• 한국미생물·생명공학회지
• /
• 제28권1호
• /
• pp.26-32
• /
• 2000

Electrostatic forces contribute to the high degree of enzyme transition state complementarity in enzyme catalyzed reaction and such forces are modified by the solvent through its dielectric constant and polar properties. The contributions of electrostatic interaction to the formation of ES complex and the stabilization of transition state of the trypsin catalyzed reaction were probed by kinetic studied with high pressure and solvent dielectric constant. A good correlation has been observed between the increase of catalytic efficiency of trypsin and the decrease of solvent dielectric constant. Activation volume linearly decreased as the dielectric constant of solvent decreased, which means the increase in the reaction rae. Moreover, the decrease of activation volume by lowering the solvent dielectric constant implies a solvent penetration of the active with and a reduction of electrostatic energy for the formation of dipole of the active site oxyanion hole. When the 야electric constant of the solvents was lowered to 4.7 unit, the loss of activation energy and that of free energy of activation were 2.262 KJ/mol and 3.169 KJ/mol, respectively. The results of this study indicate that the high pressure kinetics combined with solvent effects can provide unique information on enzyme reaction mechanisms, and the controlling the solvent dielectric constant can stabilize the transition state of the trypsin-catalyzed reaction.

• 대한기계학회논문집A
• /
• 제37권7호
• /
• pp.929-935
• /
• 2013

본 논문은 사각 보강 패널에 사용되는 모자형 보강재의 크기 최적화에 대한 결과를 제시하였다. 보강 패널은 1500 ~ 2500 m/s 의 속도를 가지는 발사체와 충돌한다. 모자형 보강재의 크기를 결정하기 위해서 크기 최적화가 수행되었다. 크기 최적화를 수행하기 위해서는 3 개의 함수들로 구성되어 있다. 이 함수들은 목적함수, 제한함수 그리고 설계 함수로 이루어져 있다. 목적 함수는 보강 패널의 1 차 고유 진동수의 최대화가 되도록 하는 것이다. 제함 함수는 보강재의 부피가 사각 패널 부피의 10 % 이내가 되도록 하는 것이며, 설계 변수로는 모자형 보강재의 치수가 된다. 최적화된 모자형 보강재를 이용하한 보강 패널을 사용하여 초고속 충돌에 대한 시뮬레이션을 수행하였으며, 최적화된 보강재에 대해서 속도와 운동 에너지 변화에 대한 결과를 얻었다. 보강 패널의 충돌 저감을 평가하기 위해서 발사체의 운동 에너지와 속도를 무차원화 계산을 수행하여 비교 분석 하였다.

• 한국추진공학회지
• /
• 제9권2호
• /
• pp.97-104
• /
• 2005

많은 장점에도 불구하고 유동함수를 이용한 수치해석용 격자생성 좌표변환기법의 단점은 저속영역에서의 격자간격이 고속영역에 비해 상대적으로 큼에 따라 수치적 처리에 많은 오차를 내포하고 있다는 점이다. 본 연구에서는 이러한 저속영역에서의 단점을 보완하기 위하여 격자간격을 속도크기 및 영역에 따라 적절히 조절할 수 있도록 수학적으로 변형된 압축성 유동함수를 이용한 좌표변환기법을 제안하고 가스터빈엔진에 주로 적용되는 유동모델로서 동심원상 두개 이상의 난류제트혼합유동에 대해 적용하였으며 해당 실험치, 즉 축 방향 평균속도분포, 난류운동에너지, 그리고 난류전단응력분포와 비교하여 난류운동에너지가 약간 과소평가 된 대칭축을 제외한 혼합경계층 내에서 $3.5\%$ 이내의 신뢰성을 확보하였다. 본 기법은 특히 터보팬엔진에 대한 내부흐름들의 혼합유동을 규명하거나 또는 난류전단응력에 의한 제트소음발생 및 저감방법을 도모하는데 유용하게 활용될 것으로 기대된다.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2008년도 추계학술대회A
• /
• pp.581-584
• /
• 2008

At the inlet and outlet differential pressure and The fluid velocity over 32m/s are damaged (Plug, sheet ring, trim) About reduction trim parts of the control valve. AOV of the differential pressure 1,500psi become often the damage in the nuclear power plant. Damages of AOV studied CFD analysis and improvement program. Multi-stage trim designs which decrease a fluid kinetic energy are demanded and AOV parts are demanded case hardening and material change.

• 충청수학회지
• /
• 제24권2호
• /
• pp.267-271
• /
• 2011

Let 0 < s < 1. For $f^{\ast}$ representing the symmetric radial decreasing rearrangement of f, we build up a fractional version of Polya-$Szeg{\ddot{o}}$ inequality: $${\int}_{\mathbb{R}^n}{\mid}(-\Delta)^{s/2}f^{\ast}(x){\mid}^2dx{\leq}{\int}_{\mathbb{R}^n}{\mid}(-\Delta)^{s/2}f(x){\mid}^2dx$$.

