• 제목/요약/키워드: interphase

검색결과 196건 처리시간 0.024초

계면상 조건이 단섬유 강화고무의 기계적 성질에 미치는 영향 (The Influence of Interphase Condition on Mechanical Properties of Short-Fiber Reinforced Rubber)

  • 류상열;이동주
    • 대한기계학회논문집A
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    • 제24권3호
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    • pp.625-633
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    • 2000
  • The mechanical and curing properties of short nylon66 fiber reinforced Chloroprene rubber have been investigated as functions of interphase conditions and fiber content. The tensile strength exhibits a dilution effect at a low fiber content in each interphase. It is found that the interphase conditions have an important affect on the dilution ratio and critical fiber content. Double coatings of bonding agent 402 and rubber solution become the best interphase model in this study. The yield strength, tensile modulus, tear strength and fracture toughness at rupture, Jr are significantly improved due to fiber concentration.

횡방향 전단하중을 받는 단일방향 복합재료의 미시역학적 거동연구 (Micromechanical behavior of unidirectional composites under a transverse shear loading)

  • 최흥섭
    • 대한기계학회논문집A
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    • 제21권11호
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    • pp.1896-1911
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    • 1997
  • Effects of fiber-matrix interphases on the micro-and macro-mechanical behaviors of unidirectionally fiber-reinforced composites subjected to transverse shear loading at remote distance have been studied. The interphases between fibers and matrix have been modeled by the spring-layer which accounts for continuity of tractions, but allows radial and circumferential displacement jumps across the interphase that are linearly related to the normal and tangential tractions. Numerical calculations for basic cells of the composites have been carried out using the boundary element method. For an undamaged composite the micro-level stresses at the matrix side of the interphase and effective shear stiffness have been computed as functions of fiber volume ratio $V_f$ and interphase stiffness k. Results are presented for various interphase stiffnesses from the perfect bonding to the case of total debonding. For a square array composite the results show that for a high interphase stiffness k>10, an increase of $V_f$ increases the effective transverse shear modulus G over bar of the composite. For a relatively low interphase stiffness k<1, it is shwon that an increase of $V_f$ slightly decreases the effective transverse shear modulus. For the perfect bonding case, G over bar for a hexagonal array composite is slightly larger than that for a square array composite. Also for a damaged composite partially debonded at the interphase, local stress fields and effective shear modulus are calculated and a decrease in G over bar has been observed.

반응성 고분자 계면상을 도입한 PP/탄소섬유 복합재료의 제조와 물성 (Fabrication of PP/Carbon Fiber Composites by Introducing Reactive Interphase and its Properties)

  • 김민영;김지홍;김원호;최영선;황병선
    • 폴리머
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    • 제24권4호
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    • pp.556-563
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    • 2000
  • 일반적으로 열가소성 복합재료는 섬유와 기지재료간의 결합력이 약하다는 단점을 가지고 있어 개발의 한계를 가져왔으나 점차적으로 수지의 개발, 공정의 개선, 계면상의 도입으로 지속적인 물성 향상을 이루고 있다. 특히 계면상의 도입은 외부에서 받은 충격을 잘 흡수할 뿐만 아니라 기지재료와 섬유와의 결합력을 높여 준다. 본 연구에서는 탄소섬유의 전기전도성을 이용하여 전착(electrodeposition)에 의해 탄소섬유와 수지 사이에 계면상을 도입하였으며 계면상 물질과 폴리프로필렌 수지와의 약한 결합력을 개선하기 위해 modified polypropylene을 수지에 첨가하였다. 대표적인 열가소성 수지인 폴리프로필렌을 기지재료로 사용하여 복합재료를 제조하여 층간전단강도, 충격강도 등의 기계적 물성을 평가한 결과, 전착을 통한 계면상을 도입하였을 경우가 물성이 우수함을 확인할 수 있었다. 전착 공정에서는 anhydride 또는 free acid group을 가진 반응성 고분자를 사용하여 수용액상에서 전하 운반체 역할을 수행할 수 있게 하였고 고분자의 종류를 달리하여 계면상 물질의 변화에 따른 복합재료의 물성 차이를 평가하였다. 또한 함침 용액의 농도, 전류밀도 및 전착시간을 변화시키면서 탄소섬유에의 전착수율을 평가하였다.

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단섬유 끝 형상이 강화고무의 인장 특성에 미치는 영향 (Effects of Short-fiber End Shape on Tensile Properties of Reinforced Rubber)

  • 류상렬;이동주
    • 대한기계학회논문집A
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    • 제25권6호
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    • pp.1023-1030
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    • 2001
  • The tensile properties of short nylon6 fiber reinforced NR and SBR have been investigated as functions of diameter ratio(DR), interphase condition, fiber aspect ratio(AR), and fiber content. The short-fiber(DR=3 and AR=2) reinforced SBR did not show the dilution effect for all interphase conditions. And the short-fiber(DR=3 and AR=2) reinforced NR did not show the dilution effect except for the no-coating. The better interphase condition, the lower dilution effect at same DR. The tensile moduli are significantly improved due to fiber content and diameter ratio at same interphase condition. The pull-out force increased with the DR. The better interphase condition, the higher pull-out force at same DR. It is found that the DR and AR have an important effect on tensile properties.

