• Title/Summary/Keyword: lamellar

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Kinetic Characterization of Swelling of Liquid Crystalline Phases of Glyceryl Monooleate

  • Lee, Jae-Hwi;Choi, Sung-Up;Yoon, Mi-Kyeong;Choi, Young-Wook
    • Archives of Pharmacal Research
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    • v.26 no.10
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    • pp.880-885
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    • 2003
  • Research in this paper focuses on the kinetic evaluation of swelling of the liquid crystalline phases of glyceryl monooleate (GMO). Swelling of the lamellar and cubic liquid crystalline phases of GMO was studied using two in vitro methods, a total immersion method and a Franz cell method. The swelling of the lamellar phase and GMO having 0 %w/w initial water content was temperature dependent. The swelling ratio was greater at $20^{\circ}^C than 37^{\circ}^C$ . The water uptake increased dramatically with decreasing initial water content of the liquid crystalline phases. The swelling rates obtained using the Franz cell method with a moist nylon membrane to mimic buccal drug delivery situation were slower than the total immersion method. The swelling was studied by employing first-order and second-order swelling kinetics. The swelling of the liquid crystalline phases of GMO could be described by second-order swelling kinetics. The initial stage of the swelling (t < 4 h) followed the square root of time relationship, indicating that this model is also suitable for describing the water uptake by the liquid crystalline matrices. These results obtained from the current study demonstrate that the swelling strongly depends on temperature, the initial water content of the liquid crystalline phases and the methodology employed for measuring the swelling of GMO.

Growth and characterization of $Al_{2}O_{3}-based\;Y_{3}Al_5O_{12},\;ZrO_{2}$ binary and ternary eutectic fibers

  • Lee, J.H.;Yoshikawa, A.;Kaiden, H.;Fukuda, T.;Yoon, D.H.;Waku, Y.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.4
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    • pp.170-175
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    • 2001
  • It was possible to grow the $Al_{2}O_{3}$ based $Y_{3}A_{5}O_{12}(YAG),ZrO_{2}$ binary and ternary eutectic fibers using micro-pulling down method with a growing rate of 0.1~15 mm/min. While $Al_{2}O_{3}/ZrO_{2}$ showed cellular-lamellar structure, $Al_{2}O_{3}$/YAG and $Al_{2}O_{3}$/YAG/$ZrO_{2}$ternary eutectic fibers showed homogeneous Chinese script lamellar structures. The microstructures of $Al_{2}O_{3}/ZrO_{2}$ binary eutectic fibers changed with solidification rate from lamellar pattern to cellular structure. The interlamellar spacing agreed with the inverse-square-root dependance on pulling rate according to $\lambda$=$kv_p\;{-1/2}$. $Al_{2}O_{3}/ZrO_{2}$ binary eutectic fibers recorded the highest tensile strength of about 1560MPa at room temperature. $Al_2O_3/YAG/ZrO_2$ternary eutectic fiber showed excellent thermal stability to $1200^{\circ}C$ without significant decrease. The maximum strength of ternary eutectic fibers recorded were 1100MPa at $25^{\circ}C$ and 970MPa at $1200^{\circ}C$, respectively.

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Electron Microscopic Observations on the Endoplasmic Reticulum and Golgi Complex during Spermiogenesis in the Long-Fingered Bat (Miniopterus schreibersi fuliginosus Hodgson) (한국산 긴날개박쥐 (Miniopterus schreibersi fuligino년)의 정자변태동안의 소포체와 골지체에 관한 전자현미경적 관찰)

