• Title/Summary/Keyword: kinetic equation

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Computer Curve-Fitting of Crystallization Peak of Amorphous $Pb(Fe_{2/3}W_{1/3})O_3$ Ceramics (비정질 $Pb(Fe_{2/3}W_{1/3})O_3$ 결정화 피크의 컴퓨터 합성)

  • 김남경
    • Journal of the Korean Ceramic Society
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    • v.31 no.10
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    • pp.1202-1208
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    • 1994
  • On heating amorphous Pb(Fe2/3W1/3)O3 ceramics, glass transition occurred at 35$0^{\circ}C$, crystallization at 394~420, 485~550 and 540~571$^{\circ}C$ (depending on the heating rates of 2.5~8$0^{\circ}C$/min), phase transformation at 680 and 73$0^{\circ}C$, and melting at 935$^{\circ}C$. A curve-fitting computer program was made using FORTRAN, based on a kinetic equation. Reconstructed thermograms (using the program) turned out to be very close to the measured DSC results for all the heating rates, with average deviation of only 4% at maximum.

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Oxidation Kinetics of Pitch Based Carbon Fibers

  • Roh, Jae-Seung
    • Carbon letters
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    • v.9 no.2
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    • pp.121-126
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    • 2008
  • High modulus pitch based carbon fibers (HM) were exposed to isothermal oxidation using tube furnace in carbon dioxide gas to study the oxidation kinetics under the temperature of $800-1100^{\circ}C$. The kinetic equation $f=1-{\exp}(-at^b)$ was introduced and the constant b was obtained in the range of 1.02~1.42. The oxidation kinetics were evaluated by the reaction-controlling regime (RCR) depending upon the apparent activation energies with the conversion increasing from 0.2 to 0.8. The activation energies decrease from 24.7 to 21.0 kcal/mole with the conversion increasing from 0.2 to 0.8, respectively. According to the RCR, the reaction was limited by more diffusion controlling regime for the HM fibers with the conversion increasing. Therefore, it seems that the oxidation which is under the diffusion controlling regime takes place continuously from the skin to the core of the fiber.

Kinetics of Initial Water Vapor Adsorption by Inonotus obliquus Mushroom Powders

  • Lee, Min-Ji;Seog, Eun-Ju;Lee, Jun-Ho
    • Preventive Nutrition and Food Science
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    • v.12 no.2
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    • pp.111-114
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    • 2007
  • Water vapor adsorption kinetics of Inonotus mushroom powders were investigated in temperature and water activity ranges of 20 to 40$^{\circ}C$ and 0.30 to 0.81, respectively. Initial water vapor adsorption rate of mushroom powders increased with increases in temperature and water activity. The temperature dependency of water activity followed the Clausius-Clapeyron equation. The net isosteric heat of sorption increased with an increase in water activity. Water vapor adsorption kinetics of the mushroom powders can be well described by a simple empirical model. Temperature dependency of the reaction rate constant followed the Arrhenius relationship. The activation energy ranged from 56.86 to 91.35 kJ/mol depending on water activity. Kinetic compensation relationship was observed between k$_o$ and E$_a$ with the isokinetic temperature of 790.27 K.

A Study on the Vibration Characteristics of 2-phase Linear Stepping Motor (2상 Linear Stepping Motor의 진동특성에 관한 연구)

  • 이상호;김동희;정도영;김춘삼;오홍석
    • Proceedings of the KIPE Conference
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    • 1999.07a
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    • pp.159-162
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    • 1999
  • In this paper, a vibration suppression method using an energy stored in winding inductance and an induced voltage of the Linear Stepping Motor(LSM) is shown, and it is applied to a new one-phase excitation method. And a magnetic equivalent circuit is based on the structure of the LSM, and then the electric equivalent circuit of the LSM is derived by solving equations for the magnetic equivalent circuit. Several dynamic characteristics of the LSM are analyzed by the ACSL with the voltage equations, the force equations and the kinetic equation, and are measured by experimental system.

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Oxidation Kinetics of Carbon Fibers

  • Roh, Jae-Seung
    • Carbon letters
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    • v.6 no.1
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    • pp.1-5
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    • 2005
  • Isotropic pitch based carbon fibers were exposed to isothermal oxidation in carbon dioxide gas to study the activation kinetics under the temperature of 800~$1100^{\circ}C$. The kinetic equation $f=1-{\exp}(-at^b)$ was introduced and the constant b was obtained in the range of 0.92~1.25. It was shown that the activated carbon fiber shows the highly specific surface area (SSA) when the constant b comes close to 1. The activation kinetics were evaluated by the reaction-controlling regime (RCR) according to changes of the apparent activation energy with changes of the conversion. It was observed that the activation energies increase from 47.6 to 51.2 kcal/mole with the conversion increasing from 0.2 to 0.8. It was found that the pores of the activated carbon fiber under the chemical reaction were developed well through the fiber.

