation of the screw-type differential settlement gauge is less than that of other types of measuring instruments, so there is less risk of loss, and the reliability of data is relatively high as the instruments are installed by drilling for each stratum. Since the greater the amount of high-precision settlement measurement data, the higher the settlement analysis precision. It is necessary to manage with higher criteria than the measurement frequency suggested in the standard specification. For the data management of the differential settlement gauge, it is desirable to create graphs of the settlement and embankment height of the relevant section over time, such as surface, differential, and settlement of pore water pressure gauge for each point. In the case of multi-layered ground with different compression characteristics, it is more appropriate to perform settlement analysis by calculating the consolidation characteristics of each stratum using a differential settlement data.

Simultaneous Removal of Cd and Cr(VI) in the Subsurface Using Permeable Reactive Barrier Filled with Fe-loaded Zeolite: Soil Box Experiment (Fe-loaded zeolite로 충진된 투수성 반응벽체를 이용한 지반 내 Cd과 Cr(VI)의 동시제거: 모형 토조 실험)

  • Rhee, Sung-Su;Lee, Seung-Hak;Park, Jun-Boum
    • Journal of the Korean Geotechnical Society
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    • v.26 no.10
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    • pp.61-68
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    • 2010
  • A pilot-scale model test was performed to estimate the availability of new material, Fe-loaded zeolite, as the filling material in permeable reactive barrier (PRB) against the contaminated groundwater with both Cd and Cr(VI). Aquifer was simulated by filling up a large scale soil tank with sands, and mobilizing the water flow by the head difference of water level in both ends of the tank. Then, the mixture of concentrated Cd and Cr(VI) solution was injected into the aquifer to form a contaminant plume, and its behavior through Fe-loaded zeolite barrier was monitored. The test results showed that Fe-loaded zeolite barrier successfully treated the contaminant plume containing both Cd and Cr(VI) and that the immobilized contaminants in the barrier were not desorbed or released. The results indicated that the Fe-loaded zeolite could be a promising material in PRBs against the multiple contaminants with different ionic forms like Cr(VI) and Cd.

Research on ANN based on Simulated Annealing in Parameter Optimization of Micro-scaled Flow Channels Electrochemical Machining (미세 유동채널의 전기화학적 가공 파라미터 최적화를 위한 어닐링 시뮬레이션에 근거한 인공 뉴럴 네트워크에 관한 연구)

  • Byung-Won Min
    • Journal of Internet of Things and Convergence
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    • v.9 no.3
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    • pp.93-98
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    • 2023
  • In this paper, an artificial neural network based on simulated annealing was constructed. The mapping relationship between the parameters of micro-scaled flow channels electrochemical machining and the channel shape was established by training the samples. The depth and width of micro-scaled flow channels electrochemical machining on stainless steel surface were predicted, and the flow channels experiment was carried out with pulse power supply in NaNO3 solution to verify the established network model. The results show that the depth and width of the channel predicted by the simulated annealing artificial neural network with "4-7-2" structure are very close to the experimental values, and the error is less than 5.3%. The predicted and experimental data show that the etching degree in the process of channels electrochemical machining is closely related to voltage and current density. When the voltage is less than 5V, a "small island" is formed in the channel; When the voltage is greater than 40V, the lateral etching of the channel is relatively large, and the "dam" between the channels disappears. When the voltage is 25V, the machining morphology of the channel is the best.

Information System Audit Improvement Plan in Requirements Engineering-based Quality Assurance and Project Management (요구공학 기반 품질보증 및 프로젝트 관리에서의 정보시스템 감리 개선 방안)

  • Jung Chul, Shin;Dong Soo, Kim;Hee Wan, Kim
    • Journal of Service Research and Studies
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    • v.11 no.1
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    • pp.45-58
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    • 2021
  • Requirements engineering can be seen as proceeding with various processes and activities such as extraction, analysis, specification, management, and verification without temporal and spatial constraints in the development environment of information systems that are becoming large and decentralized. Developing requirements well and conducting continuous evaluation and management is the shortcut to success in project management, and it is recognized as a very important matter in relation to requirements in the information system audit. When we conduct information system audit and conducting projects subject to audit, we need to improve the required engineering aspect. Therefore, this study derives inspection items suitable for the target project by referring to the audit inspection manual and audit inspection guide when conducting the current audit, and relates to the required engineering aspect among the contents of the inspection guide for each business type that is the basis for deriving the inspection items were derived for each audit point/audit area for the project management and quality assurance project type corresponding to the inspection items. The suitability of the extracted occupation items was verified through a questionnaire survey by experts.

The analysis for the HCl modification effect and formation of TiO2 on activated carbon fiber surface (활성탄소섬유 표면의 염산처리효과와 TiO2 형성에 관한 분석)

  • Oh, Won-Chun;Han, Sang-Bum;Bae, Jang-Soon
    • Analytical Science and Technology
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    • v.20 no.4
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    • pp.279-288
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    • 2007
  • We have studied a method for the preparation of $ACF/TiO_2$ composites involving the penetrationof titanium n-butoxide (TNB) solution into activated carbon fiber. It was focused on the characterization of $TiO_2$ formed in prorous carbon was which increased with surface functional groups by hydrochloric acid treatment. The conversion of TNB to $TiO_2$ for the acid treatment effect must be important for the preparationof $ACF/TiO_2$ composites. From the characterization of surface properties, both the BET surface area and the total pore volume decreased as the distribution of $TiO_2$ on the activated carbon fiber surfaces after acid treatments.The changes in XRD pattern showed the typical anatase type on $ACF/TiO_2$ composite for the sample named FT, FT1 and FT2 treated with 0.05, 0.1 and 0.5 M, respectively. However, XRD patern of FT3 treated with 0.5M showed mixed amatase-rutile structure. According to the results of SEM micrographs, the titanium complexe particles were irregularly distributed around carbon. And some large clusters were found when an amount of acid treatment increased. The EDX results of $ACF/TiO_2$ composites showed the presence of C, O and P with strong Ti peaks. Finally, the excellent photocatalytic activity of the $ACF/TiO_2$ composites between relative concentration($c/c_o$) of MB (methylene blue) and UV irradiation time could be attributed to the both effects between photocatalysis of the formation of titania complexes and adsorptivity of the activated carbon fiber.

Establishment of a deep learning-based defect classification system for optimizing textile manufacturing equipment

  • YuLim Kim;Jaeil Kim
    • Journal of the Korea Society of Computer and Information
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    • v.28 no.10
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    • pp.27-35
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    • 2023
  • In this paper, we propose a process of increasing productivity by applying a deep learning-based defect detection and classification system to the prepreg fiber manufacturing process, which is in high demand in the field of producing composite materials. In order to apply it to toe prepreg manufacturing equipment that requires a solution due to the occurrence of a large amount of defects in various conditions, the optimal environment was first established by selecting cameras and lights necessary for defect detection and classification model production. In addition, data necessary for the production of multiple classification models were collected and labeled according to normal and defective conditions. The multi-classification model is made based on CNN and applies pre-learning models such as VGGNet, MobileNet, ResNet, etc. to compare performance and identify improvement directions with accuracy and loss graphs. Data augmentation and dropout techniques were applied to identify and improve overfitting problems as major problems. In order to evaluate the performance of the model, a performance evaluation was conducted using the confusion matrix as a performance indicator, and the performance of more than 99% was confirmed. In addition, it checks the classification results for images acquired in real time by applying them to the actual process to check whether the discrimination values are accurately derived.