• Title/Summary/Keyword: iodine number

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Studies on the Fatty Acid Composition of Amorpha-fruticosa Seeds (Amorpha-fruticosa종자(種子)의 지방산조성(脂肪酸組成)에 관한 연구(硏究))

  • Whang, Byung-Ho;Lee, Sang-Young
    • Korean Journal of Food Science and Technology
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    • v.6 no.2
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    • pp.86-90
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    • 1974
  • Quantitative analysis of the fatty acids contained in Amorpha-fruticosa seeds was carried out by means of gas chromatography with F.I.D. The general components and chemical constants have been performed with A.O.A.C methods. The results are summarized as follow: 1. General components of Amorpha-fruticosa seeds come out to be 17.65% moisture, 21.02% crude protein, 12.04% crude lipid and 5.37% ash. 2. Extraction of crude lipids were performed by soxhlet extractor for 14 hour. Amounts of the crude lipids were extracted 80.25% in ether, 80.00% in methanol, 77.34% in benzene and 69.96% in hexane. 3. Chemical constants of Amorpha-fruticosa seed oil were saponification number 178.67, acid number 3.11 and iodine number 54.27. 4. The fatty acid components of Amorpha-fruticosa seeds were quantitatively determined by gas chromatography to give 78.73wt% linoleic, 5.8wt% oleic, 5.68wt% palmitic, 4.8wt% stearic and 3.40wt% linolenic acid in ether solvent and to give 77.86wt% linoleic, 7.77wt% palmitic, 5.84wt oleic and 4.97wt% stearic acid in methanol solvent. The peak of capric acid was not found. Myristic, arachidic and lauric acids were very small.

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A Study on the Quality Characteristic of Power Bio-Fuel Oil for Alternative Fuel oil (중유 대체연료로서 발전용 바이오중유의 품질특성 연구)

  • Jang, Eun-Jung;Park, Jo-Yong;Min, Kyung-Il;Yim, Eui-Soon;Ha, Jong-Han;Lee, Bong-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.562-571
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    • 2014
  • In these days, many countries carry out many renewable energy policies to increase the renewable energy portion and to reduce the GHG(Green House Gas). In Korea, RPS(Renewable Portfolio Standards) focused on over 500MW power producers is conducting. And they are using the bio-fuel oil to meet their RPS quota. The oil is a mixture of animal and vegetable fat or fatty acid ester of them and should satisfy some specifications to use the power generation such as viscosity, pour point, acid number. Depends on the raw materials, quality characteristics of power bio-fuel oil are changed. By adding the power bio-fuel oil, pour point, density, sulfur content and viscosity are decreased and acid number, iodine number, oxygen content are increased. In this study, we test the quality characteristic of power bio-fuel oil and the property changes by the blending ratio of power bio-fuel oil & conventional fuel oil.

Epidemiology of Esophageal Cancer in Yanting - Regional Report of a National Screening Programme in China

  • Wang, Xiao;Fan, Jin-Chuan;Wang, An-Rong;Leng, Yue;Li, Jun;Bao, Yu;Wang, Ying;Yang, Qing-Feng;Ren, Yu
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.4
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    • pp.2429-2432
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    • 2013
  • Background and Objectives: Yanting in Sichuan Province is one of the highest risk areas of esophageal cancer (EC) in the world. We here summarize the epidemiology of EC in Yanting using data from the national screening programme during 2006-2011. Methods: Random cluster sampling was used to select a proportion of natural villages from six towns in Yanting, and residents aged 40-69 years old were invited for screening. Participants were screened using endoscopy with iodine staining and then confirmed by histological examinations. Results: The overall detection rates of low-grade hyperplasia (LH), moderate hyperplasia (MH), high-grade hyperplasia (HH), carcinoma in situ (CIS), intramucosal carcinoma (IC) and invasive carcinoma (INC) were 5.33%, 1.28%, 0.68%, 0.15%, 0.06% and 0.29%, respectively. The detection rates of LH, MH, HH and INC increased with age, reaching the peak among those aged 60-65 years, and the prevalences of LH and MH were higher among men than among women. In addition, the detection rates of hyperplasia were much higher in mountainous than in hilly areas. Conclusions: Among the high risk population, there are a great number of people with early-stage EC or precancerous conditions who do not have presenting symptoms. In particular, the elderly, men, or those living in mountainous areas are the most vulnerable population. It is therefore important to reinforce health education and screening services among such high risk populations.

A Study on the Manufacture of Activated Carbon using Indonesian Coal (인도네시아 석탄을 이용한 활성탄 제조에 관한 연구)

  • Baek, Ill-Hyun;Kim, Tae-Young;Yeon, Ik-June;Lee, Jeong-Sik;Lee, Dong-Kyu
    • Applied Chemistry for Engineering
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    • v.9 no.3
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    • pp.419-423
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    • 1998
  • Indonesian coal-based activated carbon was manufactured with steam-reaction method. Also effects of carbonization temperature and steam amount on the process yield and quality of the product were investigated at the activation temperature of $900^{\circ}C$. The rotary kiln type furnace was used for both carbonization and activation and the optimum operation conditions were carbonization temperature of $700^{\circ}C$, steam amount of 2.7g steam/g char and activation temperature of $900^{\circ}C$. At this condition, the iodine value of activated carbon was 1,010 mg/g. Methylene Blue Adsorption Number was 230mg/g and B.E.T. surface area was $1,020m^2/g$ with the hardness about 97.

