• 제목/요약/키워드: intrinsic evolution

검색결과 49건 처리시간 0.03초

수용액에서 합성한 ZnO 나노구조체의 형상 (Shapes of ZnO Nanostructures Grown in the Aqueous Solutions)

  • 장연익;박훈;이승용;안재평;박종구
    • 한국분말재료학회지
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    • 제12권4호
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    • pp.284-290
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    • 2005
  • ZnO nanostructures with various shapes were synthesized under ambient pressure condition by a wet chemical reaction method. Nanorods of ZnO with hexagonal cross-section and their aggregates with radiate shape were synthesized. Precursor concentration affected considerably the shape evolution of ZnO nanorods. Low precursor concentration was proved to be more preferable to the growth of ZnO nanorods, which is attributed to the intrinsic characteristics of chemical reaction in the synthesis of ZnO from zinc compounds.

스크램제트 연소기 내의 난류 연소 유동 해석 (Numerical Analysis of Turbulent Combustion Flow in Scramjet Combustors)

  • 최정열;원수희;정인석
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2005년도 제31회 KOSCO SYMPOSIUM 논문집
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    • pp.261-267
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    • 2005
  • A comprehensive DES quality numerical analysis has been carried out for reacting flows in constant-area and divergent scramjet combustor configuration with and without a cavity. Transverse injection of hydrogen is considered over a broad range of injection pressure. The corresponding equivalence ratio of the overall fuel-air mixture ranges from 0.167 to 0.50. The work features detailed resolution of the flow and flame dynamics in the combustor, which was not typically available in most of the pervious studies. Much of the flow unsteadiness is related not only the cavity, but also to the intrinsic unsteadiness in the flowfield. The interactions between the unsteady flow and flame evolution may cause a large excursion of flow oscillation. The roles of the cavity, injection pressure, and heat release in determining the flow dynamics are examined systematically.

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초음속 연소기 내의 연소 불안정 메커니즘 (Mechanism of Combustion Instability in Supersonic Combustor)

  • 최정열
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2003년도 제21회 추계학술대회 논문집
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    • pp.191-194
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    • 2003
  • A series of computational simulations have been carried out for non-reacting and reacting flows in a supersonic combustor configuration with and without a cavity. Transverse injection of hydrogen, a simplest form of fuel supply, is considered in the present study with the injection pressure of 0.5 and 1.0 ㎫. The corresponding equivalence ratios are 0.17 and 0.33. The work features detailed resolution of the flow and flame dynamics in the combustor, which was not typically available in most of the previous studies. In particular, oscillatory flow characteristics are captured at a scale sufficient to identify the underlying physical mechanisms. Much of the flow unsteadiness is related not only to the cavity, but also to the intrinsic unsteadiness in the flowfield. The interactions between the unsteady flow and flame evolution may cause a large excursion of flow oscillation. The role of the cavity, injection pressure, and amount of heat addition are examined systematically.

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Empirical Mode Decomposition (EMD) and Nonstationary Oscillation Resampling (NSOR): I. their background and model description

  • Lee, Tae-Sam;Ouarda, TahaB.M.J.;Kim, Byung-Soo
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2011년도 학술발표회
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    • pp.90-90
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    • 2011
  • Long-term nonstationary oscillations (NSOs) are commonly observed in hydrological and climatological data series such as low-frequency climate oscillation indices and precipitation dataset. In this work, we present a stochastic model that captures NSOs within a given variable. The model employs a data-adaptive decomposition method named empirical mode decomposition (EMD). Irregular oscillatory processes in a given variable can be extracted into a finite number of intrinsic mode functions with the EMD approach. A unique data-adaptive algorithm is proposed in the present paper in order to study the future evolution of the NSO components extracted from EMD.

