• Title/Summary/Keyword: iron reduction

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Study on Characteristics of Change of Urea and Biuret Content by Temperature Variation in Urea Solution (요소수(Urea solution)의 온도변화에 따른 요소 및 뷰렛함량 변화 특성 연구)

  • Doe, Jin-woo;Park, Tae-sung;Lee, Yu-rim;Yim, Eui-soon;Lee, Joung-min;Kang, Hyung-kyu
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1307-1319
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    • 2018
  • As interests in the air pollution increases, many kinds of researches are underway on the reduction of air pollutants. The removal of nitrogen oxides from the emission gas of diesel vehicles using urea solution has shown a great effect. The quality of urea solution is strictly defined by domestic law, but the increase of impurities in urea solution reduces the effect of reducing nitrogen oxides. Therefore, in this study, the change of physical properties of urea solution was analyzed after heating the urea solution for a certain temperature and time. Also, the changes of physical properties of urea solution were analyzed according to kinds of storage container and temperature for storing the urea solution. After heating the urea solution for a certain period of time, the biuret content in urea solution increased and the content of urea decreased. As the urea content decreased, both density and refractive index decreased. In the storage stability test carried out at a constant temperature with iron and PET containers, no change in physical properties was observed.

Development of jigs for planar measurement with DIC and determination of magnesium material properties using jigs (마그네슘 합금 판재의 평면 DIC 측정을 위한 지그 개발과 이를 활용한 단축 변형 특성 분석)

  • Kang, Jeong-Eun;Yoo, Ji-Yoon;Choi, In-Kyu;YU, Jae Hyeong;Lee, Chang-Whan
    • Design & Manufacturing
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    • v.15 no.2
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    • pp.23-29
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    • 2021
  • The specific strength of magnesium alloy is four times that of iron and 1.5 times that of aluminum. For this reason, its use is increasing in the transportation industry which is promoting weight reduction. At room temperature, magnesium alloy has low formability due to Hexagonal closed packed (HCP) structure with relatively little slip plane. However, as the molding temperature increases, the formability of the magnesium alloy is greatly improved due to the activation of other additional slip systems, and the flow stress and elongation vary greatly depending on the temperature. In addition, magnesium alloys exhibit asymmetrical behavior, which is different from tensile and compression behavior. In this study, a jig was developed that can measure the plane deformation behavior on the surface of a material in tensile and compression tests of magnesium alloys in warm temperature. A jig was designed to prevent buckling occurring in the compression test by applying a certain pressure to apply it to the tensile and compression tests. And the tensile and compressive behavior of magnesium at each temperature was investigated with the developed jig and DIC equipment. In each experiment, the strain rate condition was set to a quasi-static strain rate of 0.01/s. The transformation temperature is room temperature, 100℃. 150℃, 200℃, 250℃. As a result of the experiment, the flow stress tended to decrease as the temperature increased. The maximum stress decreased by 60% at 250 degrees compared to room temperature. Particularly, work softening occurred above 150 degrees, which is the recrystallization temperature of the magnesium alloy. The elongation also tended to increase as the deformation temperature increased and increased by 60% at 250 degrees compared to room temperature. In the compression experiment, it was confirmed that the maximum stress decreased as the temperature increased.

Optimization of Briquette Manufacturing Conditions Using Steel Sludge (제강슬러지를 이용한 브리켓 제조 조건 최적화 연구)

  • Lee, Dong Soo;Chae, Hui Gwon;Park, Tae Jun
    • Resources Recycling
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    • v.31 no.4
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    • pp.12-18
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    • 2022
  • Korea depends on the import of raw materials such as iron ore and coal for the steel industry. These raw materials have a major impact on the cost, productivity, and quality competitiveness in the global steel industry. To secure the competitiveness of steel companies, it is necessary to reduce the country's dependence on raw materials. This can be achieved using byproducts with a high Fe content, which are primarily generated by the steel industry. These byproducts are available in the form of a very fine powder, which can disperse as dust when used directly in plant processes. Dust dispersion has a negative impact on the environment and can lead to the loss of raw materials. To enable the use of a wide range of Fe-containing byproducts, it is necessary to pretreat them in the form of larger aggregates such as pellets and briquettes. There are several methods to achieve such aggregates. There are two ways to produce briquettes: using a hot briquette, which supplies additional heat to produce briquettes, or using a cold briquette, which does not use heat. A method for producing cold briquettes using Fe-containing byproducts was investigated in this study. The yield ratio and briquette strength were examined under various manufacturing conditions.

