• Korean Membrane Journal
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• v.4 no.1
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• pp.36-40
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• 2002

The diffusion coefficients of ions in the reverse transport system using the carrier mediated membrane were estimated from the diffusional membrane permeabilities and the ion activity in membrane system. In the aqueous alkali metal ions-membrane system diffusional flux of alkali metal ions driven by coupled proton was analyzed. The aqueous phase I contained NaOH solution and the aqueous phase II also contained NaCl and HCl mixed solution. The concentration of Na ions of both phases were $10^{0},\;10^{-1},\;10^{-2},\;5{\times}10^{-1}\;and\;5{\times}10^{-2}\;mol{\cdot}dm^{-3}$ and the concentration of HCI in aqueous phase II was always kept at $1{\times}10^{-1}\;mol{\cdot}dm^{-3}$. Moreover, the carrier concentration in liquid membrane was $10^{-2}\;mol{\cdot}dm^{-3}$. The results indicated that the diffusion coefficients depend strongly on the concentration of both phases electrolyte solution equilibriated with the membrane. The points were interpreted in terms of the energy barrier theory. Furthermore, eliminating the potential terms from the membrane equation was derived.

• Membrane Journal
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• v.16 no.3
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• pp.167-181
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• 2006

Continuous Electrodeionization (CEDI) is a hybrid separation process of electrodialysis and ion exchange to produce high purity water under electric field. CEDI system is generally explained with two regimes, ionic removal and electroregeneration. The performance optimization and modification of stack configuration is required for the effective utilization and various applications of a CEDI system. Understanding on various system characterization method and ion transport equation is thus necessary to utilize the CEDI system more effectively. This article provides a general review of continuous electrodeionization, including the basic principles and current stage of technologies of a CEDI system.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 1996.11a
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• pp.134-139
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• 1996

The electron energy distributions function were analysed in sulphur hexaflouride at E/N : 500~800(Td) for a case of non-equilibrium ion in the mean electron energy. This paper describes the electron transport characteristics in SF$_{6}$ gas calculated for range of E/N values from 150~800(Td) by the Monte Carlo simulation and Boltzmann equation method using a set of electron collision cross sections determined by the authors and the values of electron swarm parameters. The results gained that the value of an electron swarm parameter such as the electron drift velocity, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients agree with the experimental and theoretical for a range of E/N. The properties of electron avalanches in an electron energy non-equilibrium region.n.

• International Journal of Concrete Structures and Materials
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• v.4 no.2
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• pp.105-108
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• 2010

In order to determine the effect of the use of limestone sand on chloride ion ingress in mortar, specimens were cast with two different sands: siliceous sand (used as reference) and limestone crushed sand (used for this study). To compare and assess the resistance of this mortar to chloride penetration, two different diffusions tests were employed: slow migration and rapid migration (AASHTO test). In this study, calculation of the effective diffusion coefficient is proposed using a model based on Nernst. Planck equation. The diffusion coefficients from each sample were compared. The results for all tests show that the diffusion coefficients for siliceous sand mortar are larger than those obtained with limestone sand. It appears also that the diffusion coefficient varies as a function of the W/C ratio.

• Proceedings of the KIEE Conference
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• 1997.07e
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• pp.1834-1836
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• 1997

In this study, we simulated the developing process of two-dimensional corona discharge using the fluid method in 760 torr. It was assumed that the transport coefficients of nitrogen gas were only the function of local electric field. Discharge mechanisms considered were a Townsend first ionization and a secondary electron emission. We obtained spatio-temporal distribution of electron and ion by calculating continuity equation using FCT algorithm and calculated an electric field distribution considering a space charge.

• Environmental Engineering Research
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• v.11 no.3
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• pp.164-171
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• 2006

Numerical modeling of the flow velocity fields for the near corona wire electrohydrodynamic (EHD) flow was conducted. The steady, two-dimensional momentum equations have been computed for a wire-plate type electrostatic precipitator (ESP). The equations were solved in the conservative finite-difference form on a fine uniform rectilinear grid of sufficient resolution to accurately capture the momentum boundary layers. The numerical procedure for the differential equations was used by SIMPLEST algorithm. The Phoenics (Version 3.5.1) CFD code, coupled with Poisson's electric field, ion transport equations and the momentum equation with electric body force were used for the numerical simulation and the Chen-Kim ${\kappa}-{\varepsilon}$ turbulent model numerical results that an EHD secondary flow was clearly visible in the downstream regions of the corona wire despite the low Reynolds number for the electrode ($Re_{cw}=12.4$). Secondary flow vortices caused by the EHD increases with increasing discharge current or EHD number, hence pressure drop of ESP increases.