Effect of Interphase Modulus and Nanofiller Agglomeration on the Tensile Modulus of Graphite Nanoplatelets and Carbon Nanotube Reinforced Polypropylene Nanocomposites

  • Karevan, Mehdi;Pucha, Raghuram V.;Bhuiyan, Md.A.;Kalaitzidou, Kyriaki
    • Carbon letters
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    • 제11권4호
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    • pp.325-331
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    • 2010
  • This study investigates the effect of filler content (wt%), presence of interphase and agglomerates on the effective Young's modulus of polypropylene (PP) based nanocomposites reinforced with exfoliated graphite nanoplatelets ($xGnP^{TM}$) and carbon nanotubes (CNTs). The Young's modulus of the composites is determined using tensile testing based on ASTM D638. The reinforcement/polymer interphase is characterized in terms of width and mechanical properties using atomic force microscopy which is also used to investigate the presence and size of agglomerates. It is found that the interphase has an average width of ~30 nm and modulus in the range of 5 to 12 GPa. The Halpin-Tsai micromechanical model is modified to account for the effect of interphase and filler agglomerates and the model predictions for the effective modulus of the composites are compared to the experimental data. The presented results highlight the need of considering various experimentally observed filler characteristics such as agglomerate size and aspect ratio and presence and properties of interphase in the micromechanical models in order to develop better design tools to fabricate multifunctional polymer nanocomposites with engineered properties.

습식법으로 제조된 BN 중간층을 가진 Cf/SiC 복합재의 제조 및 물성 평가 (Fabrication and Characterization of Cf/SiC Composite with BN Interphase Coated by Wet Chemical Process)

  • 구준모;김경호;한윤수
    • 한국표면공학회지
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    • 제50권6호
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    • pp.523-530
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    • 2017
  • In this study, we developed the h-BN interphase for ceramic matrix composites (CMCs) through a wet chemical coating method, which has excellent price competitiveness and is a simple process as a departure from the existing high cost chemical vapor deposition method. The optimum condition for nitriding an h-BN interphase using boric acid and urea as precursors were derived, and the h-BN interphase coating through a wet method on a carbon preform of 2.5 D was conducted to apply the optimum conditions to the CMCs. In order to control the coating property via the wet coating method, four parameters were investigated such as dipping time of the specimen in the precursor solution, the ratio of boric acid and urea in the precursor, the concentration of solution where the precursor was dissolved, and the cycle of dipping and dry process. The CMCs was fabricated through polymer impregnation and pyrolysis (PIP) processes and a three-point flexural strength test was conducted to verify the role of the coated h-BN interphase.

단섬유 강화고무의 파열특성 연구 (A Study on Bursting Properties of Short-Fiber Reinforced Chloroprene Rubber)

  • 류상렬;이동주
    • 대한기계학회논문집A
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    • 제30권5호
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    • pp.543-549
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    • 2006
  • The bursting properties under various conditions were investigated to ascertain the optimum conditions to yield the best properties. Fiber aspect ratio (AR: length of fiber/diameter of fiber), interphase condition and fiber content were considered as variables which impact the bursting pressure, bulge constant, torsional rigidity ratio. The bursting pressure of reinforced rubber increases up to 8.73 times compared to the virgin material. The better interphase condition shows the higher bursting pressure at given AR and fiber content. The bulge constant and torsional rigidity highly decrease with increasing AR and better interphase condition at same fiber content. The bulge constant and torsional rigidity reveal the minimum of 11% and 0.6% of the matrix, respectively. The bursted shape after test shows the different patterns between unfilled and reinforced rubbers. The case of virgin rubber shows a radiating shape while that of reinforced rubber shows a fluctuating straight line. Overall, it was found that the fiber AR and interphase condition have an important effect on bursting properties.

상간리액터 없는 병렬연결 듀얼컨버터 시스템의 동작해석과 새로운 전류제어 (Operation Analysis and New Current Control of Parallel Connected Dual Converter System without Interphase Reactors)

  • 지준근
    • 대한전기학회논문지:전기기기및에너지변환시스템부문B
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    • 제49권7호
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    • pp.488-493
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    • 2000
  • In this paper, a predictive current control of 12-pulse parallel connected dual converter system without interphase reactors(IPR) is presented. Firstly, the characteristics of system without IPR are analyzed and compared with that of system with IPR. And the predictive current control of this system is discussed. Finally the validity of the presented system and the excellence of the predictive current control response is proved through the simulation results and experimental results.

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능동 다중인터페이스 리액터와 Double PLL제어를 이용한 Modular UPS 설계 (A Modular UPS Design with an Active Multiple Interphase Reactor and Double PLL Control)

  • 박인덕;정상식;안형회;김시경
    • 전력전자학회논문지
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    • 제6권6호
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    • pp.489-497
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    • 2001
  • 병렬로 구성되 UPS 사이에 파라미터 불일치에 따른 순환전류와 전압리플이 발생되어지는데, 이들은 전체 UPS 시스템의 고장 및 신뢰성 저하를 유발한다. 본 논문에서는 이러한 문제점들은 Double 위상동동기기와 능동 다중인 터페이스 리액터를 사용하여 해결하였다. 또한 ADSP21061을 사용하여 제어기를 디지털적으로 구현하였다.

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계면상 조건과 단섬유 함유량이 단섬유 강화CR의 동적특성에 미치는 영향 (Effect of Interphase Condition and Fiber Content on the Dynamic Properties of Short-fiber Reinforced Chloroprene Rubber)

  • 류상렬;이동주
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.1151-1156
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    • 2003
  • The dynamic properties of short-fiber reinforced Chloroprene rubber for vibration isolators have been studied as functions of interphase conditions and fiber content. The loss factor showed the maximum at strain amplitude 2%, and increased 0.09 for matrix, 0.05 for reinforced rubber with increasing frequency respectively. The dynamic ratio rapidly decreased with increasing strain amplitude, and some increased with increasing frequency. The better interphase condition showed the lower dynamic ratio. Therefore, the short-fiber reinforced rubber could have the better isolation in frequency ratio(${\sqrt{2}}min$.) compared to frequency ratio(${\sqrt{2}}max$.). And we have investigate the possibility of applying short-fiber reinforced rubber to automotive engine mount.

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