Stabilization Mechanisms of Powdered and Bead Type Stabilizer Made of Mg-Fe Layered Double Hydroxide (LDH) for the Arsenic Contaminated Soil (Mg-Fe 이중층수산화물로 제조한 분말상과 입상 안정화제의 비소 오염토양 안정화 기작)

  • Kim, Seonhee;Kim, Kyeongtae;Oh, Yuna;Han, Yikyeong;Lee, Minhee
    • Journal of Soil and Groundwater Environment
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    • v.27 no.4
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    • pp.49-62
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    • 2022
  • The magnesium and iron-based layered double hydroxide (Mg-Fe LDH) was synthesized by the co-precipitation process and the bead type LDH (BLDH, 5~6 mm in diameter) was manufactured by using the Mg-Fe LDH and the starch as a binder. To evaluate the feasibility of the BLDH as the As stabilizer in the soil, various experiments were performed and the As stabilization efficiency of the BLDH was compared to that of powdered type LDH (PLDH, <149 ㎛ in diameter). For the As sorption batch experiment, the As sorption efficiency of both of the PLDH and the BLDH showed higher than 99%. For the stabilization experiment with soil, the As extraction reducing efficiency of the PLDH was higher than 87%, and for the BLDH, it was higher than 80%, suggesting that the BLDH has similar the feasibility of As stabilization for the contaminated soil, compared to the PLDH. From the continuous column experiments, when more than 7% BLDH was added into the soil, the As stabilization efficiency of the column maintained at over 91% for 7 pore volume flushing (simulating about 21 months of rainfall) and slowly decreased down to 64% after that time (to 36 months) under the non-equilibrium conditions. Results suggested that more than 7% of BLDH added in As-contaminated soil could be enough to stabilize As in soil for a long time. The main As fixation mechanisms on the LDH were also identified through the X-ray fluorescence (XRF), the X-ray diffraction (XRD), and the Fourier transform infrared (FT-IR) analyses. Results showed that the LDH has enough of an external surface adsorption capacity and an anion exchange capability at the interlayer spaces. Results of SEM/EDS and BET analyses also supported that the Mg-Fe LDH used in this study has sufficient porous structures and outer surfaces to fix the As. The reduction of carbonate (CO32-) and sulfate (SO42-) anions in the LDH after the reaction between As and the LDH was observed through the FT-IR, the XRF, and the XRD analyses, suggesting that the exchange of some of these anions with the arsenate (H2AsO4- or HAsO42-) occurs at the LDH interlayers during the stabilization process in soil.

A Study on the Co-branding Determine FactorsBetween Franchise Restaurant and Hotel F&B Department in Korea (프랜차이즈 레스토랑과 국내 호텔 식음료부문 브랜드제휴 결정요인에 관한 연구)

  • Choo, Seung Woo;Lee, Sang Youn
    • The Korean Journal of Franchise Management
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    • v.2 no.1
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    • pp.134-151
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    • 2011
  • The strategy for brand alliance is a new type of franchise to iron out the problems like the hotel restaurant's structural contradiction and decreasing profits caused by keen competition with external restaurants. This study is purposed to present the decisive factors for the brand alliance throughexamining the correlations between the brand restaurant designation standards and the expected effects from local low- and mid-priced hotel's brand alliance. The questionnaires were distributed to instructors and professors who have experience in teaching the food and beverage sections at college's hotel and tourism departments and 100 specialists at managerial level of a hotel's food and beverage parts.This survey was conducted for 20 days from December 2 to 22, 2004 and analyzed by independent t-test and canonical correlation analysis. The findings of this survey are as follows.Firstly, the service of the expected effect factors of the brand alliance was recognized relatively high by the specialists in hotel industry, while the sales effect factor of restaurant designation standards was recognized higher by the academic experts.The specialists of the hotel industry recognized the factors of menu and corporate culture higher than the academic experts. Secondly, the entire factors of the brand restaurant designation standards showed a correlation with the whole factors of the restaurant designation standards.In particular, the 'menu' factor presented the most influential to the expected effects of brand alliance.The factors of 'risk reduction' and 'synergy effect' exerted the strongest effect on the restaurant designation standards, which indicated the mutual correlation between the expected effect of brand alliance and the restaurant designation standards. Based on this study, the correlation between the expected effect of brand alliance and brand restaurant designation standards may play a primary role to choose a partner for the brand alliance, a decisive factor for the success.The execution of the brand alliance or the method to designate the alliance partner may vary from the hotel's desirable effects when the brand alliance is determined.In other words, the partner designation standards should be corresponding to the expected effects from the brand alliance between hotel and brand restaurant, and the academic and industrial experts' perceived differences in the expected effects of brand alliance and restaurant designation standards should be clarified to display the direction of decision-making and find the potential risks.

