• 한국전산유체공학회지
• /
• 제19권2호
• /
• pp.49-57
• /
• 2014

In the present study, 2-D gas-kinetic flow solver on unstructured meshes was developed for flows from continuum to transitional regimes. The gas-kinetic BGK scheme is based on numerical solutions of the BGK simplification of the Boltzmann transport equation. In the initial reconstruction, the unstructured version of the linear interpolation is applied to compute left and right states along a cell interface. In the gas evolution step, the numerical fluxes are computed from the evaluation of the time-dependent gas distribution function around a cell interface. Two-dimensional compressible flow calculations were performed to verify the accuracy and robustness of the current gas-kinetic approach. Gas-kinetic BGK scheme was successfully applied to two-dimensional steady and unsteady flow simulations with strong contact discontinuities. Exemplary hypersonic viscous simulations have been conducted to analyze the performances of the gas-kinetic scheme. The computed results show fair agreement with other standard particle-based approaches for both continuum part and transitional part.

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 2000년도 추계학술발표대회 논문집
• /
• pp.38-41
• /
• 2000

High temperature cure characteristics of polyester resin systems were investigated by isothermal and dynamic differential scanning calorimetries. During isothermal scanning, the experimental procedure was modified to reduce the initial Boss of heat. no kinetic equation from the isothermal experiment was compared with that from the dynamic experiment.

• 대한화학회지
• /
• 제65권6호
• /
• pp.419-432
• /
• 2021

According to the transition state (TS) theory, Gaussian software and Yao and Lin (YL) method, the thermodynamics and kinetic data respectively were calculated, and anharmonic effect was considered for related reactions of NO₃. The methods of calculating and fitting kinetic and thermodynamics parameters were provided by least square method and related equations in this paper. Notably, the fitted E of Arrhenius equation was close to the calculated barrier of related reaction by QCISD(T) method. Therefore, the kinetic fitting result can well express the physical meaning of E in Arrhenius equation. Besides, the conversion process and the reaction mechanism of NO₃ were researched. For NO₃, it seemed that its instability results from its easy reaction with other substances rather than the decompose reaction of itself.

• Bulletin of the Korean Chemical Society
• /
• 제18권2호
• /
• pp.171-174
• /
• 1997

The initial kinetic energy of laser-ablated Zn cation has been investigated via time-of-flight mass spectrometry. The flight times of the ions have been measured with a high voltage pulse on the extract electrode in the mass spectrometer, which has been delayed from the laser pulse. The time-of-flight equation including the initial kinetic energy term of the ion has been derived for the mass spectrometer. The optimum value of the initial kinetic energy has been extracted by fitting the measured flight times into the time-of-flight equation. The initial kinetic energy of the ions generated by Nd:YAG laser (532 nm) at the power density of 5 × 107 W/cm2 has been determined to be 22-44 kJ/mol.

• 대한기계학회논문집
• /
• 제7권4호
• /
• pp.451-460
• /
• 1983

Computational four-equation turbulence model is developed and is applied to predict twodimensional unsteady thermal surface discharge into a reservoir. Turbulent stresses and heat fluxes in the momentum and energy equations are determined from transport equations for the turbulent kinetic energy (R), isotropic rate of kinetic energy dissipation (.epsilon.), mean square temperature variance (theta. over bar $^{2}$), and rate of destruction of the temperature variance (.epsilon. $_{\theta}$). Computational results by four-equation model are favorably compared with those obtained by an extended two-equation model. Added advantage of the four-equation model is that it yields quantitative information about the ratio between the velocity time scale and the thermal time scale and more detailed information about turbulent structure. Predicted time scale ratio is within experimental observations by others. Although the mean velocity and temperature fields are similarly predicted by both models, it is found that the four-equation model is preferably candidate for prediction of highly buoyant turbulent flows.

