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Decontamination of simulated radioactive metal waste by modified electrolytic Process with neutral salt electrolytes (개선된 중성염 진해공정을 이용한 모의 방사성 금속폐기물의 제염)

  • Lee, Ji-Hoon;Yuk, Wan-Yi;Yang, Ho-Yeon;Ha, Jong-Hyun
    • Journal of Radiation Protection and Research
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    • v.27 no.2
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    • pp.95-100
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    • 2002
  • Conventional and modified electrolytic decontamination experiment were performed in the 1.7 M solution of sodium sulfate and sodium nitrate tot decontamination of carbon steel as the simulated metal wastes which have been produced in large amounts from nuclear power plants. Anode ant cathode were used as inconel and titanium respective. The reaction time and temperature were 1 hr and $25^{\circ}C$ The analyses were performed of the characteristics such as weight loss arid thickness change of metal waste. suspended solid in electrolyte and SEM observation. In modified electrolyte decontamination system with increased current density ranged from 0.1 to $0.6A/cm^2$, the metal waste showed thickness changes of $0.48{\pm}0.005$ to $67.7{\pm}0.02{\mu}m$ in 1.7 M sodium sulfate and those of $0.06{\pm}0.005$ to $17.7{\pm}0.05{\mu}m$ in sodium nitrate. Metal waste in modified electrolyte decontamination system showed the thickness change of $9.8{\pm}0.01{\mu}m$ while it reacted up to $3.7{\pm}0.03{\mu}m$ in conventional system with $0.3 A/cm^2$ of current density and 1.7 M sodium sulfate. Decontamination efficiencies of modified electrolytic process ate much hither than that of conventional electrolytic process when both are applied to metal waste.

Decision of Optimized Mix Design for Lightweight Foamed Concrete Using Bottom Ash by Statistical Procedure (통계적 방법에 의한 바텀애쉬를 사용한 경량기포 콘크리트의 최적배합 결정)

  • Kim, Jin-Man;Kwak, Eun-Gu;Cho, Sung-Hyun;Kang, Cheol
    • Journal of the Korea Concrete Institute
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    • v.21 no.1
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    • pp.3-11
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    • 2009
  • The increased demand and consumption of coal has intensified problems associated with disposal of solid waste generated in utilization of coal. Major utilization of coal by-products has been in construction-related applications. Since fly ash accounts for the part of the production of utility waste, the majority of scientific investigations have focused on its utilization in a multitude of use, while little attention has been directed to the use of bottom ash. As a consequence of this neglect, a large amount of bottom ash has been stockpiled. However, the need to obtain safe and economical solution for its proper utilization has been more urgent. The study presented herein is designed to ascertain the performance characteristics of bottom ash, as autoclaved lightweight foamed concrete product. The laboratory test results indicated that tobermorite was generated when bottom ash was used as materials for hydro-thermal reaction. According to the analysis of variance, at the fresh state, water ratio affects on flow and slurry density of autoclaved lightweight foamed concrete, but foam ratio influences on slurry density, while, at the hardened state, foam ratio affects on the density of dry and the compressive strength but doesn't affect on flexural and tensile strength. In the results of response surface analysis, to obtain target performance, the most suitable mix condition for lightweight foamed concrete using bottom ash was water ratio of 70$\sim$80% and foaming ratio of 90$\sim$100%.

Production of Fructose 6-Phoschate from Starch Using Thermostable Enzymes (내열성 효소를 이용한 전분으로부터 6-인산과당의 제조)

