• Title/Summary/Keyword: iron parameter

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Prediction Model of the Exit Cross Sectional Shape of Workpiece in Round-Oval-Round Pass Rolling

  • Lee, Youngseog;Kim, Byung-Min;Kim, Dong-Hwan
    • Journal of Mechanical Science and Technology
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    • v.16 no.6
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    • pp.785-798
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    • 2002
  • A reliable analytic model that predicts the surface profile of the exit cross section of workpiece in round-oval (or oval-round) pass sequence is established. The presented model does not require any plasticity theory but needs the only geometric information on workpiece and roll groove. Formulation is based on the linear interpolation of the radius of curvature of an incoming workpiece and that of roll groove in the roll axis direction when the maximum spread of workpiece is known beforehand. The validity of the analytic model is examined by hot rod rolling experiment with the roll gap, specimen size, design parameter of oval groove and steel grade changed. Results revealed that the cross sectional shapes predicted by the model were in good agreement with those obtained experimentally. We found that the analytic model not only has simplicity and accuracy for practical usage but also saves a large amount of computational time in comparison with finite element method.

Effect of Dissolved Oxygen (DO) on Internal Corrosion of Water Pipes

  • Jung, Hae-Ryong;Kim, Un-Ji;Seo, Gyu-Tae;Lee, Hyun-Dong;Lee, Chun-Sik
    • Environmental Engineering Research
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    • v.14 no.3
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    • pp.195-199
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    • 2009
  • A series of laboratory-scale corrosion experiments was carried out to observe the effect of dissolved oxygen (DO) in the presence of other water quality parameters, such as hardness, Cl-, and pH using various pipe materials. In addition, a simulated loop system was installed at a water treatment plant for pilot-scale experiment. Laboratory-scale experiment showed that corrosion rates for galvanized steel pipe (GSP), carbon steel pipe (CSP), and ductile cast iron pipe (DCIP) were decreased to 72%, 75%, and 91% by reducing DO concentration from 9${\pm}$0.5 mg/L to 2${\pm}$0.5 mg/L. From the pilot scale experiment, it was further identified that the average ionization rate of zinc in GSP decreased from 0.00533 to 0.00078 mg/$cm^2$/d by controlling the concentration of DO. The reduction of average ionization rate for copper pipe (CP) and stainless steel pipe (SSP) were 71.4% for Cu and 63.5% for Fe, respectively. From this study, it was concluded that DO could be used as a major parameter in controlling the corrosion of water pipes.

Removal of hexavalent chromium Cr (VI) by adsorption in blended lateritic soil

  • Sunil, B.M.;Faziludeen, Saifiya
    • Advances in environmental research
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    • v.4 no.3
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    • pp.197-210
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    • 2015
  • Hexavalent chromium [Cr (VI)] adsorption on lateritic soil and lateritic soil blended with black cotton (BC) soil, marine clay and bentonite clay were studied in the laboratory using batch adsorption techniques. In the present investigation the natural laterite soil was blended with 10%, 20% and 30% BC soil, marine clay and bentonite clay separately. The interactions on test soils have been studied with respect to the linear, Freundlich and Langmuir isotherms. The linear isotherm parameter, Freundlich and Langmuir isotherm parameters were determined from the batch adsorption tests. The adsorption of Cr (VI) on natural laterite soil and blended laterite soil was determined using double beam spectrophotometer. The distribution coefficients obtained were 1.251, 1.359 and 2.622 L/kg for lateritic soil blended with 10%, 20% and 30% BC soil; 5.396, 12.973 and 48.641 L/kg for lateritic soil blended with marine clay and 5.093, 8.148 and 12.179 L/kg for lateritic soil blended with bentonite clay respectively. The experimental data fitted well to the Langmuir model as observed from the higher value of correlation coefficient. Soil pH and iron content in soil(s) has greater influence on Cr (VI) adsorption. From the study it is concluded that laterite soil can be blended with clayey soils for removing Cr (VI) by adsorption.

Interaction between Metalloporphyrins and Diazine Tautomers

  • Xu, Huiying;Wang, Wei;Zhu, Jianqing;Xu, Xiaolu;Zhang, Deyong
    • Bulletin of the Korean Chemical Society
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    • v.34 no.12
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    • pp.3727-3732
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    • 2013
  • The interaction between metalloporphyrins and diazine tautomers was investigated using quantum chemistry method. The results showed that the metal atom in the metalloporphyrin was not coplanar with porphin ring, and zinc porphyrin has the most extent of its non-coplanar nature. The most stable complex in nine complexes was iron porphyrin. NBO analysis indicated that the interaction between the lone pair of electrons on the nitrogen atom and the unoccupied lone pair orbital of metal contributes significantly to the stability of the complexes. Through the conceptual DFT parameter and Fukui dual descriptor, the thermodynamic stability and reactivity of complexes were analyzed. The density difference function (DDF) analyzes were performed to explore the rearrangement of electronic density after the coordination interaction. NICS calculation indicated that metalloporphyrin aromaticity was reduced after the coordination interaction, and aromaticity of diazine tautomer was increased along direction vector of the coordination interaction force.

