• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.43 no.5
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• pp.440-448
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• 2015

Kinetic energy(KE) rod warhead system is a new interceptor which combines advantages of existing ones. This system is less dependant on a precision guidance than direct hit type warhead and gives high penetration rates than blast fragmentation type warhead. In this paper, isotropic KE rod warhead system is introduced with detonation/deployment model. A penetration effects of the deployed rods are calculated using TATE penetration equation. Also, an engagement performance analysis method is suggested. Finally, an optimal detonation time and engagement geometry is derived by Monte-Carlo simulation in various engagement situation using the performance analysis factor.

• Korean Chemical Engineering Research
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• v.54 no.2
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• pp.255-261
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• 2016

Adsorption experiments of Acid Yellow 14 dye using activated carbon were carried out as function of adsorbent dose, pH, initial concentration, contact time and temperature. The equilibrium adsorption data were analyzed by Langmuir, Freundlich and Temkin isotherm model. The experimental data were best represented by Freundlich isotherm model. Base on the estimated Freundlich constant (1/n=0.129~0.212) and Langmuir separation factor ($R_L=0.202{\sim}0.243$), this process could be employed as effective treatment method. The heat of adsorption of Temkin isotherm model was 5.101~9.164 J/mol indicated that the adsorption process followed a physical adsorption. Adsorption kinetics experimental data were modeled using the pseudo-first-order and pseudo-second-order kinetic equation. It was shown that pseudo-second-order kinetic equation could best describe the adsorption kinetics. Base on the negative Gibbs free energy (-4.81~-10.33 kJ/mol) and positive enthalpy (+78.59 kJ/mol) indicate that the adsorption is spontaneous and endothermic process.

• Bulletin of the Korean Chemical Society
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• v.33 no.10
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• pp.3274-3278
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• 2012

The kinetic studies on the reactions of phenyl N-phenyl phosphoramidochloridate (8) with substituted anilines ($XC_6H_4NH_2$) and deuterated anilines ($XC_6H_4ND_2$) have been carried out in acetonitrile at $60.0^{\circ}C$. The obtained deuterium kinetic isotope effects (DKIEs; $k_H/k_D$) are huge secondary inverse ($k_H/k_D$ = 0.52-0.69). A concerted mechanism is proposed with a backside attack transition state (TS) on the basis of the secondary inverse DKIEs and the variation trends of the $k_H/k_D$ values with X. The degree of bond formation in the TS is really extensive taking into account the very small values of the DKIEs. The steric effects of the two ligands on the rates are extensively discussed for the aminolyses of the chlorophosphate-type substrates on the basis of the Taft equation.

• Journal of the Korean Chemical Society
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• v.25 no.5
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• pp.291-299
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• 1981

A test particle kinetic theory for reaction dynamics in liquids is presented at the repeated ring collision level for the hard sphere model. A kinetic equation for the equilibrium time correlation function of the reactive test particle phase space density is derived and the rate kernel expression for the reversible chemical reaction of the type A +B ${\rightleftharpoons$ C + D in the presence of inert solvent S is obtained by the projection operator method.

• Journal of environmental and Sanitary engineering
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• v.17 no.1
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• pp.69-74
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• 2002

This study explored for treatment processes by investigating the treatment efficiency and reaction mechanism through oxidation reaction using UV and $O_3$ as oxidant in compensate the wastewater containing nitrobenzene that is non biodegradable organic. Also by modeling these reactions, we try to step explanation of optimum reaction rate and reaction mechanism as the development of the computer program predictable the reaction rate by modeling the reaction. By using this model, after kinetic constant for each reaction from an experimental data is made an optimization and for hardly contribute to reaction rate in reaction kinetic equation is made an ignorance and suppose the simplified reaction mechanism, examined the propriety of computer simulation model and simplified reaction mechanism by comparing and inspecting the reaction kinetic constant and masstransfer coefficient. An investigation results for destructional treatment of nitrobenzene in the wastewater as non-biddegradable organic using UV, $O_3{\;}O_2{\;}H_2O_2-UV$ as oxidant.