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Lipase-Catalyzed Synthesis of Structured Lipids with Capric and Conjugated Linoleic Acid in a Stirred-Batch Type Reactor (대두유로부터 Lipase를 이용한 재구성 지질의 합성 및 특성)

  • 신정아;이기택
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.7
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    • pp.1175-1179
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    • 2004
  • Structured lipid (SL) was produced from soybean oil with molar ratio of 1:2:2 (soybean oil:capric acid:CLA) using Chirazyme L-2 lipase (4% by weight of total substrates). The reaction was conducted for 24 hr at 55$^{\circ}C$ in a 1 L stirred-batch type reactor. SL-soybean oil contained 4.9 mol% capric acid and 4.1 mol% CLA, respectively. Iodine value of SL-soybean oil was reduced than that of soybean oil due to the incorporated capric acids. Tocopherol content in SL-soybean oil was 18.2 mg/l00 g. SL-soybean oil appeared more yellowish color than soybean oil. Reverse-phase HPLC showed that SL-triacylglycerol species containing capric acid consisted of about 12.6 area%.

Synthesis and Lubricant Properties of Vegetable Oil based on Estolides (식물유 기반 에스토라이드 합성 및 윤활 특성)

  • Son, Jeong-Mae;Kim, Nam-Kyun;Shin, Jihoon;Chung, Kunwo;Yoon, Byung-Tae;Kim, Young-Wun
    • Tribology and Lubricants
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    • v.31 no.5
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    • pp.195-204
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    • 2015
  • Several researches are focused on improving the value of fine chemicals based on biomass resources due to environmental and other concerns associated with the use of petroleum-based products. Therefore, the synthesis and application of estolides derived from plant-based waste oil materials and their application as lubricants and as processing oil for butyl rubber products have been studied. Four kinds of estolide were prepared with conversions of 71~92% over 24h using various vegetable oils, as determined by size exclusion chromatography (SEC) and nuclear magnetic resonance (NMR) spectroscopy. FT-IR spectroscopy determines the esterification of estolides using 2-ethylhexyl alcohol. The estolides have iodine values of 35~90, α-ester/α-acid ratios of 0.45~0.55, and total acid number of 114~134 mg KOH g–1. Four ball wear tests show that the wear scar diameters (WSDs) of estolides as base oil significantly decreased to 0.328~0.494 mm, compared to WSDs of 0.735 and 0.810 mm of WSD for 150N and Yubase 6, respectively, as general base oil. Thus, the estolides have better wear resistance and satisfying design objectives for the engineering of a variety of lubricant base oils.

Effects of Decoction Powder of Aconite Root on Blood Picture, Uptake of 42K and 24Na, and Thyroid Activity in Experimental Animals (부자전즙분말(附子煎汁粉末)이 실험동물(實驗動物)의 혈액상(血液像), 42K 와 24Na의 섭취(攝取) 및 갑상선(甲狀腺) 기능(機能)에 미치는 영향(影響))

  • Rhee, Young So
    • Korean Journal of Veterinary Research
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    • v.11 no.2
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    • pp.105-116
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    • 1971
  • The effects of aconite root in rats and rabbits were studied following oral administration of the powder which was prepared by lyophilization of the decoction of the salted aconite roots. The $LD_{50}$ of the powder, the blood picture, total blood volume, uptake rate of ${42}^K$ and ${24}^Na$ in various organs, oxygen consumption, thyroid activity, and histopathological changes in various organs, were observed. The results obtained were as follows: 1. The $LD_{50}$ of the powder of decoction of the aconite root was 4.07g/kg of body weight in mice which is equivalent to approximately 40g/kg of the salted aconite roots. 2. The number of erythrocytes and leukocytes, hematocrit value, and the amount of hemoglobin in blood were increased in the rats administered daily dosages of 0.1, 0.5, and 1.0g/kg respectively. No significant differences were observed in the differential count of leukocytes. A slight tendency of hemoconcentration was recognized. 3. No changes in the erythrocyte volume, plasma volume and total blood volume were observed in the rats after administration of the powder for one, three, and six days. However, those were decreased in rats treated for ten days. 4. Generally, in various organs of rats the uptake rate of ${24}^Na$ showed a tendency of increasing but that of ${42}^K$ slowed a decreasing tendency. 5. The oxygen consumption was markedly decreased in rats administered the powder. 6. Iodine-131 uptake of thyroid gland was markedly decreased in the rabbits following administration of the powder. 7. In rabbits administered 0.5g/kg for 20 days, fatty changes of hepatic cells, cloudy swelling of the epithelial cells of proximal convoluted tubules of the kidney and the dilation of splenic sinuses were observed, however, milder changes were found in rabbits treated with 0.1g/kg for the same period.

