• Journal of Electrical Engineering and Technology
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• 제10권3호
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• pp.1102-1106
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• 2015

A hybrid supercapacitor (HS) is an energy storage device used to enhance the low weight energy density (Wh/kg) of a supercapacitor. On the other hand, a sudden decrease in capacity has been pointed out as a reliability problem after many charge/discharge cycles. The reliability problem of a HS affects the early aging process. In this study, the capacity performance of a HS was observed after charge/discharge. For detailed analysis of the initial charge/discharge cycles, the charge and discharge curve was measured at a low current density. In addition, a solid electrolyte interphase (SEI) layer was confirmed after the charge/discharge. A HC composed of a lithium titanate (LTO) anode and active carbon cathode was used. The charge/discharge efficiency of the first cycle was lower than the late cycles and the charge/discharge rate was also lower. This behavior was induced by SEI layer formation, which consumed Li ions in the LTO lattice. The formation of a SEI layer after the charge/discharge cycles was confirmed using a range of analysis techniques.

• 폴리머
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• 제25권2호
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• pp.293-301
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• 2001

새로운 복합재료 제조 기술인 electron-ion technology (EIT)를 이용하여 전도성 탄소섬유/고밀도 폴리에틸렌 (CF/HDPE) 복합필름을 제조하고 탄소섬유 에폭시 sizing이 제조된 필름의 체적비저항과 인장강도 그리고 계면 특성에 미치는 영향에 대하여 연구하였다. 에폭시 sizing은 tunneling 효과를 좋게 해서 복합재료 필름의 전도성을 향상시키는 반면, 극성인 에폭시 sizing은 무극성인 폴리에틸렌과의 친화성이 없어서 탄소섬유와 폴리에틸렌간의 계면결합력을 감소시키므로 에폭시 sized 탄소섬유(CF(S))는 unsized 탄소섬유(CF(U))에 비하여 필름의 체적비저항과 인장강도를 감소시켰다. 에폭시 sizing은 탄소섬유의 nucleating efficiency를 떨어뜨려서 CF(S)/HDPE 필름이 CF(U)/HDPE 필름보다 불규칙적이고 덜 발달된 transcrystalline layer를 형성함을 관찰할 수 있었다.

• Journal of Electrochemical Science and Technology
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• 제14권3호
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• pp.272-282
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• 2023

Ni-rich layered oxides cathode has recently gained attention as an advanced cathode material due to their applicable energy density. However, as the Ni component in the layered site is increased, the high reactivity of Ni⁴⁺ results in parasitic reaction associated with decomposing electrolyte, which leads to a rapid decreasing the lifespan of the cell. The electrolyte additive triallyl borate (TAB) improves interfacial stability, leading to a stable cathode-electrolyte interphase (CEI) layer on the LNCM83 cathode. A multi-functionalized TAB additive can produce a uniformly distributed CEI layer via electrochemical oxidation, which implies an increase in long-term cycling performance. After 100 cycles at elevated temperature, the cell tested by 0.75 TAB retained 88.3% of its retention ratio, whereas the cell performed by TAB-free electrolyte retained 64.1% of its retention. Once the TAB additive formed CEI layers on the LNCM83 cathode, it inhibited the decomposition of carbonate-based solvents species in addition to the dissolution of transition metal components from the cathode. The addition of TAB to LNCM83 cathode material is believed to be a promising way to increase the electrochemical performance.

• 한국전산구조공학회논문집
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• 제25권4호
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• pp.315-321
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• 2012