• 한국미생물·생명공학회지
• /
• 제23권4호
• /
• pp.425-431
• /
• 1995

A kinetic model of the cyclodextrin formation in a heterogeneous enzyme reaction system using swollen extrusion starch as substrate was derived emphasing the structural features of extrusion starch. The degree of gelatinization, the ratio of accessible and inaccessible portion of extrusion starch, adsorption of CGTase on swollen starch, the structural transformation during reaction, and product inhibition caused by produced CDs were considered in deriving kinetic model. Various kinetic constants were also evaluated. The derived kinetic equation was numerically simulated, which result showed that the derived kinetic equations can be used to predict the experimental data reasonably well under the various experimental conditions. Kinetic model can be utilized for the optimization of enzyme reactor and the process development for CD production from swollen extrusion starch.

• 대한수학회논문집
• /
• 제22권1호
• /
• pp.145-155
• /
• 2007

In this paper, we show the convergence of approximate solutions to the convective porous media equation using methodology developed in [8]. First, we obtain the approximate transport equation for the given convective porous media equation. Then using the averaging lemma, we obtain the convergence.

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
• /
• pp.219-222
• /
• 2004

Removal characteristics of Mn and Co was studied from the contaminated solutions via surface reaction with various calcium carbonate (calcite). Synthetic calcium carbonates which has different surface morphology as well as surface areas were prepared by a spontaneous precipitation method and used. Mn and Co removal behavior by the different solid surface demonstrate characteristic sorption behaviors depend on the type of calcite used, such as surface area or surface morphology. Calcium carbonate crystals (mostly calcite) which exhibit complicated surface morphology (c-type) shows strong sorption affinity for Mn and Co removal via sorption than on the a-type or b-type calcite crystals of less complicated surfaces. The applicability of two kinetic models, the pseudo-first-order kinetic equation and the Elovich kinetic model was examined on these sorption behavior. Elovich kinetic model was found more suitable to explain the very early stage adsorption kinetics, while the pseudo-first-order kinetic equation was successfully fitted for the adsorption kinetics after 50 hours.

• 한국세라믹학회지
• /
• 제31권12호
• /
• pp.1545-1551
• /
• 1994

Various kinetic parameters of the nucleation and crystallization in anorthite glass (CaO.Al2O3.2SiO2) were calculated by nonisothermal differential thermal analysis. Base glass and glass with TiO2 were prepared by melting. In base glass, the temperature where nucleation can occur ranges from 85$0^{\circ}C$ to 9$25^{\circ}C$ and the temperature for maximum nucleation was 900$\pm$5$^{\circ}C$. In glass with TiO2, the nucleation temperature range was 800~875$^{\circ}C$ and the maximum nucleation temperature was 850$\pm$5$^{\circ}C$. Kissinger equation, Bansal equation, and modified Ozawa equation were used for calculating activation energy for crystallization, Ec. The results showed the same activation energies for both glasses with and without TiO2 in the different equations. The shape of maximum exotherm peak and Ozawa equation were used for Avrami exponent, n. The n value for each glass was 2, indicating that each glass crystallized primarily by bulk crystallization.

• 한국전자통신학회논문지
• /
• 제14권4호
• /
• pp.743-754
• /
• 2019

지표면 침식 잠재력은 비가 내린 영향으로 토양에 전달 된 운동 에너지로 평가할 수 있다. 충격 신호를 분석할 수 있는 디즈드로미터로 우적 에너지율 관계식을 산출하였다. 대륙 강수의 97%와 해양 강수의 95%가 강우량과 강우율의 관계로 이루어진 이 지수 방정식으로 설명되었다. 이 관계식의 지수는 강우 유형에 의존하지 않지만 계수는 강우 사건에 따라 조정될 수 있는 변동을 나타냈다. 이 관계식은 결정 계수, 평균 절대 오차 및 신뢰 오차에 의해 검증되었다. 특정 유형의 토양과 관련된 강수의 운동 에너지는 강우로 인한 침식의 가능성을 결정할 수 있다.