An Alysisan Experimental Study on the Evaluation Method of Clay Mineral Content through Aggregate Composition Analysis (골재의 성분분석을 통한 토분함량 평가방법에 관한 실험적 연구)

  • Kim, In;Han, Min-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.24 no.5
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    • pp.565-575
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    • 2024
  • This research was initiated to establish quality standards and testing methods for fine dust in aggregates, a component currently not regulated under the Korean Industrial Standards(KS) KS F 2527 for Concrete Aggregates. With limited existing research and no definitive quality or testing standards for fine dust, this study sought to provide a quantitative analysis of fine dust in aggregates and to set forth quality standards based on the dust content through a concrete performance evaluation. The experimental findings showed that the primary chemical constituents of the fine dust were aluminum oxide(Al2O3), iron oxide(Fe2O3), and silicon dioxide(SiO2). It was observed that increasing levels of fine dust in the aggregates led to higher values of the fine dust index(Al2O3+Fe2O3). This escalation in the fine dust index corresponded with an increase in the unit water content of the concrete and a consequent decline in compressive strength. Based on these observations, a maximum allowable limit for the fine dust index in aggregates was proposed at 23%. This limit was derived from the correlation between fine dust content and a 15% reduction in compressive strength of standard concrete specimens. The proposed evaluation method for the fine dust index based on its content in aggregates is expected to enhance concrete performance and ensure structural stability. This contribution to the field addresses a significant gap in the standards and provides a foundation for further research and standardization in the construction materials industry.

AGE AT MARRIAGE AND FERTILITY OF WOMEN IN THREE SELECTED AREAS IN KOREA, 1970 (한국 3개 지역의 결혼, 결혼년령 및 출산력에 관한 연구)