본 연구에서는 분자동역학 전산모사와 유한요소해석 기반의 균질화 기법을 통해 나노복합재의 열전도 특성을 정확하고 효율적으로 예측할 수 있는 순차적 멀티스케일 균질화 해석기법을 제안하였다. 나노입자의 크기효과가 나노복합재의 유효 열전도 특성에 미치는 영향을 조사하기 위해 크기가 다른 구형 나노입자가 첨가된 나노복합재의 열전도 계수를 분자동역학 전산모사를 통해 예측했고, 그 결과 나노입자의 크기가 작아질수록 계면에서의 Kapitza열저항에 의해 나노복합재의 열전도 계수가 점차 감소하는 것으로 나타났다. 이러한 나노입자의 크기효과를 균질화 해석모델을 통해 정확하게 묘사하기 위해 Kapitza 열저항에 의한 계면에서의 온도 불연속 구간과 고분자 기지가 높은 밀도를 가지며 흡착되는 유효계면을 추가적인 상으로 도입하여 나노복합재를 입자, Kapitza 계면, 유효계면, 기지로 구성된 4상의 연속체 구조로 모델링하였다. 이후 순차적 멀티스케일 균질화 해석기법을 통해 유효계면의 열전도 계수를 나노복합재의 열전도 계수로부터 역으로 예측했으며, 이를 입자의 반경에 대한 함수로 근사하였다. 근사 함수를 토대로 다양한 입자 체적분율과 반경에 대한 나노복합재의 유효 열전도 특성을 예측하였으며, 유효계면에 대한 매개변수 연구를 수행하였다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 하계학술대회 논문집 A
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• pp.482-485
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• 1996

In this paper, a predictive current control of 12-pulse parallel connected dual converter system without interphase reactors(IPR) is presented. Firstly, the characteristics of system without IPR are analyzed and compared with that of system with IPR. And the predictive current control of this system is discussed. Finally the validity of the presented system and the excellence of the predictive current control response is proved through the simulation results.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2003년도 춘계학술대회 논문집 전기기기 및 에너지변환시스템부문
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• pp.140-142
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• 2003

Small impedances in the superconducting Parallel circuits cause unequal distribution of the currents in the circuits. This results in Quenches or losses in some superconducting parts. This paper presents the fabrication and test results of a multi-interphase transformers (IPT) for equal current distribution in parallel circuits. Test results show that the IPT can effectively make the current distribution uniform in parallel circuits that have unequal resistances.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 추계학술발표대회 논문집
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• pp.249-251
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• 2002

It is well known that the interaction and adhesion between the glass fiber(GF) and polymer matrix has a significant effect in determining the properties of fiber-reinforced materials. Therefore, it is one of most important to modify the surface of GF with an appropriate sizing. We investigated the treatment method of GF with coupling agent to improve the interaction of the interfacial regions, and then the correlation between interfacial property and interphase microstructure was examined in an attempt to realize a proper morphology around the GF surface.

• 전기학회논문지P
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• 제57권3호
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• pp.231-235
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• 2008

Thyristor rectifiers are still the preferred choice for large magnet power supplies. However, large harmonic voltages, resulting in large current ripple, and slow dynamic response are major drawbacks of these converters. Joos presented a topology and a control technique for a hybrid large-power high-precision magnet power supply in 1996. The system consists of a phase controlled rectifier (PCR) connected in series with a high-frequency PWM converter. This paper improves the power circuit of the PWM converter using interphase transformer. Simulation result proves effect of the proposed system.

• Journal of Mechanical Science and Technology
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• 제14권12호
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• pp.1365-1375
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• 2000

Two phase flows have been numerically calculated to analyze plume characteristics and liquid circulation in gas injection through a porous plug. The Eulerian approach has been for formulation of both the continuous and dispersed phases. The turbulence in the liquid phase has been modeled using the standard $textsc{k}$-$\varepsilon$ turbulence model. The interphase friction coefficient has been calculated using correlations available in the literature. The turbulent dispersion of the phase has been modeled by the "dispersion Prand시 number". The predicted mean flows is compared well with the experimental data. The plume region area and the axial velocities are increased with the gas flow rate and with the decrease in the inlet area. The turbulent intensity also shows the same trend. Also, the space-averaged turbulent kinetic energy for various gas flow rates and inlet areas has been obtained. The results are of interest in the design and operation of a wide variety of materials and chemical processing operations.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 춘계학술대회논문집A
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• pp.85-90
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• 2000

The fracture toughness and crack propagation behaviors of short nylon66 fiber reinforced Chloroprene rubber nave been Investigated as functions of fiber aspect ratio, fiber content and interphase conditions. The J for crack initiation and rupture were determined for short-fiber reinforced rubber. The values of $J_c$ for most reinforced rubbers were low compared that of matrix. But, $J_r$ at rupture showed a higher value than that of matrix. The crack propagation behaviors were analyzed into 3 patterns with increasing fiber aspect ratio and fiber content. The tearing mechanisms of matrix and fiber reinforced rubber were observed by CCD camera focused on the tip of crack and load-displacement graph. Both cases showed a completely different behaviors