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A Kinetic Study on the Phosphorus Adsorption by Physical Properties of Activated Carbon (활성탄 물성에 따른 인 흡착의 동력학적 연구)

  • Seo, Jeongbeom;Kang, Joonwon
    • Journal of Korean Society on Water Environment
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    • v.26 no.3
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    • pp.491-496
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    • 2010
  • This study aimed to obtain equilibrium concentration on adsorption removal of phosphorus by activated carbon, to express the adsorption characteristics following Freundlich isotherm and also, based on the value obtained, to investigate the relationship between physical properties of activated carbon and dynamics of phosphorus removal by obtaining rate constant and effective pore diffusivity. The results summarized from this study are as follows. Phosphorus adsorption equilibrium reaching time of powdered activated carbon was reduced as the dosage of activated carbon increases, while granular activated carbon despite increased dosage did not have influence on adsorption equilibrium reaching times of phosphorus as well, taking more than 10 hours. It was also noted that powdered activated carbon showed better adsorption ability than granular activated carbon. The value of constant (f) of Freundlich isotherm of powered activated carbon on phosphorus was 4.26 which is bigger than those of granular activated carbon. The adsorption rate constant on phosphorus of powered activated carbon with low effective diameter and iodine number was highest as $8.888hr^{-1}$ and the effective pore diffusivity ($D_e$) was lowest as $2.45{\times}10^{-5}cm^2/hr$, and the value of phosphorus adsorption rate constant of granular activated carbon was $0.174{\sim}0.372hr^{-1}$, It was revealed that, with the same amount of dosage, the adsorptive power of activated carbon with lower effective diameter was better and its rate constant was also high.

Colonial Cyanobacteria, Microcystis Cell Density Variations using Ultrasonic Treatment (초음파 처리 조건에 따른 집락형 유해남조류 Microcystis 세포수 변화 연구)

  • Lee, Hae-Jin;Park, Hae-Kyung;Heo, Jun;Lee, Hyeon-Je;Hong, Dong-Gyun
    • Journal of Korean Society on Water Environment
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    • v.34 no.2
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    • pp.210-215
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    • 2018
  • It is difficult to count colonial cyanobacteria Microcystis cells since the thickness of colonies is constrained by amorphous mucilage, making it impossible to estimate the number of cells. Disaggregation of Microcystis colonies into single cell is needed to improve the accuracy and precision of cell density estimation of naturally collected samples. Uultrasonic treatment method is commonly used owing to the simplicity and immediacy of the procedure. However, amplitude, frequency, and duration of ultrasonic treatment also cause cell loss during the experiment. Optimal ultrasonic treatment has not been standardized yet. Therefore, the objective of this study was to investigate optimal ultrasonic treatment by analyzing cell density and colony numbers. We collected colonial Microcystis from Changnyeong-Haman weir area in Nakdong River during harmful algal boom period from September to October in 2017. Ultrasonic treatment method was applied to disrupt colonies into single cells to enumerate cell density. Among treatment conditions, results from continuously treated for 100 seconds were found to be the optimum to reduce colonies to a suspension of single cell without cell losses under high and low density of Microcystis cells. Lugol iodine fixed cells followed by sonication showed less negative impact of cell damage within the optimal treatment time (100 seconds). Furthermore, disaggregated cells treated by sonication enables microscopic observation more easily since gas vacuoles were collapsed to facilitate sedimentation of cells under the counting chamber for quantitative enumeration of buoyant Microcystis cells.

Chemical Components of Seed Oil of Sapium japonicum Pax. et Hoffm. (사람주나무 종실유의 화학적 조성)

  • Choi, Myung-Suk;Yang, Jae-Kyung;Gang, Byeng-Kuk
    • Korean Journal of Medicinal Crop Science
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    • v.8 no.3
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    • pp.274-282
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    • 2000
  • Physico-chemical characteristics and chemical composition of seed oil of Sapium japonicum were determined by various analysis methods. Physio-chemical characteristics of the extracted oil from fresh seed were specific gravity (0.928), refraction index (1.477), acid value (2.30), saponification number (190.0), and iodine value (126.0). Neutral lipid (93%) in seed oil was identified as major components, followed by glycolipid (4.9%) and phospholipid (1.3%). In GC analysis, nine fatty acids were presented in the seed oil. Among fatty acids, predominant fatty acids were oleic acid (45.8%) and linoleic acid (35.6%). The contents of fatty acids of seed oil somewhat varied with their storage period. Composition of fatty acids from lipid fractions which were isolated on silica open column was investigated. Major fatty acids in three lipid fractions were linoleic acid and linolenic acid. The fatty acid contents of fresh seed oil derived from each lipid fraction were generally high comapred to storage seed oil. From the above results, seed oil of Sapium Japonicum could be useful in cosmetics, detergents and a few pharmaceuticals.

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