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Impact of Energy Relaxation of Channel Electrons on Drain-Induced Barrier Lowering in Nano-Scale Si-Based MOSFETs

  • Mao, Ling-Feng
    • ETRI Journal
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    • v.39 no.2
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    • pp.284-291
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    • 2017
  • Drain-induced barrier lowering (DIBL) is one of the main parameters employed to indicate the short-channel effect for nano metal-oxide semiconductor field-effect transistors (MOSFETs). We propose a new physical model of the DIBL effect under two-dimensional approximations based on the energy-conservation equation for channel electrons in FETs, which is different from the former field-penetration model. The DIBL is caused by lowering of the effective potential barrier height seen by the channel electrons because a lateral channel electric field results in an increase in the average kinetic energy of the channel electrons. The channel length, temperature, and doping concentration-dependent DIBL effects predicted by the proposed physical model agree well with the experimental data and simulation results reported in Nature and other journals.

NUMERICAL ANALYSIS OF NON-EQUILIBRIUM HYDRATE PELLET DECOMPOSITION (하이드레이트 펠릿의 비평형 분해과정 수치해석)

  • Kang, Jung-Ho;Nam, Jin-Hyun;Kim, Charn-Jung;Song, Myung-Ho
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03a
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    • pp.268-275
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    • 2008
  • The prediction of hydrate pellet decomposition characteristics is required to design the regasification process of GTS (gas to solid) technology, which is considered as an economic alternative for LNG technology to transport natural gas produced from small and stranded gas wells. Mathematical model based on the conservation principles, the phase equilibrium relation, equation of gas state and phase change kinetics was set up and numerical solution procedure employing volume averaged fixed grid formulation and extended enthalpy method are implemented. Initially, porous methane hydrate pellet is at uniform temperature and pressure within hydrate stable region. The pressure starts to decrease with a fixed rate down to the final pressure and is kept constant afterwards while the bounding surface of pellet is heated by convection. The predicted convective heat and mass transfer accompanied by the decomposed gas flow through hydrate/ice solid matrix is reported focused on the comparison of spherical and cylindrical pellets having the same effective radius.

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Numerical Simulation on Interactions of Longitudinal Vortices in a Turbulent Boundary Layer (종방향 와동과 난류경계층의 상호작용에 관한 수치해석)

  • Yang Jang-Sik
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.6
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    • pp.637-644
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    • 2005
  • This paper describes the numerical simulation of the interaction between longitudinal vortices ("common flow up") and a 3-D turbulent boundary layer over a flat plate To analyze the common flow up Produced from vortex generators. the flow field behind the vortex generators Is modeled by the information that is available from studies on a half-delta winglet. Also. the Reynolds-averaged Navier-Stokes equation for three-dimensional turbulent flows. together with a two-layer turbulence model to resolve the near-wall flow, is solved by the method of AF-ADI. The computational results predict that the boundary layer is thinned in the regions where the secondary flow is directed toward the wall and thickened where it is directed away from the wall Also. the numerical results. such as Reynolds stresses. turbulent kinetic energy and skin friction characteristics generated from the vortex generators . are reasonably close to the experimental data.

NUMERICAL ANALYSIS OF NON-EQUILIBRIUM HYDRATE PELLET DECOMPOSITION (하이드레이트 펠릿의 비평형 분해과정 수치해석)

  • Kang, Jung-Ho;Nam, Jin-Hyun;Kim, Charn-Jung;Song, Myung-Ho
    • 한국전산유체공학회:학술대회논문집
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    • 2008.10a
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    • pp.268-275
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    • 2008
  • The prediction of hydrate pellet decomposition characteristics is required to design the regasification process of GTS (gas to solid) technology, which is considered as an economic alternative for LNG technology to transport natural gas produced from small and stranded gas wells. Mathematical model based on the conservation principles, the phase equilibrium relation, equation of gas state and phase change kinetics was set up and numerical solution procedure employing volume averaged fixed grid formulation and extended enthalpy method are implemented. Initially, porous methane hydrate pellet is at uniform temperature and pressure within hydrate stable region. The pressure starts to decrease with a fixed rate down to the final pressure and is kept constant afterwards while the bounding surface of pellet is heated by convection. The predicted convective heat and mass transfer accompanied by the decomposed gas flow through hydrate/ice solid matrix is reported focused on the comparison of spherical and cylindrical pellets having the same effective radius.

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A Low-Reynolds-Number 4-Equation Model for Turbulent Separated and Reattaching Flows (난류박리 및 재부착 유동의 해석을 위한 저레이놀즈수 4-방정식 난류모형의 개발)

  • 이광훈;성형진
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.8
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    • pp.2039-2050
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    • 1995
  • The nonlinear low-Reynolds-number k..epsilon. model of park and Sung is extended to predict the turbulent heat transports in separated and reattaching flows. The equations of the temperature variance( $k_{\theta}$ and its dissipation rate(.epsilon.$_{\theta}$ are solved, in concert with the equations of the turbulent kinetic energy(k) and its dissiation rate(.epsilon). In the present model, the near-wall effect and the non-equilibrium effect are fully taken into consideration. The validation of the model is then applied to the turbulent flow behind a backward-facing step and the flow over a blunt body. The predicted results of the present model are compared and evaluated with the relevant experiments.