  • Kwun, Kyu-Hyuk;Cha, Wol-Suk;Kim, Bok-Hee;Shin, Hyun-Jae
    • KSBB Journal
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    • v.22 no.5
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    • pp.345-350
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    • 2007
  • Phosphosugars are found in all living organisms and are commercially valuable compounds with possible applications in the development of a wide range of specialty chemicals and medicines. In carbohydrate metabolism, fructose 6-phosphate (F6P) is an essential intermediate formed by phosphorylation of 6' position of fructose in glycolysis, gluconeogenesis, pentose phosphate pathway and Calvin cycle. In glycolysis, F6P lies within the glycolysis metabolic pathway and is produced by isomerisation of glucose 6-phosphate. For large-scale production, F6P could be produced from starch using many enzymes such as pullulanase, starch phosphorylase, isomerase and mutase. In enzymatic reactions carried out at high temperatures, the solubility of starch is increased and microbial contamination is minimized. Thus, thermophile-derived enzymes are preferred over mesophile-derived enzymes for industrial applications using starch. Recently, we reported the production of glucose 1-phosphate (G1P) from starch by Thermus caldophilus GK24 enzymes. Here we report the production of F6P from starch through three steps; from starch to glucose 1-phosphate (glucan phosphorylase, GP), then glucose 6-phosphate (phosphoglucomutase, GM) and then F6P (phosphoglucoisomerase, GI). Using 200 L of 1.2% soluble starch solution in potassium phosphate buffer, 1,253 g of G1P were produced. Then, 30% yields of F6P were attained at the optimum reaction conditions of GM : G1 (1 : 2.3), 63.5$^{\circ}C$, and pH 6.85. The optimum conditions were found by response surface methodology and the theoretical values were confirmed by the experiments. The optimum starch concentrations were 20 g/L under the given conditions.

A Study on Concrete Curing Quality Management Based on Various Test of Construction Condition under Hot Weather Circumstance (서중(暑中) 환경에서 현장 콘크리트 시험을 통한 양생 품질관리 방안)

  • Park, Shin
    • Korean Journal of Construction Engineering and Management
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    • v.7 no.2 s.30
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    • pp.71-80
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    • 2006
  • It is required to study systematical on the concrete quality management to extend structure life because rebuilding effect is reducing under present condition of large sized and high stories structure. Concrete, which shows its intensity by hydrating action and a big change in quality according to hot weather and temperature, produces a lot of quality problem under hot and cold weather. Because of each specification and construction plan which does not have basic standard on site, concrete's quality is irregular and makes some defect. As a result, Dae-gu is fumed out to be the longest area after investigating application period and days focused on 8 cities weather information about t relationship between hot weather circumstance and construction environment. Therefore, we first surveyed the curing construction processing in the region and found out the problem of quality management. Then figure out the way of solution. Moreover, we integrated curing quality management, which is applied differently to each site, to have equal quality and to reduce defect from construction site. And then, based on various test of construction condition and analysis of quality management item, we suggest effective concrete quality management to make curing construction standard guide and plan under hot weather.

Effect of Cosurfactant on Preparation of Silica Nanoparticles using Water in Oil Microemulsion of Nonionic Surfactant (보조계면활성제가 비이온 계면활성제의 Water in Oil 마이크로에멀젼을 이용한 실리카 나노입자 제조에 미치는 영향)

  • Kim, TaeHoon;Lim, JongChoo
    • Korean Chemical Engineering Research
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    • v.46 no.2
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    • pp.356-368
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    • 2008
  • The effects of cosurfactant on silica nanoparticles were investigated in systems containing surfactant, oil and aqueous ammonia solution where nanoparticles were prepared using a single phase water-in-oil (W/O) microemulsion. For the same oil phase, a single phase region was dependent on the interaction between surfactant and oil. For the cyclohexane system, NP-5 surfactant showed a wider single phase region than NP-4. The addition of n-propanol as a cosurfactant resulted in an increase or a decrease of a single phase W/O microemulsion region depending on the continuous oil phase. For both cyclohexane and isooctane systems, the addition of n-propanol resulted in a decrease in the single phase region. On the other hand, for n-heptane system, the addition of n-propanol expanded a single phase W/O microemulsion region. Silica nanoparticles prepared within a single phase region showed that relatively large number of particles of irregular shape were obtained with the addition of n-propanol to NP surfactant system. The addition of n-propanol to LA-5 surfactant and n-heptane system produced a decrease in average particle size and an increase in the number of particles formed due to a decrease in the intermicellar exchange rate among microemulsion droplets.