SPECTROSCOPIC STUDY ON RED GIANTS IN GLOBULAR CLUSTERS (구상성단 거성들의 분광 연구)

  • LEE SANG-GAK
    • Publications of The Korean Astronomical Society
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    • v.15 no.spc1
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    • pp.15-30
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    • 2000
  • A large scatter of the chemical abundances among globular cluster red giants has been observed. Especially the chemical elements C, N, O, Na, Mg, and Al vary form star to star within globular clusters. Except for $\omega$ Cen and M22, most globular clusters could be considered to be monometallic of their iron peak elements within error ranges. The variations in light elements among globuar cluster giants appear much more pronounced than in field halo giants of comparable Fe-peak metallicity. It has been found that in general the nitrogen abundance is anticorrelated with both carbon and oxygen, while it is correlated with Na and AI. These intracluster abundance inhomogeneities can be interpreted either by mixing of nucleosythesized material from the deep stellar interior during the red giant branch phase of evolution or by inhomogeneities of primordially processed material, from which the stars were formed. The simple way of distingushing between two senarios is to obtain the element abundances of main-sequence stars in globular clusters, which are too faint for high resolution spectroscopic studies until now. Both 'evolutionary' and 'primodial' origins are accepted for explanations of abundance variations among red giants and CN-CH anticorrelations among main-sequence stars in globular clusters. This paper reviews chemical abundances of light elements among globular cluster giants, with brief reviews of cannonical stellar evolution of low mass stars after main-sequence and deep mixing for abundance variations of cluster giants, and a possible connection between deep mixing and second parameter.

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Hematological and Serum Biochemical Analyses in Experimental Caprine Besnoitiosis

  • Nazifi, Saeed;Oryan, Ahmad;Namazi, Fatemeh
    • Parasites, Hosts and Diseases
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    • v.49 no.2
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    • pp.133-138
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    • 2011
  • This study was undertaken to investigate the hematological and biochemical changes in experimentally infected goats with Besnoitia caprae from the time of infection till 360 days post-infection (PI). Six male goats were inoculated subcutaneously with $13{\times}10^7$ bradyzoites of B. caprae, and blood samples were collected from the jugular vein. The total erythrocyte and total leukocyte counts, hematocrit value, and differential leukocyte counts were determined. Serum biochemical analysis, including the total protein, albumin, total globulin, cholesterol, triglyceride, chloride, testosterone, calcium ($Ca^{2+}$), inorganic phosphorus, sodium ($Na^+$), potassium ($K^+$), iron ($Fe^{2+}$), glucose, serum amyloid A (SAA), haptoglobin (Hp), fibrinogen, ceruloplasmin, aspartate aminotransferase, alanine aminotransferase, creatine kinase, lactate dehydrogenase, and alkaline phosphatase, was undertaken. Skin biopsy from the limbs were collected at weekly intervals and histologically examined for Besnoitia cysts. Cysts were present in the skin biopsies of the leg of the infected goats from day 28 PI. There were variations in hematological analyses, but no significant difference was seen. From day 30 to 360 PI, results showed that SAA, Hp, fibrinogen, and ceruloplasmin concentrations increased, whereas testosterone concentrations decreased. Infected goats exhibited decrease of albumin and increase of serum total protein and globulin concentrations. By contrast, there were no significant differences in the remained analyses concentrations.

Simultaneous degradation of nitrogenous heterocyclic compounds by catalytic wet-peroxidation process using box-behnken design

  • Gosu, Vijayalakshmi;Arora, Shivali;Subbaramaiah, Verraboina
    • Environmental Engineering Research
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    • v.25 no.4
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    • pp.488-497
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    • 2020
  • The present study investigates the feasibility of nitrogenous heterocyclic compounds (NHCs) (Pyridine-Quinoline) degradation by catalytic wet peroxidation (CWPO) in the presence of nanoscale zerovalent iron supported on granular activated carbon (nFe0/GAC) using statistical optimization technique. Response surface methodology (RSM) in combination with Box-Behnken design (BBD) was used to optimize the process parameters of CWPO process such as initial pH, catalyst dose, hydrogen peroxide dose, initial concentration of pyridine (Py) and quinolone (Qn) were chosen as the main variables, and total organic carbon (TOC) removal and total Fe leaching were selected as the investigated response. The optimization of process parameters by desirability function showed the ~85% of TOC removal with process condition of initial solution pH 3.5, catalyst dose of 0.55 g/L, hydrogen peroxide concentration of 0.34 mmol, initial concentration of Py 200 mg/L and initial concentration of Qn 200 mg/L. Further, for TOC removal the analysis of variance results of the RSM revealed that all parameter i.e. initial pH, catalyst dose, hydrogen peroxide dose, initial concentration of Py and initial concentration of Qn were highly significant according to the p values (p < 0.05). The quadratic model was found to be the best fit for experimental data. The present study revealed that BBD was reliable and effective for the determination of the optimum conditions for CWPO of NHCs (Py-Qn).