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아연-공기전지용 페롭스카이트 산화물 촉매의 산소환원반응 특성 (Characterization of LaCoO3 Perovskite Catalyst for Oxygen Reduction Reaction in Zn-air Rechargeable Batteries)

  • 선호정;조명연;안정철;엄승욱;박경세;심중표
    • 한국수소및신에너지학회논문집
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    • 제25권4호
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    • pp.436-442
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    • 2014
  • $LaCoO_3$ powders synthesized by Pechini process were pulverized by planetary ball-milling to decrease particle size and characterized as a catalyst in alkaline solution for oxygen reduction and evolution reaction (ORR & OER). The changes of physical properties, such as particle size distribution, surface area and electric conductivity, were analyzed as a function of ball-milling time. Also, the variations of the crystal structure and surface morphology of ball-milled powders were examined by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The electrochemically catalytic activities of the intrinsic $LaCoO_3$ powders decreased with increasing ball-milling time, but their electrochemical performance as an electrode improved by the increase of the surface area of the powder.

An Analytical Framework for a Technological Innovation System: the Case of a Nuclear Power System

  • Lee, Tae Joon;Lee, Young-Joon
    • Asian Journal of Innovation and Policy
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    • 제7권2호
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    • pp.235-286
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    • 2018
  • The aim of paper is to develop an alternative framework for the study of technological innovation systems. In contrast with conventional literature, this analytical framework is designed for entrepreneurs, i.e. actors, at the micro level rather than policy-makers at the meso or macro level. Herein, the entrepreneurial innovation system is conceptually refined by synthesizing knowledge regarding technological innovation and innovation systems. Drawing upon the intrinsic technological identity essential for innovation, the entrepreneurial innovation system is shown to involve three core changes in terms of technology, organization and market, and their couplings within its internal boundary over time. This analytical framework also takes into account the fact that the innovation system is influenced by and copes with the external environment during its evolution. Moreover, the framework of the entrepreneurial innovation system considers the recent trend of sustainable development. The technical and socio-economic characteristics of a nuclear powersystem are studied empirically to articulate an analytical framework that should be very useful for technological innovation in other energy systems by reflecting their unique features.

Andreev reflection in the c-axis transport of $Bi_2$$Sr_2$Ca$Cu_2$$O_{8+x}$ single crystals near $T_c$

  • Chang, Hyun-Sik;Lee, Hu-Jong
    • Progress in Superconductivity
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    • 제3권2호
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    • pp.140-145
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    • 2002
  • An enhancement of the c-axis differential conductance around the zero-bias voltage near the superconducting transition temperature $T_{c}$ has been observed in $Au/Bi_2$$Sr_2$$CaCu_2$$O_{8+x}$ junctions. We attribute such an enhancement to the Andreev reflection (AR) between the surface Cu-O bilayer with suppressed superconductivity and the next superconducting Cu-O bilayer. The continuous evolution of the differential conductance, from gap like depression to an AR-like peak structure, around the zero-bias voltage points to weakening of the barrier strength of the nonsuperconducting layer between adjacent Cu-O bilayers as temperature approaches $T_{c}$ from below. The peak structure disappeared just below the bulk $T_{c}$ value of underdoped Bi2212 single crystals, whereas it survived up to ~1 K above $T_{c}$ in Junctions prepared on slightly overdosed crystals. According to a recently proposed theoretical consideration, a wider temperature range of the AR a bone $T_{c}$ is expected in the underdoped regime when phase-incoherent preformed pairs emerge in the pseudogap state. Our result is in contradiction to the preformed pair scenario. scenario.o.

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Dynamic Characteristics of Transverse Fuel Injection and Combustion Flow-Field inside a Scramjet Engine Combustor