Microstructures and Mechanical Properties of HAp-Ag and HAp-ZrO2Composites Prepared by SPS (SPS에 의해 제조된 HAP-Ag, HAP-ZrO2 복합체의 미세조직 및 기계적 특성)

  • Shin, Na-Young;Oh, Ik-Hyun;Lee, Hee-Jung;Shin, Seung-Yong;Lee, Hae-Hyung;Lee, Byong-Taek
    • Journal of the Korean Ceramic Society
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    • v.41 no.4
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    • pp.334-339
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    • 2004
  • Microstructures and mechanical properties of SPSed monolithic HAp, HAp-Ag, and HAp-ZrO$_2$sintered bodies were investigated by the XRD, SEM, and TEM techniques. The nano-sized HAp powders were successfully synthesized by precipitation of Ca(NO$_3$)$_2$4$H_2O$ and (NH$_4$)HPO$_4$solution. In the HAp-Ag composite, the shrinkage cavities were observed at the interfaces between HAp and large sized Ag particles due to the mismatch of their thermal expansion coefficients. However, no found the defect at the interfaces between HAp and fine-sized Ag particles. In the HAp-ZrO$_2$composite. nano-sized ZrO$_2$particles were almost dispersed at the grain boundaries of HAp phase. The fracture toughness of HAp-Ag and HAp-ZrO$_2$ composites were increased due to the plastic deformation and phase transformation mechanisms of the dispersed fine Ag and ZrO$_2$phase in the HAp matrix, respectively.

Modeling of Effective Path-Length in Satellite Link Based on Rain Cell Statistics (위성 링크에 대한 강우셀 기반 실효 경로 길이 모델링 연구)

  • Kang, Woo-Geun;Kim, Myunghoi;Kim, In-Kyum;Choi, Kyung-Soo;Lee, Byoung-Sun;Pack, Jeong-Ki
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.25 no.3
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    • pp.348-356
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    • 2014
  • The existing effective path-length model of ITU-R has some drawbacks: The prediction error is quite large compared to domestic measurement data and it is an empirical model in which the physical characteristics of rain cells are not considered. In this paper, a theoretical model for effective path-length using the rain-cell concept was proposed and its validity was verified using the measurement data. To analyze the statistical characteristics of rain cell parameters, the weather-radar data(CAPPI) measured by Korea Meterological Administration were analyzed and the correction factor was properly introduced to fit the Chollian beacon measurement data of ETRI(Electronics and Telecommunications Research Institute). To verify the proposed effective path-length model, it was compared with the Mugunghwa No. 5 beacon data measured in Chungnam National University with the support of ADD(Agency for Defense Development). It was confirmed that the prediction results of the proposed model are in good agreement with the measurement data.

An Ambient Pore Pressure and Rigidity Index from Early Part of Piezocone Dissipation Test (피에조콘 소산시험의 초기경향을 이용한 평형간극수압과 강성지수의 결정)

  • 김영상
    • Journal of the Korean Geotechnical Society
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    • v.18 no.2
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    • pp.161-170
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    • 2002
  • This paper describes a systematic way of simultaneously identifying the ambient pore pressure and the rigidity index $(=G/s_u)$ of soil by applying an optimization technique to the early part of piezocone dissipation test result. An analytical solution developed by Randolph & Wroth(1979) was implemented in normalized from to express the build-up and dissipation of excess pore pressures around a piezocone as a function of the rigidity index. An ambient pore pressure and optimal rigidity index were determined by minimizing the differences between theoretical and measured excess pore pressure curves using optimization technique. The effectiveness of the proposed back-analysis method was examined against the well-documented performance of piezocone dissipation tests(Tanaka & Sakagami, 1989), from the viewpoints of proper determination of selected target parameters and saving of test duration. It is shown that the proposed back-analysis method can evaluate properly the ambient pore pressure and the rigidity index by using only the early phase of the dissipation test data. Also, it is shown that the proposed back-analysis method permits the horizontal coefficient of consolidation to be identified rationally. Consideration for strain level of back-analyzed rigidity index shows that it corresponds to at least intermediate to large strain level.