  • Choi, Byung-Jin;Son, Sung-Won;Lee, Jung-Hun;Lee, Kae-Il
    • Applied Microscopy
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    • v.28 no.4
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    • pp.603-613
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    • 1998
  • The present study was designed in order to observe relationship between the endoplasmic reticulum and the Golgi complex during spermiogenesis of the long-fingered bat (Miniopterus schreibersi fuliginosus). The testes were obtained from adult bats and treated with the prolonged osmification or fixed with ferrocyanide reduced osmiun. In the Golgi phase, The Golgi complex shows an oval shape, and was composed of a cortex and a medullar enclosing acrosome. The Golgi vacuoles with electron-dense granules of crescent shape were fused with each other. The smooth endoplasrnic reticulum was scattered in all the area of the cytoplasm. In the cap phase, The Golgi complex was crescent in shape, and faced to a nucleus. Large and small vesicles were fused with each other, and then fused with a acrosomal vacuole. The rough endoplasmic reticulum was close to the large Golgi vacuole. In the acrosome phase, The Golgi complex was moved to behind of the acrosome face. Small vesicles were fused with an acrosome, and cisternae of the trans-face of Golgi complex was connected with an acrosome in the early acrosome phase. The smooth endoplasmic reticulum was distributed in the cytoplasm. The annulate lamellar was originated from a radial body-annulate lammellae complex. In the maturation phase, The Golgi complex with dilated cistrern appeared in the cytoplasm, and also, annulate lamellar was observed in the cytoplasm. The connection of the annulate lamellar with the cistern of radial body suggests that an annulate lamellar seems to be closely related to radial body. The smooth endoplasmic reticulum was scattered in the cytoplasm in the early Golgi phase, but annulate lamellar-radial body complex which might be a residual and disappearing form of the smooth endoplasmic reticulum appeared in the acrosome phase. The Golgi complex steadily remained in the late maturation phase when the endoplasmic reticulum began to disappear from the cytoplasm: the Golgi complex was still occurred after acrosome formation. The observations obtained in the present study, which was characterized by the presence of the Golgi complex in the late maturation phase, suggests that the Golgi complex may play an important role also even after the acrosome formation.

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Microstructures and Mechanical Properties of Al-Cu Eutectic Composite by Upward Continuous Casting (상향식 연속주조법으로 제조한 Al-Cu 공정 복합재료의 응고조직 및 기계적 성질)

  • Kwon, Kee-Kyun;Sunwoo, Kuk-Hyun;Lee, Kye-Wan
    • Journal of Korea Foundry Society
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    • v.10 no.1
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    • pp.57-63
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    • 1990
  • Continuous casting of the $Al-CuAl_2$ eutectic composite was carried out by the upward continuous casting process. The morphology of the eutectic growth and the stability of solid-liquid interface were investigated under various growth conditions. It was possible to get the planar solid-liquid interface at the condition of $G_L/R$$3.6{\times}10^3^{\circ}Csec/mm^2$. And the colony structures were formed at the conditions of $G_L/R$ < $R=0.33{\times}10^3^{\circ}Csec/mm^2$. The inter-lamellar spacing of $Al-CuAl_2$ eutectic composite was decreased with the increase of pulling speed. The reduction of inter-lamellar spacing & value of $G_L/R$ caused the increase of ultimate tensile strength and Rockwell hardness in $Al-CuAl_2$ eutectic composite.

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$Bi_2Te_3-PbTe$계 열전소재의 자연나노구조체 형성 및 특성

  • Im, Ju-Hyeok;Jeong, Gyu-Ho;Kim, Gwang-Cheon;Yu, Hyeon-U;Kim, Jin-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.263-263
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    • 2009
  • The microtstructures and properties of alloys in the pseudo-binary $Bi_2Te_3-PbTe$ system were investigated as a first step towards the design of nanostructured materials with enhanced thermoelectric properties. The liquid alloys were cooled by water quenching method. Dendritic and lamellar structures were observed clearly by using environmental scanning electron microscope(eSEM) and electron probe micro analyzer(EPMA) take into account composition ratio between $Bi_2Te_3$ and PbTe. The compound $Pb_2Bi_6Te_{11}$ precipitated as a metastable phase under all conditions. The structure of those samples changed from dendritic to lamellar by increasing $Bi_2Te_3$ ratio of composition.