A Study on the Current Sensor Using an Optical Modulator with BSO (BSO와 ZnSe를 광 변조기로 이용한 전류센서에 관한 연구)

  • 김요희;이대영
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.28A no.9
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    • pp.721-728
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    • 1991
  • In this paper, a magneto-optic modulator has been designed by using single crystal BSO and polycrystal ZnSe as Faraday cells. And practical core-type optical current sensors using pure iron and permalloy have been prepared and experimented. In order to obtain efficient magnetic field detection, LED(NEC OD08358, 0.87 $\mu$m) was used as optical source, PIN-PD(OD-8454)as optical receiver and multi-mode optical fiber (100/140$\mu$m) as transmission line. The characteristics matrix of the optical element was calculated by Stokes parameter, and optic modulation characteristics equations were derived by Muller matrix. Electromagnetic analysis program (FLUX 2D, micro VAX 3600) by finite element method was used to find the magnetic flux density around the core. The measuring error of the output voltage to input current has been masured below 5% in the range of 50A to 1000A. As the temperature was changed from -20$^{\circ}C$ to 60$^{\circ}C$, the maximum measurement error of the optical output has been found to be 0.5% at 60$^{\circ}C$. These experimental results show good temperature and linearity characteristics. The SNR of the overall system was 47dB in case of 600A (250.2 Oe) conductor current and the system has good noise immunity.

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Conceptual Design of a 10 HP Homopolar Motor with Superconducting Windings

  • Park, Sang-Ho;Kim, Yun-Gil;Lee, Se-Yeon;Choi, Kyeong-Dal;Hahn, Song-Yop;Lee, Ji-Kwang
    • Progress in Superconductivity and Cryogenics
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    • v.13 no.2
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    • pp.9-12
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    • 2011
  • Superconducting motor has a lot of benefits from high power density for ship propulsions, so a number of research project are in progress worldwide. Despite of all the benefits, there is always a difficulty of cryo-moving part for conventional air-core superconducting synchronous motors. In order to get rid of this moving cryogenic part, we propose a homopolar superconducting synchronous motor, which has high temperature superconducting armature and field coils. The rotor is supposed to be made of iron only and excited by the stationary HTS field coils. The stationary field coils make the cooling system simple and easy to realize because there is no cryo-moving part. A design result of a 10 hp homopolar synchronous motor is presented in this paper. The self and mutual inductance of the motor having the size of air gap as variable parameter are calculated by a 3-dimemsional finite element method. The value of design variables such as the dimension of a motor and the number of turns, etc. is decided by performing the coordinate transformation of the calculated inductance. The operating frequency is supposed to be below 5 Hz for low rotating speed which is needed for a purpose of ship propulsion. Low frequency also has the benefit of low AC losses.

The Coupling Effects of Excitatory and Inhibitory Connections Between Chaotic Neurons Having Gaussian-shaped Refractory Function With Hysteresis

  • Park, Changkyu;Lee, Ju-Jang
    • 제어로봇시스템학회:학술대회논문집
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    • 1998.10a
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    • pp.356-361
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    • 1998
  • Neural Networks, modeled succinctly from the real nervous system of a living body, can be categorized into two folds; artificial neural network(ANN) and biological neural network(BNN). While the former has been developed to solve practical problems using function approximation capability, pattern classification) clustering algorithm, etc, the latter has been focused on verifying the information processing capability to which brain research gives an impetus, by mimicking real biological systems. However, BNN suffers Iron severe nonlinearities dealt with. A bridge between two neural networks is chaotic neural network(CNN), which simply delineate the real nor-vous system and comprises almost all the ANN structures by selecting parameters. Main research theme of this area is to develop an explanation tool to clarify the information processing mechanism in biological systems and its extension to engineering applications. The CNN has a Gaussian-shaped refractory function with hysteresis effect and the chaotic responses of it have been observed fur a wide range of parameter space. Through the examination of the coupling effects of excitatory and inhibitory connections, the secrets of information processing and memory structure will appear.

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