  • 김모임
    • Journal of Korean Academy of Nursing
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    • v.3 no.3
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    • pp.1-14
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    • 1973
  • This study is designed to meet the following objectives: (1) To study attitude and behavior regarding marriage and age at marriage, (2) To learn correlates of age at marriage and to examine their relations, (3) To measure relative importance of the correlates of age at marriage, and (4) To study relations of age at marriage and family planning practice to fertility and their relative importance as correlates of fertility. The data are obtained by an independent cross-sectional survey in three study areas purposively selected to represent metropolitan. semihuman. rural population. The study population is confined to women age 17-50 as of survey. The overall response rate is 90%. Reliability of data is measured by . individual and aggregate inconsistency based upon a 15% subsample of the original interviews. The individual inconsistency (31%) is found to be high compared to the aggregate inconsistency (6%) for all 85 variables. However, the magnitude of differences between means is small, and the mean absolute shifts and proportional shifts are also small on the whole. In a word respondents did not change their answers too extremely or radically. The study populations of each study area are compared on some basic characteristics. It is found that the three study populations have more dissimilarities than similarities. The findings on seven different attitudinal positions of women toward marriage indicate that there have been tremendous changes in all study areas Iron "traditional" attitudes which have been prevalent for a long time in Korean society to "liberalized" or "modernized" attitudes. An apparent tendency is that women generally take a position of a "golden mean" attitude by not preferring either extreme of marriage attitudes. Nevertheless, the young, single, educated, and urbanite appears more "liberalized. " There has been some increase in ideal age at marriage from 1958 to 1970 for both sexes. No age group, marital status, or study area differentials in ideal age at marriage are found, the average ideal age at marriage in every sub-group being 24-25. Awareness of existing legal marriageable ages is low; only 4.4% are aware that "with parental permission: minimum age for males is 18 years and for females 16 years,"and only 3.7% are aware that "without parental permission: 27 years for males and 23 years for females." People in Korra tend to marry spouses who are in various social ways like themselves: the similarities include (a) education, occupational status of father, (c) economic status, (d) usual residence before marriage, and (e) religion. Both singulars and actual mean ages at marriage in this study confirm the trend of rising age at marriage previously established by other independent studies. The urban-rural differential in age at marriage is observed, but the differential narrows down gradually from 1935 to 1970. All socio-economic, demographic, and other variables pertaining to wife before and at first marriage, excluding (a) religion, (b) father′s of occupation, and (c) as: of menarche, are correlated with respondent's age at first marriage, whereas only three variables out of all socio-economic variables relating to husband before and at wife′s first marriage, viz., (a) education, (b) usual residence, and (c) economic level of his old home, are correlated with respondent′s age at marriage. Among socio-economic and modernity variables related to either husband or wife at the time of survey, only education and duration of residence are correlated with wife′s age at first marriage. Among the correlates of respondent′age at first marriage, education is in general the most important variable. However, it is found that wife′s education is more important than husband′s. The combined effects or the correlates studied explain no more than about 40% of variance for any of the selected groups of variables. Points which might counteract the effects of late marriage on fertility are not serious in Korea. For each of the correlates of the three fertility indices chosen for this study. namely, (a) number of living children, (b) number of live births, and (c) number of pregnancies, age at marriage is the major contributor to the variance in all age groups except the age group of 20-29 in which the index of family planning practice is the major contributor. The proportion of variability in fertility indices accounted for by the correlates is never more than 40% of the total variance in any age group. Based upon the findings from this study, it could be concluded that in the foreseeable future (a) celibate group will no! be increased to a point that would slow down population growth rate in Korea, (b) age at marriage will not increase continually, (c) although education stands out as the major contributing variable which independently explains the variation in age at marriage, it seems probable that education may not be the major variable in the near future, and (d) despite the fact found by this study that age at marriages has been the major contributor to the variance of each of the fertility indices used, family planning practice will play a more important role in the reduction of fertility in the Korean society. Therefore, factors interrupting practice of family planning must be eliminated and family planning program should be strengthened if further fertility reduction is needed.

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Effect of Nitrification Inhibition on Soil Phosphate Release and Nutrient Absorption and Growth of Rice Plant (질산화작용 억제 처리가 논토양의 인산 가용화와 벼의 양분흡수 및 생육에 미치는 영향)

  • Chung, Jong-Bae;Kim, Byoung-Ho
    • Korean Journal of Environmental Agriculture
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    • v.29 no.4
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    • pp.336-342
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    • 2010
  • In a pot experiment, we studied the effect of nitrification inhibition on Fe reduction and P release in paddy soil and growth and nutrient uptake of rice plant. Recommended level of fertilizers, 6 kg N, 5 kg $P_2O_5$ and 4 kg $K_2O$ per 10a, were applied, and for N fertilizer urea, urea+N-serve, and $KNO_3$ were included. Four 30-day-old seedlings were transplanted in a waterlogged 9 L pot filled with Yuga series soil, and 3 pots were prepared in each N fertilizer treatment. Changes of soil redox potential and concentration of ${NH_4}^-$, ${NO_3}^-$, $Fe^{2+}$ and ${PO_4}^{3-}$ in soil solution at 10 cm depth were monitored, and also the growth and nutrient uptake of rice plants were measured. Concentration of ${NH_4}^+$ in soil solution was highest in urea+N-serve treatment, and followed by urea and $KNO_3$ treatments. Addition of N-serve could effectively inhibit nitrification in the soil. In the treatment of $KNO_3$, relatively higher ${NO_3}^-$ concentration was found at 10 cm depth soil. In urea+N-serve treatment redox potential was lower than -100 mV during the experiment, but in the treatment of $KNO_3$ the potential was maintained above 0 mV until ${NO_3}^-$ remaining in soil solution. Reduction of Fe(III) and solubilization of P were highly correlated with redox potential changes in the three N fertilizer treatments. Concentrations of Fe(II) and ${PO_4}^{3-}$ in soil solution at 10 cm depth were much higher in the urea+N-serve treatment. The most vigorous rice seedling growth was found in the urea treatment. Although the availability of N and P in soil was enhanced in the urea+N-serve treatment through the suppression of nitrification, excessive solubilization of Fe could limit the growth of rice plants.