• Nuclear Engineering and Technology
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• v.47 no.5
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• pp.608-616
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• 2015

The migration of silver (Ag) in silicon carbide (SiC) and $^{110m}Ag$ through SiC of irradiated tristructural isotropic (TRISO) fuel has been studied for the past three to four decades. However, there is no satisfactory explanation for the transport mechanism of Ag in SiC. In this work, the diffusion coefficients of Ag measured and/or estimated in previous studies were reviewed, and then pre-exponential factors and activation energies from the previous experiments were evaluated using Arrhenius equation. The activation energy is $247.4kJ{\cdot}mol^{-1}$ from Ag paste experiments between two SiC layers produced using fluidized-bed chemical vapor deposition (FBCVD), $125.3kJ{\cdot}mol^{-1}$ from integral release experiments (annealing of irradiated TRISO fuel), $121.8kJ{\cdot}mol^{-1}$ from fractional Ag release during irradiation of TRISO fuel in high flux reactor (HFR), and $274.8kJ{\cdot}mol^{-1}$ from Ag ion implantation experiments, respectively. The activation energy from ion implantation experiments is greater than that from Ag paste, fractional release and integral release, and the activation energy from Ag paste experiments is approximately two times greater than that from integral release experiments and fractional Ag release during the irradiation of TRISO fuel in HFR. The pre-exponential factors are also very different depending on the experimental methods and estimation. From a comparison of the pre-exponential factors and activation energies, it can be analogized that the diffusion mechanism of Ag using ion implantation experiment is different from other experiments, such as a Ag paste experiment, integral release experiments, and heating experiments after irradiating TRISO fuel in HFR. However, the results of this work do not support the long held assumption that Ag release from FBCVD-SiC, used for the coating layer in TRISO fuel, is dominated by grain boundary diffusion. In order to understand in detail the transport mechanism of Ag through the coating layer, FBCVD-SiC in TRISO fuel, a microstructural change caused by neutron irradiation during operation has to be fully considered.

• Korean Journal of Metals and Materials
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• v.49 no.10
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• pp.818-822
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• 2011

ZnO nanorods were grown on Au-coated Si substrates by vapor phase transport (VPT) at the growth temperature of $600^{\circ}C$ using a mixture of zinc oxide and graphite powders as source material. Au thin films with the thickness of 5 nm were deposited by ion sputtering. Temperature-dependent photoluminescence (PL) was carried out to investigate the optical properties of the ZnO nanorods. Five peaks at 3.363, 3.327, 3.296, 3.228, and 3.143 eV, corresponding to the free exciton (FX), neutral donor bound exciton ($D^{\circ}X$), first order longitudinal optical phonon replica of free exciton (FX-1LO), FX-2LO, and FX-3LO emissions, were obtained at low-temperature (10 K). The intensity of these peaks decreased and their position was red shifted with the increase in the temperature. The FX emission peak energy of the ZnO nanorods exhibited an anomalous behavior (red-blue-red shift) with the increase in temperature. This is also known as an "S-shaped" emission shift. The thermal activation energy for the exciton with increasing temperature in the ZnO nanorods is found to be about 26.6 meV; the values of Varshni's empirical equation fitting parameters are = $5{\times}10^{-4}eV/K$, ${\beta}=350K$, and $E_g(0)=3.364eV$.

• Journal of Radiation Protection and Research
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• v.17 no.2
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• pp.49-59
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• 1992

A new model was developed in order to investigate the effects of chelating agents on the migration of a radionuclide in the form of ion or chelate. The migration behavior of the chelated radionuclide was analyzed by formulating a convective-dispersion transport equation which included a degradation of chelating agent and chelated radionuclide. The mathematical model was analytically solved and checked with the existing retardation factor. The results show that the migration velocity of the chelated radionuclide was much faster than the ionic one due to the decreased retardation. Therefore, it was concluded that a new remedial action should be developed to reduce the generation and release of chelating agents from the nuclear power plant into the environment.

• Korea-Australia Rheology Journal
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• v.17 no.4
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• pp.207-215
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• 2005

We present a finite difference solution for electrokinetic flow in rectangular microchannels encompassing Navier's fluid slip phenomena. The externally applied body force originated from between the nonlinear Poisson-Boltzmann field around the channel wall and the flow-induced electric field is employed in the equation of motion. The basic principle of net current conservation is applied in the ion transport. The effects of the slip length and the long-range repulsion upon the velocity profile are examined in conjunction with the friction factor. It is evident that the fluid slip counteracts the effect by the electric double layer and induces a larger flow rate. Particle streak imaging by fluorescent microscope and the data processing method developed ourselves are applied to straight channel designed to allow for flow visualization of dilute latex colloids underlying the condition of simple fluid. The reliability of the velocity profile determined by the flow imaging is justified by comparing with the finite difference solution. We recognized the behavior of fluid slip in velocity profiles at the hydrophobic surface of polydimethylsiloxane wall, from which the slip length was evaluated for different conditions.