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Impact of Fungus on Egg Shell of Tropical Tasar Silk Worm, Antheraea mylitta: An Ultra-structural Approach

  • Barsagade, Deepak Dewaji;Pankule, Sushama Dilip;Tembhare, Dnyaneshwar Bapuji
    • International Journal of Industrial Entomology and Biomaterials
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    • v.18 no.2
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    • pp.77-82
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    • 2009
  • The egg shell of the tropical tasar silkworm, Antheraea mylitta is formed from the substances secreted by the follicular epithelium during the late vitellogenic stage. TEM study reveals the inner travecular and outer lamellar layer of chorion. The travecular layer is composed of the innermost wax layer, inner and outer chorionic layer. The inner and outer chorionic layers are connected to each other by vertical pillers forming of cavities. The lamellar layer is perforated by the aeropyles. SEM study reveals the differentiation of an anterior surface of the egg shell into four zones-micropylar, edge, aeropyles crown and disc zone. In the mycosis infected eggs the aeropyles and egg-shell surface are fully packed with the hyphae of the fungus, Aspergillus sydowi blocking of plastron respiration and causing the death of developing embryo so that mycosis infected eggs become sterile.

The Study on the Unidirectionally Solidified $Al-CuAl_2$ Eutectic Composites;Effect of Vibration on the Lamellar Spacing and Fault Density (일방향 응고한 $Al-CuAl_2$ 공정복합재료에 관한 연구;층상간격과 결함밀도에 미치는 응고조건과 진동의 영향)

  • Lee, Kil-Hong;Lee, Hyun-Kyu
    • Journal of Korea Foundry Society
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    • v.17 no.2
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    • pp.188-194
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    • 1997
  • The effects of solidification condition and vibration on structure refinement were investigated for unidirectionally solidified $Al-CuAl_2$ eutectic composites. Eutectic composites were unidirectionally solidified under vibration with different growth rates (R) and thermal gradient(G). The lamellar structure was varied according to growth condition (G/R ratio). For the structure refinement the effect of G/R was found out to be greater than that of vibration. The interlamellar spacing(${\lambda}$) in this materials was varied with the growth rates(R) with "${\lambda}^2R$=Constant" relationship.

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Temperature Gradient Estimation of Floating Zone Furnace by Mean Lamellar Spacing Measurement in DS-processed TiAl Alloys

  • Jung, I.S.;Park, Jong-Moon;Wee, D.M.;Oh, Myung-Hoon
    • Journal of the Korean Society for Heat Treatment
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    • v.28 no.2
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    • pp.82-86
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    • 2015
  • In this study, the temperature gradient of a floating zone (FZ) apparatus, which is very difficult to directly measure, could be estimated by using the relationships between the lamellar spacing of directionally solidified TiAl alloys and the solidification rate, It was found that the calculated temperature gradient of the FZ apparatus was much higher, and almost ten times higher than that of a Bridgman type directional solidification apparatus.

Effect of crystalline lamellar orientation on the creep and wear of ultra-high molecular weight polyethylene (초고분자량 폴리에닐렌 미세구조가 변형과 마모에 미치는 영향)

  • 이권용
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1998.10a
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    • pp.100-105
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    • 1998
  • 초고분자량 폴리에틸렌(Ultra-High Molecular Weight Polyethylene)은 인공관절 라이너에 쓰이는 대표적 생체재료이다. 초고분자량 폴리에틸렌의 변형과 마모에 영향을 주는 인자에 대한 기본적 연구를 위하여 본 연구에서는 미세구조 결정상의 정도와 결정구조 방향성에 따른 초고분자량 폴리에틸렌의 크리프 변형 및 마모 특성의 연구를 행하였다. 압출 제작된 초고분자량 폴리에틸렌 봉(extruded UHMWPE rod)단면의 중앙(center) 부분과 원주(periphery)부분으로부터 각각 직사각형 및 원통형의 시편을 제작하여 크리프 실험과 마모 실험을 실시하였다. 원주 시편의 크리프 변형율은 중앙 시편의 크리프 변형율보다 11% 크며 (p<0.05), 마모양도 원주 시편이 중앙 시편보다 두 배나 큰 것으로(p<0.05)관측되었다. 이 결과들로부터 초고분자량 폴리에틸렌의 크리프 변형과 마모가 미세 결정구조 방향성에 영향을 받는 것으로 나타났다.

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