• Coupled systems mechanics
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• v.6 no.1
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• pp.17-28
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• 2017

In this work, we extend the previously developed split kinetic energy (dubbed KEP) method by Mineo and Chao (2012) by modifying the mass parameter to include the negative mass. We first show how to separate the total system into the subsystems with 3 attractive delta potentials by using the KEP method. For repulsive delta potentials, we introduce "negative" mass terms. Two cases are demonstrated using the "negative" mass terms for repulsive delta potential problems in quantum mechanics. Our work shows that the KEP solution scheme can be used to obtain not only the exact energies but also the exact wavefunctions very precisely.

• Journal of the Korean Solar Energy Society
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• v.30 no.4
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• pp.9-14
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• 2010

The main cause of global warming is carbon dioxide generated from the use of fossil fuels, and active research on the reduction of carbon is in progress to slow down the increasing global warming. Wind turbines generate electricity from kinetic energy of wind and are considered as representative for an energy source that helps to reduce carbon emission. Since the kinetic energy of wind is proportional to the cube of the wind speed, the intensity of wind affects wind farm construction validity the most. Therefore, to organize a wind farm, validity analysis should be conducted first through measurement of the wind resources. To facilitate the approval and permission and reduce installation cost, measuring sensors should be installed at locations below the actual wind turbine hub. Wind conditions change in shape with air density, and air density is most affected by the variable sterrain and surface type. So the magnitude of wind speed depends on the ground altitude. If wind conditions are measured at a location below the wind turbine hub, the wind speed has to be extrapolated to the hub height. This correction of wind speed according to height is done with the Deacon equation used in the statistical analysis of previously observed data. In this study, the optimal Deacon equation parameter was obtained through the analysis of the correction of the wind speed error with the Deacon equation based on the characteristics of terrain.

• Bulletin of the Korean Chemical Society
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• v.14 no.1
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• pp.95-100
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• 1993

A noise-induced transition is presented for a bistable system subjected to a multiplicative random force, which is singular at the unstable state. The stationary probability distribution is obtained from the Fokker-Planck equation and the effects of the singularity is analyzed. On the basis of noise-induced phase transition with Gaussian white noise, the relaxation time and the transition rate of the system are evaluated up to the first order correction of D. In the parameter region v < l, the transition rates decrease as the exponent v goes to 1 and as the coefficient of the linear term of the kinetic equation increases.

• Journal of Korean Society on Water Environment
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• v.21 no.6
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• pp.602-608
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• 2005

A laboratory-scale experiment was conducted to investigate control of soluble microbial products (SMP) by the internal recycle rate in the submerged membrane separation activated sludge process. The internal recycle rate of the reactor RUN 1 and RUN 2 were 100 % and 200 %, respectively. SMP concentration was rapidly accumulated in the reactor (RUN 1). The variation of accumulated SMP concentration was related to the denitrification rate at the beginning experiment however SMP concentration decreased without correlatively to the denitrification rate during long operation time. The microbial kinetic model was rapidly presented in the both microbial growth and extinction in the reactor (RUN 1). In the SMP kinetic model, Internal recycle rate is the lower, value of UAP and BAP which SMP matter were presented low. The study about development of kinetic model is relatively well adjusted to the experiment exception SMP. In the future, SMP formation equation must be thought that continually research is necessary.

• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.151-151
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• 2022

The impact of raindrops on the soil surface causes soil detachment, which may be estimated by measuring the kinetic energy (KE) of the raindrops. Since direct measurements of rainfall force on ground surfaces are not generally available, empirical equations are an alternative option to estimate KE from rainfall intensity (I), which has the greatest influence over soil erosion and is easily accessible. Establishing the optimal formulation for the relationship between kinetic energy and rainfall intensity has proven to be difficult. Thus, this research considered thirty-seven rainfall events observed from June 2020 to December 2021 using a laster optical disdrometer erected in Kyungpook National University to examine the characteristics of KE-I relationships. We concentrated our discussion on the formation of two different expressions of the KE, including KE expenditure (KE_exp) and KE content (KE_con). The following conclusions were drawn: (1) We employed statistical analysis to demonstrate that the KE_exp is more suitable expression for establishing an empirical rule between KE and I than the KE_con. (2) A power-law model was used to find the best correlation between KE_exp-I relationship, whereas the best match between KE_con and I were found using an exponential equation.