• 제목/요약/키워드: internal bond

검색결과 190건 처리시간 0.025초

NMR Relaxation Study of Segmental Motions in Polymer-n-Alkanes

  • Chung Jeong Yong;Lee Jo Woong;Park Hyungsuk;Chang Taihyun
    • Bulletin of the Korean Chemical Society
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    • 제13권3호
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    • pp.296-306
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    • 1992
  • $^{13}C$ spin-lattice relaxation times were measured for n-alkanes of moderate chain length, ranging from n-octane to n-dodecane, under the condition of proton broad-band decoupling within the temperature range of 248-318 K in order to gain some insight into basic features of segmental motions occurring in long chain ploymeric molecules. The NOE data showed that except for methyl carbon-13 dipole-dipole interactions between $^{13}C$ and directly bonded $^1H$ provide the major relaxation pathway, and we have analyzed the observed $T_1data$ on the basis of the internal rotational diffusion theory by Wallach and the conformational jump theory by London and Avitabile. The results show that the internal rotational diffusion constants about C-C bonds in the alkane backbone are all within the range of $10^9\;-10^10\;sec^{-1}$ in magnitude while the mean lifetimes for rotational isomers are all of the order of $10^{-11}\;-10^{-10}$ sec. Analysis by the L-A theory predicts that activation energies for conformational interconversion between gauche and trans form gradually increase as we move from the chain end toward the central C-C bond and they are within the range of 2-4 kcal/mol for all the compounds investigated.

가상 인플루언서에 대한 소비자의 유사성 지각이 정서적 유대감을 통해 구매의도에 미치는 영향 (The Effect of Consumers' Perception of Similarity Toward Virtual Influencer on Purchase Intention Through Emotional Bond)

  • 이지현;김한구
    • 한국정보시스템학회지:정보시스템연구
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    • 제31권2호
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    • pp.89-110
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    • 2022
  • Purpose To verify the factors that encourage consumers' favorable reaction toward virtual influencer, we proposed consumers' perception of subjective and objective similarity. The purpose of this study is to comprehensively investigate the impacts of consumers' perception toward virtual influencer on purchase intention through psychological distance and parasocial relationship. Design/methodology/approach This study was designed to examine the structural relationships among consumers' perceived external similarity, internal similarity, controllability, animacy toward virtual influencer, psychological distance, parasocial relationship and purchase intention. Findings The results are as follows. First, perceived external similarity, internal similarity, perceived controllability, and animacy had a positive impact on psychological distance. Second, psychological distance had a positive impact on parasocial relationship, whereas it had no significant impact on purchase intention. However, we found that the relation between psychological distance and purchase intention was mediated by parasocial relationship. Lastly, parasocial relationship had a positive impact on purchase intention. Based on these results, this study can propose the way to generate revenue to companies that consider advertising campaign using virtual influencer.

HIP처리가 플라즈마 용사된 열차폐 코팅층의 접착강도와 고온특성에 미치는 영향 (Effects of Hot Isostatic Pressing on Bond Strength and Elevated Temperature Characteristics of Plasma sprayed TBC)

  • 박영규;김성휘;김두수;이영찬;최철;정진성;김길무;김재철
    • 한국재료학회지
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    • 제10권4호
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    • pp.312-316
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    • 2000
  • HIP처리가 가스터빈 고정익 등 고온부품에 적용되는 열차폐 코팅층의 접착강도 및 고온특성에 미치는 영향을 조사하였다. 시편은 IN738LC 초합금 표면에 8wt%Y$_2$O$_3$-$ZrO_2$분말을 플라즈마 용사법으로 코팅한 후 $1200^{\circ}C$, 100MPa의 고온, 고압에서 4시간 동안 HIP 처리하여 준비하였다. 실험결과 HIP 처리된 코팅의 경우 미세균열과 기공이 상당량 감소하였으며 EDX분석을 통해 계면에서 원자간 상호확산이 발생한 것을 확인하였다. 이러한 코팅층의 치밀화 및 상호확산으로 인해 HIP처리된 코팅층의 접착강도는 48% 이상 크게 증가하였으며 조직 또한 균질화 되었다. 반면 가열과 냉각이 반복되는 환경에서 코팅층의 내구력은 HIP 처리된 경우가 다소 저하되었다. 이는 코팅과 모재와의 열팽창 차이로 인한 변형을 완화시켜주는 기공과 미세균열이 감소되었기 때문으로 판단된다.

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Using Mean Residual Life Functions for Unique Insights into Strengths of Materials Data

  • Guess Frank M.;Zhang Xin;Young Timothy M.;Leon Ramon V.
    • International Journal of Reliability and Applications
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    • 제6권2호
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    • pp.79-85
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    • 2005
  • We show how comparative mean residual life functions (MRL) can be used to give unique insights into strengths of materials data. Recall that Weibull's original reliability function was developed studying and fitting strengths for various materials. This creative comparing of MRL functions approach can be used for regular life data or any time to response data. We apply graphical MRL's to real data from tests of tensile strength of high quality engineered wood.