  • Park, J-Y;V. Yang;F. Ma
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2004년도 제22회 춘계학술대회논문집
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    • pp.62-68
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    • 2004
  • A comprehensive numerical analysis has been carried out for both non-reacting and reacting flows in a scramjet engine combustor with and without a cavity. The theoretical formulation treats the complete conservation equations of chemically reacting flows with finite-rate chemistry of hydrogen-air. Turbulence closure is achieved by means of a k-$\omega$ two-equation model. The governing equations are discretized using a MUSCL-type TVD scheme, and temporally integrated by a second-order accurate implicit scheme. Transverse injection of hydrogen is considered over a broad range of injection pressure. The corresponding equivalence ratio of the overall fuel/air mixture ranges from 0.167 to 0.50. The work features detailed resolution of the flow and flame dynamics in the combustor, which was not typically available in most of the previous studies. In particular, the oscillatory flow characteristics are captured at a scale sufficient to identify the .underlying physical mechanisms. Much of the flow unsteadiness is related not only to the cavity, but also to the intrinsic unsteadiness in the flow-field. The interactions between the unsteady flow and flame evolution may cause a large excursion of flow oscillation. The roles of the cavity, injection pressure, and heat release in determining the flow dynamics are examined systematically.

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AZ80 마그네슘 합금 압출재의 압축 성형조건에 따른 방위특성 분석 (Texture Evolution of Extruded AZ80 Mg Alloy under Various Compressive Forming Conditions)

  • 윤종헌;이상익;이정환;박성혁;조재형
    • 소성∙가공
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    • 제21권4호
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    • pp.240-245
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    • 2012
  • With the increasing demand for light-weight materials to reduce fuel consumption, the automobile industry has extensively studied magnesium alloys which are light weight metals. The intrinsic poor formability and poor ductility at ambient temperature due to the hexagonal close-packed (HCP) crystal structure and the associated insufficient number of independent slip systems restricts the practical usage of these alloys. Hot working of magnesium alloys using a forging or extrusion enables net-shape manufacturing with enhanced formability and ductility since there are several operative non-basal slip systems in addition to basal slip plane, which increases the workability. In this research, the thermomechanical properties of AZ80 Mg alloy were obtained by compression testing at the various temperatures and strain rates. Optical microscopy and EBSD were used to study the microstructural behavior such as misorientation distribution and dynamic recrystallization. The results were correlated to the hardening and the softening of the alloy. The experimental data in conjunction with a physical explanation provide the optimal conditions for net-shape forging under hot or warm temperatures through control of the grain refinement and the working conditions.

{100} 단결정 수소화 티타네이트(H2Ti3O7)를 활용한 저함량 Irridium 수전해 양극 촉매 개발 (Low-iridium Doped Single-crystalline Hydrogenated Titanates (H2Ti3O7) with Large Exposed {100} Facets for Enhanced Oxygen Evolution Reaction under Acidic Conditions)

  • 정선영;한혁수
    • 마이크로전자및패키징학회지
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    • 제30권1호
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    • pp.79-89
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    • 2023
  • 산성 조건에서의 산소 발생 반응(OER)의 효율 향상 및 안정적인 전기 촉매 개발은 양이온 교환 막 (PEM) 수전해 장치의 상용화를 위한 바람직한 목표다. 여기서 우리는 산성 OER에 대해 Ir 함량이 낮은 유망한 촉매로서 Ir이 도핑된 수소화 티타네이트 (Ir-HTO) 나노벨트를 보고한다. 크게 확인할 수 있는 {100}면이 있는 단결정 HTO 나노벨트에 낮은 함량의 Ir(~3.36 at %)을 추가하면 산성 조건에서 OER에 대한 촉매 활성과 안정성이 크게 향상된다. Ir-HTO는 상용적인 대조군 IrO2 촉매보다 성능이 뛰어나다. 10mA cm-2의 전류밀도에서 과전압은 Ir-HTO가 25% 감소했다. Ir-HTO 촉매 성능은 산성 OER에 대한 가장 효율적인 전기 촉매로서 자리 잡고 있다. 심층적인 전기화학적 특성화를 통해 Ir-HTO에 대해 개선된 고유한 촉매 활성 및 안정성도 확인되었다. 따라서, 우리의 실험결과는 낮은 함량의 Ir이 도핑된 단결정 HTO 나노벨트가 산성조건에서 효율적이고 내구성 있는 OER 촉매로 유망 될 수 있음을 보여준다.