Comparison of the Effectiveness of Dietary Intervention between Calorie Restriction Diet and Food Selective Method according to Yin and Yang Constitution in Obese Woman (열량제한식과 체질식에 따른 비만 여성의 체중감량 효과)

  • Sim, Seon-Ha;Hur, Bons-Soo;Hong, Kyung Hee
    • The Korean Journal of Food And Nutrition
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    • v.28 no.2
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    • pp.302-312
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    • 2015
  • This study was conducted to evaluate the effects of constitutional diets in comparison with general low calorie diets in obese women. The subjects were 52 adult obese women that participated in a calorie restriction diet program (control group, n=16) or a constitutional diet program (experimental group, n=36) for 8 weeks. The subjects in the experimental group were classified as negative (Yin) or positive (Yang) constitution. The obesity management program focused on the calorie restriction diet (300~400 kcal reduction per day) for the control group, whereas, for a constitutional diet without calorie restrictions was allowed for the experimental group. Daily intakes of nutrient and food were assessed using a 24 hr recall method. Body measurements and blood biochemical parameters were measured at baseline and after 8 weeks. After the intervention, weight, body fat, BMI, waist circumference and hip circumference decreased significantly in both the control and experimental group. Energy intake increased from 1,679.6 kcal to 1,810.6 kcal along with significant increase in protein, carbohydrate, fiber, calcium, phosphorus, iron, zinc, vitamin A, vitamin $B_1$, vitamin $B_2$, niacin and vitamin C in the experimental group. Calcium intake increased from 54.0% to 72.4% of DRI in the experimental group. Hemoglobin concentrations were significantly decreased in the control group, but were increased in the experimental group. In addition, blood glucose, serum total cholesterol and triglyceride were significantly decreased in the experimental group. In conclusion, consumption of a constitutional diet without calorie restrictions for 8 weeks was effective for weight reduction with improvement of blood glucose, serum cholesterol and triglyceride.

The Effect of Lime and Wollastonite on an Acid Sulfate Soil (특이산성토에 대한 석회 및 규회석의 효과)

  • Park, Nae Joung;Park, Young Sun;Lee, Kyu Ha;Kim, Yung Sup
    • Korean Journal of Soil Science and Fertilizer
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    • v.5 no.1
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    • pp.25-32
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    • 1972
  • The effects of limestone and wollastonite on an acid sulfate soil were studied. In addition, the effect of wollastonite was analyzed in terms of those due to calcium and to silica in the paddy field and in the laboratory with equivalent amounts of lime and wollastonite on a calcium basis. 1. Lime and wollastonite as liming materials were equally effective in neutralizing the soil acidity. 2. Lime, however was more reactive, raising the pH up to neutralization point in three days under waterlogged conditions at $25^{\circ}C$, in the lab study, and introduced alkali damage to transplanted rice seedlings showing marked restrictions of tillering in the field even though lime was applied two weeks before transplanting. On the other hand, wollastonite reacted very slowly, taking one week to two weeks to reach neutralization even when thoroughly mixed, and did not restrict the tillering. 3. Both lime and wollastonite effectively reduced the toxic aluminium in soil as well as in the soil solution but not always in the case of ferrous iron. However the reduction effect of the toxic substances in the experimental field was not so great as expected, because typical toxic symptoms were mild only. 4. Lime considerably increased the availability of silica in soil resulting in an increase of silica content in straw. Wollastonite released extra available silica itself resulting in a greater uptake of silica. 5. Increase of silica uptake by these materials was effective in reducing rate of infection of neck blast and resulted in higher rate of ripening, and in turn increased the paddy yield. 6. Application of either one significantly diminished the effect of the other. 7. Wollastonite markedly increased tillering in the early growing stage, but decreased the rate of effective tillers finally, resulting in about the same number of ears per hill at harvesting. 8. These liming materials appear to increase the number of grains per panicle slightly.

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