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Ba-Ferrite계 자기연마재 거동이 연마특성에 미치는 영향 (The Effects of Ba-Ferrite Magnetic Abrasive Behavior on Polishing Characteristics)

  • 윤여권;김희남
    • 대한안전경영과학회지
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    • 제11권4호
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    • pp.311-317
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    • 2009
  • In this paper deals with behavior of the magnetic abrasive using Ba-Ferrite on polishing characteristics in a new internal finishing of STS304 pipe applying magnetic abrasive polishing. The magnetic abrasive using Ba-Ferrite grain WA used to resin bond fabricated low temperature. And Ba-Ferrite of magnetic abrasive powder fabricated that Ba-Ferrite was crused into 200 mesh. The previous research have made an experiment in the static state the movement of magnetic abrasive grain is nevertheless in the dynamic state. In this paper, We could have investigated into the changes of the movement of magnetic abrasive grain. In reference to this result, we could have made the experiment which is set under the condition of the magnetic flux density, polishing velocity according to the form of magnetic brush.

Characteristics of Particleboard Fabricated from Waste Wood Particles with Gingko Tree Leaves

  • Park, Sang-Bum;Lee, Sang-Min;Park, Jong-Young
    • 한국가구학회지
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    • 제18권2호
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    • pp.106-110
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    • 2007
  • This study was performed to find potentialities of the leaves of gingko tree (Gingko biloba L.) as a raw material for particleboard (PB) manufacturing. Various amounts of the leaves were mixed with wasted wood particles to manufacture PB. Physical and mechanical properties, such as density, internal bond (IB) strength, and modulus of rupture (MOR) of manufactured PB were not much different from those of the control board. Formaldehyde emission values decreased with increasing the amount of leaves. Especially, the formaldehyde emission of PB made with 5 percent of leaves was decreased to 1.31 mg/l, which is about 36% lower emission than that of the control. From these results, the leaves of gingko tree may be considered as an additive of lowering formaldehyde emission in a functional PB manufacturing process.

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압력보상형 유압펌프 신뢰성 시험평가 기술 (Reliability Test Assessment Technique for Pressure Compensation Type Hydraulic Pump)

  • 정동수
    • 한국신뢰성학회지:신뢰성응용연구
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    • 제11권4호
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    • pp.371-385
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    • 2011
  • Because consumer mostly utilizes company test standard, supplier spends burden of expenses on building test equipments and managing expert manpower to fulfill consumer's various tests. Therefore, it is urgent to standardize test assessment which has a bond of sympathy between consumer and supplier and evaluates reliability of their products. This study develops reliability assessment standard which is composed of 12 test items considering international and domestic test standards, company internal test standards of consumer companies and field conditions. Also this study introduces overall technical procedure on accelerated test with no failure which is used for the main technology of reliability assessment. To verify effectiveness of reliability assessment, the test results are herein analyzed through building the test equipments and performing the test items.

Ba-Ferrite 자기연마재의 거동이 연마특성에 미치는 영향 (The Effects of Ba-Ferrite Magnetic Abrasive Behavior on Polishing Characteristics)

  • 김희남;송승기;윤여권;김희원;김복수;안효종;심재환
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2003년도 춘계학술대회 논문집
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    • pp.565-568
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    • 2003
  • In this paper we deal with behavior of the magnetic abrasive using Ba-Ferrite on polishing characteristics in a new internal finishing of STS304 pipe applying magnetic abrasive polishing. The magnetic abrasive using Ba-Ferrite grain WA was used to resin bond fabricated at low temperature. And Ba-Ferrite of magnetic abrasive powder was crused into 200 mesh. The previous research made an experiment in the static and the dynamic state on the movement of magnetic abrasive grain. In this paper. We investigated into the changes of the movement of magnetic abrasive grain. In reference to this result. we have made the experiment which is set under the condition of the magnetic flux density. polishing velocity according to the form of magnetic brush.

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Eccentric compressive behavior of novel composite walls with T-section

  • Qin, Ying;Chen, Xin;Xi, Wang;Zhu, Xingyu;Chen, Yuanze
    • Steel and Composite Structures
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    • 제35권4호
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    • pp.495-508
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    • 2020
  • Double skin composite walls are alternatives to concrete walls to resist gravity load in structures. The composite action between steel faceplates and concrete core largely depends on the internal mechanical connectors. This paper investigates the structural behavior of novel composite wall system with T section and under combined compressive force and bending moment. The truss connectors are used to bond the steel faceplates to concrete core. Four short specimens were designed and tested under eccentric compression. The influences of the thickness of steel faceplates, the truss spacing, and the thickness of web wall were discussed based on the test results. The N-M interaction curves by AISC 360, Eurocode 4, and CECS 159 were compared with the test data. It was found that AISC 360 provided the most reasonable predictions.

Mechanical and Physical Properties of Zinc Borate-Modified Oriented Strandboard (OSB)

  • Lee, Sun-Young;WU, Qinglin
    • Journal of the Korean Wood Science and Technology
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    • 제36권5호
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    • pp.11-23
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    • 2008
  • The mechanical and physical properties of zinc borate (ZB)-modified oriented strandboard (OSB) from southern wood species were investigated in this study. OSB panels treated with ZB were not significantly weaker than the untreated samples in terms of specific modulus of elasticity (SMOE) and specific modulus of rupture (SMOR). ZB showed the negative effect on specific internal bond (SIB) strength, since some of ZB would persist as a powder state on the flake surfaces, thereby reducing the bonding efficiency of the adhesive. The ZB level did not show significant effect on thickness swelling (TS). ZB-modified OSB showed the suitable mechanical and physical properties for the structural wood composites.