• 한국분무공학회지
• /
• 제19권2호
• /
• pp.75-81
• /
• 2014

Swirl flow in the gun type burner has a decisive effect on the stabilization of the flame, improvement of the combustion efficiency, and also a reduction of NOx. This swirl flow is created by the spinner which is inside the airtube that guide the combustion air. Gun type burner has generally the inner devices composed nozzle adapter, spark gap ignitor, and spinner. These inner components change the air flow behavior passing through air tube. Meanwhile, turbulent characteristics of this air flow are important to understand the combustion phenomena in the gun type burner, because the mixture of fuel and air are depended on. However, nearly all of the studies have been analyzed the turbulent flow of simplified combustion formation without the inner devices. So, this study conducted the measurement using by hot-wire anemometer and analyzed turbulent flow characteristics of the swirl flow discharged from the air tube with inner devices. Turbulence characteristics come up in this study were turbulence intensity, kinetic energy and shear stress of the air flow with the change of the distance of axial direction from the exit of the air tube.

• 한국자동차공학회논문집
• /
• 제14권3호
• /
• pp.125-132
• /
• 2006

Transient kinetics of $NH_3$ adsorption/desorption and of SCR(selective catalytic reduction) of NO with $NH_3$ were studied over vanadium based catalysts, such as $V_2O_5/TiO_2$ and $V_2O_5-WO_3/TiO_2$. In the present catalytic reaction process, NO adsorption is neglected while $NH_3$ is strongly chemisorbed on the catalytic surface. Accordingly, it is ruled out the possibility of a reaction between strongly adsorbed $NH_3$ and NO species in line with the hypothesis of an Eley-Rideal mechanism. The present kinetic model assumes; (1) non-activated $NH_3$ adsorption, (2) Temkin-type $NH_3$ coverage dependence of the desorption energy, (3) non-linear dependence of the SCR reaction rate on the $NH_3$ surface coverage. Thus, the surface heterogeneity for adsorption/desorption of $NH_3$ is taken into account in this model. The present study extends the pure chemical kinetic model based on a powdered-phase catalytic system to the chemico-physical one applicable to a realistic monolith reactor.

• 대한금속재료학회지
• /
• 제49권1호
• /
• pp.52-57
• /
• 2011

Nickel ferrite ($NiFe_2O_4$) powder was prepared through the ceramic route by calcination of a stoichiometric mixture of nickel oxide (NiO) and iron oxide ($Fe_2O_3$). The pressed pellets of $NiFe_2O_4$ were isothermally reduced in pure hydrogen at 800, 900, 1000 and $1100^{\circ}C$. Based on thermogravimetric analysis, the reduction behavior and the kinetic reaction mechanisms of the synthesized ferrite were studied. The initial ferrite powder and various reduction products were characterized by XRD, SEM, reflected light microscope and VSM to reveal the effect of hydrogen reduction on the composition, microstructure, magnetic properties and reaction kinetics of the produced Fe-Ni alloy. Complete reduction of the $NiFe_2O_4$ was achieved with synthesis of homogeneous nanocrystalline Fe-Ni alloys. Arrhenius equation with the approved mathematical formulations for a gas-solid reaction was applied for calculating the activation energy ($E_a$) values and detecting the controlling reaction mechanism.

• 한국안전학회지
• /
• 제14권4호
• /
• pp.3-12
• /
• 1999

This research concentrates on the influence of non-linearities associated with impact for the nonlinear rocking behavior of rigid block subjected to one dimensional sinusoidal excitation of horizontal direction. The transition of two governing rocking equations, the abrupt reduction in the kinetic energy associated with impact, and sliding motion of block. In this study, two type of rocking vibration system are considered. One is the undamped rocking vibration system, disregarding energy dissipation at impact and the other is the damped rocking system, including energy dissipation and sliding motion. The response analysis using non-dimensional rocking equation is carried out for the change of excitation parameters and friction coefficient. The chaos responses were discovered in the wide response region, particularly, for the case of high excitation amplitude and their chaos characteristics were examined by the time history, Poincare map, power spectra and Lyapunov Exponent of rocking responses. The complex behavior of chaos response, in the phase space, were illustrated by Poincare map. The bifurcation diagram and Poincare map were shown to be effective in order to understand chaos of rocking system.

• 한국공작기계학회:학술대회논문집
• /
• 한국공작기계학회 2001년도 추계학술대회(한국공작기계학회)
• /
• pp.363-368
• /
• 2001

Studies on brake system recently are focused on braking performance, especially the consideration on safety of braking system in an extreme situation and reduction of vibration and noise during braking operation. The thermal crack and Judder from the friction between brake disc and pad can bring the threaten of passengers' safety in the end. Braking force comes from the change of kinetic energy to friction energy. Since heat energy is developed from here, the analysis on thermal stress and thermal strain can be the good data when selecting the material of brake pad and designing heat radiation holes on the disc and it will also be the data when designing the thickness of the disc. This paper is intended to show a creative design method by suggesting the thermal analysis data through FEM study and using shape design parameters.