Effect of Fluoride and Laser on Artificial Caries-like Lesion Formation in Bovine Enamel (불소 및 레이저가 우치법랑질의 인공우식병소에 미치는 영향)

  • Kim, Jae-Gon;Baik, Byeong-Ju;Ju, Hoon;Yun, Hyun-Du
    • Journal of the korean academy of Pediatric Dentistry
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    • v.24 no.3
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    • pp.660-677
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    • 1997
  • The purpose of this study was to examine the morphological characteristics and combined effects of fluoride application and laser irradiation on artificial caries-like lesion formation in bovine enamel. Enamel specimens were divided into five experiment group and placed in no-treatment(group C), APF application alone(group F), laser irradiation alone(group L), APF application before laser irradiation (group FL), and APF application after laser irradiation(group LF) on artificial caries-like lesion. Sound enamel was used as a control group. The ultrastructural changes and physical effects of the fluorided and lased enamel has been investigated by using SEM, enamel solubility and microhardness test as well as distributions of calcium, phosphorus and fluoride in internal enamel by using EPMA. The following results were obtained. 1. In the all experiment groups, the amounts of dissolved calcium of enamel surfaces significantly decreased according to increasing exposure time of acid solution than control group(P<0.001). Group L showed higher than that group FL and LF in 30 and 60min(P<0.05). 2. The microhardness values of enamel surface in the control group was highest than that in the other experiment groups. Group F, L, FL and LF were significantly increased than group C(P<0.001). The enamel surface treated with APF produced deposites of numerous small globules and lased enamel showed a cracker-like appearance with microcrack and small pore. Numerous deposits were infiltrated in the fissured portion of enamel treated with APF after laser irradiation. 4. In the case of APF application alone, the elevation of the fluoride profile can be seen within $5{\mu}m$ of the outermost layer and a similar profile observed in the specimen treated with APF before laser irradiation. However, the specimen treated with APF after laser Irradiation showed a large elevation within $10{\mu}m$ of the outermost layer of the enamel. 5. The higher Ca/P ratios were observed in $10{\mu}m$ depth of lased and fluorided enamel when compared to the sound and carious enamel. The fluoride content decreased rapidly with distance from enamel surface, in the group F, fluoride concentration was significantly higher than that in the group C, L, FL, LF and control group according to increasing enamel depth (P<0.05).

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Current status on global sweetpotato cultivation and its prior tasks of mass production (세계 고구마 재배현황 및 대량생산의 선결과제)

  • Kim, Ho Soo;Lee, Chan-Ju;Kim, So-Eun;Ji, Chang Yoon;Kim, Sung-Tai;Kim, Jin-Seog;Kim, Sangyong;Kwak, Sang-Soo
    • Journal of Plant Biotechnology
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    • v.45 no.3
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    • pp.190-195
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    • 2018
  • Sweetpotato [Ipomoea batatas (L.) Lam] represents an attractive starch crop that can be used to facilitate solving global food and environmental problems in the $21^{st}$ century. It can be used as industrial bioreactors to produce various high value-added materials, including bio-ethanol, functional feed, antioxidants, as well as food resources. The non-profit Center for Science in the Public Interest (CSPI) announced sweetpotato as one of the ten 'super foods' for better health, since it contains high levels of low molecular weight antioxidants such as vitamin-C, vitamin-E and carotenoids, as well as dietary fiber and potassium. The United States Department of Agriculture (USDA) also reported that sweetpotato is the best bioenergy crop among starch crops on marginal lands, that does not affect food security. The Food and Agriculture Organization (FAO) estimated that world population in 2050 will be 9.7 billion, and require approximately 1.7 times more food than today. In this respect, sweetpotato will be a solution to solving problems such as food, energy, health, and environment facing the globe in the $21^{st}$ century. In this paper, the current status of resources, and cultivation of sweetpotato in the world was first described. Development of a new northern route of the sweetpotato and its prior tasks of large scale cultivation of sweetpotato, were also described in terms of global food security, and production of high-value added biomaterials.